TH2017A - Benzoyl urea - Google Patents

Abstract

1-Phenyl (chemical formula) X represents oxygen or sulfur. R1 represents hydrogen, halogen, nitro, alkyl, or alkylthioide. R², R⁴, and R⁵ represent identical or different radicals and represent hydrogen or halogens. R³ represents hydrogen, halogen, or nitro. R⁶ and R⁷ represent identical or different radicals and represent hydrogen, halogen, or alkyls. R⁸ and R⁹ represent identical or different radicals and represent hydrogen or halogens. R⁻¹⁰ represents halogen alkyls and halogenanoacoxy, with some exceptions, which are substances with insecticide and miticide properties.

Claims (10)

1. 1-Phenyl is the chemical formula. X represents oxygen or sulfur. R1 represents hydrogen, halogen, nitro, alkyl, or alkylthioide. R², R³, and R³ are identical or different radicals and represent hydrogen or halogens. R³ represents hydrogen, halogen, or nitro. R² and R³ are identical or different radicals and represent hydrogen, halogen, or alkyls. R³ and R³ are identical or different radicals and represent hydrogen or halogens. R³³ and R¹³ represent halogens, alkyls, and halogenanoacoxy. If X represents oxygen, R², R³ ... (1) If X represents oxygen or sulfur, and R⁶ represents chlorine, and R⁸ represents hydrogen or chlorine, and R⁹ represents hydrogen, and R⁻¹⁰ represents hydrogen or halogen, and a) both R⁻¹ and R⁵ represent halogens, or b) R⁻¹ represents halogens, or alkyl radicals, and in these cases the radical R⁻¹⁰ always represents halogenanoalkylthio, and (2) if X represents oxygen or sulfur, and R⁶ represents chlorine, and R⁸ represents hydrogen or chlorine, and R⁹ represents hydrogen, and R⁻¹⁰ represents halogenanoalkylthio or halogenanoacoxy, and a) R⁻¹ and R⁻³ represent halogens, and R⁻², R⁴ and R⁵ represent hydrogen, or b) R⁵ and R⁻³ represent halogens, and R⁻¹, R⁻² and R⁴ represent hydrogen, or c) R⁻¹ and R⁴ represent halogens, and R⁻², R³ and R³ are used to represent hydrogen, or d) R² and R⁵ are used to represent halogens, and R¹, R³, and R⁴ are used to represent hydrogen. In these cases, the radical R⁷ is always used to represent hydrogen or alkyls. 2. Formula (I) as defined in Relief 1, where X represents sulfur or oxygen, R1 represents hydrogen, halogen, nitro or a radical of choice from a series of C1-C6-alkyl and C1-C6 alkylthio, R2, R4 and R5 are identical or different radicals and represent hydrogen or halogen, R3 represents hydrogen, halogen or nitro, R6 and R7 are identical or different radicals and represent hydrogen, halogen or C1-C6 alkyl radicals, R8 and R9 are identical or different radicals and represent hydrogen or halogen, and R10 represents a halogenanoalkylthio or a halogenanoalkoxy with 1 to 4 carbon atoms (which is proposed to be chlorodifluoromethylthio, trifluoromethylthio, chlorodifluoromethoxy). or trifluoromethoxy) and (1) if X is used to replace oxygen and R2,R3,R4,R6,R8 and R9 are used to replace hydrogen and R7 is used to replace hydrogen or halogen and a) both R1 and R5 are used to replace halogen or b) are used to replace halogen, nitro or C1-C6-alkyl and R5 is used to replace hydrogen. In these cases, the R10 radical always replaces C1-C4 halokylthio, and (2) if X replaces oxygen or sulfur and R6 replaces chlorine and R8 replaces hydrogen or chlorine and R9 replaces hydrogen and R10 replaces C1-C4-halogenoalkylthio or C1-C4-halogenoalkoxy and a) R1 and R3 replace halogen and R2,R4 and R5 replace hydrogen or b) R5 and R3 replace halogen and R1,R2 and R4 replace hydrogen or c) R1 and R4 replace halogen and R2,R3 and R5 replace hydrogen or d) R2 and R5 replace halogen and R1,R3 and R4 replace hydrogen, in these cases the R7 radical always replaces hydrogen or C1-C6-alkylthio. 3. Formula (I) as defined in Recourse 1, where X represents oxygen or sulfur, R1 represents hydrogen, fluorine, chlorine, bromine, nitro, methyl, ethyl, normalpropyl, isopropyl, normalbutyl, isobutyl, secondarybutyl, tertiarybutyl, methylthio, ethylthio, normalpropylthio, isopropylthio, normalbutylthio, isobutylthio, secondarybutylthio, or tertiarybutylthio, R2, R4, and R5 are identical or different radicals. R2 is a homogeneous or heterogeneous radical and can be used to replace hydrogen, fluorine, chlorine, or bromine. R3 is used to replace hydrogen, fluorine, chlorine, bromine, or nitro. R6 and R7 are homogeneous or heterogeneous radicals and can be used to replace hydrogen, fluorine, chlorine, bromine, methyl, ethyl, normalprobable, isobrobable, normalbutyl, isobutyl, secondarybutyl, or tertiarybutyl. R8 and R9 are homogeneous or heterogeneous radicals and can be used to replace hydrogen, fluorine, chlorine, or bromine. R10 is used to replace trifluoromethylthio. or trifluoromethoxy and (1) if X represents oxygen and R2, R3, R4, R6, R8 and R9 represent hydrogen and R7 represent hydrogen, fluorine, chlorine or bromine and a) both R1 and R5 represent fluorine, chlorine and/or bromine or (b) R1 represents fluorine, chlorine, bromine, nitro or the aforementioned alkyl radicals and R5 represents hydrogen. In these cases, the R10 radical always represents trifluoromethylthio and (2) if X represents oxygen or sulfur and R6 represents chlorine and R8 represents hydrogen or chlorine and R9 represents hydrogen and R10 represents trifluoromethylthio or trifluoromethoxy and (a) R1 and R3 represent fluorine, chlorine or bromine and R2, R4 and R5 represent hydrogen or (b) R5 and R3 represent fluorine, chlorine, or bromine. Or bromine and R1, R2 and R4 are used to replace hydrogen, or (C) R1 and R4 are used to replace fluorine, chlorine or bromine and R2, R3 and R5 are used to replace hydrogen, or (d) R2 and R5 are used to replace fluorine, chlorine or bromine and R1, R3 and R4 are used to replace hydrogen. In these cases, the R7 radical is always used to replace hydrogen or the broad alkyl radicals mentioned above. 