SU706416A1 - Copper bis(para-aminosalicyl)monohydroxoborate as biostimulator for increasing sugar beet crop - Google Patents

Description

(54) BIS (p-AMINRSALITSIL) mbNOPSH OKgABD MEDIUM as a biostimulant of the increase in the harvest of sapphire C1B1SLYu nyashnog uppa, which, firstly, indicates that there is no complexation of 66 | ijjjNHj in the long wavelength strait and even their fusion in the compounds of copper shows a bond between the metal and the amino group of metals, which is enhanced in the range of MOLSo 4 C. The band at a rate of 3336 cm relates to the oscillation of the OY-soil associated with boron, and 31303100 cm to the absorption of a phenolic OY-group. Thermal analysis indicates the absence of water of crystallization. The compounds were synthesized by the interaction of p-aminosalicylic acid; its Mtrievoy salt, boron kyotot and syyud Meda in a water-alcohol medium according to the following scheme; ; aUHjCeKjOHCOOH + ZWHjdjHsQHCOONa 4 g eVOz biS1g (1tgS5NsONSOO) in (it) (T1H2SbNzSOSOO) gnas + This is a small-crystalline substance, little-1 soluble in alcohol and in chit-ln chinah, Ia chidas, in chahmas, I acid chambers, I am acidic, I can not use them in acidic acidic acid lines, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic, I am acidic. When treating seeds with sugar and sugar coating, they are powdered in doses of 3-6 g / kg and mn bis (p-amNosalitsil) with honey hypoxyloborate (much more, the yield of roots, green mass, sugar content of sugar ebysla (much more, than the corresponding pentaerythritolates). In the semi-sucrose (fodder beet), increase the rate of nitrogen from nitrogen. : in the root and green mass. Increase.ro j

Culture

Year

The roots

Sugar q / ha q / ha increment

kg / ha% of the stimulating effect and the effect on yield increase can be directly related to the effect of the associated cattle, multiplex failure of p-aminosylistocic acid. Example. Bis (p-aminosalische) copper monogadsoborate. A mixture of 15.31 g of p-aminosalicic acid, 21.11 g of sodium salt of p-amino Syzyl ticyclic acid dihydrate and 6.2 g of boric acid is dissolved in a mixture of 80 ml of ethyl alcohol and 10 ml of water while being transferred. (It is necessary to mix, avoid rubbing on the vessel wall, which may lead to premature crystallization of the reaction mixture). Continuing the stirring, add a solution: add small portions of the solution. A solution of 8.53 g of CuCl 2 H, O in 30 ml of water. Upon completion of the addition of the copper chloride solution, the desired product crystallizes by friction, for example by stirring on a magnetic stirrer. After toro, as the main mass crystallizes, the reaction mixture is left to stand for 1-2 hours. Then it is sucked off, washed with ice water until no reaction to chlorine ions in the wash water, then with cold ethyl alcohol and dried at room temperature to air-dry. condition The output is 60% of theoretical (37-44 g). Found,%: B 2.94; N 7.36; H 3.37; . C 45.93; Si 8.61 .... Cu (NH2CeH30HCbo) BqH (NH2C6COCOO) ji Calculated,%: B 2.98; IS) 7.72; HJ, 33, C46.34; .-:: - ::: .- - -: -. . The yellow crystalline substance d, 0,68 g / cm, in ethanol decomposes, forming a black precipitate.

Polusaharna beets

Control

Powdered 3 g / kg of seeds with a compound of formula 1

Sugar Beet Control

Powdered 5 g / kg of seeds with a compound of formula 1

100

42,8

10.4

118.6 50.8 41

100

50.4

112.1 56.5

9.7

Claims (2)

27 Claims of invention Bis (pa (minosalitsil) copper monohydroxoborate i as a biostimulator for increasing the yield of sugar beet. 7064166 Information sources taken into account during expert analysis, 1. Telzheiska P.N. and Schwarz L.M. Salicilic acid combined number and its derivatives Codes. Chemicals. 1977, T.Z., issue 9, a279-1295. 2. USSR author's certificate N 350771, 2 10 cl. C 05 D 9/02, 1971. 3-Copyright Certificate CtCP № 467585, cl. C 05 D 9/02, 1973.