SK501342014U1 - Biologically degradable polymeric composition with improved qualities - Google Patents

Abstract

The biodegradable composition comprises 5 to 95 wt. % of polyhydroxyalkanoate and 95 to 5 wt. % polylactic acid or lactide, 2 to 67 parts plasticizer or plasticizer mixture per 100 parts polymer blend. Also described is a composition comprising 0.05 to 5 wt. % reactive additive. Citric acid esters, glycerol esters, phosphoric esters, sebacic esters and other liquid organic low molecular weight polyesters are used as plasticizers. The reactive additive is selected from the group of chemicals such as acrylic polymers, epoxidized acrylic polymers, diisocyanates and derivatives thereof, epoxidized oils, oligomeric copolymers of various monomers with glycidyl methacrylate or acrylate, and others.

Description

Biodegradable polymer composition with improved properties

Technical field

The invention relates to a biodegradable composition with improved properties. More particularly, the invention relates to a polymer blend of PLA and PHB, plasticized with a suitable plasticizer with the addition of a flexible modifier, which is characterized by improved properties, in particular increased toughness, which is suitable for packaging applications.

BACKGROUND OF THE INVENTION

Over the past twenty years, there has been a growing interest in renewable polymers, mainly for two reasons: environmental concerns with applications mainly in agriculture and packaging, but also the awareness of the depletion of oil resources. One such polymer whose growth is increasing is polylactic acid (PLA) or polylactide, which is produced from agricultural products and is readily biodegradable. The lactide is a cyclic dimer prepared from lactic acid, which is obtained by fermentation of starch or sugar from various sources (L. Yu et al., Pro. Polym. Sci. 31, 576602; 2006). PLA has been a polymer for many years, but monomer preparation techniques from agricultural raw materials have improved its economy, and today it is at the forefront of the biodegradable plastics industry (Y. Tokiwa et al., Int. J. Mol. Sci., 10, 3722-3742; 2009).

A special class of polyesters is naturally made up of a wide range of microorganisms, which serve as a source of carbon and energy. Poly-P-hydroxybutyrate (PHB) has been studied in the scientific literature at the beginning of the last century rather than a curiosity. Only in relation to the environmental aspects of plastics did research lead to the commercialization of PHB. The brittleness of PHB was improved by copolymerization of β-hydroxybutyrate with β-hydroxyvalerate (Holmes et al., EP 0052459; 1982). Although PHBs can be processed on conventional devices, their processing applications are limited by their commercial applications. This is related to the limited processing conditions, mainly due to its low thermal stability and relatively slow crystallization kinetics. Another limiting factor for its wider use is the relatively high price of this product.

Various biodegradable materials and techniques for their processing e.g. extrusion, the resulting materials often resulting from mixtures of polymeric components with adequate morphology given by the distribution of the components, their dispersion and their interaction. Polymeric mixtures are physical or mechanical mixtures of two or more polymers, and there are only secondary intermolecular interactions between the macromolecular chains of the different polymers, or the chains between the different types of polymers are only partially crosslinked. Most often, polymer blends are used as engineering plastics in applications, particularly in the automotive and electronics industries. This is usually a polymer blend formed from conventional polymers. Natural polymer blends usually improve some of the utility properties of pure ingredients, with the aim of extending the use of natural polymer polymers for higher value-added products (many applications of biomaterials in medicine), with a perspective of application in packaging, especially for special food packaging .

Both the above-mentioned polymers, PHB and PLA, have high strength characteristics, i. high modulus of elasticity as well as strength. They can be processed into conventional plastics

- 2 devices, but some processing problems as well as some features limit their commercial applications. First of all, it is the relatively low thermal stability associated with the relatively slow crystallization kinetics, which makes it necessary to adjust the processing conditions very precisely. In addition, the susceptibility to thermal degradation also acts during product utilization. Another limiting factor for wider use is the relatively high cost of this plastic. From the mechanical properties, low deformability, which leads to relatively high brittleness and low toughness of the material, is problematic.

