SU1657558A1 - Way of processing dyed or printed cellulose textile material - Google Patents

Abstract

The invention relates to dyeing and finishing production, in particular, to a method for treating a dyed or printed cellulose-containing textile material with a cation-containing compound. The invention makes it possible to increase the color fastness to wet treatments up to 5 points due to the fact that a compound of the general formula -Ci .2-tH-CH2-PfCH7CH-CII2-N- is used as a cation-containing compound. OH OH r (CH, VN p 2-6; p 1-3, RfxNx N4,, i M5C2 C2H5 (® ® in the amount of 1-60 g / l. 3 tab. SP with

Description

The invention relates to dyeing and finishing production, in particular to a method for treating a dyed or printed cellulose-containing textile material with cation-containing compounds.

A known method of treating a dyed or printed cellulose-containing textile material with a quaternary ammonium compound containing epoxy groups (USSR author's certificate No. 1035108, cl. D 06 P 5/22, 1980).

The disadvantage of this method is not sufficiently high color resistance to wet treatments.

The purpose of the invention is to increase the color fastness to wet treatments.

In the proposed method, a compound of the general formula is used as a cationic compound (CAS):

.CH2-CH-CHfRrCH, -CH-CH, -N - l- (CH, VN

§ i i ini

i HE

he

I n

n

about ate vj

ate

00

(one)

where 2-6; p 1-3;

Ki% C & ® ,, 6D.

n5s

-X

c.it,

N

i

in the amount of 1 to 60 g / l

The starting materials and amounts for the preparation of cation-containing compounds are listed in Table 1.

The resulting product contains 40–60% of the active weight of the yellow-brown brown with a density of 13–15 g / cm3 and water that is mixed in any ratios of the concentration of the scientific preparation, 1 is shown in Table 2. t PIR is connected 4 ppiruyut in alkaline rn ipoiuui ni ipynna mi cellulose will compose and fiber to facilitate its mixing

The presence of cipvKType unity (i) of quaternary tzpots helps to increase the amount of dyeing on all dyes and invoking vt reactivity of paintworking (| abl 3) the same intensification of flushing saving water and electricity consumption

11 steps (the method can be washed with 1 m of tuium traspraoka of continuous or periodic deistors of the syringes tsigers COPYURN p s1L HLhm int or its beauty rnmpriTch

P i m p p P p m chapop, N-th merspricepch, ij i 11ioi y o ky

value / lg p ft m ange m i

rzbatypryug pi 30 s in the p rn of the head of m-mder pschei

1g liter 1 t 1 1) n 1d "lnna is 1 0 eftM4 processing iC min. Then, there, glrd, cg ntrifugirotni and cyiiJKa Color hichtoichive to water sweat and - air npi - 40 ° C

EXAMPLE 2 X-cotton yarn in Example 1 is processed in aai.ne containing 5 g l of Compound 1 (Table I) and

2 g l of sodium hydroxide at 50 ° C. Bath module 1 20 processing time 30 min. After washing and neutralizing the yarn is dried. The paint is more / more stable to water and / and washed at 95 ° C than the paint of example 1

Primerz The knitted fabric of the hopper fiber is processed on a dyeing machine by conventional decoction / bleaching and then treated with a mixture of vanchy 1 20 containing g

Compound 2 (table 1) 15

Sodium hydroxide 6

Processing temperature 55 ° С time 50 min Grikogazhmoe sweaty after pro

washings are dyed by known technology with reactive blue C 4 In comparison with the known dyeing method, the dye has a twofold use of 5 Example 4 Polyester blend fabric

and 67/33% cellulose fibers in the field, the scoop is impregnated with a bath containing g l 1

Disperse blue C I 7310

10Reactive Blue C I 53

Sodium alginate 2

After drying at 100 ° C and heat treatment at 195 ° C for 50 seconds, the fabric is impregnated with a bath containing g l 1 15Compound 1 (table 1) 60

Sodium hydroxide 20

After passing through the plus and from the press to 70% humidity, the fabric is left for 10 hours at a constant rotation of 20 and the ambient temperature. When pulling out the fabric, the reactive dye is completely fixed and the cellulose fiber is crosslinked using compound 1, as a result, Heads 25

PRI me R 5 Cotton fabric printed with six inks containing reactive dyes.

