SK612012U1 - A luminiscent materials - Google Patents

A luminiscent materials Download PDF

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Publication number
SK612012U1
SK612012U1 SK61-2012U SK612012U SK612012U1 SK 612012 U1 SK612012 U1 SK 612012U1 SK 612012 U SK612012 U SK 612012U SK 612012 U1 SK612012 U1 SK 612012U1
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Slovakia
Prior art keywords
materials
base material
synthetic
luminous
weight
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SK61-2012U
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Slovak (sk)
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SK6395Y1 (en
Inventor
Ladislav Kozmer
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Ladislav Kozmer
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Publication date
Application filed by Ladislav Kozmer filed Critical Ladislav Kozmer
Priority to SK61-2012U priority Critical patent/SK6395Y1/en
Publication of SK612012U1 publication Critical patent/SK612012U1/en
Publication of SK6395Y1 publication Critical patent/SK6395Y1/en
Priority to PCT/SK2013/000005 priority patent/WO2013165321A1/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/56—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing sulfur
    • C09K11/562—Chalcogenides
    • C09K11/565—Chalcogenides with zinc cadmium
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22—Luminous paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/58—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing copper, silver or gold
    • C09K11/582—Chalcogenides
    • C09K11/584—Chalcogenides with zinc or cadmium
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/64—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing aluminium
    • C09K11/641—Chalcogenides
    • C09K11/643—Chalcogenides with alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/54—Pigments; Dyes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80—Optical properties, e.g. transparency or reflexibility
    • C04B2111/807—Luminescent or fluorescent materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Paints Or Removers (AREA)
  • Road Signs Or Road Markings (AREA)
  • Luminescent Compositions (AREA)

Abstract

Fluorescent materials created by the mixture of base material which amounts from 50% to 90% of the total weight and phosphorogenic pigment which amounts from 10% to 50% of the total weight, and the fluorescent material is in form of compact mass or in a form of surface coating material. Base material are materials used in building industry, such as gypsum, mosaic wall coating or sealant substance while all materials are based on anorganic raw materials and organic sealant, nonplasticized or plasticized polyurethane (PUR), epoxide resin, transparent lackquers based on synthetic substances, synthetic and non- synthetic cover coating. Phosphorogenic pigment is zinc sulphide and coper or strontium aluminate.

Description

Oblasť technikyTechnical field

Doterajší stav technikyBACKGROUND OF THE INVENTION

V mnohých prípadoch je požiadavka na zviditeľnenie rôznych závažných informácií, súvisiacich so zabezpečením ochrany zdravia a bezpečnosti občanov ( napr.: cestné dopravné značenie), zviditeľnenie informácií v oblasti reklamy, označenie rôznych objektov, inštitúcií, budov, a pod. - za zníženej viditeľnosti alebo po zatmení.In many cases, there is a requirement for the visibility of various relevant information related to ensuring the protection of the health and safety of citizens (eg: road signs), visibility of information in the field of advertising, marking of various objects, institutions, buildings, etc. - in poor visibility or after eclipse.

Tento problém sa v súčasnosti rieši použitím reflexných prvkov, čo vyžaduje kontakt so svetelným zdrojom, alebo osvetlením svetelným zdrojom. Existujú napríklad laky na nechty, ktoré po osvetlení UV svetlom svietia (lak od firmy Acmellight) alebo rôzne svetielkujúce puzzle, prípadne nábytkové doplnky. Nevýhodou týchto riešení je väčšinou potreba svetelného zdroja.This problem is currently solved by the use of reflective elements, which requires contact with the light source or illumination of the light source. For example, there are nail polishes that shine after UV light (Acmellight varnish) or various luminous puzzles or furniture accessories. The disadvantage of these solutions is mostly the need for a light source.

