SU701517A3 - Fungicidic composition - Google Patents

Fungicidic composition

Info

Publication number
SU701517A3
SU701517A3 SU752102879A SU2102879A SU701517A3 SU 701517 A3 SU701517 A3 SU 701517A3 SU 752102879 A SU752102879 A SU 752102879A SU 2102879 A SU2102879 A SU 2102879A SU 701517 A3 SU701517 A3 SU 701517A3
Authority
SU
USSR - Soviet Union
Prior art keywords
cultivated
fungicidic
composition
percentage
healthy
Prior art date
Application number
SU752102879A
Other languages
Russian (ru)
Inventor
Като Тосиро
Сасаки Мицури
Ооиси Тадаси
Мукаи Кунио
Original Assignee
Сумитомо Кемикал Компани Лимитед (Фирма)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP740074A priority Critical patent/JPS5120571B2/ja
Priority to JP5153074A priority patent/JPS5133970B2/ja
Application filed by Сумитомо Кемикал Компани Лимитед (Фирма) filed Critical Сумитомо Кемикал Компани Лимитед (Фирма)
Application granted granted Critical
Publication of SU701517A3 publication Critical patent/SU701517A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds
    • C07F9/06Phosphorus compounds without P—C bonds
    • C07F9/16Esters of thiophosphoric acids or thiophosphorous acids
    • C07F9/165Esters of thiophosphoric acids
    • C07F9/18Esters of thiophosphoric acids with hydroxyaryl compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals

Description

This invention relates to chemical plant protection products, namely, the use of a fungicidal composition based on thiophosphoric ester. A fungicide is known, the active principle of which is 0-2, 4 5 Trichlorophenyl-O-methi.p-isopropylphosphate 1. However, it is not effective against diseases that develop parami-ixcH in soil. Also known is the soil fungicide pentachloronitrobenzene, which has insufficient fungicidal activity 2. More technically closest to the proposed are biologically active compounds, the active substances of which are used syioT 0-2, 4,6-trichlorophenyl-O, O-dialkio thioPhosphates. However, they have antiparathyritic activity 3. With the aim of finding A new fungicidal composition- with a high fungicidal activity suggests using compounds of the general formula CI, 0 Cn, where R and Rj are each atom of chlorine or bromine; . methyl or ethyl group, as an active substance in the amount of from 0.1 to 90 wt.%. Thiophosphoric acid4 esters can be obtained by reacting 2, 4, 6-trisubstituted phenol with 0,0-dimethylthiophosphoryl chloride, preferably in the presence of a binder (its acid agent, or by reacting a salt of 2,4, 6-trisubstituted phenol with 0.0 -dimethylthiophosphoryl chloride, This reaction is conducted respectfully in an inert organic solvent at a temperature of from 70 to 100 ° C. chemical structures. and physical constants of the proposed compounds are presented in the table.
Compound-i
Compound-I Chemical Structure
- "4-0- / Vert,
SNO
C1
WA .. „,
SNZO
Table 1
Physical constant
T, pl.79-79,5 °
Mp 73-74 ° C
snzO ..,. AL
SNZO
C1:
SNSO.
Jo
// Л f у-СгНз
 / five
c, n,
The form of use of drugs is normal. In these forms, the active substances are contained in an amount of from 0.1 to 90% by weight, preferably from 5 to 60% by weight. Example 1. Fight against the cucumber vybrovanie (test in a pot). The cultivated land was evenly filled in a flower pot with a diameter of 9 cm. On the surface of the named land, 10 MP were filled and inoculated on a Gorgaszh pathogenic land, in which Risoctoni solani {Rhizoctonla solani) was cultivated. Then, each of the aqueous solutions of test digdakaliums in the form of emulsifiable concentrates was poured into 100
