SU577961A3 - Способ очистки отработанных вод от сульфитов и сульфатов аммони и щелочного металла - Google Patents

Способ очистки отработанных вод от сульфитов и сульфатов аммони и щелочного металла

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Publication number
SU577961A3
SU577961A3 SU7402022198A SU2022198A SU577961A3 SU 577961 A3 SU577961 A3 SU 577961A3 SU 7402022198 A SU7402022198 A SU 7402022198A SU 2022198 A SU2022198 A SU 2022198A SU 577961 A3 SU577961 A3 SU 577961A3
Authority
SU
USSR - Soviet Union
Prior art keywords
iron
sulfates
waste water
alkali metal
removing ammonium
Prior art date
Application number
SU7402022198A
Other languages
English (en)
Inventor
М.Дулин Джеккьюс
Росенберг Гарвей
С.Росар Эдвард
М.Дженко Джозеф
Original Assignee
Индастриал Рисерсез, Инк (Фирма)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by Индастриал Рисерсез, Инк (Фирма) filed Critical Индастриал Рисерсез, Инк (Фирма)
Application granted granted Critical
Publication of SU577961A3 publication Critical patent/SU577961A3/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/507—Sulfur oxides by treating the gases with other liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/008—Sludge treatment by fixation or solidification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S106/00—Compositions: coating or plastic
    • Y10S106/01—Fly ash
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/01—Waste acid containing iron
    • Y10S423/02—Sulfuric acid
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/09—Reaction techniques
    • Y10S423/17—Microbiological reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Treating Waste Gases (AREA)
  • Compounds Of Iron (AREA)
  • Removal Of Specific Substances (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Catalysts (AREA)

Description

(54) СПОСОБ ОЧИСТКИ ОТРАБОТАННЫХ
ВОД ОТ СУЛЬФИТОВ И СУЛЬФАТОВ АММОНИЯ И ЩЕНОЧНОГО
МЕТАЛЛА 1ЮТ соедине1ш  алюми1ш , железа, свинца серебра, 1нка меди и их солей. В качестве источника железа можно использо1ть элементарное железо в виде грунтовых вод с .1СОКИМ содержанием железа, железный лом, альную печную пыль, железосодержащую летучую )лу, железосодержащие отходы городских печей 1  сжигани  мусора, железосодержащий ншам, риты железа из воды после промьшки угл , елезосодержащую рудничную воду. В качестве источника серной кислоты можно потребл ть рудничные и шахтные сточные воды. В случе использовлни  в процессе очистки элегентарного железа или соединений двухвалентного :елеза процесс провод т путем как абиотического, ак и биотического введени  одного или нескольих видов бактерий такого типа, которые окисл }т серу и железо. Дл  зтого используют железобакерии разновидности Тиобациллюс (Ферроксиданс, иооксиданс, Конкретивороус, Неополитанус или иопарус), Ферробациллюс (Феррооксиданс) или сислотоустойчивые нитевидные железобактерии разювидности Металлогениум. Дл  бактериальной актавации через отработан сую воду можно пропускать воздух , При этом получают BOflKbie или безводные немстворимые основные ферро-или алюмогидроксишсульфаты и дисульфиты, преимущественно натэий или аммонийгидроксиферррдиеульфаты, или сме лшнные сульфаты и сульфить, которые отвечают зби (ей формулеv Mv (Na, NH4)w Fex (;Sbu)v (OH)z h HjO , где M - элемент-группы щелочных металлов, кроме натри , и аутогенных металлов, в частности кобальта, магни , марганца, бора, титана, кальци , меди,свинца, цинка, мыщь ка, молибдена, олова, сурьмы, селена, галли , ванади , никел , берилли . циркони , серебра, теллура, висмута, ртути, стронци , бари , хрома, илашны,11алла;иш, алюмини  или урана; V равно 0-6; U 3 или 4; . Тип конечного продукта зависит от величины рИ реакционной массы. Сидеронатрит, NaFe (S04)20H X X SHjO, и/или метасидеронатрит, Na-, Fej {804) 4 (ОН) 2 |зН2О, получают при велитане рН около 2,0, натро розит , ЫаРез(5О4)2 (ОН)б или аммонио розит, МН4Рез{504)2(ОН)б -прирН 1,8-2,5. Депегит, Nas Fe4 (SOjls (504) 2 (ОН) з ЗН2О, роздрит, Ыа2Ре{80з)2(ОР1) ЗН2О, и ириит, NaFe3 (5Оз) 2 (ОН) б, получают при величине рН 2,2 5 ,5. Натроалунит, NaAla (804)2 (ОН) 6. получают при рН 2-4. Катионы, присутствующие в воде, такие как медь, свинец, серебро, цинк соосаждают с упом нутыми натриевыми или аммониевыми соединени ми, в частности с аргето розитом, АдРез (S04) 2 (ОН) , беавиритом, Pb(Cu, Fe, А1)з (804)2 (ОН), плюмбо розитом , PbFe6{S04)4 (OH)i2. Г р и м е р 1. Отработанную воду, содержащую сульфат натри  или аммони , предварительно концентрируют выпариванием. Концентрированный раствор подают в реакционный аппарат, куда ввод т концентрированный раствор соединений железа и/или серной кислоты. Процесс ведут при 54,44°С. Результаты приведены в таблице.
Мол рное
соотношение
Na;Fe
25,6
25,6 25,6
4,0 4,03
реООН
rare т.
Дл  получени  аммонио розита примен ют вместо натри  аммоний. Дп  получени  натроалунита, NaAlj (504)2 (ОН) 6 используют вместо железа алюминий
SU7402022198A 1973-04-23 1974-04-22 Способ очистки отработанных вод от сульфитов и сульфатов аммони и щелочного металла SU577961A3 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US35350873A 1973-04-23 1973-04-23
US05/411,367 US3984312A (en) 1973-04-23 1973-10-31 Process for insolubilizing potentially water pollutable wastes from sodium or ammonium type sulfur dioxide air pollution control systems

