SU1315401A1 - Ruby glass - Google Patents

Ruby glass Download PDF

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Publication number
SU1315401A1
SU1315401A1 SU853928417A SU3928417A SU1315401A1 SU 1315401 A1 SU1315401 A1 SU 1315401A1 SU 853928417 A SU853928417 A SU 853928417A SU 3928417 A SU3928417 A SU 3928417A SU 1315401 A1 SU1315401 A1 SU 1315401A1
Authority
SU
USSR - Soviet Union
Prior art keywords
glass
sno
cao
ruby
mgo
Prior art date
Application number
SU853928417A
Other languages
Russian (ru)
Inventor
Олег Гургенович Галустян
Галина Ивановна Артамонова
Тамара Никитична Яковлева
Юлия Михайловна Чураева
Александр Александрович Шелудченко
Валерий Сергеевич Иванов
Зинаида Дмитриевна Евдокимова
Таисия Васильевна Селезнева
Original Assignee
Государственный научно-исследовательский институт стекла
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Государственный научно-исследовательский институт стекла filed Critical Государственный научно-исследовательский институт стекла
Priority to SU853928417A priority Critical patent/SU1315401A1/en
Application granted granted Critical
Publication of SU1315401A1 publication Critical patent/SU1315401A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

Изобретение относитс  к составам рубиновых стекол, которые могут быть использованы в светотехнике и строительстве. Целью изобретени   вл етс  ускорение процесса наводки. Стекло содержит, мас.%: SiOg 66-75; 0,1-3; 0,2-3; СаО 4-10; 10-18; SnO 0,1-1,2; CujO 0,1- 1,5; MgO 0,1-4,7; и/или , 0,05-3. Стекло вар т при температуре 1390-1440 С, врем  наводки 0,01- 0,05 ч, КТР (88-103)10 светопропускание 20-35%. 2 табл. град , сд 4This invention relates to ruby glass compositions that can be used in lighting engineering and construction. The aim of the invention is to accelerate the pickup process. Glass contains, wt%: SiOg 66-75; 0.1-3; 0.2-3; CaO 4-10; 10-18; SnO 0.1-1.2; CujO 0.1-1.5; MgO 0.1-4.7; and / or, 0.05-3. The glass is cooked at a temperature of 1390-1440 ° C, the pickup time is 0.01-0.05 hours, the CTE (88-103) 10 light transmittance is 20-35%. 2 tab. hail, cd 4

Description

Изобретение относитс  к составам цветных стекол, в частности к рубиновым , и может быть использовано в светотехнике и строительстве.The invention relates to compositions of colored glass, in particular ruby glass, and can be used in lighting engineering and construction.

Цель изобретени  - ускорение процесса наводки,The purpose of the invention is to accelerate the process of pickup,

Дл  синтеза стекла используют следующие сырьевые материалы: кварцевый песок, глинозем, борную кислоту, мел, доломит, соду, оксиды олова, меди, железа, магни , фос орно-кислый аммоний , В качестве восстановителей ис-. пользуют известные соединени : уголь, винно-каменную кислоту.The following raw materials are used to synthesize glass: quartz sand, alumina, boric acid, chalk, dolomite, soda, oxides of tin, copper, iron, magnesium, phosphoric acid ammonium. known compounds are used: coal, tartaric acid.

J5 целью ускорени  процесса наводки, оно Варку стекла осуществл ют в газо- дополнительно содержит MgO, Р, 0J5 aiming to speed up the process, it brewing the glass is carried out in the gas additionally contains MgO, P, 0

и/или Ре,0з при следующем соотношевых или ванных печах в среде от слабовосстановительной до восстановительной при температурах от 1380 до 1450 С. Стекломассу вырабатьшают 20 различными способами, в том числе прокатом и вгыт гиванием.and / or Re, 0h in the following proportionally or bath furnaces in the medium from weakly reducing to reducing at temperatures from 1380 to 1450 C. Glass mass is produced in 20 different ways, including rolling and casting.

Составы стекол приведены в табл. 1.The compositions of the glasses are given in table. one.

Физико-химические свойства пред- 25 лагаемого стекла представлены в табл. 2.Physico-chemical properties of the proposed glass are presented in Table. 2

НИИ компонентов, мас.%:Research Institute of components, wt.%:

SiOrSiOr

А1,0зA1,0z

Р.ОЗ СаОR.OZ CaO

NaaONaaO

SnO Sno

CujOCujO

MgOMgO

P,OS и/или Ре„0P, OS and / or D „0

2323

66-75 0,1-3 0,2-3 4-10 10-18 0,1-1,2 0,1-1,5 0,1-4,7 0,05-3,066-75 0.1-3 0.2-3 4-10 10-18 0.1-1.2 0.1-1.5 0.1-4.7 0.05-3.0

7575

0,20.2

33

66

10ten

0,50.5

1one

1,31,3

33

6868

2,42.4

0,20.2

10ten

1515

0,10.1

0,10.1

4four

0,20.2

6969

0,40.4

0,50.5

4four

1818

1one

1,51.5

4,74.7

0,90.9

Таким образом, состав рубинового стекла обеспечивает выработку стекла прокатом и ВВС и позвол ет сократить врем  наводки. Стекло может найти применение в строительстве и производстве светотехнических изделий взамен рубинов на основе сульфоселе- нидов кадми .Thus, the composition of the ruby glass provides the production of glass by rolling and the Air Force and makes it possible to reduce the pickup time. Glass can be used in the construction and production of lighting products instead of rubies based on cadmium sulfoselenide.

