SU136553A1 - The method of producing cyclocabi - Google Patents
The method of producing cyclocabiInfo
- Publication number
- SU136553A1 SU136553A1 SU672492A SU672492A SU136553A1 SU 136553 A1 SU136553 A1 SU 136553A1 SU 672492 A SU672492 A SU 672492A SU 672492 A SU672492 A SU 672492A SU 136553 A1 SU136553 A1 SU 136553A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- rubber
- cyclo
- producing
- cyclocabi
- phenol
- Prior art date
Links
Landscapes
- Paper (AREA)
- Polyesters Or Polycarbonates (AREA)
Description
Известен способ получени цикл(,каучука циклизацно Heii.i;icnKJ3iiцированного каучука в фенольном растворе в присутствии кислот. известно исиользование циклокаучука совместно с модифицированными фенольноформальдегидными, или малеиновыми. ii.iii алкидными смолами дл закреплени на ме чованно однако такое закрепление требует времени около 120-300 сек.A known method of obtaining a cycle (rubber cyclizing Heii.i; icnKJ3ii rubber in a phenolic solution in the presence of acids. It is known to use a cyclo-rubber together with modified phenol-formaldehyde or maleic. Ii.iii alkyd resins to fix on a sheet, however, such anchoring takes time about 120 300 seconds
Предлагаемый сиособ получени циклокаучука от,- ичаетс от известного тем, что к фенолу добавл ют небольшое количество эфира двухосновной кислоты. Краски, изготовленные на циклокаучуке, иолучснном по предлагаемому способу, закре1к:1 ютс на меловаино бумаге в течение 10-60 сек.The proposed method for the preparation of a cyclo-rubber from, is derived from the well-known fact that a small amount of a dibasic acid ester is added to the phenol. The paints made on the cyclocoupler, which was observed according to the proposed method, were fixed: 1 on the chalk paper for 10-60 seconds.
Пример. В реактор загружают 145 вес. ч. безводного фенола; 7,5 вес. ч. дибутилового эфира фталевой кислоты или дибутилового эфира себациновой кислоты: 7,5 вес. ч. и тиокиси фосфора и 100 вес. ч. мелко нарезанного каучука (светлый крен непластифицированный). Смесь выдерживают при температуре 60--80 в течение 2-5 час. Затем темиературу повышают до 180, и смесь выдерживают еш,е 2 час. После это1о включают мешалку, и процесс ведут при посто нном перемешивании в течение 6 час. Реактор охлаждаю до температуры 120-125, и смесь раствор ют в 450 объемных част х уайт-спирита. Полученные в резуль-, тате побочных реакций смолы и часть фенола удал ют отстаиванием раствора промывкой его дистиллированной водой и водным фенолом. Циклокаучук высаживают спиртом и высушивают в ваку -cylIiи.чьнo I шкафу при температуре НО-120°.Example. Charged to the reactor 145 weight. anhydrous phenol; 7.5 wt. including dibutyl ester of phthalic acid or dibutyl ester of sebacic acid: 7.5 wt. including phosphorus and thioxides and 100 wt. h. finely chopped rubber (light roll unplasticized). The mixture is maintained at a temperature of 60--80 for 2-5 hours. Then tem perature is increased to 180, and the mixture is kept at an esh of 2 hours. After this, the stirrer is turned on, and the process is carried out with constant stirring for 6 hours. The reactor is cooled to a temperature of 120-125, and the mixture is dissolved in 450 volume parts of white spirit. The resins and part of the phenol obtained as a result of the side reaction are removed by settling the solution by washing it with distilled water and aqueous phenol. The cyclo-rubber is planted with alcohol and dried in a vacuum-cylIi.chno I cabinet at a temperature of НО-120 °.
Краска, изготовленна на основе полученного циклокаучука, по рецепту в вес. ч.:Paint made on the basis of the obtained cyclo-rubber, according to the recipe in weight. including:
лак основной розовый ..... белила cvxne. .....basic pink lacquer ..... whitewash cvxne. .....
jYo 136553- 2 22 ,3%-ный раствор циклокаучука в трансформаторном масле ... 60 Закрепл етс на мелованной бумаге:jYo 136553- 2 22, 3% solution of cyclo-rubber in transformer oil ... 60 Fixed on coated paper:
а)в случае применени дибутилового эфира себациновой кислоты в течение 10-15 сек;a) in the case of using sebacic dibutyl ester for 10-15 seconds;
б)в случае иримеиении дибутилового фталево кислоты в течение 60 сек.b) in case of dibutyl phthalic acid irimeation for 60 seconds.
Пред м е т и з о б р е т е н и Prevention and Consideration
Снособ получени циклокаучука посредством циклизации в фено.чьном растворе в присутствии кислот, отличающийс те.м. что, с целью ускоренного (10-60 сек) закреплени на бумаге красок, изготовленны .х на основе циклокаучука, к фенолу Яобавл ют небольшое количество эфира двухосновной кис;1оты.A method for producing a cyclo-rupture by means of cyclization in a phenolic solution in the presence of acids, differing in temperature meter. that, for the purpose of accelerating (10-60 sec.) fixing on paper paints made of cyclo-rubber based on x, to phenol I add a small amount of dibasic ester ether;
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU672492A SU136553A1 (en) | 1960-07-05 | 1960-07-05 | The method of producing cyclocabi |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU672492A SU136553A1 (en) | 1960-07-05 | 1960-07-05 | The method of producing cyclocabi |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU136553A1 true SU136553A1 (en) | 1960-11-30 |
Family
ID=48292821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU672492A SU136553A1 (en) | 1960-07-05 | 1960-07-05 | The method of producing cyclocabi |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU136553A1 (en) |
-
1960
- 1960-07-05 SU SU672492A patent/SU136553A1/en active
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