SU458539A1 - The method of obtaining -vinylacetylene alcohols - Google Patents
The method of obtaining -vinylacetylene alcoholsInfo
- Publication number
- SU458539A1 SU458539A1 SU1932803A SU1932803A SU458539A1 SU 458539 A1 SU458539 A1 SU 458539A1 SU 1932803 A SU1932803 A SU 1932803A SU 1932803 A SU1932803 A SU 1932803A SU 458539 A1 SU458539 A1 SU 458539A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- obtaining
- alcohols
- vinylacetylene
- calculated
- found
- Prior art date
Links
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
ЛИЗ насыщенным раствором , далее экстрагируют эфиром и высушивают над MgSO4. После отгонки эфира остаток в токе азота перегон ют в вакууме.LIZ with a saturated solution, then extracted with ether and dried over MgSO4. After distilling off the ether, the residue in a stream of nitrogen is distilled in vacuo.
Получено 9,31 г (61,25%) 5, 5, 6-триметилгептен-1-ин-3-ола-5; т. кип. 48-5071 мм, п9.31 g (61.25%) of 5, 5, 6-trimethylhepten-1-yn-3-ol-5; m.p. 48-5071 mm, n
1,4740, й2°4 0,8600.1.4740, d2 ° 4 0.8600.
CioHieO.CioHieO.
Вычислено, %: С 78,99; Н 10,52.Calculated,%: C 78.99; H 10.52.
Найдено, %: С 78,27, Н 10,38.Found,%: C 78.27, H 10.38.
MRo найдено 49,40; вычислено 47,75.MRo found 49.40; calculated 47.75.
Пример 2. Аналогично вышеописанному из 2,4 г магни , 12,8 г диметилвинилэтинилхлорметана и 10,5 г циклогексанона получено 9 г (43,4%) 4-(1-оксициклогексил-1)-5-метилгексен-1 ина-3, т. кип. 98-100711 мм; пExample 2. Similarly to the above, 9 g (43.4%) of 4- (1-hydroxycyclohexyl-1) -5-methylhexene-1 ina-3 was obtained from 2.4 g of magnesium, 12.8 g of dimethylvinyl ethynyl chloromethane and 10.5 g of cyclohexanone. , t. kip. 98-100711 mm; P
1,5100; й;204 0,9600.1,5100; st; 204 0.9600.
CisHsoO.CisHsoO.
Найдено, %: С 80,94; Н 10,8. Вычислено, %: С 8175; Н 10,24. MRo найдено 59,88; вычислено 59,08.Found,%: C 80.94; H 10.8. Calculated,%: C 8175; H 10.24. MRo found 59.88; calculated 59.08.
П р и м е р 3. Из 24 г магни , 12,8 г диметилвинилэтинилхлорметана и 7,8 г изомасл ного альдегида получено 9,8 г (59,02%) 5, 5, 7-триметилоктен-1-ин-3-ола-6, т. кип. 68 - -7073 мм; п20 1,4810; 0,9200.PRI me R 3. From 24 g of magnesium, 12.8 g of dimethylvinyl ethynyl chloromethane and 7.8 g of isobutyraldehyde, 9.8 g (59.02%) of 5, 5, 7-trimethylotene-1-yn were obtained. -ola-6, t. Kip. 68 - -7073 mm; p20 1.4810; 0.9200.
CnHi/O.CnHi / O.
Найдено, %: С 78,90, Н 10,80. Вычислено, %: С 79,99; Н 10,84. MR0 найдено 50,83, вычислено 50,93.Found,%: C 78.90, H 10.80. Calculated,%: C 79.99; H 10.84. MR0 found 50.83, calculated 50.93.
Предмет изобретени Subject invention
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SU1932803A SU458539A1 (en) | 1973-06-08 | 1973-06-08 | The method of obtaining -vinylacetylene alcohols |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SU1932803A SU458539A1 (en) | 1973-06-08 | 1973-06-08 | The method of obtaining -vinylacetylene alcohols |
Publications (1)
Publication Number | Publication Date |
---|---|
SU458539A1 true SU458539A1 (en) | 1975-01-30 |
Family
ID=20556770
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SU1932803A SU458539A1 (en) | 1973-06-08 | 1973-06-08 | The method of obtaining -vinylacetylene alcohols |
Country Status (1)
Country | Link |
---|---|
SU (1) | SU458539A1 (en) |
-
1973
- 1973-06-08 SU SU1932803A patent/SU458539A1/en active
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