Claims (1)

Формула изобретени Invention Formula Рубиновое стекло, включающее SiO А1,0з, , СаО, Na,jO, SnO,, , отличающеес  тем, что, сRuby glass including SiO A1,0z, CaO, Na, jO, SnO ,, characterized in that, with ИИ компонентов, мас.%:AI components, wt.%: SiOrSiOr А1,0зA1,0z Р.ОЗ СаОR.OZ CaO NaaONaaO SnO Sno CujOCujO MgOMgO P,OS и/или Ре„0P, OS and / or D „0 2323 ТаблицаTable 66-75 0,1-3 0,2-3 4-10 10-18 0,1-1,2 0,1-1,5 0,1-4,7 0,05-3,066-75 0.1-3 0.2-3 4-10 10-18 0.1-1.2 0.1-1.5 0.1-4.7 0.05-3.0 1one 6666 2,552.55 2,52.5 99 16sixteen 0,30.3 0,60.6 33 7070 0,10.1 1,61.6 8eight 1717 0,50.5 0,40.4 22 7371,37371.3 0,60,50,60,5 0,60,80,60,8 5.54,55.54.5 16,517,516,517,5 0,71,20.71.2 0,71,50.71.5 2,30,5 2,02.30.5 2.0 0,8 0,05 0,40.8 0.05 0.4 0,1 0,20.1 0.2 СвойстваProperties riiiziiizniriiriiiziiiznirii Температура варки, СCooking temperature, С Температура, °С, соответствующа  в зкостиTemperature, ° C, appropriate viscosity 103 Па-с 10 Па-с103 Pa-s 10 Pa-s Врем  наводки , чTime pickup, h Коэффициент термического расширени  ы (20-300) С,Coefficient of thermal expansion s (20-300) C, 1о1-1град1-1-1grad 1440 1420 1380 1450 1410 1400 1390 14101440 1420 1380 1450 1410 1400 1390 1410 1020 1140 1200 1000 1100 1100 1060 .1110 870 800 800 860 820 840 860 8301020 1140 1200 1000 1100 1100 1060 .1110 870 800 800 860 820 840 860 830 0,05 0,02 0,02 0,05 0,03 0,03 0,04 0,010.05 0.02 0.02 0.05 0.03 0.03 0.04 0.01 88 9888 98 93 90 103 10093 90 103 100 92 9892 98 Светопропускание , % (Л 690) 25Light transmission,% (L 690) 25 3535 Таблица 2table 2 Составы стеклаGlass compositions 93 90 103 10093 90 103 100 92 9892 98 2020 30 2530 25 3535 30 2030 20
SU853928417A 1985-07-19 1985-07-19 Ruby glass SU1315401A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU853928417A SU1315401A1 (en) 1985-07-19 1985-07-19 Ruby glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU853928417A SU1315401A1 (en) 1985-07-19 1985-07-19 Ruby glass

Publications (1)

Publication Number Publication Date
SU1315401A1 true SU1315401A1 (en) 1987-06-07

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Family Applications (1)

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SU (1) SU1315401A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2660921A1 (en) * 1990-04-13 1991-10-18 Saint Gobain Vitrage Int GLASS GLAZING TINTED IN PARTICULAR FOR THE ROOF OF MOTOR VEHICLES.
WO2005102948A2 (en) * 2004-04-23 2005-11-03 Koninklijke Philips Electronics N.V. Coloured glass
WO2006073703A1 (en) * 2004-12-30 2006-07-13 Owens Corning Intellectual Capital, Llc. Low boron glass composition for loose-fill and acoustical fiberglass insulation
WO2006130381A3 (en) * 2005-05-27 2007-02-01 Guardian Industries Method of making clear glass composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Патент US № 3779734, кл. С 03 С 3/20, 1973. Патент Польши № 87323, кл. С 03 С t/10, 1976, *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2660921A1 (en) * 1990-04-13 1991-10-18 Saint Gobain Vitrage Int GLASS GLAZING TINTED IN PARTICULAR FOR THE ROOF OF MOTOR VEHICLES.
WO2005102948A2 (en) * 2004-04-23 2005-11-03 Koninklijke Philips Electronics N.V. Coloured glass
WO2005102948A3 (en) * 2004-04-23 2006-03-16 Koninkl Philips Electronics Nv Coloured glass
WO2006073703A1 (en) * 2004-12-30 2006-07-13 Owens Corning Intellectual Capital, Llc. Low boron glass composition for loose-fill and acoustical fiberglass insulation
US7648929B2 (en) 2004-12-30 2010-01-19 Owens Corning Intellectual Capital, Llc Low boron glass composition for loose-fill fiberglass insulation
WO2006130381A3 (en) * 2005-05-27 2007-02-01 Guardian Industries Method of making clear glass composition
US7562538B2 (en) 2005-05-27 2009-07-21 Guardian Industries Corp. Method of making clear glass composition

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