SU1211252A1 - Method of producing 1,1-bisacetoxy-2,2,2-trichlorethane - Google Patents
Method of producing 1,1-bisacetoxy-2,2,2-trichlorethane Download PDFInfo
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- SU1211252A1 SU1211252A1 SU823534064A SU3534064A SU1211252A1 SU 1211252 A1 SU1211252 A1 SU 1211252A1 SU 823534064 A SU823534064 A SU 823534064A SU 3534064 A SU3534064 A SU 3534064A SU 1211252 A1 SU1211252 A1 SU 1211252A1
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- USSR - Soviet Union
- Prior art keywords
- bisacetoxy
- producing
- trichlorethane
- catalyst
- simplify
- Prior art date
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
I I
Изобретение относитс к усовер- шёйствованному способу получени 1,1-бисацетокси-2,2,2-трихлорэта- йа который может использоватьс в качестве полупродукта синтеза различных органических соединений, в том числе пестицидов.The invention relates to an improved method for producing 1,1-bisacetoxy-2,2,2-trichloroethane which can be used as an intermediate for the synthesis of various organic compounds, including pesticides.
Целью изобретени вл етс упрощение процесса.The aim of the invention is to simplify the process.
Пример. Получение 1,1-бис- ацетокси-2,2,2-трихлорэтана.Example. Preparation of 1,1-bis-acetoxy-2,2,2-trichloroethane.
. Смесь 44 г (0,3 моль) хлррал , 31 г (0,3 моль) уксусного ангидрида и 0,1 г (0,13 мас.%) треххлористого. A mixture of 44 g (0.3 mol) hlrral, 31 g (0.3 mol) of acetic anhydride and 0.1 g (0.13 wt.%) Trichloride
Редактор М. Недолуженко Заказ 607/29Editor M. Nedoluzhenko Order 607/29
Составитель Л. ЕпишинаCompiled by L. Epishina
Техред А.Кикемезей Корректор И. ЭрдейиTehred A. Kikemezey Proof-reader I. Erdeyi
Тираж 379 Подписное ВНИИПИ Государственного комитета СССРCirculation 379 Subscription VNIIPI USSR State Committee
по делам изобретений и открытий 113035, Москва, Ж-35, Раушска наб., д. 4/5for inventions and discoveries 113035, Moscow, Zh-35, Raushsk nab., 4/5
Филиал 1ШП Патент, г. Ужгород, ул. Проектна ,4Branch 1ShP Patent, Uzhgorod, st. Project, 4
211252J211252J
фосфора вьщерживают при комнатной. Температуре без перемешивани до прекращени роста коэффициента преломлени (3-4 сут) и получают 75 г 5 (100%) технического продукта, который практически нацело перегон етс при 126-128 с (25-28 мм рт.ст., пЬ 1,4553, d4 1,4098. Теоретические данные: т.кип. 111-112 С/10 ммphosphorus at room temperature. The temperature without stirring until the refractive index ceases to grow (3-4 days) yields 75 g of 5 (100%) technical product, which is almost completely distilled at 126-128 s (25-28 mm Hg, pb 1.4553 , d4 1.4098. Theoretical data: bp 111-112 C / 10 mm
10 рт.ст., 1,4557.10 Hg, 1.4557.
Найдено,% С 28,73, Н 2,85, .се 42,44. - ..Found,% C, 28.73; H, 2.85; all 42.44. - ..
С g Н ; С Ь 0C g N; C b 0
Вычислено,%: С 28,88, Н 2,83, 15 се 42,63.Calculated,%: C 28.88, H 2.83, 15 ce 42.63.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SU823534064A SU1211252A1 (en) | 1982-12-01 | 1982-12-01 | Method of producing 1,1-bisacetoxy-2,2,2-trichlorethane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SU823534064A SU1211252A1 (en) | 1982-12-01 | 1982-12-01 | Method of producing 1,1-bisacetoxy-2,2,2-trichlorethane |
Publications (1)
Publication Number | Publication Date |
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SU1211252A1 true SU1211252A1 (en) | 1986-02-15 |
Family
ID=21043405
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SU823534064A SU1211252A1 (en) | 1982-12-01 | 1982-12-01 | Method of producing 1,1-bisacetoxy-2,2,2-trichlorethane |
Country Status (1)
Country | Link |
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SU (1) | SU1211252A1 (en) |
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1982
- 1982-12-01 SU SU823534064A patent/SU1211252A1/en active
Non-Patent Citations (1)
Title |
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Патент DD № 128817, кл. С 07 С 69/62, опублик. 1976. Мирскова А.Н. и др. j,ft -Ди- хлорвиниловые эфиры карбоковых кислот. Изв. СО АН СССР. Сер. хим., 1971. № 14, вьш. 6, с. 72-76. Мамедов Ш., Гаджизаде Ф.: Синтез сложных и смешанных простых сложных эфиров 2,2,2-трихлорэтандио- ла-1,1. ЖОХ, т. 32, с. 799, 1962. Bandett Р. et аС. Acy oines et hydrates di-o-ac tyBes d aWehydes. HeBv. Chim. Acta, 1970, v. 53, p. 1330-36. * |
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