TH32423B - Solid titanium catalyst components Process for preparing such things Catalyst used to polymerization olefins With such thing And the process of polymerization olefin - Google Patents

Abstract

This invention Resulting in solid titanium catalyst components Which contains magnesium, titanium, halogen and electron carriers. Without removing titanium when washing with hexane at room temperature And a reduced proportion of titanium content At least 15% by weight when washed with 90 ํ ortho-dichlorobenzene. The catalyst component was prepared by a process where hard titanium (i) was without the removal of titanium when it was washed. Hexane at room temperature Contact with polar compounds containing 0.50 to 4.00 dipol momentum (Debye) to reduce titanium content. By at least 25% by weight, provided that the solid titanium catalyst components can be prepared With at least 7 catalyst's body weight ratio to make the polymerization sun Containing catalyst This hard titanium It can be used to make (co) polymersunolifins with high activity to obtain high stereecoolary polyolefins. By reducing the amount of polyolefins With lower stereo records

Claims (7)

1.Hard titanium catalyst components It contains magnesium, titanium, halogen and electron emitters and has the following properties: (1) Titanium content is less than 2.5% by weight (2) Total content of magnesium and halogen at 65%. At least but less than 92% by weight (3) Electron content ranges from 8 to 30% by weight (4) Proportional by body weight of electrons to titanium ranges from 6 to 30%. 40 and (5) such solid titanium catalyst components have a volume ratio. Titanium was reduced by less than 15% by weight when washed at 90 ° C for 1 hour with 100 ml of i-dichlorobenzene per component of catalyst tetrium. It is about 0.5 g of solid titanium and does not lose its catalyst. Titanium was washed at 25 ° C for 5 minutes with 500 ml of hexane per 1 gram of the aforementioned kata liter of titanium. 2.Olifin polymerization polymerization catalyst containing (a) hard titanium catalyst as per claim 1 (b) organometallic compound; and (C) organic organovilane compounds containing at least one alkoxy group 3.Olifin polymerization process consisting of polymerization or Copolymerization oliphene with catalyst for polymers of olefins according to claim 2. 4.Pre-polymerization catalyst containing pre-polymer or pre-copolymer Of olfin combined with (A) solid titanium catalyst components according to claim 1 and (b) organometallic compounds; and (c) organic organosylane compounds with alkoxi concentrations. At least one group 5. Olefin polymerization process consisting of polymerization or Copolymerization oliphene with catalyst for olefin polymers containing Pre-polymeride catalyst according to claim 4 and may contain (b) organometallic compounds and / or (c) organic organosylane compounds with At least one block of lock is optional. 6. Preparation process for solid titanium catalyst components containing Solid non-titanium components (i) obtained by conducting (a) magnesium compounds in liquid state, (b) liquid titanium compounds and (c) electrons in contact and in contact with aromatic compounds. Polar halogenated hydrocarbons (ii) with a bipolar moment of 0.50 to 4.00 debye at 60 to 160 ° C to reduce the titanium content in components containing hard titanium (i) by at least 25%. By weight to prepare solid titanium catalyst (a) components with weight ratio The electron-to-titanium emitters range from 6 to 40, where the solid titanium catalyst (a) consists of magnesium, titanium, halogen and electron emitters. The properties are as follows: (1) Titanium content is not more than 2.5% by weight (2) Magnesium and halogen content is at least 65% by weight but less than 92% by weight (3) quantity. Set the electrons in the range of 8 to 30% by weight (4) the weight ratio of the electrons to the titania ranges from 6 to 40 and (5) the solid titanium catalyst components. With volume ratio Titanium was reduced by less than 15% by weight when washed at 90 ° C for 1 hour with 100 ml of O-Dichlorobenzene per kata component. 0.5 g of such solid titanium and components of a titanium catalyst. It did not lose titanium at all when it was washed at 25 ° C for 5 minutes with 500 ml of hexane per solid titanium chili. Such quantity 1 gram 7. Procedures for the preparation of hard titanium catalyst components (a) in accordance with claim 6, where such components without hard titanium (i) are solids obtained by Processes consisting of conductivity (a) magnesium compound in liquid state, (b) titanium compound in liquid state, and (c) electron exposure. One solid, and then the first solid in contact with (b) the titanium compound in the liquid state.