SK282175B6 - Pipe junction and method for production of pipe junctions from polyolefin - Google Patents

Pipe junction and method for production of pipe junctions from polyolefin Download PDF

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Publication number
SK282175B6
SK282175B6 SK215-94A SK21594A SK282175B6 SK 282175 B6 SK282175 B6 SK 282175B6 SK 21594 A SK21594 A SK 21594A SK 282175 B6 SK282175 B6 SK 282175B6
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SK
Slovakia
Prior art keywords
pipe
clamping ring
connecting part
pipe end
ambient temperature
Prior art date
Application number
SK215-94A
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Slovak (sk)
Other versions
SK21594A3 (en
Inventor
Friedrich Imgram
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Wirsbo Pex Gmbh
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Application filed by Wirsbo Pex Gmbh filed Critical Wirsbo Pex Gmbh
Publication of SK21594A3 publication Critical patent/SK21594A3/en
Publication of SK282175B6 publication Critical patent/SK282175B6/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L47/00Connecting arrangements or other fittings specially adapted to be made of plastics or to be used with pipes made of plastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/66Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by liberation of internal stresses, e.g. shrinking of one of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C57/00Shaping of tube ends, e.g. flanging, belling or closing; Apparatus therefor, e.g. collapsible mandrels
    • B29C57/02Belling or enlarging, e.g. combined with forming a groove
    • B29C57/04Belling or enlarging, e.g. combined with forming a groove using mechanical means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112Single lapped joints
    • B29C66/1122Single lap to lap joints, i.e. overlap joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/122Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
    • B29C66/1222Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a lapped joint-segment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/122Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
    • B29C66/1226Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least one bevelled joint-segment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/52Joining tubular articles, bars or profiled elements
    • B29C66/522Joining tubular articles
    • B29C66/5221Joining tubular articles for forming coaxial connections, i.e. the tubular articles to be joined forming a zero angle relative to each other
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/52Joining tubular articles, bars or profiled elements
    • B29C66/522Joining tubular articles
    • B29C66/5229Joining tubular articles involving the use of a socket
    • B29C66/52297Joining tubular articles involving the use of a socket said socket comprising slip-off prevention means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L47/00Connecting arrangements or other fittings specially adapted to be made of plastics or to be used with pipes made of plastics
    • F16L47/20Connecting arrangements or other fittings specially adapted to be made of plastics or to be used with pipes made of plastics based principally on specific properties of plastics
    • F16L47/22Connecting arrangements or other fittings specially adapted to be made of plastics or to be used with pipes made of plastics based principally on specific properties of plastics using shrink-down material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C57/00Shaping of tube ends, e.g. flanging, belling or closing; Apparatus therefor, e.g. collapsible mandrels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C61/00Shaping by liberation of internal stresses; Making preforms having internal stresses; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/116Single bevelled joints, i.e. one of the parts to be joined being bevelled in the joint area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/737General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined
    • B29C66/7371General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined oriented or heat-shrinkable
    • B29C66/73715General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined oriented or heat-shrinkable heat-shrinkable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)
  • Branch Pipes, Bends, And The Like (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Non-Disconnectible Joints And Screw-Threaded Joints (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Details Of Indoor Wiring (AREA)

Abstract

A pipe end (13) of a pipe (12) consisting of polyolefin is deformed cold, that is to say at ambient temperature, with the aid of an expanding mandrel. Once the expanding mandrel has been withdrawn, the expanded pipe end (13) and a respectively desired connecting part, or the pipe end (11) of a further pipe (10), are plugged onto one another. The pipe end (13) consisting of polyolefin experiences only a reversible deformation and, as a result of it deforming back to its original shape, forms a firm, gas-tight connection to the connecting part or to the other pipe end (11). <IMAGE>

Description

Oblasť technikyTechnical field

Vynález sa týka spôsobu výroby potrubného spoja, pri ktorom sa rozšíri rúrový koniec rúry z polyoleflnu a nasunie sa na pripojovaciu časť, ako aj takto vyrobeného potrubného spoja.The invention relates to a method for producing a pipe joint in which the pipe end of a polyolefin pipe is expanded and slid onto the connection part as well as the pipe joint thus produced.

