SU374340A1 - COMPOSITION ON THE BASIS OF PET - Google Patents

COMPOSITION ON THE BASIS OF PET

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Publication number
SU374340A1
SU374340A1 SU1664296A SU1664296A SU374340A1 SU 374340 A1 SU374340 A1 SU 374340A1 SU 1664296 A SU1664296 A SU 1664296A SU 1664296 A SU1664296 A SU 1664296A SU 374340 A1 SU374340 A1 SU 374340A1
Authority
SU
USSR - Soviet Union
Prior art keywords
polystyrene
composition
weight
pet
basis
Prior art date
Application number
SU1664296A
Other languages
Russian (ru)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to SU1664296A priority Critical patent/SU374340A1/en
Application granted granted Critical
Publication of SU374340A1 publication Critical patent/SU374340A1/en

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Description

1one

Изобретение касаетс  создани  изделий из полистирола.The invention relates to the creation of products from polystyrene.

Известны композиции на основе полистирола И1 полимерного или сажевого наполнителей. Однако издели , полученные на основе этих композиций, короб тс  при повышенных температурах , а пленки имеют большую усадку.Known compositions based on polystyrene I1 polymeric or carbon black fillers. However, the products obtained from these compositions are boxed at elevated temperatures, and the films have a greater shrinkage.

Цель изобретени  - снизить усадку пленок и повысить формоустойчивость изделий на основе полистирола при повышенных температурах .The purpose of the invention is to reduce the shrinkage of films and improve the dimensional stability of products based on polystyrene at elevated temperatures.

Это обеспечиваетс  введением в полистирол порошка полиамида 68 с размером частиц менее 40 мк И1 сажи ДГ-100 (газовой канальной диффузионной с удельной геометрической поверхностью около 100 ).This is ensured by the introduction of polyamide 68 powder with a particle size of less than 40 microns I1 of carbon black DG-100 (gas channel diffusion with a specific geometric surface of about 100) into polystyrene.

Предлагаема  композици  характеризуетс  значительно меньшими внутренними напр жени ми , отсутствием усадки выше температуры стекловани  (100°С и короблени  прИ этих температурах, а также повышенной величиной прочности.The proposed composition is characterized by significantly lower internal stresses, the absence of shrinkage above the glass transition temperature (100 ° C and warping at these temperatures, as well as increased strength.

Пример. Композицию на основе полистирола эмульсионной полимеризации марки А (ГОСТ 9440-60), содержащую 0,5% вес. порошка из отходов вторичной переработки полиамида 68 с размером частиц менее 40 мкм и 0,05% вес. сажи ДГ-100, получают смешиванием в течение одного часа на шаровой мельнице . Из этой композиции отпрессовывают при температуре 180°С и удельном давленииExample. Composition based on polystyrene emulsion polymerization grade A (GOST 9440-60), containing 0.5% weight. powder from waste recycling polyamide 68 with a particle size less than 40 microns and 0.05% weight. soot DG-100, obtained by mixing for one hour in a ball mill. From this composition, it is pressed at a temperature of 180 ° C and a specific pressure

1,6 кг/см пленки толщимой 0,2 мм.1.6 kg / cm film thickness of 0.2 mm.

На чертеже изображены дилатометрические кривые пленки, полученных на полистироле (крива  /), а также пленок, полученных из композиций, содержащих только 0,5% вес.The drawing shows the dilatometric curves of the film obtained on polystyrene (curve /), as well as films obtained from compositions containing only 0.5% by weight.

полиамида (крива  2) и 0,05% вес. сажи ДГ-100 (крива  3), а также ненаполненного полистирола (крива  4), т. е. смеси 0,5% вес. полиамида и 0,5% вес. сажи ДГ-100.polyamide (curve 2) and 0.05% weight. soot DG-100 (curve 3), as well as unfilled polystyrene (curve 4), i.e. a mixture of 0.5% by weight. polyamide and 0.5% weight. soot DG-100.

Результаты прочностных испытаний пленокThe results of the strength tests of films

из полистирола № композиций на его основе, а также величины коэффициентов термического линейного расширени  представлены в таблице . Предмет изобретени  Композици  на основе полистирола и полиамидного наполнител , отличающа с  тем, что, с целью снижени  усадки и повышени  5 формоустойчивости изделий из полистирола при повышенных температурах, порошок полиамида 68 с размером частиц менее 40 мк в количестве 0,05-0,8 вес. % введен в композицию совместно с 0,01-0,1 вес. % канальной, диффузионной газовой сажи с удельной геометрической поверхностью около 100 ( ДГ-100).polystyrene No. of compositions based on it, as well as the values of thermal linear expansion coefficients are presented in the table. The subject of the invention is a composition based on polystyrene and polyamide filler, characterized in that, in order to reduce shrinkage and increase 5 dimensional stability of polystyrene products at elevated temperatures, polyamide 68 powder with a particle size less than 40 microns in an amount of 0.05-0.8 weight . % introduced into the composition together with 0.01-0.1 weight. % channel diffusion carbon black with a specific geometric surface of about 100 (DG-100).

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SU1664296A 1971-05-26 1971-05-26 COMPOSITION ON THE BASIS OF PET SU374340A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU1664296A SU374340A1 (en) 1971-05-26 1971-05-26 COMPOSITION ON THE BASIS OF PET

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU1664296A SU374340A1 (en) 1971-05-26 1971-05-26 COMPOSITION ON THE BASIS OF PET

Publications (1)

Publication Number Publication Date
SU374340A1 true SU374340A1 (en) 1973-03-20

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Family Applications (1)

Application Number Title Priority Date Filing Date
SU1664296A SU374340A1 (en) 1971-05-26 1971-05-26 COMPOSITION ON THE BASIS OF PET

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SU (1) SU374340A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0601312A1 (en) * 1992-12-07 1994-06-15 Vorwerk & Co. Interholding GmbH Injection moulded plastic part
US5494628A (en) * 1992-12-24 1996-02-27 Vorwerk & Co. Interholding Gmbh Mat produced on the basis of a nonwoven
US5578648A (en) * 1992-10-30 1996-11-26 Vorwerk & Co. Interholding Gmbh Lamination adhesive containing thermoplastic resins and unmelted thermoplastic fibers

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5578648A (en) * 1992-10-30 1996-11-26 Vorwerk & Co. Interholding Gmbh Lamination adhesive containing thermoplastic resins and unmelted thermoplastic fibers
EP0601312A1 (en) * 1992-12-07 1994-06-15 Vorwerk & Co. Interholding GmbH Injection moulded plastic part
US5494628A (en) * 1992-12-24 1996-02-27 Vorwerk & Co. Interholding Gmbh Mat produced on the basis of a nonwoven
US5766735A (en) * 1992-12-24 1998-06-16 Vorwerk & Co. Interholding Gmbh Mat produced on the basis of a nonwoven
US5993933A (en) * 1992-12-24 1999-11-30 Vorwerk & Co. Interholding Gmbh Mat produced on the basis of a nonwoven

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