SU589884A3 - Herbicide - Google Patents
HerbicideInfo
- Publication number
- SU589884A3 SU589884A3 SU731972713A SU1972713A SU589884A3 SU 589884 A3 SU589884 A3 SU 589884A3 SU 731972713 A SU731972713 A SU 731972713A SU 1972713 A SU1972713 A SU 1972713A SU 589884 A3 SU589884 A3 SU 589884A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- mixture
- dimethyl
- wild oats
- components
- wild
- Prior art date
Links
- 230000002363 herbicidal effect Effects 0.000 title description 5
- 239000004009 herbicide Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 description 19
- 241000196324 Embryophyta Species 0.000 description 7
- 235000007320 Avena fatua Nutrition 0.000 description 6
- 244000075850 Avena orientalis Species 0.000 description 6
- 235000005373 Uvularia sessilifolia Nutrition 0.000 description 6
- 238000012360 testing method Methods 0.000 description 4
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- JARFAUHJHIUGCO-UHFFFAOYSA-N 1,2-dimethyl-3,5-diphenyl-3h-pyrazole Chemical class CN1N(C)C(C=2C=CC=CC=2)C=C1C1=CC=CC=C1 JARFAUHJHIUGCO-UHFFFAOYSA-N 0.000 description 2
- UPMXNNIRAGDFEH-UHFFFAOYSA-N 3,5-dibromo-4-hydroxybenzonitrile Chemical compound OC1=C(Br)C=C(C#N)C=C1Br UPMXNNIRAGDFEH-UHFFFAOYSA-N 0.000 description 2
- 240000008100 Brassica rapa Species 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- SGJNNTYIZXBZQH-UHFFFAOYSA-N 1,2-dimethyl-3,5-diphenyl-1,3-dihydropyrazol-1-ium;methyl sulfate Chemical compound COS([O-])(=O)=O.C[NH+]1N(C)C(C=2C=CC=CC=2)C=C1C1=CC=CC=C1 SGJNNTYIZXBZQH-UHFFFAOYSA-N 0.000 description 1
- FNZBVOIGOZBHCS-UHFFFAOYSA-N 5,5-diphenyl-1,4-dihydropyrazole Chemical compound C1C=NNC1(C=1C=CC=CC=1)C1=CC=CC=C1 FNZBVOIGOZBHCS-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 241000219198 Brassica Species 0.000 description 1
- 235000003351 Brassica cretica Nutrition 0.000 description 1
- 235000011292 Brassica rapa Nutrition 0.000 description 1
- 235000003343 Brassica rupestris Nutrition 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- 239000005489 Bromoxynil Substances 0.000 description 1
- 241001233845 Calepina Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- MXTMXRYBYWOAGX-UHFFFAOYSA-N dimethyl(diphenyl)azanium Chemical compound C=1C=CC=CC=1[N+](C)(C)C1=CC=CC=C1 MXTMXRYBYWOAGX-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 235000010460 mustard Nutrition 0.000 description 1
- 150000002825 nitriles Chemical group 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000001550 testis Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
- A01N39/04—Aryloxy-acetic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
(54) ГЕРБИШДНЫЙ СОСТАВ(54) FOOTBALL COMPOSITION
1one
Изобретение относитс к химическим средствам дл борьбы с сорной и нежелательной растительностью, а именно к гербицидным составам на fxJHoee смесей органических веществ.This invention relates to chemical agents for controlling weeds and undesirable vegetation, namely, herbicidal compositions on fxJHoee mixtures of organic substances.
Известны гербицидные композиции, действующим веществом которых вл етс 3,5-дибром-4-гидрокси-бенаонитрил 11.Herbicidal compositions are known whose active ingredient is 3,5-dibromo-4-hydroxy-benonitrile 11.
Известны также двухкомпонентные гербицчдные составы, одним из компонентов которых вл етс данное соединение. К таким составам относитс , например, состав, действующим началом которого вл етс . смесь, содержаща дигалоий-4-гидроксибензонитрил и диоксид 3-алкил-2,1,3-бензотиааиазинона-4 2j.Bicomponent herbaltic formulations are also known, one of the components of which is this compound. Such compositions include, for example, a composition whose active principle is. a mixture containing dihalo-4-hydroxybenzonitrile and 3-alkyl-2,1,3-benzothia-aiazinone-4 2j dioxide.