Doterajší stav technikyBACKGROUND OF THE INVENTION

Pri známom obdobnom postupe, ktorý je zverejnený v DOS 38 17 442.1, sa takýto potrubný spoj, ktorý sa napríklad vyrobí pomocou zvieracieho puzdra, ktoré premostí pripojovacie časti oboch rúr. Zvieracie puzdro môže pozostávať napríklad z termoplastického materiálu ako je zosieťovaný polyolefln. Toto púzdro sa spojuje s koncovými časťami tak, že zosieťovaný polyolefln po ohriatí nad bodom topenia kryštalitov je v zohriatom stave tvarovateľný a v tomto zohriatom stave sa môže po rozšírení nasunúť na pripojovacie časti. Rovnakým spôsobom sa môže nasunutý rúrový koniec rúry zo zosieťovaného polyoleflnu na pripojovaciu časť, napríklad na T-kus.In a known analogous process, which is disclosed in DOS 38 17 442.1, such a pipe joint is produced, for example, by means of a clamping sleeve which bridges the connecting portions of the two pipes. The clamping sleeve may consist, for example, of a thermoplastic material such as cross-linked polyolefin. This sheath is joined to the end portions such that the crosslinked polyolefin after being heated above the melting point of the crystallites is deformable in the heated state and, in this heated state, can be slid onto the connecting portions after being expanded. In the same way, the pipe end of the crosslinked polyolefin pipe can be slid onto the connecting part, for example a T-piece.

Ďalej je z EP-A-0 102 919 známy spôsob spojenia rúrok a rúrkový spoj takto vyrobený, pri ktorom sa prvý koniec rúry zo zosieťovaného polyoleflnu rozšíri následkom kryštalickej teploty tavenia. Do rozšíreného a ochladeného konca rúry sa zavedie druhý koniec rúry. Nakoniec sa rozšírená rúra pôsobením kryštalickej teploty tavenia oteplí, pričom sa druhý koniec rúry nasadí za tepla čím vznikne tesné spojenie rúrových koncov.Furthermore, EP-A-0 102 919 discloses a method for joining pipes and pipe joints thus produced, in which the first end of the crosslinked polyolefin pipe is expanded due to the crystalline melting temperature. A second end of the pipe is introduced into the expanded and cooled end of the pipe. Finally, the expanded pipe is warmed by the crystalline melting temperature, whereby the other end of the pipe is hot-fused to form a tight connection of the pipe ends.

Uskutočnenie tohto postupu prináša so sebou v praxi určité ťažkosti, pretože zosieťovaný polyolefln sa musí zohriať na relatívne vysokú teplotu, napríklad nad 135 °C v prípade zosieťovaného polyoleflnu a len pri tejto teplote má dostatočne ľahkú tvárnosť. Z toho potom vyplýva potreba, príslušné časti vzájomne spojiť v takom krátkom čase, aby v priebehu tohto času nenastalo ešte ochladenie pod bod topenia kryštalitov.The practice of carrying out this process presents some difficulties in practice, since the crosslinked polyolefin must be heated to a relatively high temperature, for example above 135 ° C in the case of the crosslinked polyolefin, and only at this temperature it has a sufficiently easy formability. Consequently, there is a need for the respective parts to be joined together in such a short time that during this time cooling does not occur below the melting point of the crystallites.

Podstata vynálezuSUMMARY OF THE INVENTION

Úloha vynálezu pozostáva z vytvorenia potrubného spoja, ktorý je vyrobiteľný pri podmienkach okolia a vytvárajúceho bezpečný a tesný spoj ako aj v nájdení spôsobu výroby potrubného spoja, spomenutým spôsobom tak, že výroba bezpečného potrubného spoja sa uskutoční pri bežnej teplote, t. j. pri teplote okolia.SUMMARY OF THE INVENTION The object of the present invention is to provide a pipe joint that is capable of being produced under ambient conditions and which provides a secure and tight joint, as well as a method for manufacturing a pipe joint by the aforementioned method. j. at ambient temperature.