t, square 81-83 s
P1 1,5500
90
p 1.5620
20 h; j3 1,5672 amount of 15 ml per pot. At the end of 2 hours, each pot was planted, but 10 pieces of cucumber seeds of the Kara Aonagafushinari variety (Kog-q Achopada ustiinofi); And after 5 days, the disease of cucumber seedlings was studied to calculate the percentage of healthy seedlings. the number of healthy percent of patients on healthy seedlings, the number of seeds sown on untreated and non-cultivated, plot The results of the tests are presented in table 2.
Concentration of the active ingredient, parts per mil250 125 62.5
250 125 62.5
250 125 62.5
250 125 62.5 125 62.5
6125
SNSO / .250CiHjO
CHjO. H //
 .Р-0 - // Vci 250
();
-R-0
VG SNZ
(CHjOl.-P-O-fJV-KOz 250 CH, - ZSNz
.Table 2
The percentage of healthy seedlings,% Lyon
100 100 90
100 100 70
100 100 60
100 100 80
100
250
80
60
100
90
50
62.5
Uninoculated, unprocessed
Note: Known compounds 1.
 3 soil sales available
Example 2. Fighting the crumble of cucumbers (tested in iKax barrels) ..
The cultivated land was filled up with plastic, the barrels were sized 0.1 m, L.x. the surface of the named earth was evenly covered and the pathogenic soil was icoculified,
which was cultivated by PJJBOK toni of solani (Bh-izootonia sobani) and the pathogenic earth was sufficiently mixed with the cultivated earth to a depth of 3 to 5 cm from the surface. Then each of the water
Connection1 2 3 4 5 6
ABOUT
II
I-C1: P - O
I
(CgN50) g R-ZSNz
Continuation of table 2
100 fungicide (the same designations are used below).
solutions, test chlorides in the form of emulsifiable concentrates were poured into this treated soil at the rate of 300 ml per barrel.
After 2 hours, 30 pieces of Kara variety Aonagafushinari (Kag Ql Aondo aiustiinaH) were planted in each barrel and after a month, the disease state of the cucumber seedlings was examined for calculation. % of healthy sleepers. This percentage was calculated in Example 1.
The test results are presented in the table. D. - ..,
T & B l and c a 3
The percentage of healthy sunbeds
3
98 98 97 97 97 95
200
200
About II P
CL
CH-O- /
ABOUT
C1
C1
C1 - y - N0,
C1 - Inoculated Mushroom, Untreated
raw, untreated
Example 3. Fighting dry rot of Japanese radish with dry rot: (tested in barrels).
Cultivated land was poured into plastic kegs 0.1 m in size. Then, the pathogenic land in which Fusarium oxiforum F. rafani (Fusar-iuni ox sporum f. I-apViani) was cultivated was smashed and inoculated with cultivated land 5 cm from the surface, 30 seeds of this type were planted in the ground thus treated. n per pot of donskoy radishes
Continued .S -,
200
200
Vr-Tn.
200
36
98
Vise varieties - 40 nichi (jyase-4o nictii) and seeds were covered with earth. After 3 hours, each of the aqueous solutions of test chemicals was poured into the ground in an amount of 300 ml per barrel. After the radish had ripened for one month in a greenhouse with an adjustable air supply at 26–28 ° C, the condition of radish patients was examined to calculate the percentage of healthy seedlings. The percentage was calculated according to example 1.
The results of the tests. presented in table 4.
Table 4
Continuation of table 4
SU752102879A 1974-01-14 1975-01-13 Fungicidic composition SU701517A3 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP740074A JPS5120571B2 (en) 1974-01-14 1974-01-14
JP5153074A JPS5133970B2 (en) 1974-05-08 1974-05-08

