JPS5674127A - Production of organosilicon polymer - Google Patents
Production of organosilicon polymerInfo
- Publication number
- JPS5674127A JPS5674127A JP15158479A JP15158479A JPS5674127A JP S5674127 A JPS5674127 A JP S5674127A JP 15158479 A JP15158479 A JP 15158479A JP 15158479 A JP15158479 A JP 15158479A JP S5674127 A JPS5674127 A JP S5674127A
- Authority
- JP
- Japan
- Prior art keywords
- silyl
- aryl
- alkyl
- hydrogen
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
PURPOSE: When the pyrolytic polycondensation reactions of an organosilicon compound is conducted by heating, a specific amount of hydrogen is added to the reaction system, thus forming an organosilicon polymer containing silicon and carbon atoms as the main chain components with narrow molecular weight distribution.
CONSTITUTION: An organosilicon compound, preferably a cyclic polysilane of formula I (R1, R2 are H, alkyl, aryl, silyl; n is 4 or more) or a chain polysilane of formula II (R3, R4 are H, alkyl, aryl, silyl, hydroxyl, alkoxy group; R5, R6 are H, alkyl, aryl, silyl; m is 2 or more), is heated to effect pyrolytic polycondensation to produce a polymer containing silicon and carbon atoms as the main chain components wherein hydrogen is added to the reaction system and the reaction is conducted under a hydrogen partial pressure of 20W100kg/cm2 at 25°C.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15158479A JPS5674127A (en) | 1979-11-22 | 1979-11-22 | Production of organosilicon polymer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15158479A JPS5674127A (en) | 1979-11-22 | 1979-11-22 | Production of organosilicon polymer |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5674127A true JPS5674127A (en) | 1981-06-19 |
Family
ID=15521701
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15158479A Pending JPS5674127A (en) | 1979-11-22 | 1979-11-22 | Production of organosilicon polymer |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5674127A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6262822A (en) * | 1985-09-13 | 1987-03-19 | Shin Etsu Chem Co Ltd | Production of polycarbosilane |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51126300A (en) * | 1975-04-26 | 1976-11-04 | Res Inst Iron Steel Tohoku Univ | Method for manufacturing an organoo silicon polymer having silicon and carbon atoms as main skeleton component |
-
1979
- 1979-11-22 JP JP15158479A patent/JPS5674127A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51126300A (en) * | 1975-04-26 | 1976-11-04 | Res Inst Iron Steel Tohoku Univ | Method for manufacturing an organoo silicon polymer having silicon and carbon atoms as main skeleton component |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6262822A (en) * | 1985-09-13 | 1987-03-19 | Shin Etsu Chem Co Ltd | Production of polycarbosilane |
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