S ohľadom na potrubný spoj je táto úloha vyriešená tým, že tento pozostáva z pripojovacej časti a z pri teplote okolia rozšíreného rúrového konca, pri teplote okolia samovoľne spätne pretvarovateľného, ktorý je pevne a tesne spojený s koncovou časťou pripojovacej časti, pričom rúra má vnútorný priemer, ktorý je menší ako vonkajší priemer pripojovacej časti.With respect to the pipe connection, this object is achieved by the fact that it consists of the connection part and at the ambient temperature of the expanded pipe end, at the ambient temperature of the self-reshapable which is firmly and tightly connected to the end part of the connection part. which is smaller than the outer diameter of the connecting portion.

Podľa vynálezu je spôsob výroby potrubného spoja vyriešený tým, že koniec rúry, ktorej vnútorný priemer je menší, ako vonkajší priemer pripojovacej časti, sa pomocou rozpínacieho tŕňa, pri teplote okolia, reverzibilne roztiahne na taký vnútorný priemer, ktorý je väčší ako je vonkajší priemer pripojovacej časti. Po odstránení rozpínacieho tŕňa sa ešte stále rozšírený koniec rúry nasunie na pripojovaciu časť, pričom koniec rúry sa samovoľným spätným pretvarovaním reverzibilne rozšíreného konca rúry pevne a tesne spojí s pripojovacou časťou.According to the invention, the method of manufacturing a pipe joint is solved by expanding the end of a pipe whose inner diameter is smaller than the outer diameter of the connecting part by means of an expanding mandrel, at ambient temperature, reversibly expanding to an inner diameter larger than the outer diameter of the connecting part. section. After removal of the expanding mandrel, the still expanded pipe end is slid onto the connecting portion, whereby the pipe end is firmly and tightly connected to the connecting portion by spontaneously reforming the reversibly expanded pipe end.

Vynález spočíva na prekvapujúcom poznatku, že polyofelíny, zvlášť so strednou hustotou, vysokou hustotou ale bo zosieťované polyofeliny majú dostatočne veľkú, reverzibilnú tvarovateľnosť aj v studenom a čiastočne kryštalickom stave, t. j. v zohriatom stave neprekračujúcom teplotu topenia kryštalitov. To znamená, že polyolefln je mechanickým účinkom tvarovateľný, ale vo vytvarovanom stave sa snaží dosiahnuť svoj pôvodný tvar. Pri použití dostatočne veľkej sily, napríklad pomocou rozpínacieho tŕňa bežného typu, na rozširovanie rúr, je možné rúrové konce rúr z polyolefínov reverzibilne rozširovať. Pri daných podmienkach, pri teplote okolia, nastáva samovoľné spätné pretvarovanie do pôvodného stavu, t. j. na pôvodnú šírku rúry s relatívne malou rýchlosťou, takže je možné rozpínací tŕň z rozšírenej rúry vybrať a ešte roztiahnutý rúrový koniec na požadovanú pripojovaciu časť nasunúť. Na druhej strane, je rýchlosť samovoľného spätného pretvarovania sa do pôvodného stavu taká veľká, že nevzniká nijaký nežiaduci čakací čas.The invention is based on the surprising finding that polyofelins, in particular of medium density, high density or crosslinked polyofelins, have a sufficiently large, reversible formability even in the cold and partially crystalline state, i. j. in a heated state not exceeding the melting point of the crystallites. This means that the polyolefin is malleable by mechanical action, but in the formed state it seeks to achieve its original shape. When a sufficiently large force is used, for example by means of an expanding mandrel of a conventional type, to expand the tubes, the pipe ends of the polyolefin tubes can be reversibly expanded. Under the given conditions, at ambient temperature, the spontaneous re-deformation takes place, i.e.. j. to the original width of the pipe at a relatively low velocity so that the expanding mandrel can be removed from the expanded pipe and the still expanded pipe end slid onto the desired connecting portion. On the other hand, the rate of spontaneous reshaping is so great that there is no undesirable waiting time.