Однако известные гербицицные составы данной группы недостаточно эффект1шны.However, the known herbicidal compositions of this group are not sufficiently effective.
Цель изобретени - получение нового гербищицного состава дл одновременного прраж€(ни дикого овса и щироколистннх сорн ков.The purpose of the invention is to obtain a new herbaceous composition for simultaneous predation (neither wild oats and broad weeds).
Эта цель достигаетс тем, что, в качестве азотсодержащего гетероциклическое This goal is achieved by the fact that, as a nitrogen-containing heterocyclic
ГО соеднненн используют соли 1,2-.д метил-3,5-днфеннлпиразолина общей формулыGO compounds use the salts of 1,2-d methyl-3,5-dnfennlpyrazolina of the general formula
СвН5-| СвН5 Ijt;jf ХSvN5- | SvH5 Ijt; jf X
ItIt
СНз СНзSNS SNZ
где X- анион неорганической кислоты ,where X is the anion of the inorganic acid,
а в качестве нитрила замещеннрй бензой« ной кислоты используют 3,5-дибром-4-гидроксибевзонитрнл формулы ОНand 3,5-dibromo-4-hydroxybevzonitrnl of the formula OH is used as the nitrile substituted by benzoic acid;
Весовое соотнощение компонентов смеси находитс в пределах 2-4:1 соответст венно.The weight ratio of the components of the mixture is in the range of 2-4: 1, respectively.
Формы применени описываемого состава обычные: растворы, эмульсии, пасты или порощки. Их готов т известными способами.The form of application of the composition described is usual: solutions, emulsions, pastes or powders. They are prepared by known methods.
Пример. Растени дикого овса выращивали в теплице в специальных щиках до стадии по влени четвертого иcтa После этого листь опрыскивали водным раствором действующего вещества: соль 1,2-диметил 3,5-дифениппиразолива ( в расчете на катион), 3,5- 4и6ром-4-гиарокси бензонитрил и смесь этих двух компонентов . Раствор в каждом случае содержал ОД вес. % поверхн остно-акт liBHoro, веществ ва. Контролем служили необработанные растени . Оценку гербицидного действи проводили через четыре недели после обработки путем срезани и взвешивани листьев, В табл, 1 приведены данные, которые свидетельствуют о совместимости компонентов смеси,.Example. Plants of wild oats were grown in a greenhouse in special boxes until the fourth stage of appearance. After this, the leaves were sprayed with an aqueous solution of the active ingredient: 1,2-dimethyl salt of 3,5-diphenippirasoliva (per cation), 3,5-4,66-4- hyaroxy benzonitrile and a mixture of these two components. The solution in each case contained OD weight. % of surface-act liBHoro, substances wa. Untreated plants served as controls. Evaluation of the herbicidal action was carried out four weeks after treatment by cutting and weighing the leaves. Table 1 shows data that indicate the compatibility of the components of the mixture.
В дальнейших опытах в качестве тестрастений использовали дикий овес, желтую вечерницу, дикую и шаровую горчицу. Было установлено, что при использовании 3,5-с 1ибром-4-гидроксибензонитрила (бромоксинила ) в количестве ОД4 кг/га дикий овес совершенно не повреждаетс , а желта вечерница , дика горчица и шарова горчица полностью уничтожены. Использование солей 1,2-диметил-3,5-дифенилпиразолина в дозе Oj672 кг/га (по катиону) приводит к поражению дикого овса примерно на 8О%. . При использовании смеси указанных выше компонентов достигаетс полное уничтожени широколистных сорн ков и поражение дикого овса примерно на 90%. Результаты йс- питаний представлены в табл. I.In further experiments, wild oats, yellow evening feast, wild and ball mustard were used as testes. It was found that when using 3,5-c 1ibrom-4-hydroxybenzonitrile (bromoxynil) in an amount of OD4 kg / ha, wild oats were not damaged at all, and the yellow evening party, wild mustard and mustard ball were completely destroyed. The use of 1,2-dimethyl-3,5-diphenylpyrazoline salts in a dose of Oj672 kg / ha (by cation) leads to the defeat of wild oats by about 8O%. . When using a mixture of the above components, it is achieved complete destruction of broadleaf weeds and the defeat of wild oats by about 90%. The results of nutrition are presented in table. I.
