SU644389A3 - Способ получени хлорсодержащих третичных фосфиноксидов - Google Patents
Способ получени хлорсодержащих третичных фосфиноксидовInfo
- Publication number
- SU644389A3 SU644389A3 SU752113032A SU2113032A SU644389A3 SU 644389 A3 SU644389 A3 SU 644389A3 SU 752113032 A SU752113032 A SU 752113032A SU 2113032 A SU2113032 A SU 2113032A SU 644389 A3 SU644389 A3 SU 644389A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- mol
- chloride
- hydrogen chloride
- product
- reaction
- Prior art date
Links
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims 11
- 239000000460 chlorine Substances 0.000 title claims 11
- 229910052801 chlorine Inorganic materials 0.000 title claims 11
- 238000000034 method Methods 0.000 title claims 11
- 150000003004 phosphinoxides Chemical group 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 29
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 29
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims 28
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims 27
- 239000000047 product Substances 0.000 claims 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 15
- 238000006243 chemical reaction Methods 0.000 claims 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 8
- 239000012043 crude product Substances 0.000 claims 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 6
- USJRLGNYCQWLPF-UHFFFAOYSA-N chlorophosphane Chemical compound ClP USJRLGNYCQWLPF-UHFFFAOYSA-N 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000007789 gas Substances 0.000 claims 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 5
- 238000001228 spectrum Methods 0.000 claims 5
- 238000005160 1H NMR spectroscopy Methods 0.000 claims 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 4
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 239000007787 solid Substances 0.000 claims 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- 238000005481 NMR spectroscopy Methods 0.000 claims 3
- 230000008878 coupling Effects 0.000 claims 3
- 238000010168 coupling process Methods 0.000 claims 3
- 238000005859 coupling reaction Methods 0.000 claims 3
- 239000000155 melt Substances 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 3
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 claims 3
- 239000002798 polar solvent Substances 0.000 claims 3
- 239000000126 substance Substances 0.000 claims 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 2
- 239000007983 Tris buffer Substances 0.000 claims 2
- 238000001816 cooling Methods 0.000 claims 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 2
- 238000004821 distillation Methods 0.000 claims 2
- 238000004508 fractional distillation Methods 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 238000002844 melting Methods 0.000 claims 2
- 230000008018 melting Effects 0.000 claims 2
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 claims 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 2
- 239000002244 precipitate Substances 0.000 claims 2
- 238000000746 purification Methods 0.000 claims 2
- 239000002994 raw material Substances 0.000 claims 2
- 239000011541 reaction mixture Substances 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 239000000243 solution Substances 0.000 claims 2
- -1 (hydroxymethyl) methylphosphonium chloride Chemical compound 0.000 claims 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 claims 1
- BGEBZHIAGXMEMV-UHFFFAOYSA-N 5-methoxypsoralen Chemical compound O1C(=O)C=CC2=C1C=C1OC=CC1=C2OC BGEBZHIAGXMEMV-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 claims 1
- 206010041662 Splinter Diseases 0.000 claims 1
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 229910052786 argon Inorganic materials 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- VACOMSNNWGXHSF-UHFFFAOYSA-N chloro(dimethylphosphoryl)methane Chemical compound CP(C)(=O)CCl VACOMSNNWGXHSF-UHFFFAOYSA-N 0.000 claims 1
- LSKVBJHJMLFTDB-UHFFFAOYSA-N chloro(methyl)phosphane Chemical compound CPCl LSKVBJHJMLFTDB-UHFFFAOYSA-N 0.000 claims 1
- ZQWCJXYCTIBMSH-UHFFFAOYSA-N chloroform phosphane Chemical compound C(Cl)(Cl)Cl.P ZQWCJXYCTIBMSH-UHFFFAOYSA-N 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 229910052805 deuterium Inorganic materials 0.000 claims 1
- 229940117389 dichlorobenzene Drugs 0.000 claims 1
- RQOKIVVUNQCMJS-UHFFFAOYSA-N dimethylphosphorylmethanol Chemical compound CP(C)(=O)CO RQOKIVVUNQCMJS-UHFFFAOYSA-N 0.000 claims 1
- 238000000605 extraction Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 claims 1
- 239000011261 inert gas Substances 0.000 claims 1