V porovnaní s iným materiálom majú polyoleflny tú prednosť, že rozšírenie, pokiaľ zostáva aj naďalej po spojení s pripojovacou časťou, nespôsobuje tvorbu trhlín v dôsledku napätia.Compared to another material, polyolefins have the advantage that the extension, as long as it remains after connection to the connection portion, does not cause stress cracking.

Spôsob, podľa vynálezu, ponúka zvlášť výhodnú možnosť, spojovať rúry z polyoleflnu, najmä rúry z polyoleflnu so strednou hustotou, vysokou hustotou alebo zosieťované polyoleflny, bez použitia tepelnej energie s akoukoľvek žiadanou spojovacou časťou. Pritom sa získa samovoľným spätným pretvarovaním rozšíreného rúrového konca zvlášť pevné a tesné, najmä plynotesné spojenie. Pri tomto samovoľnom spätnom pretvarovaní priľahne polyolefln na, v danom prípade danú, povrchovú štruktúru na pripojovacej časti. Ako takéto povrchové štruktúry zvyšujúce spojovaciu pevnosť prichádzajú do úvahy napríklad zosilnenia, vrúbky, drážky alebo tyhovanie, s ktorými spätne pretvarovaný polyolefln prichádza do záberu.The process according to the invention offers a particularly advantageous possibility to join polyolefin pipes, in particular medium density, high density or crosslinked polyolefins, without the use of thermal energy with any desired connecting part. In this case, a particularly rigid and tight, in particular gas-tight connection is obtained by spontaneously re-shaping the expanded pipe end. In this spontaneous re-shaping, the polyolefin adheres, in the present case, to the surface structure on the attachment portion. Examples of such surface structures which increase the bond strength are, for example, the reinforcements, notches, grooves or stiffening with which the reshaped polyolefin comes into engagement.

V súvislosti s predtým opísaným spôsobom je možné, ak je potrebné, ďalšie zabezpečenie zhotovených potrubných spojov. K tomu môžu slúžiť rúrové svorky známeho druhu. Je ale tiež možné, na rúrový koniec rúry z polyolefínu nasunúť zvierajúci krúžok. Tento zvierajúci krúžok sa môže, pokiaľ je tiež z reverzibilne pretvarovateľného materiálu, nasunúť hneď zo začiatku na rúrový koniec. Je ale tiež možné po zhotovení potrubného spoja, nasunúť zo strany rúry na koniec potrubného spoja, napríklad pomocou známych hydraulických prostriedkov, nepretvarovateľný alebo málo pretvarovateľný zvierajúci krúžok, napríklad z kovu.In connection with the method described above, it is possible, if necessary, to further secure the pipe connections made. Pipe clamps of known type can serve for this purpose. However, it is also possible to slide the clamping ring onto the pipe end of the polyolefin pipe. This clamping ring can, if it is also made of a reversibly deformable material, slide from the beginning onto the pipe end. However, it is also possible after insertion of the pipe joint to slide a non-deformable or low deformable clamping ring, for example of metal, from the pipe side onto the end of the pipe joint, for example by known hydraulic means.

