SU388002A1 - Library library - Google Patents

Library library

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Publication number
SU388002A1
SU388002A1 SU1680548A SU1680548A SU388002A1 SU 388002 A1 SU388002 A1 SU 388002A1 SU 1680548 A SU1680548 A SU 1680548A SU 1680548 A SU1680548 A SU 1680548A SU 388002 A1 SU388002 A1 SU 388002A1
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SU
USSR - Soviet Union
Prior art keywords
library
derivatives
organochlorosilyl
nsi
bis
Prior art date
Application number
SU1680548A
Other languages
Russian (ru)
Inventor
В. И. Савушкина Б. М. Табенко Е. А. Чернышев
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to SU1680548A priority Critical patent/SU388002A1/en
Application granted granted Critical
Publication of SU388002A1 publication Critical patent/SU388002A1/en

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Description

1one

Изобретение относитс  к области получени  бис- (органохлорсилил)-производных ароматических или гетероциклических сульфидов, которые  вл ютс  новым классом кремнийорганиЧ6СКИХ мономеров и могут быть использо;ваны в качестве одной из компонент при получении полимеров силоксанового типа.The invention relates to the field of producing bis- (organochlorosilyl) derivatives of aromatic or heterocyclic sulfides, which are a new class of organosilicon monomers and can be used as one of the components in the preparation of siloxane-type polymers.

Известен способ получени  бис-(органохлорсилил )-тиофенов пиролизом в газовой фазе производных тиофена, например хлортиенилхлорсилана , с трихлорсиланом или органилхлоркремнийгидридом . Однако во взаимодействие с сероводородом в подобных услови х указанные соединени  :ранее не вводились .A known method for producing bis- (organochlorosilyl) -thiophenes by pyrolysis in the gas phase of thiophene derivatives, for example chlorothylchlorosilane, with trichlorosilane or organochlorine silicon hydride. However, the indicated compounds were interacting with hydrogen sulfide under similar conditions: they were not previously administered.

Предлагаемый способ получени  бис-(органохлорсилил )-производных ароматических или гетероциклических сульфидов заключаетс  Е том, что галогенпроизводные фенил-, к-сенил-, нафтил-, тиенил- и т. п. хлорсилано-в подвергают взаимодействию с сероводородом в газовой фазе в проточной системе при нагревании, например, до 400-650°С.The proposed method for the preparation of bis (organochlorosilyl) derivatives of aromatic or heterocyclic sulfides consists in the fact that the halogen derivatives of phenyl, c-senyl, naphthyl, thienyl, etc., chlorosilane-are reacted with hydrogen sulfide in the gas phase in the flow-through system when heated, for example, to 400-650 ° C.

Реакции протекают по схеме:Reactions proceed according to the scheme:

,,Si( ,, Si (

-llf,Cl5-nSi) S Л 5ias-nR,,+ HHal-llf, Cl5-nSi) S L 5ias-nR ,, + HHal

R,C. -X-fH,S- R, C. -X-fH, S-

-R CU-nSi)S SiCU-nR,i + HHu. S-R CU-nSi) S SiCU-nR, i + HHu. S

s «s "

SU1680548A 1971-07-08 1971-07-08 Library library SU388002A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU1680548A SU388002A1 (en) 1971-07-08 1971-07-08 Library library

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU1680548A SU388002A1 (en) 1971-07-08 1971-07-08 Library library

Publications (1)

Publication Number Publication Date
SU388002A1 true SU388002A1 (en) 1973-06-22

Family

ID=20482671

Family Applications (1)

Application Number Title Priority Date Filing Date
SU1680548A SU388002A1 (en) 1971-07-08 1971-07-08 Library library

Country Status (1)

Country Link
SU (1) SU388002A1 (en)

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