- 239000012263 liquid product Substances 0.000 claims 1
- 239000002932 luster Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 1
- HXZSFRJGDPGVNY-UHFFFAOYSA-N methyl(oxido)phosphanium Chemical compound C[PH2]=O HXZSFRJGDPGVNY-UHFFFAOYSA-N 0.000 claims 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 238000012856 packing Methods 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 230000008707 rearrangement Effects 0.000 claims 1
- 238000001953 recrystallisation Methods 0.000 claims 1
- 238000010992 reflux Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 238000004611 spectroscopical analysis Methods 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 239000006188 syrup Substances 0.000 claims 1
- 235000020357 syrup Nutrition 0.000 claims 1
- GMGSXHKWHPREMC-UHFFFAOYSA-M tris(hydroxymethyl)-methylphosphanium;chloride Chemical compound [Cl-].OC[P+](C)(CO)CO GMGSXHKWHPREMC-UHFFFAOYSA-M 0.000 claims 1
- 238000005292 vacuum distillation Methods 0.000 claims 1
- 239000002699 waste material Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
- C07F9/5304—Acyclic saturated phosphine oxides or thioxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
- C07F9/5407—Acyclic saturated phosphonium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2412800A DE2412800C3 (de) | 1974-03-16 | 1974-03-16 | Verfahren zur Herstellung von halogenhaltigen tertiären Phosphinoxiden |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU644389A3 true SU644389A3 (ru) | 1979-01-25 |
Family
ID=5910319
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU752113032A SU644389A3 (ru) | 1974-03-16 | 1975-03-14 | Способ получени хлорсодержащих третичных фосфиноксидов |
Country Status (15)
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4487968A (en) * | 1982-06-28 | 1984-12-11 | Fmc Corporation | Production of tertiary haloalkylphosphine oxides |
| JPS6199247U (US06168776-20010102-C00041.png) * | 1984-11-30 | 1986-06-25 | ||
| GB8704240D0 (en) * | 1987-02-24 | 1987-04-01 | Albright & Wilson | Phosphine oxides |
| CN103497216B (zh) * | 2013-10-24 | 2016-06-01 | 黎明化工研究设计院有限责任公司 | 一种制备双(七氟异丙基)三氟化膦的方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3716580A (en) * | 1968-12-17 | 1973-02-13 | Monsanto Co | Functional tertiary phosphine oxides |
| US3732316A (en) * | 1970-11-12 | 1973-05-08 | Hooker Chemical Corp | Process for producing methyl phosphine oxides |
-
1974
- 1974-03-16 DE DE2412800A patent/DE2412800C3/de not_active Expired
-
1975
- 1975-02-27 GB GB8259/75A patent/GB1481897A/en not_active Expired
- 1975-03-12 BE BE154245A patent/BE826578A/xx not_active IP Right Cessation
- 1975-03-13 US US05/557,926 patent/US3998886A/en not_active Expired - Lifetime
- 1975-03-13 SE SE7502828A patent/SE405858B/xx not_active IP Right Cessation
- 1975-03-13 NL NL7503013.A patent/NL159391B/xx not_active IP Right Cessation
- 1975-03-14 SU SU752113032A patent/SU644389A3/ru active
- 1975-03-14 DK DK106075A patent/DK136774C/da not_active IP Right Cessation
- 1975-03-14 IT IT48620/75A patent/IT1032321B/it active
- 1975-03-14 DD DD184784A patent/DD119246A5/xx unknown
- 1975-03-14 AT AT196175A patent/AT329587B/de not_active IP Right Cessation
- 1975-03-14 CH CH331875A patent/CH596230A5/xx not_active IP Right Cessation
- 1975-03-14 FR FR7508134A patent/FR2264036B1/fr not_active Expired
- 1975-03-17 JP JP3211975A patent/JPS536138B2/ja not_active Expired
- 1975-03-20 CA CA222,635A patent/CA1030160A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL159391B (nl) | 1979-02-15 |
| SE405858B (sv) | 1979-01-08 |
| DE2412800A1 (de) | 1975-09-18 |
| CA1030160A (en) | 1978-04-25 |
| BE826578A (fr) | 1975-09-12 |
| DE2412800B2 (de) | 1978-10-05 |
| JPS536138B2 (US06168776-20010102-C00041.png) | 1978-03-04 |
| AT329587B (de) | 1976-05-25 |
| FR2264036B1 (US06168776-20010102-C00041.png) | 1978-02-24 |
| DE2412800C3 (de) | 1979-05-31 |
| ATA196175A (de) | 1975-08-15 |
| NL7503013A (nl) | 1975-09-18 |
| DD119246A5 (US06168776-20010102-C00041.png) | 1976-04-12 |
| GB1481897A (en) | 1977-08-03 |
| FR2264036A1 (US06168776-20010102-C00041.png) | 1975-10-10 |
| DK106075A (US06168776-20010102-C00041.png) | 1975-09-17 |
| JPS50131930A (US06168776-20010102-C00041.png) | 1975-10-18 |
| DK136774C (da) | 1978-05-01 |
| US3998886A (en) | 1976-12-21 |
| DK136774B (da) | 1977-11-21 |
| CH596230A5 (US06168776-20010102-C00041.png) | 1978-03-15 |
| IT1032321B (it) | 1979-05-30 |
| SE7502828L (US06168776-20010102-C00041.png) | 1975-09-17 |
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