SU440377A1 - The method of rubber regeneration - Google Patents

The method of rubber regeneration

Info

Publication number
SU440377A1
SU440377A1 SU1813505A SU1813505A SU440377A1 SU 440377 A1 SU440377 A1 SU 440377A1 SU 1813505 A SU1813505 A SU 1813505A SU 1813505 A SU1813505 A SU 1813505A SU 440377 A1 SU440377 A1 SU 440377A1
Authority
SU
USSR - Soviet Union
Prior art keywords
rubber
regenerate
regeneration
rubber regeneration
phenylenediamine
Prior art date
Application number
SU1813505A
Other languages
Russian (ru)
Inventor
Владимир Федорович Бочаров
Михаил Ефремович Романович
Сергей Михайлович Григорович
Original Assignee
Днепропетровский Филиал Научно-Исследовательского Института Строительного Производства
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Днепропетровский Филиал Научно-Исследовательского Института Строительного Производства filed Critical Днепропетровский Филиал Научно-Исследовательского Института Строительного Производства
Priority to SU1813505A priority Critical patent/SU440377A1/en
Application granted granted Critical
Publication of SU440377A1 publication Critical patent/SU440377A1/en

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Landscapes

  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Description

1one

Изобретение относитс  к регенерации резин на основе бутилкаучука, вулканизованного смолами.This invention relates to the regeneration of butyl rubber-based rubber, a vulcanized resin.

Известны способы регенерации резин на основе бутилкаучука с использованием в качестве активаторов галогенсодержащих кетонов и ароматических соединений.Known methods for the regeneration of rubber based on butyl rubber using halogen-containing ketones and aromatic compounds as activators.

Недостатком применени  данных активаторов  вл ютс  невысокие физико-механические показатели получаемого регенерата.The disadvantage of using these activators is the low physicomechanical characteristics of the resulting regenerate.

Цель изобретени  - использование в качестве активатора дл  регенерации резин на основе бутилкаучука М-фенил-М-изопропил-п.фенилепдиамина , обеспечивающего повышение физико-механических и пласто-эластических показателей регенерата.The purpose of the invention is to use as an activator for the regeneration of rubber based on the butyl rubber M-phenyl-M-isopropyl-p. Phenylenediamine, which improves the physico-mechanical and plasto-elastic parameters of the regenerate.

Способ заключаетс  в следующем. К ЮО вес. ч. отработанной или бракованной резины на основе бутилкаучука, вулканизированного смолами, предварительно раздробленной на дробильных вальцах добавл ют 2-4 вес. ч. М-фепил-Ы-изоиропил-п-фенилендиамина.The method is as follows. To Yuo weight. Part of waste or rejected rubber based on butyl rubber, vulcanized with resins, previously crushed on the crushing rolls, add 2-4 weight. h. M-phenyl-N-isoyl propyl-p-phenylenediamine.

Смесь нагревают в воздушной среде при 120-140°С в течение 2-3 час, после чего дерулканизат обрабатывают на гладких вальцах .The mixture is heated in air at 120-140 ° C for 2-3 hours, after which the devulcanate is treated on smooth rollers.

Пример. Резиновую диафрагму, использовавшуюс  при вулканизации шин разрезают на куски. Куски пропускают через вальцы с рифленой поверхностью валков. Образующуюс  при этом щерщавую дробленую шкурку весом 10 кг пропускают несколько раз через гладкие вальцы, где добавл ют 300 г N-фенил - N-изопропил - п - фенилендиамина. Полученную в виде листа смесь помещают вExample. The rubber diaphragm used to vulcanize tires is cut into pieces. Pieces are passed through rollers with a grooved roll surface. The resulting crushed crushed pelt weighing 10 kg is passed several times through smooth rollers, where 300 g of N-phenyl-N-isopropyl-p-phenylenediamine are added. The mixture obtained in the form of a sheet is placed in

сушильный шкаф, где выдерживают при 135°С в течение 2,5 час.drying oven, where it is maintained at 135 ° C for 2.5 hours.

После прогрева девулканизат обрабатывают на гладких вальцах до получени  ровногоAfter heating, the devulcanizate is processed on smooth rollers until an even

блест щего полотна.shiny canvas.

Дл  определени  физико-механических показателей регенерата на лабораторных вальцах готов т смесь следующего состава (вес. ч.): регенерат - 100,0; белила цинковые-5 ,0; тиурам-1,0; каптакс-0,5; сера- 2,0; режим вулканизации составл ет 30 мин при 160°С.To determine the physico-mechanical parameters of the regenerate, a mixture of the following composition (weight h) is prepared on laboratory rolls: regenerate - 100.0; zinc white-5, 0; thiuram-1.0; captax-0.5; sulfur - 2.0; vulcanization is 30 minutes at 160 ° C.

Свойства полученного регенерата в сравнеНИИ с регенератом известного способа привод тс  в таблице.The properties of the obtained regenerate in comparison with the regenerate of a known method are listed in the table.

Предмет изобретени Subject invention

Способ регенерации резин на основе бутилкаучука , вулканизованного смолами, в присутствии активатора, отличающийс  тем, что, с целью улучшени  свойств регенерата, в качестве активатора используетс  Ы-фенил-Ыизопропил-п-фенилендиамин .A method of regenerating rubber based on butyl rubber, vulcanized with resins, in the presence of an activator, characterized in that, in order to improve the properties of the regenerate, L-phenyl-Yisopropyl-p-phenylenediamine is used as an activator.

SU1813505A 1972-07-21 1972-07-21 The method of rubber regeneration SU440377A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU1813505A SU440377A1 (en) 1972-07-21 1972-07-21 The method of rubber regeneration

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU1813505A SU440377A1 (en) 1972-07-21 1972-07-21 The method of rubber regeneration

Publications (1)

Publication Number Publication Date
SU440377A1 true SU440377A1 (en) 1974-08-25

Family

ID=20522770

Family Applications (1)

Application Number Title Priority Date Filing Date
SU1813505A SU440377A1 (en) 1972-07-21 1972-07-21 The method of rubber regeneration

Country Status (1)

Country Link
SU (1) SU440377A1 (en)

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SU433165A1 (en) METHOD OF REGENERATION OF RUBBER1 This invention relates to methods for regenerating rubber based on butyl rubber, vulcanized with resins, using activators. Methods are known to regenerate vulcanized butyl rubber using activators, for example, alkylphenol disulfide, halogen-containing patterns, and body patterns and aromatics and aromatics with the use of activators; as well as improving the quality of the regenerate, it is proposed to use as an activator in the regeneration of butyl rubber, vulcanized with resins, diphenylguanium Din. The method consists in the following. To 100 weight. Part of waste or rejected rubber based on butyl rubber, vulcanized with resins, previously crushed on the crushing rollers, add 2-4 weight. including activator of destruction - diphenylguanidine known method. The mixture is heated in an air or vapor-air environment at a temperature of 160-180 ° C for 2-3 hours. After heating, the devulcanized product is subjected to additional mechanical treatment to homogenize and purify the impurities and part of the slightly devulcanised rubber. Example. The butyl rubber rubber diaphragm used in the vulcanization of tires is cut into pieces and passed through rollers with a grooved roll surface. The resulting sheet is placed in a laboratory autoclave, where it is kept at 180 ° C for 2 hours. After heating, the devulcanate is processed on smooth rollers until an even gloss is obtained. The properties of the floor epnogo regenerator to regenerate in comparison with the known method shown in tablitse.15
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