Publications (1)

Publication Number Publication Date
SU577961A3 true SU577961A3 (ru) 1977-10-25

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Application Number Title Priority Date Filing Date
SU7402022198A SU577961A3 (ru) 1973-04-23 1974-04-22 Способ очистки отработанных вод от сульфитов и сульфатов аммони и щелочного металла

Country Status (8)

Country Link
US (1) US3984312A (ru)
JP (1) JPS5729240B2 (ru)
CA (1) CA1032673A (ru)
DD (1) DD111359A5 (ru)
DE (1) DE2419606A1 (ru)
FR (1) FR2226200B1 (ru)
GB (1) GB1471594A (ru)
SU (1) SU577961A3 (ru)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111278536A (zh) * 2017-09-13 2020-06-12 Sk新技术株式会社 用于减少二氧化碳和含金属的粉尘的方法

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2328658A1 (fr) * 1975-10-20 1977-05-20 Pechiney Aluminium Perfectionnements a l'epuration de solutions sulfuriques diluees
GB1525553A (en) * 1976-04-19 1978-09-20 American Electronic Lab Method and composition for removing sulphur dioxide from flue gases
US4397742A (en) * 1979-06-20 1983-08-09 Minnick L John Composition and method combining fluidized bed residue with scrubber sludge
ZA807812B (en) * 1979-12-21 1981-12-30 Stablex Ag Treatment of hazardous waste
US4668124A (en) * 1985-04-22 1987-05-26 Engelhard Corporation Disposal of material containing vanadium as landfill
US4726710A (en) * 1986-06-16 1988-02-23 Industrial Resources, Inc. Co-disposal pollution control method
US4832701A (en) * 1986-06-17 1989-05-23 Intevep, S.A. Process for the regeneration of an additive used to control emissions during the combustion of high sulfur fuel
US4735729A (en) * 1986-06-20 1988-04-05 Zimpro Inc. Ash concentration and disposal method
US5082586A (en) * 1988-03-21 1992-01-21 Natec Resources, Inc. SOx NOx pollution control composition
US5069720A (en) * 1988-06-17 1991-12-03 Fuel Tech, Inc. Method and composition for the reduction of ammonia emissions from non-acidic residue
US4844815A (en) * 1988-08-12 1989-07-04 Chemical Waste Management, Inc. Stabilization of mercury-containing waste
US5246273A (en) * 1991-05-13 1993-09-21 Rosar Edward C Method and apparatus for solution mining
GB2250984A (en) * 1992-02-05 1992-06-24 Engelhard Corp Disposal of nitrate waste cake
US5431825A (en) * 1992-10-29 1995-07-11 Chemical Waste Management, Inc. Method for the reduction and stabilization of metals
US5645730A (en) * 1995-02-21 1997-07-08 Envirocorp Services & Technology, Inc. Acid wastewater treatement
US5700107A (en) * 1995-07-25 1997-12-23 Habour Remediation And Transfer Inc. (Hr&T) Method of soil remediation
JP3739480B2 (ja) * 1995-10-31 2006-01-25 栗田工業株式会社 排煙脱硫排水の処理方法
GR1004538B (el) * 1997-04-23 2004-04-22 �. ������ Μεθοδος αφαιρεσης αιωρουμενων σωματιδιων και μειωσης του βοριου απο τα ημιακαθαρτα νερα