П р и м е р 2. Полевые испытани смеси соли 1,2-диметил-3,5-дифенилпиразолина (ДМДФП) и 3,5-дибром-4-гидроксибензонитрила . дл уничтожени сорн ков в посевах хлебных злаков.PRI mme R 2. Field testing of a mixture of 1,2-dimethyl-3,5-diphenylpyrazoline salt (DMDPA) and 3,5-dibromo-4-hydroxybenzonitrile. for weed control in cereal crops.
Опытные участки обрабатывали данной смесью ь форме водного раствора после по влени всходов злаков и про влени вных признаков засорени участков сорными растени ми. Оценку эффективности гербицндного состава проводили через один-полтора мес ца после обработки. В табл.2 даны результаты испытаний эффективности смеси и в посевах ровой пшешщы; в табл.3 - в посевах озимой пшеницы; в табл,4 - в посевах чмен .The test plots were treated with this mixture in the form of an aqueous solution after the appearance of seedlings of cereals and the obvious signs of contamination of the plots with weeds. Evaluation of the effectiveness of the herbal composition was carried out one and a half months after treatment. Table 2 presents the results of testing the effectiveness of the mixture in the fields of the harvester; in table 3 - in winter wheat crops; in Table 4, in barley crops.
Т а б л и ц а 1Table 1
1,2-диметил-3,5-дифенилпиразолин метилсульфат0,6721,2-dimethyl-3,5-diphenylpyrazoline methyl sulfate 0.672
1,2«.диметил-3,5-дифенилпиразолин1,2 ".dimethyl-3,5-diphenylpyrazoline
хлоридchloride
ВодаWater
1Д2 1D2
0,43 0,56 1Д2 0.43 0.56 1D2
9999
er 1Д2 0,56 1Д2 0,28 1Д2 0,56er 1D2 0.56 1D2 0.28 1D2 0.56
7979
8989
83 О83 O
Oj672Oj672
86 О86 o
Таблиц а2Table 2
100 97 99 100 97 99
99 98 90 99 99 9999 98 90 99 99 99
9999
ТаблицаЗTable3
I Т а б л и ц а 4I T a b l and c a 4
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US30768972A | 1972-11-17 | 1972-11-17 | |
US00307671A US3857692A (en) | 1972-11-17 | 1972-11-17 | 1,2-dimethyl-3,5-diphenylpyrazolium salts and 3,5-dibromo-4-hydroxybenzonitrile herbicidal compositions |
US307670A US3867403A (en) | 1972-11-17 | 1972-11-17 | 1,2-dialkyl-3,5-diphenylpyrazolium salts |
Publications (1)
Publication Number | Publication Date |
---|---|
SU589884A3 true SU589884A3 (en) | 1978-01-25 |
Family
ID=27405270
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SU731972713A SU589884A3 (en) | 1972-11-17 | 1973-11-16 | Herbicide |
Country Status (21)
Country | Link |
---|---|
JP (1) | JPS5747643B2 (en) |
AR (1) | AR218206A1 (en) |
BR (1) | BR7308966D0 (en) |
CA (1) | CA1049536A (en) |
CH (1) | CH585002A5 (en) |
DD (1) | DD111275A5 (en) |
DE (1) | DE2355242C2 (en) |
DK (1) | DK137665B (en) |
FI (1) | FI55926C (en) |
FR (1) | FR2206907B1 (en) |
GB (1) | GB1454907A (en) |
IE (1) | IE38409B1 (en) |
IL (1) | IL43559A (en) |
IT (1) | IT1047934B (en) |
NL (1) | NL183561C (en) |
NO (1) | NO141184C (en) |
PL (1) | PL93753B1 (en) |
SE (1) | SE421103B (en) |
SU (1) | SU589884A3 (en) |
TR (1) | TR17383A (en) |
YU (1) | YU40095B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0024188A1 (en) * | 1979-08-14 | 1981-02-25 | Fbc Limited | Herbicides that contain difenzoquat |
JPS6227037Y2 (en) * | 1980-10-28 | 1987-07-10 | ||
JPH0516338Y2 (en) * | 1989-03-28 | 1993-04-28 | ||
