SU529178A1 - Method of producing ion exchanger - Google Patents

Method of producing ion exchanger

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Publication number
SU529178A1
SU529178A1 SU2116783A SU2116783A SU529178A1 SU 529178 A1 SU529178 A1 SU 529178A1 SU 2116783 A SU2116783 A SU 2116783A SU 2116783 A SU2116783 A SU 2116783A SU 529178 A1 SU529178 A1 SU 529178A1
Authority
SU
USSR - Soviet Union
Prior art keywords
ion exchanger
producing ion
hours
volume
water
Prior art date
Application number
SU2116783A
Other languages
Russian (ru)
Inventor
Станислав Николаевич Ильичев
Маина Павловна Ковалева
Алевтина Александровна Мощевитина
Мария Исаковна Лобова
Original Assignee
Предприятие П/Я А-3699
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Предприятие П/Я А-3699 filed Critical Предприятие П/Я А-3699
Priority to SU2116783A priority Critical patent/SU529178A1/en
Application granted granted Critical
Publication of SU529178A1 publication Critical patent/SU529178A1/en

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  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Description

сополимера при 90-110 С Б точение 12 24 час.copolymer at 90-110 C B turning 12 24 hours.

А чи опо.г;нмер имеет сле.а.юцдукз -i.neivsenrf-ipiiyio  чойку;And chi opo.g; nmer has the following aa.u.-i.neivsenrf-ipiiyio choke;

CH2-CH-C-NHOHCH2-CH-C-NHOH

II оII o

Пример, к 1 00 г пористогс. сополимера метилакрилата с 7% дивииилбеноолп с гранулами размером 0,3-1,0 мм прибавл ют 1200 мл воды, 315 г ч- олшюкислого гидрокси.тамина и постепепио в точелие 12 час 240 г едкого нбгтра, Смес нагре-вают до при перемешивании л выдерживают 24 часа. Охлажденный продукт перенос т на воронку Бюхнера, отдел ют гранулы от маточного раствора к промывают последовательно водой, сол ной кислотой и снова водой до  е тральной реакции промывных вод по метилоранжу,Example, to 1 00 g poristogs. copolymer of methyl acrylate with 7% diviylbenoolp with granules of 0.3-1.0 mm in size, 1200 ml of water, 315 g of hydroxyamine hydrochloride acid and gradually added to 12 hours 240 g of caustic nbgr are added. The mixture is heated until maintain 24 hours. The cooled product is transferred to a Büchner funnel, the granules are separated from the mother liquor and washed successively with water, hydrochloric acid and again with water until the actual reaction of the washing water according to methyl orange,

Анионит, полученный по предложеннс-му ;j.iOco5y, мо ::ст быть использоваг; в гкдромс-таллургическом процессе при очистке медь-;;.инковых растворов от железа.The anion exchanger obtained according to the proposed; j.iOco5y, mo :: st to be used; in the gkdroms-tollurgichesky process during the purification of copper - ;;; incine solutions from iron.

Синтезированный анионит исследуют в модельном растворе, содержащем (в г/л) Си .- 1,06 In - 1,03: The synthesized anion exchange resin is examined in a model solution containing (in g / l) Cu. - 1.06 In - 1.03:

11,2. 11.2.

Услови  исследованк : Объем исходного раствора Test conditions: Volume of initial solution

100 M-i, Объем набухшей смолы 3 мл, Врем  контакта анионита 24 ч ( из них 8 час непрерыв™100 M-i, The volume of the swollen resin 3 ml, The contact time of anion exchange resin 24 hours (of which 8 hours of continuous ™

перемешивание в терме-стате при 18-2О°С). Рабоча  форма антлскчта 5Од. Статическа  обменна  емкость до хлориону и.з ОД н раствора соллгюй кис.лоты 6,4 мг экв/г; удс;льньш объем 5,6 мг/г, осмотическа  :табильн;:)сть ..mixing in a term-stat at 18-2 ° C). Antlskchta 5Od working form. Static exchange capacity to chlorion and OD of one solution of solvent solution of 6.4 mg eq / g; uds; linsh volume is 5.6 mg / g, osmotic: tabl; :) st ..

Сравнительние данные нокотс.рых свойств гфедложенного анионита и ГЭБОСТНОГО ионита приведены в таблице.The comparative data of the knockdown properties of aerated anion exchanger and HEBOST ion exchanger are shown in the table.

Сорбировало Си in Fe(H)Sorbed Cu in Fe (H)

Ге (III)Ge (III)

рНpH

SU2116783A 1975-03-24 1975-03-24 Method of producing ion exchanger SU529178A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU2116783A SU529178A1 (en) 1975-03-24 1975-03-24 Method of producing ion exchanger

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU2116783A SU529178A1 (en) 1975-03-24 1975-03-24 Method of producing ion exchanger

Publications (1)

Publication Number Publication Date
SU529178A1 true SU529178A1 (en) 1976-09-25

Family

ID=20613753

Family Applications (1)

Application Number Title Priority Date Filing Date
SU2116783A SU529178A1 (en) 1975-03-24 1975-03-24 Method of producing ion exchanger

Country Status (1)

Country Link
SU (1) SU529178A1 (en)

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