Some procedures have been published to improve toughness. The most effective seems to be the copolymerization of β-hydroxybutyrate with β-hydroxyvalerate (Holmes et al., EP 0052459; 1982), or other higher homologues of polyhydroxyalkanoates. However, this procedure leads to a relatively significant increase in the cost of the material (Organ S.J., Barham P.J. J. Mater. Sci. 26, 1368, 1991). Another possibility is the addition of a plasticizer, but the effect achieved is relatively small and insufficient without further adjustments (Billingham N.C., Henman T. J., Holmes P. A. Development in Polymer Degradation 7, chapter 7, Elesevier Sci publ. 1987). A special process which has a relatively good effect is calendering at elevated temperature. However, only relatively thin flat products can be prepared by this procedure (Barham P.J., Keller A., J. Polymer Sci., Polym. Phys. Ed. 24, 69 1986). Thermal degradation during polymer shaping can be suppressed by solid-state extrusion of powders (Luepke T., Radusch H.J., Metzner K., Macromol. Symp. 127, 227, 1998), but it is a relatively demanding and not generally and widely applicable processing process. A simple method is to heat the formed and crystallized material to a temperature of about 120 ° C and above, but again, the increase in toughness is only temporal when the normal elongation at break of about 30%, maximum 60% (de Koning GJM, Lemstra PJ, Polymer 34) 4098 (1993).

An effective way of modifying polymeric materials is by mixing them with another plastic. In such a case, a tough plastic is added to increase the toughness of the brittle plastic while accepting a decrease in the strength parameters, especially the modulus. Various biodegradable materials and techniques for their processing e.g. extrusion, the resulting materials often resulting from mixtures of polymeric components with adequate morphology given by the distribution of the components, their dispersions and their interaction. Polymeric mixtures are physical or mechanical mixtures of two or more polymers, and there are only secondary intermolecular interactions between the macromolecular chains of the different polymers, or the chains between the different types of polymers are only partially crosslinked. Most often, polymer blends are used as engineering plastics in applications, particularly in the automotive and electronics industries. This is usually a polymer blend formed from conventional polymers. Natural polymer blends usually improve some of the utility properties of pure ingredients, with the aim of extending the use of natural polymer polymers for higher value-added products (many applications of biomaterials in medicine), with a perspective of application in packaging, especially for special food packaging .

PLA and PHB are biodegradable polymers from renewable natural resources, destined for the production of environmentally acceptable plastic materials with excellent performance properties. On the other hand, these polymers themselves are brittle with minimal ductility, limiting their potential applications. Theoretical study of PHB-PLA mixtures has shown that mechanical properties are somewhat between the properties of the individual components. In addition, most of these mixtures cannot be simply mixed with other polymers, resulting in reduced mechanical properties (T. Yokohara and M. Yamaguchi, Eur. Polym. J. 44, 677-685; 2008).

International Application WO / 2007/095712 (Femandes J., et al.) Discloses environmentally degradable polymer compositions and a process for their preparation from PHB and its copolymer with PLA using a plasticizer of natural origin, natural fibers, natural fillers, thermal stabilizer, nucleant , a compatibilizer, a surfactant and processing aids. The same Applicant in another similar application (WO / 2007/095709) extended these polymer compositions by the addition of another biocompatible polycaprolactone polymer, while abandoning the use of strictly natural ingredients, but considerably extending the applications of these compositions. Also, International Application WO / 2007/095711 from the same Applicant describes biodegradable polymer compositions and a process for their preparation, wherein the composition comprises PLA or its copolymers, a renewable plasticizer, a nucleant, a coating, and a thermal stabilizer.

The biodegradable polymer compositions of nanocomposite materials for packaging with specific polymer blends of PLA with PHB and a copolymer of butylene adipate with terephthalate and modified cast nanoparticles that are useful for barrier packaging are the subject of a patent (A. Mohanty, WO / 2007/022080). The patent (D. Shichen and Ch. Keunsuk, WO / 2010/151872) is a solution to improve the moisture barrier properties by using a combination of PLA with PHB coextrusion to produce a layered biaxially oriented film that can be advantageously metallized. Both polymers can be modified by mixing with other polymer components.