Prehľad obrázkov na výkreseOverview of the figures in the drawing

Príklady vyhotovenia, spôsobom, podľa vynálezu vyrobených potrubných spojov sú znázornené na obrázkoch a sú ďalej podrobne vysvetlené a opísané so vzťažnými označeniami. Ukazujú: obr. 1 pohľad v reze potrubného spoja z pripojovacej časti a z rúrového konca nasunutého postupom podľa vynálezu; obr. 2 pohľad v reze potrubného spoja, podľa obrázku 1, so zvieracím krúžkom;Examples of embodiments of pipe joints produced according to the invention are shown in the figures and are further explained and described in detail with reference numerals. FIG. 1 is a cross-sectional view of a pipe joint from a connection portion and a pipe end inserted according to the method of the invention; Fig. 2 is a cross-sectional view of the pipe joint of FIG. 1 with a clamping ring;

obr. 3 pohľad v reze potrubného spoja, podľa vynálezu, medzi dvoma rúrovými koncami.Fig. 3 is a cross-sectional view of a pipe joint according to the invention between two pipe ends.

Príklady uskutočnenia vynálezuDETAILED DESCRIPTION OF THE INVENTION

Pri pohľade v reze na obr. 1 je možné vidieť pripojovaciu časť 1, ktorou môže byť napríklad rovný kus rúry, koleno alebo iný spojovací kus na spojenie dvoch rúr, ale aj naAs seen in section in FIG. 1, it is possible to see the connecting part 1, which may be, for example, a straight pipe piece, an elbow or another coupling piece for connecting two pipes, but also for

SK 282175 Β6 príklad trojnásobný spojovací kus ako T-kus. Táto pripojovala časť 1 je vyrobená z materiálu ako je kov, sklo, keramika, plast alebo z nejakého iného, na daný účel použitia, vybraného materiálu. Na každom spojovanom mieste je pripojovacia časť 1 vybavená povrchovou štruktúrou zvyšujúcou spojovaciu pevnosť. V znázornenom príklade vyhotovenia je táto povrchová štruktúra tvorená zosilnenou, ku koncu sa zmenšujúcou koncovou časťou 2, miesto nej môžu byť tiež jedno alebo viaceré zosilnenia, vrúbky, drážky alebo ryhovanie alebo im podobné.Example of a triple connecting piece as a T-piece. This attached part 1 is made of a material such as metal, glass, ceramic, plastic or some other, for a given purpose, selected material. At each joining point, the connecting portion 1 is provided with a surface structure increasing the bonding strength. In the illustrated embodiment, the surface structure is formed by a reinforced end-to-end end portion 2, instead of one or more reinforcements, notches, grooves or grooves or the like.

Znázornenie na obr. 1 ukazuje rúru 3 z polyoleflnu, výhodne zo stredne hustého alebo vysoko hustého zosieťovaného polyoleflnu. Vnútorný priemer rúry 3 je menší ako vonkajší priemer pripojovacej časti 1, môže, ako je to znázornené, v podstate mať rovnaký priemer ako je vnútorný priemer pripojovacej časti 1, čím sa môže zabrániť vytvoreniu odporu prúdenia zúženiami a usadeninami v zúženiach, z média pretekajúceho cez pripojovaciu časť 1 a rúruThe representation of FIG. 1 shows a pipe 3 of polyolefin, preferably of medium or high density crosslinked polyolefin. The inner diameter of the pipe 3 is smaller than the outer diameter of the connecting portion 1, as shown, may have substantially the same diameter as the inner diameter of the connecting portion 1, thereby avoiding the formation of flow resistance through the constrictions and deposits in the constrictions from the medium flowing through the connection part 1 and the pipe

