SU685144A3 - Method of synthesis of acrylonitrile - Google Patents
Method of synthesis of acrylonitrileInfo
- Publication number
- SU685144A3 SU685144A3 SU772455461A SU2455461A SU685144A3 SU 685144 A3 SU685144 A3 SU 685144A3 SU 772455461 A SU772455461 A SU 772455461A SU 2455461 A SU2455461 A SU 2455461A SU 685144 A3 SU685144 A3 SU 685144A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- acrylonitrile
- synthesis
- added
- water
- propylene
- Prior art date
Links
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title description 3
- 238000000034 method Methods 0.000 title description 2
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- URWAJWIAIPFPJE-YFMIWBNJSA-N sisomycin Chemical compound O1C[C@@](O)(C)[C@H](NC)[C@@H](O)[C@H]1O[C@@H]1[C@@H](O)[C@H](O[C@@H]2[C@@H](CC=C(CN)O2)N)[C@@H](N)C[C@H]1N URWAJWIAIPFPJE-YFMIWBNJSA-N 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
- B01J27/0576—Tellurium; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Description
(54) СПОСОБ ПОЛУЧЕНИЯ АКРИЛОНИТРИЛА(54) METHOD OF OBTAINING ACRYLONITRILE
фонировани отсто вшейс жидкости пасту снова перевод т в суспензию в 2,5 л воды и нагревают до 60 С. Затем прибавл ют 30 г окиси вольфрама WOj, потом 60,4 г нитрата меди СиШО)- . Аммиак ввод т, пока рН не достигнет 6,3-6,5. После осаждени , декантации и сифонировани отсто вшейс жидкости пасту отмывают при перемешивании 4 л холодной воды в течение 10 мин, затем отдел ют фильтрацией, высушивают в течение 12 ч при . 10 вес.ч. воды добавл ют к 100 вее.ч. сухого порошка и перемешивают, добавл 10,2 г окиси теллура, ТеО, высушивают при 120°С, добавл ют графит (1% по весу) и таблетируют.Spraying the liquid paste into the suspension is again transferred to a suspension in 2.5 liters of water and heated to 60 ° C. Then 30 g of tungsten oxide WOj are added, then 60.4 g of copper nitrate SISO) -. Ammonia is injected until the pH reaches 6.3-6.5. After precipitation, decantation and siphoning of the supernatant, the paste is washed with stirring 4 liters of cold water for 10 minutes, then separated by filtration, dried for 12 hours at. 10 weight.h. water is added to 100 wt. dry powder and stirred, added 10.2 g of tellurium oxide, TeO, dried at 120 ° C, graphite (1% by weight) was added and tableted.
Таблетки 4 х 4 мм подвергают термической обработке в токе воздуха в течение 16 ч при .Tablets 4 x 4 mm are subjected to heat treatment in a stream of air for 16 h at.
90 г приготовленного катализатора (атомное отношение Sb : Sn ; W i : Си : Те 4 : 2 : 0,25 t 0,5 : : 0,125) помещают в U -образную стекл нную трубку (двн 10 мм) и нагреваю в ванне из расплавленных нитратов до .90 g of the prepared catalyst (atomic ratio Sb: Sn; W i: Cu: Te 4: 2: 0.25 t 0.5:: 0.125) are placed in a U-shaped glass tube (dv 10 mm) and heated in a bath of molten nitrates to.
Через катализатор пропускают 27 л/ч смеси, содержащей, мол.%: 6Through the catalyst pass 27 l / h mixture containing, mol.%: 6
пропилена, 7 аммиака, 70 воздуха и 17 воды.propylene, 7 ammonia, 70 air and 17 water.
При зтих услови х 72,% пропилена превращаетс в акрилонитрил, 6,5% в цианистоводородную кислоту, 0,9% в акролеин, 10% в COg, 5% в СО, 4,7% пропилена не вступает в реакцию.Under these conditions, 72% propylene is converted to acrylonitrile, 6.5% to hydrocyanic acid, 0.9% to acrolein, 10% to COg, 5% to CO, 4.7% of propylene does not react.
Claims (2)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7605039A FR2342281A1 (en) | 1976-02-24 | 1976-02-24 | CATALYST AND PROCESS FOR PREPARING UNSATURATED NITRILS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU685144A3 true SU685144A3 (en) | 1979-09-05 |
Family
ID=9169499
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU772455461A SU685144A3 (en) | 1976-02-24 | 1977-02-24 | Method of synthesis of acrylonitrile |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS52102895A (en) |
| BE (1) | BE850736A (en) |
| BR (1) | BR7701089A (en) |
| DE (1) | DE2706271C3 (en) |
| ES (1) | ES456263A1 (en) |
| FR (1) | FR2342281A1 (en) |
| GB (1) | GB1518636A (en) |
| IT (1) | IT1082470B (en) |
| NL (1) | NL7701939A (en) |
| SU (1) | SU685144A3 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57134454A (en) * | 1981-02-12 | 1982-08-19 | Takeda Chem Ind Ltd | Preparation of unsaturated aliphatic dinitrile |
| US4532083A (en) * | 1982-10-29 | 1985-07-30 | The Standard Oil Company | Multiply promoted Sn/Sb oxide catalysts |
-
1976
- 1976-02-24 FR FR7605039A patent/FR2342281A1/en active Granted
-
1977
- 1977-01-26 BE BE1007906A patent/BE850736A/en unknown
- 1977-02-10 GB GB5565/77A patent/GB1518636A/en not_active Expired
- 1977-02-15 DE DE2706271A patent/DE2706271C3/en not_active Expired
- 1977-02-18 BR BR7701089A patent/BR7701089A/en unknown
- 1977-02-23 IT IT67403/77A patent/IT1082470B/en active
- 1977-02-23 NL NL7701939A patent/NL7701939A/en active Search and Examination
- 1977-02-23 JP JP1828377A patent/JPS52102895A/en active Pending
- 1977-02-24 ES ES456263A patent/ES456263A1/en not_active Expired
- 1977-02-24 SU SU772455461A patent/SU685144A3/en active
Also Published As
| Publication number | Publication date |
|---|---|
| NL7701939A (en) | 1977-08-26 |
| BE850736A (en) | 1977-07-26 |
| DE2706271C3 (en) | 1979-04-26 |
| JPS52102895A (en) | 1977-08-29 |
| BR7701089A (en) | 1977-11-01 |
| GB1518636A (en) | 1978-07-19 |
| FR2342281A1 (en) | 1977-09-23 |
| ES456263A1 (en) | 1978-05-16 |
| DE2706271A1 (en) | 1977-08-25 |
| FR2342281B1 (en) | 1981-11-27 |
| IT1082470B (en) | 1985-05-21 |
| DE2706271B2 (en) | 1978-06-15 |
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