More theoretical work is devoted to the use of a mixture of PHB with PLA in medical composite biomaterials. Such is a highly porous hydroxyapatite tissue engineering composite where bone crystallinity and thus tissue biodegradation have decreased significantly compared to pure PHB (N. Sultana and M. Wang, J. Experim. Nanoscience 3, 121-132; 2008). As can be seen, PLA and PHB mixtures are not yet common in practice, due to their limited processability and insufficient mechanical properties. On the other hand, both types of polymers are perspective and from theoretical studies their mixtures have great potential for use in special applications, for example in food packaging.

In the processing of PLA, it is also possible to employ the application of multifunctional chain extenders, which are oligomeric compounds with epoxy groups, which preferentially react with the terminal carboxyl groups of the PLA to form esters with increased molar mass and higher viscosity. Such compounds also include Joncryl, a registered trademark of BASF. For example, small amounts of Joncryl-ARD improve the rheological and mechanical properties of PLA (British Plastics & Rubber, Publ. Give: 01-JUN-10). Some patents describe the effects of epoxy-acrylate copolymers for various forms (melt, latexes) of PLA processing. E.g. Randall, J.R. et al., US Patent 7566753 discloses an efficient and flexible method of making a branched PLA resin using a standard melt processing process. There are fewer examples of the use of these compounds in separate PHB or generally PHA. One of the few patents is, for example, WO / 2010/008445, describing a process for the preparation of a branched PHB composition and its use, wherein the branching properties of Joncryl ADR 4368-CS (styrene glycidyl methacrylate) are used to achieve a higher PHA melt strength.

The novel polymer blends of the present invention solve the processability problems and improve the mechanical properties of the PLA and PHB polymer blends. The new polymer blend achieves unexpected properties. Usually, to achieve increased toughness of the brittle plastic, a high toughness component is sought as a second component of the mixture, with the toughness values of the mixture being between the values for each polymer separately. In the embodiment according to the invention, the desired, very pronounced effect is achieved by mixing two brittle plastics. New

The polymer composition produces a material having a substantially increased toughness, which is manifested in particular by a high degree of elongation at break. A significant effect is achieved when compared to each polymer forming the composition when tested individually, even if each individual polymer is plasticized. This behavior, when mixing two brittle plastics to produce a tough material, is unexpected and unique in technical practice.

SUMMARY OF THE INVENTION

The present invention provides a biodegradable composition comprising from 5 to 95% by weight. % polyhydroxyalkanoate and 95 to 5 wt. % of lactic acid or lactide, 2 to 67 parts of the jacketing agent or plasticizer mixture per 100 parts of the polymer mixture.

According to another embodiment, the composition comprises 0.05 to 5 wt. % reactive additive as compatibilizer.

In yet another embodiment, citric acid esters, glycerin esters, phosphoric esters, sebacic esters and other liquid organic low molecular polyesters are used as plasticizers. According to another embodiment, the reactive additive as a compatibilizer is selected from the group of chemicals such as acrylic polymers, epoxidized acrylic polymers, diisocyanates and derivatives thereof, epoxidized oils, oligomeric copolymers of various monomers with glycidyl methacrylate or acrylate, and others. By reactive additive in the function of compatibilizer we mean a group of additives whose main function is to modify the character of the interfacial interface and to modify the morphology of mixtures of two or more polymers.

DETAILED DESCRIPTION OF THE INVENTION

Example 1

A blend of the composition shown in Table 1 was prepared in a laboratory twin screw mixer at a melt temperature of 190 ° C and 100 rpm. The mixture was extruded through a circular die, cooled with water and granulated after drying. Films 100 micron thick were prepared from the prepared granulate by chill roll technology on a laboratory single screw extruder, with a melt temperature of 190 ° C and a screw speed of 30 rpm. 15 mm wide strips were prepared from the foils to measure mechanical properties by tensile testing in accordance with STN ISO 527. The test was performed on a Zwick Roel shredder at a jaw movement speed of 50 mm / min at room temperature. The tensile strength at break (ob), the relative elongation at break (εδ) and the toughness were calculated from the tensile curve, which was calculated as the integral area under the tensile curve. The results of the measurements are shown in Tab. First