3. Pri vyhotovení rúrového spoja sa rúrový koniec 4 natoľko rozšíri pri teplote okolia, napríklad pomocou rozpínacieho tŕňa bežného typu, že vnútorný priemer rúrového konca 4 je najmenej tak široký, ako je vonkajší priemer pripojovacej časti 1, v oblasti zosilnenej koncovej časti 2. Po nasunutí cez zosilnenú koncovú časť 2 rúrový koniec 4 samovoľne získa pôvodný tvar s pôvodným rozmerom. Následkom toho priľahne rúrový koniec 4, ako je to znázornené, na vonkajší profil pripojovacej časti 1. Pretože rúrový koniec 4 mal pôvodne taký vnútorný priemer, ktorý bol menší ako vonkajší priemer pripojovacej časti 1, nasunie sa rúrový koniec 4 pozdĺž svojej dĺžky tesne na koncovú časť 2 pripojovacej časti 1. Tým vznikne na konci značný veľkoplošný, veľmi tesný spoj medzi rúrovým koncom 4 a pripojovacou časťou 1.3. In the embodiment of the pipe joint, the pipe end 4 is expanded so much at ambient temperature, for example by means of an expanding mandrel of the conventional type, that the inner diameter of the pipe end 4 is at least as wide as the outer diameter of the connecting portion 1 in the region of the reinforced end portion. sliding over the reinforced end portion 2 the pipe end 4 spontaneously acquires the original shape with the original dimension. As a result, the pipe end 4, as shown, adheres to the outer profile of the connecting part 1. Since the pipe end 4 initially had an inner diameter that was smaller than the outer diameter of the connecting part 1, the pipe end 4 slid along its length just over the end This results in a large, very large, very tight joint at the end between the pipe end 4 and the connecting part 1.

Obr. 2 ukazuje ďalšie vyhotovenie predtým opísaného potrubného spoja, pričom zodpovedajúce časti sú vybavené rovnakými vzťahovými značkami. Pri tomto vyhotovení sa použije zvierajúci krúžok 5 na dodatočné zabezpečenie vyhotoveného tesného spoja medzi rúrovým koncom 4 a pripoj ovacou časťou 1.Fig. 2 shows a further embodiment of the previously described pipe joint, the corresponding parts being provided with the same reference numerals. In this embodiment, a clamping ring 5 is used to additionally secure the made tight joint between the pipe end 4 and the connection part 1.

Tento zvierajúci krúžok 5 je prednostne z rovnakého materiálu ako rúra 3. V znázornenom príklade vyhotovenia je rúra 3, ako aj zvierajúci krúžok, zo zosieťovaného polyetylénu. Vnútorný priemer zvierajúceho krúžku 5 je tesne napasovaný na vonkajší priemer rúry 3 napasovaný a nasunie sa pred zhotovením potrubného spoja na rúrový koniecThis clamping ring 5 is preferably of the same material as the pipe 3. In the illustrated embodiment, the pipe 3 and the clamping ring are made of cross-linked polyethylene. The inner diameter of the clamping ring 5 is tightly fitted to the outer diameter of the pipe 3 fitted and slid onto the pipe end before making the pipe joint.

4. Pri nasledujúcom rozpínacom postupe sa zvierajúci krúžok 5 spolu s rúrovým koncom 4 predbežne roztiahne, takže roztiahnutý rúrový koniec 4 spolu s nasadeným zvierajúcim krúžkom 5 sa nasunie na koncovú čas 2 pripojovacej časti 1. Následné samovoľné spätné pretvarovanie vedie potom, podľa opísaného spôsobu, k tesnému spoju medzi rúrovým koncom 4 a koncovou časťou 2 pripojovacej časti 1, pričom sa aj zvierajúci krúžok 5 stiahne a dodatočne stlačí rúrový koniec 4 v oblasti zvierajúceho krúžku 5 proti koncovej časti 2.4. In the following expansion procedure, the clamping ring 5 together with the pipe end 4 is pre-expanded so that the expanded pipe end 4 together with the clamping ring 5 is pushed onto the end part 2 of the connecting part 1. Subsequent spontaneous re-deformation then to the tight connection between the pipe end 4 and the end part 2 of the connecting part 1, whereby the clamping ring 5 also contracts and additionally compresses the pipe end 4 in the region of the clamping ring 5 against the end part 2.