Podstata technického riešeniaThe essence of the technical solution

Nedostatky prechádzajúcich materiálov odstraňuje predmet tohto technického riešenia aplikácia svetielkujúcich materiálov, a to tak v samotnej hmote ako aj v povrchovej úprave. U materiálov podľa tohto riešenia sa svetielkujúci účinok dosahuje tým, že absorbujú denné svetlo a vyžarujú ho v tmavom prostredí, pričom intenzita a dĺžka časového úseku svietenia je funkciou pomeru citovaných materiálov - v časovom intervale od 2 hodín až do 24 hodín v tmavom prostredí. Farebná škála svetiel a odtieňov svetiel je rôzna.The object of this invention is eliminated by the application of luminous materials, both in the material itself and in the surface treatment. In the materials of the present invention, the luminous effect is achieved by absorbing daylight and emitting it in a dark environment, the intensity and length of the illumination period being a function of the ratio of the materials cited - from 2 hours to 24 hours in the dark. The color range of lights and shades varies.

Podstatou technického riešenia sú svetielkujúce materiá^f ktoré pozostávajú zo zmesi základného materiálu v množstve 50,00 až 90,00 % hmotnostnýčn a fosforeskujúceho pigmentu v množstve 10,00 až 50,00 % hmotnostných, pričom svetielkujúci materiál je vo forme kompaktnej hmoty alebo povrchovej náterovej hmoty. Základným materiálom sú materiály používané v stavebníctve - sadra, mozaiková omietka, škárovacie hmoty na báze anorganických surovín a organických tmelov alebo polyuretán mäkčený inemäkčený, epoxidové živice, transparentné laky na báze syntetických látok, syntetická a nesyntetická farba vrchná. Fosforeskujúci pigment je sulfid zinočnatý a meď alebo hlinitan strontnatý.The present invention is based on a luminous material consisting of a mixture of a base material in an amount of 50.00 to 90.00% by weight and a phosphorescent pigment in an amount of 10.00 to 50.00% by weight, wherein the luminous material is in the form of a compact or surface material. of paint. The basic materials are materials used in construction - gypsum, mosaic plaster, jointing materials based on inorganic raw materials and organic sealants or polyurethane softened in softened, epoxy resins, transparent varnishes based on synthetic substances, synthetic and non-synthetic top paint. The phosphorescent pigment is zinc sulfide and copper or strontium aluminate.

Príklady uskutočnenia technického riešeniaExamples of technical solution

Nasledovné príklady uskutočnenia slúžia na ilustráciu uskutočnenia technického riešenia a neobmedzujú rozsah použitia.The following exemplary embodiments serve to illustrate embodiments of the invention and do not limit the scope of use.

Príklad 1Example 1

Zmieša sa 75 % hmotnostných škárovacej cementovej hmoty Ceresit napr. pri obkladaní stien, podláh a pod. s 25 % hmotnostnými fosforeskujúceho pigmentu - sulfid zinočnatý a meď.75% by weight of the cementitious cementitious compound Ceresit e.g. when lining walls, floors, etc. with 25% by weight of a phosphorescent pigment - zinc sulfide and copper.

Príklad 2Example 2

Zmieša sa 50% hmotnostných sadry s 50% hmotnostnými fosforeskujúceho pigmentu hlinitanu strontnatého. Zo zmesi možno vyrábať rôzne predmety napr. záhradnej architektúry, ako sú sošky, záhradné osvetlenia, lavičky a podobne.50% by weight of gypsum is mixed with 50% by weight of the phosphorescent strontium aluminate pigment. Various articles can be made from the mixture e.g. landscape architecture such as statuettes, garden lighting, benches and the like.

Príklad 3Example 3

Na výrobu mozaikovej omietky sa zmieša sa 75% hmotnostných omietky s 25% hmotnostnými fosforeskujúceho pigmentu - sulfid zinočnatý a meď.To make the mosaic plaster, 75% of the plaster is mixed with 25% by weight of a phosphorescent pigment - zinc sulfide and copper.

Príklad 4Example 4

Na výrobu farieb napr. na povrchovú úpravu zábradlí, smerných stĺpikov, vodiacich čiar na cesty a chodníky a pod. sa zmieša 70% hmotnostných syntetickej akrylátovej farby s 30% hmotnostnými fosforeskujúceho pigmentu - hlinitanu strontnatého.For the production of paints eg. for surface treatment of railings, guide posts, guide lines for roads and pavements, etc. 70% by weight of a synthetic acrylic paint is mixed with 30% by weight of a phosphorescent strontium aluminate pigment.