Tab. 1. Composition and properties of prepared mixtures

1 2 3 4 PLA mass parts 0 100 70 70 PHB mass parts 100 0 30 30 TAC mass parts 0 0 0 10 sb % 3 4.2 25 326 ob MPa 27.5 53 41.5 24.7 tenacity - 123.75 333.9 1556.25 12078.3

TAC - triacetin

Example 2

-5 Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 2.

Tab. 2. Composition and properties of prepared mixtures

5 6 7 8 PLA mass parts 90 90 95 5 PHB mass parts 10 10 5 95 TAC mass parts 0 10 10 10 sb % 3.1 101 12 7 ob MPa 57.7 40.5 45.5 37.5 tenacity - 268305 6135.75 4720.25 3130.0

Example 3

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 3.

Tab. 3. Composition and properties of prepared mixtures

9 10 PLA mass parts 20 20 PHB mass parts 80 80 TAC mass parts 0 10 eb % 15 270 ob MPa 39.1 27.3 tenacity - 879.75 11056.5

Example 4

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 4.

Tab. 4. Composition and properties of prepared mixtures

11 12 13 14 PLA mass parts 10 10 10 10 PHB mass parts 90 90 90 90 TAC mass parts 0 8 37 60 eb % 3 6 14 7 ab MPa 17 16.5 9.7 6.7 tenacity - 76.5 148.5 203.7 120.3

Example 5

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 5.

-6Tab. 5. Composition and properties of prepared mixtures

15 16 PLA mass parts 50 50 PHB mass parts 50 50 TAC mass parts 0 10 eb % 2.8 300 ab MPa 39.5 27.2 tenacity - 165.9 12240

Example 6

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 6.

Tab. 6. Composition and properties of prepared mixtures

17 18 PLA mass parts 85 85 PHB mass parts 15 15 TAC mass parts 0 10 sb % 15 368 ab MPa 58 29.5 tenacity - 1305 16284

Example 7

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 7.

Tab. 7. Composition and properties of prepared mixtures

17 19 PLA mass parts 85 85 PHB mass parts 15 15 triethylcitrate mass parts 0 12 eb % 15 375 ab MPa 58 28.2 tenacity - 1305 15862.5

Example 8

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 8.

Tab. 8. Composition and properties of prepared mixtures

20 21 22 PLA mass parts 85 85 85 PHB mass parts 15 15 15

-Ί -

triethylcitrate mass parts 14 7 0 TAC mass parts 0 7 14 ab % 450 445 462 ab MPa 26.9 27.8 29.1 tenacity - 18157.5 18556.5 20166.3

Example 9

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 9.

Tab. 9. Composition and properties of prepared mixtures

23 24 25 26 PLA mass parts 85 85 85 85 PHB mass parts 15 15 15 15 plasticizer 10 parts by weight triethylcitrate trioctyl dibutyl dioctyl sb % 460 472 410 453 ab MPa 25 26.4 31.8 30.8 tenacity - 17250 18691 18557 20928

Example 10

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 10.

Tab. 10. Composition and properties of prepared mixtures

1 2 PLA mass parts 90 90 PHB mass parts 10 10 TAC mass parts 10 10 Joncryl 4368 mass parts 0 2 eb % 101 290 ab MPa 40.5 30.4 tenacity - 6135.75 13224

Joncryl - styrene acrylic resin functionalized by epoxide

Príkladll

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 11.

Tab. 11. Composition and properties of prepared mixtures

3 4 5 6 PLA mass parts 50 50 50 50 PHB mass parts 50 50 50 50

TAC mass parts 10 10 10 10 Joncryl 4368 mass parts 0 0.05 2 5 ab % 300 350 401 395 ab MPa 27.2 28.1 29.0 30.5 tenacity - 12240 14752 17443 18071

Example 12

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 12.

