GB1285164A - Polyiminoalanes, preparation of the same, catalysts containing the polyiminoalanes, and polymerisation employing these catalysts - Google Patents
Polyiminoalanes, preparation of the same, catalysts containing the polyiminoalanes, and polymerisation employing these catalystsInfo
- Publication number
- GB1285164A GB1285164A GB2041371A GB2041371A GB1285164A GB 1285164 A GB1285164 A GB 1285164A GB 2041371 A GB2041371 A GB 2041371A GB 2041371 A GB2041371 A GB 2041371A GB 1285164 A GB1285164 A GB 1285164A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyiminoalanes
- polymerisation
- catalysts
- ticl
- aluminium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Confectionery (AREA)
Abstract
1285164 Polymerisation catalysts SNAM PROGETTI SpA 19 April 1971 [22 Jan 1970] 20413/71 Heading B1E [Also in Division C3] A catalytic system suitable for use in the stereospecific polymerisation of conjugated dienes comprises a polyimine of aluminium having the repeating unit where R is an alkyl, cycloalkyl or aryl radical, n is an integer and some of X are halogen atoms, the remainder being hydrogen atoms, in association with a compound of a Group IV to VIII transition metal such as TiCl 4 , TiI 4 , TiBr 4 , VCl 3 , ZrCl 4 , chloride of Co, Mn or Ni and cobalt acetylacetonate. In the polymerisation process the catalytic system may be preformed either by reacting the aluminium iminic polymer with the transition metal compound or it may be formed in situ by reacting the two catalytic components in the presence of the polymerisable monomer. In a particular example isoprene is polymerised to the 1, 4 cis polymer using a catalyst consisting of partially chlorinated polyiminoalane and TiCl 4 in an hydrous n-hexane.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1965270 | 1970-01-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1285164A true GB1285164A (en) | 1972-08-09 |
Family
ID=11160084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2041371A Expired GB1285164A (en) | 1970-01-22 | 1971-04-19 | Polyiminoalanes, preparation of the same, catalysts containing the polyiminoalanes, and polymerisation employing these catalysts |
Country Status (17)
| Country | Link |
|---|---|
| JP (1) | JPS5117996B1 (en) |
| AT (1) | AT307724B (en) |
| BE (1) | BE761741A (en) |
| CA (1) | CA974347A (en) |
| CS (3) | CS167301B2 (en) |
| DK (1) | DK142952C (en) |
| ES (1) | ES387782A1 (en) |
| FR (1) | FR2075698A5 (en) |
| GB (1) | GB1285164A (en) |
| HU (2) | HU165430B (en) |
| LU (1) | LU62461A1 (en) |
| NL (1) | NL168528C (en) |
| NO (1) | NO134119C (en) |
| RO (2) | RO59995A (en) |
| SE (2) | SE376620B (en) |
| SU (1) | SU436497A3 (en) |
| YU (2) | YU34573B (en) |
-
1971
- 1971-01-04 CA CA102,137A patent/CA974347A/en not_active Expired
- 1971-01-15 CS CS31071A patent/CS167301B2/cs unknown
- 1971-01-15 CS CS856674A patent/CS167302B2/cs unknown
- 1971-01-15 CS CS856774A patent/CS182824B2/en unknown
- 1971-01-18 YU YU11071A patent/YU34573B/en unknown
- 1971-01-19 ES ES387782A patent/ES387782A1/en not_active Expired
- 1971-01-19 SU SU1607853A patent/SU436497A3/en active
- 1971-01-19 BE BE761741A patent/BE761741A/en not_active IP Right Cessation
- 1971-01-19 FR FR7101620A patent/FR2075698A5/fr not_active Expired
- 1971-01-21 DK DK25771A patent/DK142952C/en not_active IP Right Cessation
- 1971-01-21 HU HUSA002248 patent/HU165430B/hu unknown
- 1971-01-21 LU LU62461D patent/LU62461A1/xx unknown
- 1971-01-21 NO NO21971A patent/NO134119C/no unknown
- 1971-01-21 HU HUSA002163 patent/HU165429B/hu unknown
- 1971-01-22 RO RO6568371A patent/RO59995A/ro unknown
- 1971-01-22 JP JP165871A patent/JPS5117996B1/ja active Pending
- 1971-01-22 RO RO7177529A patent/RO66745A/en unknown
- 1971-01-22 NL NL7100919A patent/NL168528C/en not_active IP Right Cessation
- 1971-01-22 AT AT54271A patent/AT307724B/en not_active IP Right Cessation
- 1971-01-22 SE SE77371A patent/SE376620B/xx unknown
- 1971-04-19 GB GB2041371A patent/GB1285164A/en not_active Expired
-
1974
- 1974-04-05 SE SE7404656A patent/SE416207B/en not_active IP Right Cessation
-
1977
- 1977-07-08 YU YU170077A patent/YU39052B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CS167301B2 (en) | 1976-04-29 |
| CS182824B2 (en) | 1978-05-31 |
| DE2102964A1 (en) | 1971-08-19 |
| FR2075698A5 (en) | 1971-10-08 |
| YU170077A (en) | 1982-06-30 |
| HU165430B (en) | 1974-08-28 |
| JPS5117996B1 (en) | 1976-06-07 |
| DE2102964B2 (en) | 1976-12-09 |
| NO134119C (en) | 1976-08-18 |
| DK142952B (en) | 1981-03-02 |
| NL168528B (en) | 1981-11-16 |
| CS167302B2 (en) | 1976-04-29 |
| HU165429B (en) | 1974-08-28 |
| ES387782A1 (en) | 1974-01-01 |
| BE761741A (en) | 1971-07-01 |
| SE416207B (en) | 1980-12-08 |
| NL168528C (en) | 1982-04-16 |
| SU436497A3 (en) | 1974-07-15 |
| DK142952C (en) | 1981-10-05 |
| YU34573B (en) | 1979-10-31 |
| YU11071A (en) | 1979-04-30 |
| YU39052B (en) | 1984-02-29 |
| CA974347A (en) | 1975-09-09 |
| NL7100919A (en) | 1971-07-26 |
| SE376620B (en) | 1975-06-02 |
| LU62461A1 (en) | 1971-08-27 |
| NO134119B (en) | 1976-05-10 |
| RO59995A (en) | 1976-05-15 |
| AT307724B (en) | 1973-06-12 |
| RO66745A (en) | 1981-01-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |