SU486063A1 - The method of purification of cobalt solutions from manganese - Google Patents

The method of purification of cobalt solutions from manganese

Info

Publication number
SU486063A1
SU486063A1 SU1971121A SU1971121A SU486063A1 SU 486063 A1 SU486063 A1 SU 486063A1 SU 1971121 A SU1971121 A SU 1971121A SU 1971121 A SU1971121 A SU 1971121A SU 486063 A1 SU486063 A1 SU 486063A1
Authority
SU
USSR - Soviet Union
Prior art keywords
manganese
purification
cobalt
cobalt solutions
solutions
Prior art date
Application number
SU1971121A
Other languages
Russian (ru)
Inventor
Леонид Александрович Казанский
Борис Георгиевич Гулевич
Георгий Айзикович Лифшиц
Татьяна Борисовна Собиева
Original Assignee
Всесоюзный научно-исследовательский и конструкторский институт "Цветметавтоматика"
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Всесоюзный научно-исследовательский и конструкторский институт "Цветметавтоматика" filed Critical Всесоюзный научно-исследовательский и конструкторский институт "Цветметавтоматика"
Priority to SU1971121A priority Critical patent/SU486063A1/en
Application granted granted Critical
Publication of SU486063A1 publication Critical patent/SU486063A1/en

Links

Description

Корректировка рН реакционной среды водой существенно уменьшает возникновение очаговых зон с повышенным значением рН, что наблюдаетс  при нейтрализации пульпы щелочным агентом, и повышает селективность осаждени  гидроокиси марганца.Adjusting the pH of the reaction medium with water significantly reduces the occurrence of focal zones with an increased pH value, which is observed when the pulp is neutralized with an alkaline agent, and increases the selectivity of precipitating manganese hydroxide.

Пульпу осажденной гидроокиси марганца через буферную емкость непрерывно перекачивают на фильтрацию, причем величина расхода пульпы на фильтрацию автоматически согласовываетс  с подачей раствора на очистку .The pulp of precipitated manganese hydroxide through the buffer tank is continuously pumped to the filtration, and the filtration flow rate of the pulp is automatically coordinated with the supply of the solution for cleaning.

ПрИменение описываемого способа позвол ет оптимизировать услови  процесса и практически исключить соосаждение кобальта с гидроокисью марганца.The use of the described method allows to optimize the process conditions and practically exclude the co-precipitation of cobalt with manganese hydroxide.

Предмет изобретени Subject invention

Способ очистки кобальтовых растворов от ма рганца, включающий окисление марганцаThe method of purification of cobalt solutions from manganese, including the oxidation of manganese

газообразным хлором и осаждение его в виде гидроокиси при рН 1,0-1,8, отличающийс  тем, что, с целью снижени  содержани  кобальта в гидроокиси .марганца, сокращени  расхода реагентов и оптимизации условийgaseous chlorine and precipitating it as a hydroxide at a pH of 1.0-1.8, characterized in that, in order to reduce the cobalt content in the manganese hydroxide, reduce the consumption of reagents and optimize conditions

очистки кобальтового раствора от марганца рН подаваемого на очистку раствора довод т до 1,4-1,6, величину окислительно-восстановительного потенциала среды при окислении марганца поддерживают в пределах 1000-cleaning the cobalt solution from manganese, the pH of the solution supplied to the purification is adjusted to 1.4-1.6, the value of the redox potential of the medium during the oxidation of manganese is maintained within 1000-

1100 МБ относительно платинового и водородного электродов подачей газообразного хлора , а рН гидролиза марганца-добавлением воды.1100 MB relative to the platinum and hydrogen electrodes supplying chlorine gas, and the pH of the hydrolysis of manganese-the addition of water.

SU1971121A 1973-11-20 1973-11-20 The method of purification of cobalt solutions from manganese SU486063A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU1971121A SU486063A1 (en) 1973-11-20 1973-11-20 The method of purification of cobalt solutions from manganese

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU1971121A SU486063A1 (en) 1973-11-20 1973-11-20 The method of purification of cobalt solutions from manganese

Publications (1)

Publication Number Publication Date
SU486063A1 true SU486063A1 (en) 1975-09-30

Family

ID=20567899

Family Applications (1)

Application Number Title Priority Date Filing Date
SU1971121A SU486063A1 (en) 1973-11-20 1973-11-20 The method of purification of cobalt solutions from manganese

Country Status (1)

Country Link
SU (1) SU486063A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000056943A1 (en) * 1999-03-24 2000-09-28 Lakefield Research Limited Purification of cobalt solutions containing iron and manganese with oxidation mixture of s02 and oxygen

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000056943A1 (en) * 1999-03-24 2000-09-28 Lakefield Research Limited Purification of cobalt solutions containing iron and manganese with oxidation mixture of s02 and oxygen

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