Tab. 12. Composition and properties of prepared mixtures

7 8 9 10 11 12 Pla mass parts 85 85 85 85 85 85 PHB mass parts 15 15 15 15 15 15 TAC mass parts 2 2 10 10 67 67 Joncryl 4368 mass parts 0 2 0 2 0 2 ab % 16 180 300 350 561 572 ab MPa 55.2 49.3 32.4 29.2 20.8 21.2 tenacity - 1324 13311 14580 15330 11668 18189

Example 13

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 13.

Tab. 13. Composition and properties of prepared mixtures

13 14 Pla mass parts 85 85 PHB mass parts 15 15 TAC mass parts 9 8 epoxidized rapeseed oil mass parts 1 2 ab % 350 330 ab MPa 35.2 42.8 tenacity - 18480 21186

Example 14

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 14.

Tab. 14. Composition and properties of prepared mixtures

15 16 P LA Hmôt díly 85 85 PHB Hmôt díly 15 15 triethylcitrate Hmôt díly 12 12

epoxidized rapeseed oil Hmôt díly 1 2 eb % 357 412 ab MPa 35 41.1 tenacity - 18742.5 25399.8

Príkladl5

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 15.

Tab. 15. Composition and properties of prepared mixtures ___

17 18 19 20 21 PLA mass parts 85 85 85 85 85 PHB mass parts 15 15 15 15 15 plasticizer LYP TAC TEC TOF DBS TAC / TEC mass parts 12 12 12 12 6/6 Joncryl 4368 mass parts 1 1 1 1 1 eb % 356 318 371 307 354 ob MPa 48.3 42.5 39.1 41.5 37.4 tenacity - 25792.2 20272.5 21759.15 19110.75 19859.4

TAC - triacetím, TEC - triethyl citrate, TOF - trioctylphosphate, DBS - dibutyl sebacate

Example 16

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 16.

Tab. 16. Composition and properties of prepared mixtures

22 23 24 25 PLA mass parts 85 85 85 85 PHB mass parts 15 15 15 15 additive Type ESO EOO HMDI PEGMM mass parts 1 1 1 1 TAC mass parts 12 12 12 12 eb % 298 301 315 288 ob MPa 41.5 38.2 44.7 37.9 tenacity - 18550.5 17247.3 21120.75 16372.8

ESO - epoxylated soybean oil, EOO - epoxylated olive oil, HMDI - hexamethylene diisocyanate, PEGMM - polyethylene glycidyl methacrylate - co-methacrylate

Example 17

Following the procedure of Example 1, mixtures were prepared with the composition and properties shown in Table 17.

-10Tab. 17. Composition and properties of prepared mixtures

26 27 28 29 PLA mass parts 95 95 5 5 PHB mass parts 5 5 95 95 TAC mass parts 10 10 10 10 Joncryl 4368 mass parts 0 2 0 2 ab % 358 392 180 220 ob MPa 47.5 49.9 28.1 30.5 tenacity - 25507 29341 5058 10065

Industrial usability

The mixture can be used in all applications where a combination of biodegradability and high toughness is required, especially in the packaging industry.

Claims (2)

-11 PROTECTION Claims A biodegradable polymer composition comprising a polymer blend and a plasticizer or blend of plasticizers, wherein the polymer blend is comprised of 5 to 95 wt. % polyhydroxyalkanoate and 95 to 5 wt. 2 to 67 parts by weight of a plasticizer or plasticizer mixture are used per 100 parts by weight of the polymer blend, characterized in that citric acid esters, glycerin esters, phosphoric esters, sebacic esters and other esters are used as plasticizers. liquid organic esters or low molecular weight polyesters. The biodegradable polymer composition of claim 1, further comprising 0.05 to 5 wt. % reactive additive as compatibilizer, characterized in that the reactive additive as compatibilizer is selected from the group of chemicals such as acrylic polymers, epoxidized acrylic polymers, diisocyanates and derivatives thereof, epoxidized oils, oligomeric copolymers of various monomers with glycidylmethacrylates .