GB9725140D0 (en) * 1997-11-27 1998-01-28 Kambanellas Chrysostomos A Method for removing collodial and other suspended particles from lightly pollu ed water
US7481987B2 (en) * 2005-09-15 2009-01-27 Solvay Chemicals Method of removing sulfur trioxide from a flue gas stream
GR1006401B (el) * 2008-01-18 2009-05-26 Νικολαος Νταϊλιανης Αυτονομη, αυτοματη μεταφερομενη μοναδα παραγωγης τρισθενους θειικου σιδηρου για επιτοπια χρηση σαν κροκιδωτικο
CA2874325A1 (en) * 2012-05-22 2013-11-28 Fmc Wyoming Corporation Fly ash and fly ash leachate treatment
CN103950999A (zh) * 2014-03-28 2014-07-30 北京中凯宏德科技有限公司 含硫酸钠废水的除钠方法
US10315943B2 (en) * 2015-04-20 2019-06-11 Arizona Board Of Regents On Behalf Of Arizona State University Methods and systems for pH treatment and extraction of leachable resources and pollutants from sludge
US20180361316A1 (en) * 2015-12-14 2018-12-20 Carmeuse Research And Technology Powdered compostion comprising one or more double salt(s) for use in combustion gas purification
CN108101173A (zh) * 2017-11-30 2018-06-01 重庆庆龙精细锶盐化工有限公司 含硫废水综合处理工艺
CN111847701B (zh) * 2019-04-29 2022-05-03 中冶长天国际工程有限责任公司 一种超高浓度氨氮废水的预处理方法
CN116002642A (zh) * 2022-10-20 2023-04-25 四川龙蟒磷化工有限公司 一种低硫低成本的电池级磷酸铁的制备方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2296423A (en) * 1938-12-07 1942-09-22 Louis F Clark Process for recovering iron and aluminum compounds
US3505008A (en) * 1967-10-30 1970-04-07 Dow Chemical Co Separation of fly ash and sulfur dioxide from flue gases
US3468797A (en) * 1968-03-28 1969-09-23 Diamond Shamrock Corp Pickle liquor disposal
US3763038A (en) * 1970-04-10 1973-10-02 Kurita Water Ind Ltd Process for purifying water that contains organic matter
US3720609A (en) * 1970-04-17 1973-03-13 G & W Corson Inc Process for treating aqueous chemical waste sludges and composition produced thereby
US3617559A (en) * 1970-04-30 1971-11-02 Us Interior Neutralization of ferrous iron-containing acid wastes
US3785840A (en) * 1972-06-05 1974-01-15 Corson G & W H Lime-fly ash-sulfite mixtures
US3859799A (en) * 1973-01-23 1975-01-14 Dravo Corp Landfill disposal of power plant wastes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111278536A (zh) * 2017-09-13 2020-06-12 Sk新技术株式会社 用于减少二氧化碳和含金属的粉尘的方法
CN111278536B (zh) * 2017-09-13 2023-05-02 Sk新技术株式会社 减少二氧化碳和含金属的粉尘的方法

Also Published As

Publication number Publication date
FR2226200B1 (ru) 1980-02-08
FR2226200A1 (ru) 1974-11-15
US3984312A (en) 1976-10-05
AU6808874A (en) 1975-10-23
JPS5729240B2 (ru) 1982-06-21
CA1032673A (en) 1978-06-06
DE2419606A1 (de) 1974-11-21
JPS5014151A (ru) 1975-02-14
GB1471594A (en) 1977-04-27
DD111359A5 (ru) 1975-02-12

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