PL382404A1 (en) * | 2007-05-11 | 2008-11-24 | Zakłady Chemiczne ORGANIKA-SARZYNA Spółka Akcyjna | New ionic vapours comprising (4-chloro-2-methylphenoxy)acetic anion and methods for production thereof |
PL237908B1 (en) * | 2018-02-01 | 2021-06-14 | Przed Produkcyjno Consultingowe Adob Spolka Z Ograniczona Odpowiedzialnoscia Spolka Komandytowa | Herbicidal ionic liquid with 4-chloro-2-methylphenoxyacetic acid anion and eutectic mixture containing it |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2260485C2 (en) * | 1971-12-17 | 1983-12-29 | American Cyanamid Co., Wayne, N.J. | 1,2-dialkyl-3,5-diphenylpyrazolium salts and herbicidal agents containing them |
US3922161A (en) * | 1972-11-17 | 1975-11-25 | American Cyanamid Co | Novel herbicidal compositions |
-
1973
- 1973-10-23 IE IE1903/73A patent/IE38409B1/en unknown
- 1973-10-23 CA CA184,017A patent/CA1049536A/en not_active Expired
- 1973-11-05 IL IL43559A patent/IL43559A/en unknown
- 1973-11-05 DE DE2355242A patent/DE2355242C2/en not_active Expired
- 1973-11-05 AR AR250836A patent/AR218206A1/en active
- 1973-11-06 TR TR17383A patent/TR17383A/en unknown
- 1973-11-08 GB GB5196673A patent/GB1454907A/en not_active Expired
- 1973-11-13 YU YU2922/73A patent/YU40095B/en unknown
- 1973-11-14 BR BR8966/73A patent/BR7308966D0/en unknown
- 1973-11-14 NL NLAANVRAGE7315588,A patent/NL183561C/en not_active IP Right Cessation
- 1973-11-15 CH CH1608673A patent/CH585002A5/xx not_active IP Right Cessation
- 1973-11-15 DK DK618173AA patent/DK137665B/en not_active IP Right Cessation
- 1973-11-16 IT IT53751/73A patent/IT1047934B/en active
- 1973-11-16 SU SU731972713A patent/SU589884A3/en active
- 1973-11-16 NO NO4407/73A patent/NO141184C/en unknown
- 1973-11-16 PL PL1973166588A patent/PL93753B1/en unknown
- 1973-11-16 DD DD174700A patent/DD111275A5/xx unknown
- 1973-11-16 SE SE7315581A patent/SE421103B/en unknown
- 1973-11-16 FR FR7340995A patent/FR2206907B1/fr not_active Expired
- 1973-11-16 FI FI3551/73A patent/FI55926C/en active
- 1973-11-17 JP JP48128815A patent/JPS5747643B2/ja not_active Expired
Also Published As
Publication number | Publication date |
---|---|
BR7308966D0 (en) | 1974-08-22 |
IL43559A (en) | 1978-09-29 |
FI55926B (en) | 1979-07-31 |
TR17383A (en) | 1975-03-24 |
YU292273A (en) | 1982-06-30 |
JPS5747643B2 (en) | 1982-10-12 |
FI55926C (en) | 1979-11-12 |
NL183561B (en) | 1988-07-01 |
JPS504242A (en) | 1975-01-17 |
SE421103B (en) | 1981-11-30 |
DK137665C (en) | 1978-11-20 |
FR2206907B1 (en) | 1977-06-10 |
PL93753B1 (en) | 1977-06-30 |
DE2355242C2 (en) | 1985-08-08 |
NL183561C (en) | 1988-12-01 |
YU40095B (en) | 1985-08-31 |
NO141184B (en) | 1979-10-22 |
FR2206907A1 (en) | 1974-06-14 |
NO141184C (en) | 1980-01-30 |
IE38409L (en) | 1974-05-17 |
IT1047934B (en) | 1980-10-20 |
IE38409B1 (en) | 1978-03-01 |
CH585002A5 (en) | 1977-02-28 |
GB1454907A (en) | 1976-11-10 |
AR218206A1 (en) | 1980-05-30 |
AU6190873A (en) | 1975-05-01 |
DE2355242A1 (en) | 1974-05-22 |
DD111275A5 (en) | 1975-02-12 |
DK137665B (en) | 1978-04-17 |
NL7315588A (en) | 1974-05-21 |
CA1049536A (en) | 1979-02-27 |
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