SU741803A3 - Gasoline additive detergent composition - Google Patents

Gasoline additive detergent composition Download PDF

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Publication number
SU741803A3
SU741803A3 SU752302052A SU2302052A SU741803A3 SU 741803 A3 SU741803 A3 SU 741803A3 SU 752302052 A SU752302052 A SU 752302052A SU 2302052 A SU2302052 A SU 2302052A SU 741803 A3 SU741803 A3 SU 741803A3
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SU
USSR - Soviet Union
Prior art keywords
acids
mol
polyisobutyl
composition
ethylene oxide
Prior art date
Application number
SU752302052A
Other languages
Russian (ru)
Inventor
Гарвей Мачлидер Уоррен
Мартин Боллингер Джозеф
Original Assignee
Ром Энд Хаас Компани (Фирма)
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Publication of SU741803A3 publication Critical patent/SU741803A3/en

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/221—Organic compounds containing nitrogen compounds of uncertain formula; reaction products where mixtures of compounds are obtained
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • C10L1/2387—Polyoxyalkyleneamines (poly)oxyalkylene amines and derivatives thereof (substituted by a macromolecular group containing 30C)

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Multifunctional additives for gasoline fuels comprise a mixt of (a) a polyamine ether of formula (I) R2O-CH2-CHOH-CH2(NHCH2CH2)nNHCH2-CHOH-CH2-OR2 (I) (where n = 1-5; R2 is alkyl-substd. benzene ring) and (b) a polycarboxylic acid ester (II). The additives act as detergents, antioxidants, corrosion inhibitors, water demulsifiers and antifreezes; their effectiveness is comparable to that of cpds. (I) alone (see BE 836908) but they are less expensive to produce.

Description

Желательно, чтобы полиизобутильна  или полиизопропюшна  группа имела молекул рную масчу 500-2000.It is desirable that the polyisobutyl or polyisopropyl group have a molecular mass of 500-2000.

композицию ввод т в бензин в количестве 0,026-0,04, вес.%. the composition is introduced into gasoline in the amount of 0.026-0.04% by weight.

Композици  может добавл тьс  к этилированному , слабо этилированному или неэтилироданному бензину, т. е. к дистиллированному зтлеводородному горючему , содержащему большую часть углеводородного основного горючего , перегон ющегос  в интервале перегонки бензина. Эта добавка обеспечивает детергентность карбюратора, системы зажигани  и камеры сгорани , ингибирование ржавчины.The composition can be added to leaded, lightly leaded or unleaded gasoline, i.e., to distilled hydrogen-hydrogen fuel containing most of the hydrocarbon main fuel distilled in the gasoline distillation interval. This additive provides detergent carburetor, ignition system and combustion chamber, rust inhibition.

Аминовые, аддукты, примен ющиес  в данном случае, могут быть получены, например.Amine, adducts used in this case can be obtained, for example.

взаимодействием полиизобутштенфенола с эпихлоргидр1шом с последующим аминированнем зтилендиамином или другим полиамином.by the interaction of polyisobutyrichenol with epichlorohydrin followed by aminating with ethylenediamine or another polyamine.

Лучшими зфирами поликарбоновых кислот  вл ютс  смешанные эфиры ди- или три-карбоновых кислот. Особенно подход щим эфиром поликарбоновой кислоты  вл етс  смешанный адипатдиэфир, содержащий моноизодещш, монооктилфеноксиполиэтоксиэтанол (содержащий в среднем 5 моль сконденсированной окиси этилена ), смешанный эфир адипиновой кислоты, полученный обычной этерификацией. The best polycarboxylic acids are mixed esters of di- or tri-carboxylic acids. A particularly suitable polycarboxylic ester is a mixed adipatdiester containing a monoisubstituent, monooctylphenoxypolyethoxyethanol (containing an average of 5 mol of condensed ethylene oxide), a mixed ester of adipic acid, obtained by conventional esterification.

В таблице показано действие карбюраторных смесей.The table shows the effect of carburetor mixtures.

Исходный стандартный бензинSource Standard Petrol

Аддукт амина)Amine adduct)

0,030.03

Смесь аддукта амина и смешанного эфира адшгановойA mixture of amine adduct and mixed ester ester

кислотыacids

Где RI -. Н или полиизобутилен с мол .массой-670. Where is RI -. H or polyisobutylene with a mol. Mass-670.

хх)xx)

Смешанный эфир адипиновой кислоты и моно-изодецил, многооктилфенокси полиэтоксиэтанола (содержащего в в среднем 5 моль конденсированной окиси этилена). Как видно из таблицы, смесь аддукта амина н смещанного кислого эфира адипиновой кислоты вьп-одно отличаетс  от одного аминоводного аддукта. Можно также примен ть и другие эфиры адипиновой кислотыдапример.смешашше иры адипиновой кнслоты.содержащие смешанный С, го алкил/апкилфенокси (алкил С4-2о) папиэтокси94Mixed esters of adipic acid and mono-isodecyl, polyoxyethyl polyoxyethylphenoxy (containing on average 5 moles of condensed ethylene oxide). As can be seen from the table, the mixture of the amine adduct n the displaced acid ester of adipic acid top one differs from the one of the amphibious adduct. Other esters of adipic acid such as an example of a mixture of adipic acid containing mixed C, go alkyl / apkylphenoxy (alkyl C4-2o) papiethoxy94 can also be used.