Príklad 5Example 5

Zmieša sa 85% hmotnostných nemäkčeného polyuretánu, napríklad v tvare dosiek s 15% hmotnostnými pigmentu - sulfid zinočnatý a meď. Zo zmesi možno vyrábať rôzne predmety, napríklad orientačné tabule, tabuľky názvov ulíc, bilboardy, reklamné tabule a podobne.85% by weight of unplasticized polyurethane is mixed, for example in the form of plates with 15% by weight of zinc sulfide pigment and copper. Various articles can be made from the mixture, for example, signboards, street name plates, billboards, billboards, and the like.

Príklad 6Example 6

Pre výrobu transparentných lakov napr. na rôzne povrchové úpravy predmetov — smerové stĺpiky, vodiace čiary sa zmieša sa 84% hmotnostných epoxidového laku so 16 % hmotnostnými fosforeskujúceho pigmentu - hlinitanu strontnatého.For the production of transparent varnishes e.g. For various finishes of articles - directional posts, guide lines, 84% by weight of epoxy varnish is mixed with 16% by weight of a phosphorescent pigment - strontium aluminate.

Príklad 7Example 7

Pre výrobu náterových organických látok napríklad na povrchovú úpravu vianočných ozdôb alebo iných dekoračných predmetov sa zmieša sa 90% hmotnostných základného materiálu (napríklad PVC) s 10% hmotnostnými fosforeskujúceho pigmentu - hlinitanu strontnatého.For the production of coating organic substances, for example for the coating of Christmas decorations or other decorative items, 90% by weight of a base material (e.g. PVC) is mixed with 10% by weight of a phosphorescent pigment - strontium aluminate.

Priemyselná využiteľnosťIndustrial usability

Predmet úžitkového vzoru podľa tohto riešenia sa uplatní tak v individuálnej aplikácii ako aj v sériovej výrobe - nevyžaduje zdroj el. energie, zdrojom je denné svetlo, slnečné žiarenie.The subject of utility model according to this solution is applied both in individual application and in serial production - it does not require power source. energy, the source is daylight, sunlight.

Možno ho využiť označenie prechodu pre chodcov v obciach a mestách, na značenie ciest, označenie názvov ulíc a čísiel v obciach a mestách, označenie orientačných tabúľ v prírode, ako aj na výrobu rôznych prvkov záhradnej architektúry (balustrády, sošky, chodníky) umožňujúcich ľahkú orientáciu za zníženej viditeľnosti alebo po zatmení, v oblasti reklám - podstatné zvýšenie účinnosti a kreativity bilboardov, pútačov apod. Vhodná je aj povrchová úprava zábradlí, orientačných a smerných stĺpikov, vodiacich čiar, a pod. V stavebníctve sú to zase zaujímavé škárovacie hmoty a mozaikové omietky. Vo forme náterov je možné ju využiť aj napríklad pri výrobe vianočných ozdôb, ďalej pri potlači textilu. V dopravných prostriedkoch (bicykloch) ako nátery rámov kolies a podobne.It can be used to mark pedestrian crossings in municipalities and towns, to mark roads, to mark street names and numbers in towns and cities, to mark signposts in nature, and to produce various elements of garden architecture (balustrades, statuettes, walkways) for easy orientation in reduced visibility or after eclipse, in the field of ads - significantly increase the efficiency and creativity of billboards, eye-catchers, etc. Also suitable is the surface treatment of railings, orientation and directional posts, guide lines, etc. In construction they are interesting grout materials and mosaic plasters. In the form of coatings, it can also be used, for example, in the production of Christmas decorations, as well as in textile printing. In vehicles (bicycles) as coatings for wheel frames and the like.

