SU524519A3 - The method of obtaining Tris = (2-chloroethyl) = phosphite - Google Patents
The method of obtaining Tris = (2-chloroethyl) = phosphiteInfo
- Publication number
- SU524519A3 SU524519A3 SU1955015A SU1955015A SU524519A3 SU 524519 A3 SU524519 A3 SU 524519A3 SU 1955015 A SU1955015 A SU 1955015A SU 1955015 A SU1955015 A SU 1955015A SU 524519 A3 SU524519 A3 SU 524519A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- chloroethyl
- phosphite
- tris
- ethylene oxide
- obtaining tris
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 3
- 125000001340 2-chloroethyl group Chemical group [H]C([H])(Cl)C([H])([H])* 0.000 title 1
- 239000007983 Tris buffer Substances 0.000 title 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 title 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 title 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 3
- LUVCTYHBTXSAMX-UHFFFAOYSA-N tris(2-chloroethyl) phosphite Chemical compound ClCCOP(OCCCl)OCCCl LUVCTYHBTXSAMX-UHFFFAOYSA-N 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- -1 phosphorous ester Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
- C07F9/1411—Esters of phosphorous acids with hydroxyalkyl compounds with further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
Description
1one
Изобретение относитс к получению эфирОБ фосфористой кислоты, а именно к улучшенному способу получени трис-(2-хлоэтил )-фосфйта формулыThis invention relates to the production of phosphorous ester OB, namely, an improved process for the preparation of a tris (2-chloroethyl) phosphite of formula
(ClCHgCH OjP.(ClCHgCH OjP.
Это соединение используетс дл производства фосфорорганических термостабилизаторов полимеров и огнестойких добавок к различным веществам.This compound is used to produce organophosphorus thermostabilizers for polymers and flame retardants for various substances.
Известен способ получени трис-(2-хлорэтил )-фосфита взаимодействием треххлористого фосфора с окисью этилена; про1дукт образуетс с высоким выходом, но почти неизменно содержит относительноA known method for producing tris- (2-chloroethyl) phosphite by reacting phosphorus trichloride with ethylene oxide; The product is formed with a high yield, but almost invariably contains relatively
высокое количество (более 5%) фосфонастов в качестве побочных продуктов реакции . Эти примеси трудно отделить от трис (2-хлорэтил)-фосфита, поэтому они остаютс и в продуктах переработки, используемых в промышленности, и оказывают неблагопри тное действие на свойства этих продуктов.high amount (more than 5%) of phosphonasts as by-products of the reaction. These impurities are difficult to separate from tris (2-chloroethyl) phosphite, therefore they remain in the processed products used in industry and have an adverse effect on the properties of these products.
С целью повышени чистоты продукта ПJpoцecc взаимодействи треххлористого фосIn order to increase the purity of the product PJpocecc, the interaction of phosphorus trichloride
фора с окисью этилена провод т в среде дихлорэтана. Этот растворитель позвол ет понизить содержание побочных продуктов в трис-(2-хлорэтил)-фосфата до уровн ниже 5%.The ethylene oxide cortice is carried out in dichloroethane. This solvent allows the content of by-products in Tris (2-chloroethyl) phosphate to be reduced to a level below 5%.
Реагенты ввод т обычно в стехиометрическом количестве но можно примен ть небольшой избыток или недостаток окиси этилена. Реакци лучше всего идет при температуре, не превышающей 45 С.The reagents are usually introduced in stoichiometric amounts, but a slight excess or deficiency of ethylene oxide can be used. The reaction goes best at a temperature not exceeding 45 C.
Процесс желательно проводить путем растворени треххлористого фосфора в дихлорэтане , затем постепенно добавл к нему окись этилена. Последнюю можно вводить в виде раствора в дихлорэтане,The process is preferably carried out by dissolving phosphorus trichloride in dichloroethane, then gradually adding ethylene oxide to it. The latter can be introduced in the form of a solution in dichloroethane,
Добавление окиси этилена должно производитьс быстро и позвол ть поддерживать температуру реакционной среды в желаемых пределах. Предпочтительно заканчивать добавление окиси этилена не больше п ти часов, лучше всего не дольше одного часа.The addition of ethylene oxide should be carried out quickly and keep the temperature of the reaction medium within the desired limits. It is preferable to finish adding ethylene oxide for no more than five hours, preferably no longer than one hour.
Дихлорэтан можно добавл ть в любом количестве, однако лучше от 50 до 10ОО вес. ч. на каждые 1ОО вес. ч. общего коDichloroethane can be added in any amount, however, preferably from 50 to 10OO weight. hours for every 1OO weight. h. general co
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28397372A | 1972-08-25 | 1972-08-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU524519A3 true SU524519A3 (en) | 1976-08-05 |
Family
ID=23088365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1955015A SU524519A3 (en) | 1972-08-25 | 1973-08-21 | The method of obtaining Tris = (2-chloroethyl) = phosphite |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS4962425A (en) |
| BE (1) | BE804011A (en) |
| CA (1) | CA989860A (en) |
| DE (1) | DE2338005A1 (en) |
| ES (1) | ES418151A1 (en) |
| FR (1) | FR2197009B1 (en) |
| GB (1) | GB1393223A (en) |
| IT (1) | IT990049B (en) |
| NL (1) | NL7311176A (en) |
| SU (1) | SU524519A3 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113968880B (en) * | 2021-11-12 | 2024-05-28 | 上海华谊（集团）公司 | Preparation method of tris- (2-chloroethyl) phosphite ester |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE790849Q (en) * | 1970-02-02 | 1973-04-30 | Olin Corp | NEW HALOGENIC PHOSPHORIC POLYESTERS FLAMMATION RETARDERS AND POLYURETHANE FOAM CONTAINING THESE POLYESTERS |
-
1973
- 1973-06-14 CA CA174,102A patent/CA989860A/en not_active Expired
- 1973-07-26 DE DE19732338005 patent/DE2338005A1/en active Pending
- 1973-07-27 IT IT5170373A patent/IT990049B/en active
- 1973-07-31 FR FR7327976A patent/FR2197009B1/fr not_active Expired
- 1973-08-14 NL NL7311176A patent/NL7311176A/xx unknown
- 1973-08-21 SU SU1955015A patent/SU524519A3/en active
- 1973-08-23 JP JP9395873A patent/JPS4962425A/ja active Pending
- 1973-08-23 GB GB4003273A patent/GB1393223A/en not_active Expired
- 1973-08-24 BE BE134924A patent/BE804011A/en unknown
- 1973-08-24 ES ES418151A patent/ES418151A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE804011A (en) | 1974-02-25 |
| NL7311176A (en) | 1974-02-27 |
| DE2338005A1 (en) | 1974-03-07 |
| FR2197009A1 (en) | 1974-03-22 |
| ES418151A1 (en) | 1976-03-16 |
| IT990049B (en) | 1975-06-20 |
| CA989860A (en) | 1976-05-25 |
| GB1393223A (en) | 1975-05-07 |
| FR2197009B1 (en) | 1977-02-25 |
| JPS4962425A (en) | 1974-06-17 |
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