A) Reactive yellow C I 3

30B) Reactive Orange C I 5

C) Reactive RedS I 24

D) Reactive Blue I 5

E) Green Reactive 8

F) Black Reactive I 8

35 alkali thickener and anti-edematant additive after fixation by steaming under washing in a washing unit with eight passes through the following baths

1 Cold water 402 Water 50 ° С

345 Cationic polyelectrolyte 1 (table 1) 2 g liter bath temperature 90 ° С

6 Water 80 ° C

7Water 50 ° С

458 cold water

By the result of a single pass of the fabric with a washer at a speed of 70m min, perfect washing of the non-fixed dye is achieved; the print possesses a high color resistance to water and

washable print resistance to action

light does not change

PRI me R 6 Cotton yarn

on X reels on a dyeing machine, color 55 is dyed in the usual way dye

mi%

Reactive orange С I 4 20 Reactive red С I 2 35

Reactive BlueS I 4 02

Then the yarn is washed for 5 minutes with cold water and again for 5 minutes with water at 50 ° C. After that, the yarn is treated in a water bath containing 2 g of lactic-active polyelectrolyte 2 (Table 1). Tempe Satura 90 ° C, Yumin Time It should be washed with water at 50 ° C for 5 minutes - short rinsing with cold water. The resistance of this very intense color to water is 4 5 / 4-5 / 4-5, while the color pop popular in a known manner possesses a system. 4/3/4.

Sample Knit ass sweater with viscose stapling and I and dynamic MPJJH-C-racer, MPJJH-O-shaped, known in a known way with 4.5% c.GWNM C, I rinse 5 RH with 2Q-25 ° C. then 5 min with water at PDl C w then sbr-zbetyvae) with at 90 ° С 10 min and a water bath containing 2 g l of cata- tive polyelectrolytes 3 (Table 1) Stability of the paint in the wet state Pre-equilibrium resistance achieved in a short way

EXAMPLE 8. Cotton fabric dyed on a jigger with a straight blue C.78 intensity 2% after washing is washed with water from a bath and at 30P is processed in a bath containing 5 g l of compounds 1 ( Table 1) Bath module 1 5 Color has good resistance to water and to wash

EXAMPLE 9 Cotton dyed dyed and fixed as in example 1 was treated at 60 ° C for 20 minutes in a bath containing 2.5 g of copper hydrate sulfate and 10.0 ml of glacial acetic acid. Bath module 1 5 This method allows to increase the color stability to washing and to light.

EXAMPLE 10 Cotton fabric is mercerized and dyed to a saturation of 2% straight orange C I 39, treated with a bath containing 1 g / l of compound 4 (Table 1), the bath modulus is 1. 5, processing time 30 min. Then follows rinsing with warm and cold water and drying. Color resistant to water, sweat and friction.

EXAMPLE The cotton fabric, pre-trimmed and dyed as in Example 10, is treated at 40 ° C in a bath containing 3 g / l of compound 5 (Table 1) and 2 g / l of sodium hydroxide. Bath module 1: 20, processing time 30 min. This is followed by washing, neutralization and drying. Color resistant to water, sweat and friction.

Example 12 Cotton fabric, pre-trimmed and finished in the beginning of Example 10, is treated at 20 ° G in a bath containing 2 g / l of Compound 6 (Table 1) Bath module 1 20 Processing time KiYumin. Then wash with tiai. The stain is water resistant to Gotu i crap o

EXAMPLE 13 (contour, iV Samples of cotton non-mercerized fabric printed with a hard-wearing dye with a reactive blue C 13 are processed for 2 minutes at a combo bath of 1 20 and 95 ° C in a bath of 2 g / test drug (gb It should be; h: o: cold with cold water (20 C) dg; l p vi for 1 min. P.rsng and I 20 Moi ratios the sample is covered with .- sample wet tissue and prog i with installed nl T Mnepa vpy i, married clap to full: with lu.iryujrfi.ii IC about samples of IA samples Grdgzhivlyut onrloku accompanying fabric and recording knowledge of the fuzzy pods iptyaynogo sam ples

Sample 1 Test for the closure of npoBt den without rinse preparation The final PG n tann 1 and the textile material has (or ovoid tears (epno white places) and white gopch / w / i yelnn tctn has a hpcht hetnopT gTy, i iCVVV 11, Sun Okr, ICKH n water g nfi.ii

Pattern 2 Test for washing products using .IH.VM known npen, ip, ni Remkgotse / FiA end printing printed material has nabo calf races first white megtd and 1l of the guideline on the fabric has poorly barked bow bow This means that angles chivogt coloring to lorosh water

Obraz 3 3 1 cm st. Cm. Prodrone using the proposed r; pen, i-rata 1 (gabl 1). The final printed textile material has slightly colored s white spaces and the accompanying gcane remained unpainted. This means that y). (The sharpness of coloring in water is excellent.

Claims (1)

Invention Formula The method of treating a dyed or kiln cellulose-containing textile material with a cationic compound at 20-100 ° C is different, in order to increase the color fastness to wet treatments, a compound of the general formula -CHfCH-CHj-RfCHj-rii vM.N - | - (SNg) p-Ct-ONon, (HJP n 2 - 6; p 1 - 3; g, ©, I5C2 L CH-N © V G i, -K: N © 0 in the amount of 1 - 60 g / l. Table 1 Continued table. 2 Table 3