Publications (1)

Publication Number Publication Date
SU701517A3 true SU701517A3 (en) 1979-11-30

Family

ID=26341686

Family Applications (1)

Application Number Title Priority Date Filing Date
SU752102879A SU701517A3 (en) 1974-01-14 1975-01-13 Fungicidic composition

Country Status (16)

Country Link
AR (1) AR209290A1 (en)
CA (1) CA1049547A (en)
CH (1) CH612943A5 (en)
CS (1) CS181284B2 (en)
DE (1) DE2501040B2 (en)
DK (1) DK137761C (en)
ES (1) ES433737A1 (en)
FR (1) FR2257598B1 (en)
GB (1) GB1467561A (en)
HU (1) HU172092B (en)
IL (1) IL46427A (en)
IT (1) IT1036863B (en)
NL (1) NL157309B (en)
PL (1) PL94954B1 (en)
SU (1) SU701517A3 (en)
TR (1) TR18202A (en)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS626557B2 (en) * 1978-07-21 1987-02-12 Sumitomo Chemical Co
IE56044B1 (en) * 1982-09-22 1991-03-27 Schering Agrochemicals Ltd Fungicidal mixtures
JPS59122404A (en) * 1982-12-15 1984-07-14 Sumitomo Chem Co Ltd Fungicidal composition for agriculture and horticulture
JPS59210006A (en) * 1983-05-13 1984-11-28 Sumitomo Chem Co Ltd Agricultural and horticultural fungicidal composition
JPS6097907A (en) * 1983-11-01 1985-05-31 Sumitomo Chem Co Ltd Agricultural and horticultural fungicidal composition
DE102006023263A1 (en) 2006-05-18 2007-11-22 Bayer Cropscience Ag Synergistic drug combinations
EP2489264A3 (en) 2006-09-18 2012-10-24 Basf Se Pesticidal mixtures comprising an anthranilamide insecticide and a carboxamide fungicide
EP2258177A3 (en) 2006-12-15 2011-11-09 Rohm and Haas Company Mixtures comprising 1-methylcyclopropene
EP2679094A1 (en) 2007-02-06 2014-01-01 Basf Se Pesticidal mixtures
WO2008129060A2 (en) 2007-04-23 2008-10-30 Basf Se Plant produtivity enhancement by combining chemical agents with transgenic modifications
AU2008303528B2 (en) 2007-09-26 2013-05-23 Basf Se Ternary fungicidal compositions comprising boscalid and chlorothalonil
DE102007045920B4 (en) 2007-09-26 2018-07-05 Bayer Intellectual Property Gmbh Synergistic drug combinations
JP5481999B2 (en) * 2008-12-22 2014-04-23 住友化学株式会社 Process for producing modified O- (2,6-dichloro-4-methylphenyl) -O, O-dimethyl phosphorothioate
EP2453750A2 (en) 2009-07-16 2012-05-23 Bayer CropScience AG Synergistic active substance combinations containing phenyl triazoles
WO2011026796A1 (en) 2009-09-01 2011-03-10 Basf Se Synergistic fungicidal mixtures comprising lactylates and method for combating phytopathogenic fungi
AU2011347752A1 (en) 2010-12-20 2013-07-11 Basf Se Pesticidal active mixtures comprising pyrazole compounds
EP2481284A3 (en) 2011-01-27 2012-10-17 Basf Se Pesticidal mixtures
JP6049684B2 (en) 2011-03-23 2016-12-21 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Compositions containing polymeric ionic compounds containing imidazolium groups
EP2750507A2 (en) 2011-09-02 2014-07-09 Basf Se Agricultural mixtures comprising arylquinazolinone compounds
PL3300602T3 (en) 2012-06-20 2020-08-24 Basf Se Pesticidal mixtures comprising a pyrazole compound
US20150257383A1 (en) 2012-10-12 2015-09-17 Basf Se Method for combating phytopathogenic harmful microbes on cultivated plants or plant propagation material
JP6576829B2 (en) 2012-12-20 2019-09-18 ビーエーエスエフ アグロ ベー.ブイ. Composition comprising a triazole compound
EP2783569A1 (en) 2013-03-28 2014-10-01 Basf Se Compositions comprising a triazole compound
EP2835052A1 (en) 2013-08-07 2015-02-11 Basf Se Fungicidal mixtures comprising pyrimidine fungicides
EP3046915A1 (en) 2013-09-16 2016-07-27 Basf Se Fungicidal pyrimidine compounds
WO2015036059A1 (en) 2013-09-16 2015-03-19 Basf Se Fungicidal pyrimidine compounds
EP2979549A1 (en) 2014-07-31 2016-02-03 Basf Se Method for improving the health of a plant
JP2017538860A (en) 2014-10-24 2017-12-28 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Non-amphoteric quaternizable water-soluble polymer for modifying the surface charge of solid particles
EP2910126A1 (en) 2015-05-05 2015-08-26 Bayer CropScience AG Active compound combinations having insecticidal properties

Also Published As

Publication number Publication date
HU172092B (en) 1978-05-28
CA1049547A1 (en)
DK5675A (en) 1975-09-15
CH612943A5 (en) 1979-08-31
CA1049547A (en) 1979-02-27
TR18202A (en) 1976-11-25
DK137761B (en) 1978-05-01
CS181284B2 (en) 1978-03-31
IL46427D0 (en) 1975-04-25
ES433737A1 (en) 1976-12-16
FR2257598A1 (en) 1975-08-08
GB1467561A (en) 1977-03-16
NL157309B (en) 1978-07-17
FR2257598B1 (en) 1978-02-03
AR209290A1 (en) 1977-04-15
PL94954B1 (en) 1977-09-30
NL7500293A (en) 1975-07-16
IL46427A (en) 1977-07-31
DE2501040A1 (en) 1975-07-17
DE2501040B2 (en) 1976-07-08
IT1036863B (en) 1979-10-30
DK137761C (en) 1978-10-09

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