SU436497A3 - Способ получения высокомолекулярнб1хполидиенов - Google Patents
Способ получения высокомолекулярнб1хполидиеновInfo
- Publication number
- SU436497A3 SU436497A3 SU1607853A SU1607853A SU436497A3 SU 436497 A3 SU436497 A3 SU 436497A3 SU 1607853 A SU1607853 A SU 1607853A SU 1607853 A SU1607853 A SU 1607853A SU 436497 A3 SU436497 A3 SU 436497A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- polymer
- catalyst
- polymerization
- aluminum
- atoms
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 9
- 229920000642 polymer Polymers 0.000 description 21
- 239000003054 catalyst Substances 0.000 description 19
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 13
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 12
- 238000006116 polymerization reaction Methods 0.000 description 11
- 229920001195 polyisoprene Polymers 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 150000001993 dienes Chemical class 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- -1 aluminum imine Chemical class 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 238000004566 IR spectroscopy Methods 0.000 description 2
- 229910010165 TiCu Inorganic materials 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 1
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 1
- 208000004998 Abdominal Pain Diseases 0.000 description 1
- 208000002881 Colic Diseases 0.000 description 1
- 241001441571 Hiodontidae Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910021380 Manganese Chloride Inorganic materials 0.000 description 1
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910021551 Vanadium(III) chloride Inorganic materials 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- FJDJVBXSSLDNJB-LNTINUHCSA-N cobalt;(z)-4-hydroxypent-3-en-2-one Chemical compound [Co].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O FJDJVBXSSLDNJB-LNTINUHCSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- CJSBUWDGPXGFGA-UHFFFAOYSA-N dimethyl-butadiene Natural products CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229940099607 manganese chloride Drugs 0.000 description 1
- 235000002867 manganese chloride Nutrition 0.000 description 1
- 239000011565 manganese chloride Substances 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Confectionery (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1965270 | 1970-01-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU436497A3 true SU436497A3 (ru) | 1974-07-15 |
Family
ID=11160084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1607853A SU436497A3 (ru) | 1970-01-22 | 1971-01-19 | Способ получения высокомолекулярнб1хполидиенов |
Country Status (17)
| Country | Link |
|---|---|
| JP (1) | JPS5117996B1 (enExample) |
| AT (1) | AT307724B (enExample) |
| BE (1) | BE761741A (enExample) |
| CA (1) | CA974347A (enExample) |
| CS (3) | CS167301B2 (enExample) |
| DK (1) | DK142952C (enExample) |
| ES (1) | ES387782A1 (enExample) |
| FR (1) | FR2075698A5 (enExample) |
| GB (1) | GB1285164A (enExample) |
| HU (2) | HU165429B (enExample) |
| LU (1) | LU62461A1 (enExample) |
| NL (1) | NL168528C (enExample) |
| NO (1) | NO134119C (enExample) |
| RO (2) | RO66745A (enExample) |
| SE (2) | SE376620B (enExample) |
| SU (1) | SU436497A3 (enExample) |
| YU (2) | YU34573B (enExample) |
-
1971
- 1971-01-04 CA CA102,137A patent/CA974347A/en not_active Expired
- 1971-01-15 CS CS31071A patent/CS167301B2/cs unknown
- 1971-01-15 CS CS856774A patent/CS182824B2/cs unknown
- 1971-01-15 CS CS856674A patent/CS167302B2/cs unknown
- 1971-01-18 YU YU11071A patent/YU34573B/xx unknown
- 1971-01-19 FR FR7101620A patent/FR2075698A5/fr not_active Expired
- 1971-01-19 BE BE761741A patent/BE761741A/xx not_active IP Right Cessation
- 1971-01-19 ES ES387782A patent/ES387782A1/es not_active Expired
- 1971-01-19 SU SU1607853A patent/SU436497A3/ru active
- 1971-01-21 NO NO21971A patent/NO134119C/no unknown
- 1971-01-21 HU HUSA002163 patent/HU165429B/hu unknown
- 1971-01-21 HU HUSA002248 patent/HU165430B/hu unknown
- 1971-01-21 LU LU62461D patent/LU62461A1/xx unknown
- 1971-01-21 DK DK25771A patent/DK142952C/da not_active IP Right Cessation
- 1971-01-22 NL NL7100919A patent/NL168528C/xx not_active IP Right Cessation
- 1971-01-22 RO RO7177529A patent/RO66745A/ro unknown
- 1971-01-22 AT AT54271A patent/AT307724B/de not_active IP Right Cessation
- 1971-01-22 RO RO6568371A patent/RO59995A/ro unknown
- 1971-01-22 JP JP46001658A patent/JPS5117996B1/ja active Pending
- 1971-01-22 SE SE77371A patent/SE376620B/xx unknown
- 1971-04-19 GB GB2041371A patent/GB1285164A/en not_active Expired
-
1974
- 1974-04-05 SE SE7404656A patent/SE416207B/sv not_active IP Right Cessation
-
1977
- 1977-07-08 YU YU170077A patent/YU39052B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DK142952B (da) | 1981-03-02 |
| CS167301B2 (enExample) | 1976-04-29 |
| DK142952C (da) | 1981-10-05 |
| ES387782A1 (es) | 1974-01-01 |
| DE2102964B2 (de) | 1976-12-09 |
| YU39052B (en) | 1984-02-29 |
| BE761741A (fr) | 1971-07-01 |
| FR2075698A5 (enExample) | 1971-10-08 |
| JPS5117996B1 (enExample) | 1976-06-07 |
| NO134119B (enExample) | 1976-05-10 |
| DE2102964A1 (enExample) | 1971-08-19 |
| NO134119C (enExample) | 1976-08-18 |
| CS182824B2 (en) | 1978-05-31 |
| CA974347A (en) | 1975-09-09 |
| NL168528C (nl) | 1982-04-16 |
| YU34573B (en) | 1979-10-31 |
| HU165429B (enExample) | 1974-08-28 |
| CS167302B2 (enExample) | 1976-04-29 |
| NL7100919A (enExample) | 1971-07-26 |
| SE376620B (enExample) | 1975-06-02 |
| GB1285164A (en) | 1972-08-09 |
| RO66745A (ro) | 1981-01-30 |
| RO59995A (enExample) | 1976-05-15 |
| LU62461A1 (enExample) | 1971-08-27 |
| YU11071A (en) | 1979-04-30 |
| YU170077A (en) | 1982-06-30 |
| SE416207B (sv) | 1980-12-08 |
| HU165430B (enExample) | 1974-08-28 |
| AT307724B (de) | 1973-06-12 |
| NL168528B (nl) | 1981-11-16 |
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