SU601277A1 - Способ получени аллилацетата - Google Patents
Способ получени аллилацетатаInfo
- Publication number
- SU601277A1 SU601277A1 SU752101054A SU2101054A SU601277A1 SU 601277 A1 SU601277 A1 SU 601277A1 SU 752101054 A SU752101054 A SU 752101054A SU 2101054 A SU2101054 A SU 2101054A SU 601277 A1 SU601277 A1 SU 601277A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- catalyst
- allyl acetate
- mixture
- palladium
- removal
- Prior art date
Links
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 title claims 21
- 238000000034 method Methods 0.000 title claims 6
- 239000003054 catalyst Substances 0.000 claims 33
- 239000000203 mixture Substances 0.000 claims 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 12
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical group [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 10
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 6
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical class [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 5
- 238000006243 chemical reaction Methods 0.000 claims 5
- 239000003153 chemical reaction reagent Substances 0.000 claims 5
- ZKXWKVVCCTZOLD-UHFFFAOYSA-N copper;4-hydroxypent-3-en-2-one Chemical compound [Cu].CC(O)=CC(C)=O.CC(O)=CC(C)=O ZKXWKVVCCTZOLD-UHFFFAOYSA-N 0.000 claims 5
- 235000011091 sodium acetates Nutrition 0.000 claims 5
- 229910052725 zinc Inorganic materials 0.000 claims 5
- 239000011701 zinc Substances 0.000 claims 5
- 235000013904 zinc acetate Nutrition 0.000 claims 5
- 229910052763 palladium Inorganic materials 0.000 claims 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 3
- 229910052802 copper Inorganic materials 0.000 claims 3
- 239000010949 copper Substances 0.000 claims 3
- 238000004519 manufacturing process Methods 0.000 claims 3
- 239000001301 oxygen Substances 0.000 claims 3
- 229910052760 oxygen Inorganic materials 0.000 claims 3
- 150000002941 palladium compounds Chemical class 0.000 claims 3
- 150000003839 salts Chemical class 0.000 claims 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- 239000012190 activator Substances 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 230000000694 effects Effects 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- QAGCAZIOEZRYMH-UHFFFAOYSA-K [Na+].[Zn++].CC([O-])=O.CC([O-])=O.CC([O-])=O Chemical class [Na+].[Zn++].CC([O-])=O.CC([O-])=O.CC([O-])=O QAGCAZIOEZRYMH-UHFFFAOYSA-K 0.000 claims 1
- 150000001242 acetic acid derivatives Chemical class 0.000 claims 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims 1
- 230000003213 activating effect Effects 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- -1 arsht Chemical group 0.000 claims 1
- 210000000988 bone and bone Anatomy 0.000 claims 1
- 229910052793 cadmium Inorganic materials 0.000 claims 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 230000003993 interaction Effects 0.000 claims 1
- YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 claims 1
- LKOBTUTURSPCEE-UHFFFAOYSA-N pent-1-en-4-yne Chemical group C=CCC#C LKOBTUTURSPCEE-UHFFFAOYSA-N 0.000 claims 1
- 238000007790 scraping Methods 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- 150000003681 vanadium Chemical class 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/16—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU752101054A SU601277A1 (ru) | 1975-01-31 | 1975-01-31 | Способ получени аллилацетата |
| US05/653,375 US4056563A (en) | 1975-01-31 | 1976-01-28 | Method of producing allylacetate |
| DE19762603550 DE2603550A1 (de) | 1975-01-31 | 1976-01-30 | Verfahren zur herstellung von allylacetat |
| FR7602633A FR2299307A1 (fr) | 1975-01-31 | 1976-01-30 | Procede de preparation de l'acetate d'allyle |
| GB4016/76A GB1501041A (en) | 1975-01-31 | 1976-02-02 | Method of preparing allyl acetate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU752101054A SU601277A1 (ru) | 1975-01-31 | 1975-01-31 | Способ получени аллилацетата |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU601277A1 true SU601277A1 (ru) | 1978-04-05 |
Family
ID=20608770
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU752101054A SU601277A1 (ru) | 1975-01-31 | 1975-01-31 | Способ получени аллилацетата |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4056563A (enExample) |
| DE (1) | DE2603550A1 (enExample) |
| FR (1) | FR2299307A1 (enExample) |
| GB (1) | GB1501041A (enExample) |
| SU (1) | SU601277A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4571431A (en) * | 1984-08-20 | 1986-02-18 | Phillips Petroleum Company | Process for the production of allyl acetate |
| US4550097A (en) * | 1984-08-20 | 1985-10-29 | Phillips Petroleum Company | Catalyst for the production of allyl acetate |
| US4587229A (en) * | 1984-10-22 | 1986-05-06 | Phillips Petroleum Company | Catalyst for the production of allyl acetate |
| US4634794A (en) * | 1984-10-22 | 1987-01-06 | Phillips Petroleum Co. | Process for the production of allyl acetate |
| US4647690A (en) * | 1984-10-22 | 1987-03-03 | Phillips Petroleum Company | Process for the production of allyl acetate |
| CN107774306B (zh) * | 2016-08-29 | 2019-12-10 | 中国石油化工股份有限公司 | 醋酸乙烯合成用的催化剂 |
| CN107774304B (zh) * | 2016-08-29 | 2019-11-08 | 中国石油化工股份有限公司 | 醋酸乙烯生产用的催化剂 |
| CN107774305B (zh) * | 2016-08-29 | 2019-12-10 | 中国石油化工股份有限公司 | 醋酸乙烯生产用催化剂 |
| CN107774313B (zh) * | 2016-08-29 | 2020-01-03 | 中国石油化工股份有限公司 | 乙炔法醋酸乙烯合成用催化剂 |
| CN107774337B (zh) * | 2016-08-29 | 2019-12-10 | 中国石油化工股份有限公司 | 天然气合成乙炔法醋酸乙烯所用的催化剂 |
| CN107774308B (zh) * | 2016-08-29 | 2019-12-10 | 中国石油化工股份有限公司 | 醋酸乙烯催化剂 |
| CN107774332B (zh) * | 2016-08-29 | 2019-11-08 | 中国石油化工股份有限公司 | 醋酸乙烯合成用催化剂及其制备方法 |
| CN107774309B (zh) * | 2016-08-29 | 2019-12-10 | 中国石油化工股份有限公司 | 用于合成乙炔法醋酸乙烯所用的催化剂 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3609180A (en) * | 1965-08-27 | 1971-09-28 | Hiroshi Shigematsu | Process for preparing carboxylic acid esters of unsaturated alcohols |
-
1975
- 1975-01-31 SU SU752101054A patent/SU601277A1/ru active
-
1976
- 1976-01-28 US US05/653,375 patent/US4056563A/en not_active Expired - Lifetime
- 1976-01-30 FR FR7602633A patent/FR2299307A1/fr active Granted
- 1976-01-30 DE DE19762603550 patent/DE2603550A1/de not_active Withdrawn
- 1976-02-02 GB GB4016/76A patent/GB1501041A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2603550A1 (de) | 1976-08-05 |
| US4056563A (en) | 1977-11-01 |
| GB1501041A (en) | 1978-02-15 |
| FR2299307B1 (enExample) | 1979-02-02 |
| FR2299307A1 (fr) | 1976-08-27 |
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