4. Any substance as defined in any of the claims 1 through 3 in which X of formula (I) as defined in any of the claims 1 through 3 in which X of formula (I) as defined in claim 1 is used to replace oxygen. 5. Formula (I) as defined in Recourse I, where X represents oxygen, R1 represents hydrogen, fluorine, chlorine, bromine, nitromethyl or methylthio; R2, R4 and R5 represent hydrogen, fluorine, chlorine or bromine; R3 represents hydrogen, fluorine, chlorine or nitromethyl; R6 and R7 are identical or different radicals and represent hydrogen, chlorine or methyl; R8 and R9 are identical or different radicals and represent hydrogen, fluorine or chlorine; and R10 represents trifluoromethylthio. or trifluoromethoxy and (1) if R2, R3, R4, R6, R8 and R9 replace hydrogen and R7 replace hydrogen or chlorine and (a) both R1 and R5 replace fluorine, chlorine and/or bromine or (b) R1 replaces fluorine, chlorine, bromine, nitro or methyl and R5 replaces hydrogen, in these cases the radical R10 replaces trifluoromethylthio and (2) if R6 replaces chlorine and R8 replaces hydrogen or chlorine and R9 replaces hydrogen and R10 replaces trifluoromethylthio or trifluoromethoxy and (a) R1 and R3 replace fluorine, chlorine and/or bromine and R2, R4 and R5 replace hydrogen, or (b) R5 and R3 replace fluorine, chlorine and/or bromine and R1, R2 and R4 replace hydrogen, or (c) R1 and R4 replace fluorine, chlorine and/or bromine and R2, R3 and R5 replace hydrogen or bromine and R1, R3 and R4 replace hydrogen. In these cases, the R7 radical always replaces hydrogen or methyl. 6. The process for preparing 1-phenyl-3-benzoyl (thio) urea, formula (I) (chemical formula), where X represents oxygen or sulfur, R1 represents hydrogen, halogen, nitro, alkyl, or alkyl thio; R2, R4, and R5 are identical or different radicals and represent hydrogen or halogen; R3 represents hydrogen, halogen, or nitro; R6 and R7 are identical or different radicals and represent hydrogen, halogen, or alkyl; R8 and R9 are identical or different radicals and represent hydrogen or halogen; and R10 represents halogenoalkyl thio. or halogenomethoxy and (1) if X replaces oxygen and R2,R3,R4,R6,R8 and R9 replace hydrogen and R7 replace hydrogen or halogen and (a) both R1 and R5 replace halogen or (b) R1 replaces halogen, nitro or alkyl and R5 replaces hydrogen, in these cases the radical R10 replaces halogenoalkylthio and (2) if X replaces oxygen or sulfur and R6 replaces chlorine and R8 replaces hydrogen or chlorine and R9 replaces hydrogen and R10 replaces halogenoalkylthio. or halogeno alkoxy and (a) R1 and R3 are used to replace halogens and R2, R4 and R5 are used to replace hydrogen, or (b) R5 and R3 are used to replace halogens and R1, R2 and R4 are used to replace hydrogen, or (c) R1 and R4 are used to replace halogens and R2, R3 and R5 are used to replace hydrogen, or (d) R2 and R5 are used to replace halogens and R1, R3 and R4 are used to replace hydrogen. In these cases, the R7 radical is always used to replace hydrogen or alkyl, which is characterized by a) a reaction between the substituted aniline, formula (II) (chemical formula) in which R6, R7, R8, R9 and R10 have the meanings as defined above, and benzoyl-iso(thio)cyatene, formula (III) (chemical formula) in which X, R1, R2, R3, R4, and R5 have the meanings as defined above, if appropriate, the reaction will occur in the presence of a diluent, or b) a reaction between Phenyl-iso(thio)cyanate substituted with formula (IV) (chemical formula) where X,R6,R7,R8,R9 and R10 have the meanings as defined above with benzoic acid amide formula (V) (chemical formula) where R1,R2,R3,R4 and R5 have the meanings as defined above. If appropriate, the reaction will occur in the presence of a catalyst and if appropriate, the reaction will occur in the presence of a diluent. 7. Anti-animal substances which are characterized by the presence of at least one of the formulations (I) as defined in Requisition 1 or 6 as a component. 8. The use of formulation (I) as specified in claim 1 or 6 against pests, especially insects and arachnids. 9. A pest control mechanism characterized by the release of a formulation (I) as specified in claim 1 or 6 that acts against the proposed pests, namely insects or arachnids, or on the environment in which the pests live. 10. A process for preparing an anti-pesticide which is characterized by the mixing of formulation (I) as specified in claim 1 or 6 with a bulking agent and/or surfactant (10 claims, - Figure).