SU150503A1 - - Google Patents
Info
- Publication number
- SU150503A1 SU150503A1 SU756410A SU756410A SU150503A1 SU 150503 A1 SU150503 A1 SU 150503A1 SU 756410 A SU756410 A SU 756410A SU 756410 A SU756410 A SU 756410A SU 150503 A1 SU150503 A1 SU 150503A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- catalyst
- piperylene
- isoprene
- oxygen
- nitrogen
- Prior art date
Links
- RRHGJUQNOFWUDK-UHFFFAOYSA-N isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 7
- PMJHHCWVYXUKFD-SNAWJCMRSA-N Piperylene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- -1 nitrogen-oxygen Chemical compound 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 230000003197 catalytic Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N CuO Inorganic materials [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 229910015707 MoOz Inorganic materials 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L Molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- IZYSFFFJIOTJEV-UHFFFAOYSA-P diazanium;dioxido(dioxo)tungsten Chemical compound [NH4+].[NH4+].[O-][W]([O-])(=O)=O IZYSFFFJIOTJEV-UHFFFAOYSA-P 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 229910003439 heavy metal oxide Inorganic materials 0.000 description 1
- PPXGQLMPUIVFRE-UHFFFAOYSA-N penta-2,4-dienal Chemical class C=CC=CC=O PPXGQLMPUIVFRE-UHFFFAOYSA-N 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
Description
Известные способы получени пентадиеналей сложны.Known methods for the preparation of pentadienals are complex.
Предлагаемый способ получени пептадиеналей (например, пентадиен-2 ,4-ал и бутен-3-метилеп-2-ал -(а)-винилахролеина) отличаетс тем, что пиперилен и изопрен подвергают каталитическому окислению азотно-кислородной смесью в присутствии медных катализаторов с добавками окислов т желых металлов (Mo,W).The proposed method for the preparation of peptadienals (e.g. pentadiene-2, 4-al and butene-3-methylep-2-al - (a) -vinyl-chloraine) is characterized in that piperylene and isoprene are subjected to catalytic oxidation with a nitrogen-oxygen mixture in the presence of additions of heavy metal oxides (Mo, W).
Это позвол ет упростить процесс и использовать в качестве исходного сырь доступные диеновые углеводороды.This simplifies the process and uses available diene hydrocarbons as feedstock.
При осуществлении этого способа окисление пиперилена и изопрена провод т в стекл нном реакторе путем пропускани над катализатором смеси диена, кислорода и азота, вз тых в определенном соотношении при температуре 400-430°С и времени контакта 0,5-1 сек.In this process, the oxidation of piperylene and isoprene is carried out in a glass reactor by passing a mixture of diene, oxygen and nitrogen over the catalyst, taken in a certain ratio at a temperature of 400-430 ° C and a contact time of 0.5-1 sec.
Пример. Смесь пиперилена или изопрена, кислорода и азота, вз тых в соотношении 1:1, 3:2,7, пропускают над катализатором (медный катализатор с добавками окислов Мо, W, нанесенных на силит), помещенным в стекл нный реактор, обогреваемый баней при 400 430°С. Врем контакта 0,5-1 сек.Example. A mixture of piperylene or isoprene, oxygen and nitrogen, taken in a ratio of 1: 1, 3: 2.7, is passed over the catalyst (a copper catalyst with additives of Mo, W oxides deposited on silica) placed in a glass reactor heated 400 430 ° C. Contact time 0.5-1 sec.
В случае окислени пиперилена получают пентадиеналь-2,4 с температурой кипени 52-53°С при 48In the case of the oxidation of piperylene, pentadienal-2.4 is obtained with a boiling point of 52-53 ° C at 48
изопрена - бутен-3-метилен-2-ал -(а)-винилакролеин кипени 66-GB C при 25 мм рт. ст., ng 1,4925.isoprene - butene-3-methylene-2-al - (a) -vinyl acrolein; boiling 66-GB C at 25 mm Hg. Art., ng 1,4925.
Выходы пентадиеналей до 150 г с 1 уг катализатора в час. Селективность по кислороду 159/0.Pentadienale outputs up to 150 g from 1 corner of catalyst per hour. Oxygen selectivity 159/0.
При приготовлении катализатора носитель (силит с размером зерна 1; 5-3,0 мм) пропитывают гор чим раствором нитрата окиси меди, молибденовой кислоты и вольфрамата аммони . Выпаривают, высушивают в течение 2 час при 150°С и прокаливают при 240-250°С в течение 2 час. Состав катализатора в процентах от веса носител - СиО 1 5 МоОз 0,01, WOs 0,01.When preparing the catalyst, the carrier (silicate with a grain size of 1; 5-3.0 mm) is impregnated with a hot solution of copper oxide nitrate, molybdic acid and ammonium tungstate. Evaporated, dried for 2 hours at 150 ° C, and calcined at 240-250 ° C for 2 hours. The composition of the catalyst as a percentage of the weight of the carrier - CuO 1 5 MoOz 0.01, WOs 0.01.
РТ. ст., ПцRT. Art., PTs
1,5085, в случае температурой1.5085, in case of temperature
N° 150503- 2 -N ° 150503-2 -
Предмет изобретени Subject invention
Способ получени пептадиеналей, например пентадиеп-2,4-ал и бутей З-метилен-2-ал (а)-винилакролеина, отла чающийс тем, что пиперилен . и изопрен подвергают каталитическому окислению азотпо-кислородной смесью в присутствии медных катализаторов с добавками окислов Мо и W.A process for the preparation of petadienals, e.g. pentadiene-2,4-al and bute Z-methylene-2-al (a) -vinyl acrolein, based on piperylene. and isoprene is subjected to catalytic oxidation with a nitrogen-oxygen mixture in the presence of copper catalysts with additives of Mo and W oxides.
Publications (1)
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SU150503A1 true SU150503A1 (en) |
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