9595

81 9881 98

Claims (2)

84, 90 , 83 94 этанольный эфир ( содержащий 1-20 моль конденсированной окиси этилена, лучше 1-5 моль конденсированной окиси этилена). Эти смешанные эфиры можно затем смещать с аминовым аддуктом, как это показано в таб;пще. По изобретению можно также использовать и другие кислоты, кроме адипиновой, например многоосновные кислоты, образующиес  при димери5 , 7418 заюш или тримериэации полиненасыщенных жирных кислот. Два примера из этих кислот представл ют собой тример-С54- и димер Сзб-ные кислоты, эффективность щлугих смесей лфисадок аналогична Т1риведе1шым в таблице. j Формула изобретени  1. Детергентна  композици  присадок к бензииу , отличающа с  тем, что, с целью повыщени  эксплуатационных свойств композиции, она содержит соединение общей ю формулы ОНОН I, CH2-CHGH,,()ttmCH Cll-CK2, II Д.tt где п - целое число от 1 до 5: 2Q 36 где X - полиизогфошшьна  юш полиизобутильна  группа; RI X или Н,   эфир ди- или трикарбоиовой кислоты Cj-Cs4 при следующем соотношении компонентов , вес.%: Соед$шение общей формулы (1)1-99 Эфир ди- или трикарбоновой кислоты С2-С54До 100 2. Композици  по п. 1, о т л и ч а ю щ а   с   тем, 1ш полиизопропильна  или нолиизобутильна  группа имеет среднюю мол.массу 500-2000 Источники информации, гфин тые во внимание при экспертизе 1.Патент США N 383899 Ь кл. 44-66, опублик. 1.10.74. 84, 90, 83 94 ethanol ether (containing 1-20 mol of condensed ethylene oxide, preferably 1-5 mol of condensed ethylene oxide). These mixed esters can then be shifted with an amine adduct, as shown in the table below. According to the invention, it is also possible to use other acids besides adipic acid, for example, polybasic acids formed during dimery5, 7418 hap or trimerization of polyunsaturated fatty acids. Two examples of these acids are the trimer-C54 and dimer, sbc-acid, the efficiency of each mixture is similar to that given in the table. j. Claim 1. Detergent composition of additives for benzium, characterized in that, in order to improve the performance properties of the composition, it contains a compound of the general formula ONOH I, CH2-CHGH, () ttmCH Cll-CK2, II D.ttt n is an integer from 1 to 5: 2Q 36 where X is a polyisobutyl polyisobutyl group; RI X or H, di- or tricarboxylic acid ester Cj-Cs4 in the following ratio, wt.%: Compound of general formula (1) 1-99 Di-or tricarboxylic ester C2-C54To 100 2. Composition according to claim 1, that is, a polyisopropyl or polyisobutyl group has a mass molar mass of 500-2000 Sources of information, which are taken into account in the examination 1. US patent N 383899 Cl. 44-66, published. 1.10.74. 2.Патент ФРГ N 2065049, кл. 46а, 81/22, опублик. 1973 (прототип).2. The patent of Germany N 2065049, cl. 46a, 81/22, publ. 1973 (prototype).
SU752302052A 1974-12-24 1975-12-22 Gasoline additive detergent composition SU741803A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US53607574A 1974-12-24 1974-12-24

Publications (1)

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SU741803A3 true SU741803A3 (en) 1980-06-15

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SU752302052A SU741803A3 (en) 1974-12-24 1975-12-22 Gasoline additive detergent composition

Country Status (8)

Country Link
BE (1) BE836910A (en)
BR (1) BR7508548A (en)
CH (1) CH606392A5 (en)
DE (1) DE2555922C2 (en)
FR (1) FR2296009A1 (en)
IT (1) IT1051910B (en)
MX (1) MX3324E (en)
SU (1) SU741803A3 (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3574576A (en) * 1965-08-23 1971-04-13 Chevron Res Distillate fuel compositions having a hydrocarbon substituted alkylene polyamine
GB1398067A (en) * 1972-12-26 1975-06-18 Chevron Res Fuel additives and use thereof
CA1039302A (en) * 1973-05-02 1978-09-26 Robert R. Kuhn Motor fuel composition

Also Published As

Publication number Publication date
BR7508548A (en) 1976-08-24
IT1051910B (en) 1981-05-20
BE836910A (en) 1976-06-21
FR2296009A1 (en) 1976-07-23
DE2555922A1 (en) 1976-07-08
DE2555922C2 (en) 1984-09-20
MX3324E (en) 1980-09-25
CH606392A5 (en) 1978-11-30
FR2296009B1 (en) 1978-05-19

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