Claims (4)

NÁROKY NA OCHRANUPROTECTION REQUIREMENTS 1. Svetielkujúce materiály-vyznačujúce sa tým, že pozostávajú zo zmesi základného materiálu v množstve 50,00 až 90,00 % hmotnostných a fosforeskujúceho pigmentu v množstve 10,00 až 50,00 % hmotnostných, pričom svetielkujúci materiál je vo forme kompaktnej hmoty alebo povrchovej náterovej hmoty.1. Luminous materials, characterized in that they consist of a mixture of a base material in an amount of 50.00 to 90.00% by weight and a phosphorescent pigment in an amount of 10.00 to 50.00% by weight, wherein the luminous material is in the form of a compact mass or surface paint. 2. Svetielkujúce materiály podľa nároku ^vyznačujúce sa tým, že základným materiálom sú materiály používané v stavebníctve - sadra, mozaiková omietka, škárovacie hmoty na báze anorganických surovín a organických tmelov.Luminous materials according to claim 1, characterized in that the base material is materials used in the construction industry - gypsum, mosaic plaster, grouting materials based on inorganic raw materials and organic sealants. 3. Svetielkujúce materiály podľa nároku 1; vyznačujúce sa tým, že základným materiálom sú polyuretán mäkčený i nemäkčený, epoxidové živice, transparentné laky na báze syntetických láto^gynte(ic^á nesyntetická farba vrchná.The luminous materials of claim 1 ; characterized in that the base material is both plasticized and unplasticized polyurethane, epoxy resins, transparent lacquers based on synthetic lithium (non-synthetic topcoat). 4. Svieti^^?hateria^^ýzŽ^^hjCe sa tým, že fosforeskujúci pigment je sulfid zinočnatý a meď alebo hlinitan strontnatý.4. The battery is lit by the fact that the phosphorescent pigment is zinc sulfide and copper or strontium aluminate. ÚRAD PRIEMYSELNÉHO VLASTNÍCTVA SLOVENSKEJ REPUBLIKYINDUSTRIAL PROPERTY OFFICE OF THE SLOVAK REPUBLIC Jána Švermu 43,974 04 Banská Bystrica 4Jan Sverma 43,974 04 Banska Bystrica 4 VÝSLEDOK REŠERŠERESEARCH RESEARCH PÚV 61-2012PUV 61-2012 A. Zatriedenie predmetu prihlášky úžitkového vzoru podľa MPTA. Classification of the subject of the utility model application according to the IPC C09K 11/00C09K 11/00 B. Prehľadávané oblasti______________________________________B. Areas to be examined______________________________________ Prieskum v minimálnej PCT dokumentácii: C09KSurvey in minimal PCT documentation: C09K Prieskum v dokumentoch nepatriacich do minimálnej PCT dokumentácie: C09KResearch in non-PCT documents: C09K C. Dokumenty, ktoré sú považované za relevantnéC. Documents considered relevant
SK61-2012U 2012-04-30 2012-04-30 A luminiscent materials SK6395Y1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
SK61-2012U SK6395Y1 (en) 2012-04-30 2012-04-30 A luminiscent materials
PCT/SK2013/000005 WO2013165321A1 (en) 2012-04-30 2013-04-15 Fluorescent materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SK61-2012U SK6395Y1 (en) 2012-04-30 2012-04-30 A luminiscent materials

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SK612012U1 true SK612012U1 (en) 2012-10-02
SK6395Y1 SK6395Y1 (en) 2013-03-01

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3032703B1 (en) * 2015-02-12 2019-06-21 By Flavie PHOSPHORESCENT CERAMIC MATERIAL
EP3342763B1 (en) 2016-12-29 2021-11-10 STRABAG Sp. z o.o. A method for producing a luminescent pavement, a luminescent pavement obtained by said method, a combination and use of the combination

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6207077B1 (en) * 2000-02-18 2001-03-27 Orion 21 A.D. Pty Ltd Luminescent gel coats and moldable resins
DE102008011405A1 (en) * 2008-02-27 2009-09-10 Lufthansa Technik Ag Escape route marking for a vehicle and method for making an escape route marking
US20100291409A1 (en) * 2009-05-18 2010-11-18 Natglow Usa, Inc. Method for making a photoluminescent article
DE102009036481A1 (en) * 2009-08-07 2011-02-10 Nightec Gmbh & Co. Kg Photoluminescent granules and process for its preparation

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WO2013165321A1 (en) 2013-11-07

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