Obr. 3 ukazuje potrubný spoj, ktorý je vytvorený medzi dvoma rúrovými koncami. Obe rúry môžu byť z rovnakých alebo z rôznych materiálov; sú rúry vyhotovené zo zosieťovaného polyoleflnu a slúžia ako potrubie pre korozívne médiá. Ako príklad sa môžu uviesť priemyselné, ale zvlášť aj domáce alebo komunálne odpadové vody, ktoré vyžadujú zvlášť korózii odolné rúrové materiály. Na tieto účely sa v praxi osvedčili rúry zo zosieťovaného polyoleflnu.Fig. 3 shows a pipe joint that is formed between two pipe ends. Both tubes may be of the same or different materials; the pipes are made of cross-linked polyolefin and serve as a conduit for corrosive media. By way of example, industrial, but in particular also domestic or municipal waste water, which requires particularly corrosion-resistant pipe materials. For this purpose, crosslinked polyolefin pipes have been proven in practice.

V znázornenom príklade vyhotovenia majú obe rúry rovnaké vonkajšie a vnútorné priemery. Ale nezáleží na tom, že sa môžu vyrobiť rovnaké potrubné spoje v danom prípade aj medzi rúrami s rôznymi priemermi, pokiaľ takto spojené rozdiely vo vnútorných priemeroch nespôsobia neprijateľné odpory prúdenia a usadeniny. Prvá rúra 10 má prvý rúrový koniec 11, druhá rúra 12 má druhý rúrový koniec 13. Je vidieť, že vnútorný priemer druhého rúrového konca 13 je rozšírený a tento rozšírený druhý rúrový koniec 13 je nasunutý na prvý rúrový koniec 11 prvej rúry 10. Toto rozšírenie sa ako v uvedenom príklade vyhotovenia napríklad uskutoční vhodným rozpínacím tŕňom pri teplote okolia a podlieha opísanému samovoľnému spätnému pretvarovaniu, pomocou ktorého sa rozšírený rúrový koniec 13 snaží znovu nadobudnúť svoj predchádzajúci stav. Veľkoplošné, tesné dosadnutie medzi oboma rúrovými koncami 11 a 13 aj tu vytvára tesný potrubný spoj, ktorý vďaka odolnosti materiálu voči korózii proti uvedenej odpadovej vode bude tesný aj pri dlhom používaní.In the illustrated embodiment, both tubes have the same outer and inner diameters. However, it does not matter that the same pipe joints can be produced in the present case also between tubes of different diameters, provided that the differences in internal diameters so connected do not cause unacceptable flow resistances and deposits. The first pipe 10 has a first pipe end 11, the second pipe 12 has a second pipe end 13. It can be seen that the inner diameter of the second pipe end 13 is widened and this expanded second pipe end 13 is slid onto the first pipe end 11 of the first pipe 10. This extension For example, as in the present embodiment, it is carried out with a suitable expanding mandrel at ambient temperature and is subject to the spontaneous re-deformation described above, by means of which the expanded pipe end 13 seeks to regain its previous state. The large-area, tight abutment between the two pipe ends 11 and 13 also forms a tight pipe connection here, which, due to the corrosion resistance of the material against said waste water, will be tight even during prolonged use.

Ako na obr. 2 znázorňujúcom príklad výroby, aj tu sa môže dodatočne zabezpečiť spoj pomocou zvierajúceho krúžku; treba ale dávať pozor, aby pri tlaku takéhoto zvierajúceho krúžku, nenastala nijaká neprípustná zmena tvaru prvého rúrového konca 11, ktorá predstavuje odpor prúdeniu pretekajúcej odpadovej vody alebo dáva podnet na usadeniny z odpadovej vody v oblasti miesta spoja. Namiesto zvierajúceho krúžku sa môže danom prípade použiť tiež upevňovací prostriedok na dodatočné zabezpečenie miesta spoja.As in FIG. 2 showing an example of manufacture, here again the connection can be additionally secured by a clamping ring; however, care must be taken that, under the pressure of such a clamping ring, there is no unacceptable change in the shape of the first pipe end 11, which constitutes a flow resistance of the flowing waste water or gives rise to waste water deposits in the area of the joint. Instead of the clamping ring, a fastening means can also be used in the present case to additionally secure the connection point.

Rúry zo zosieťovaného polyoleflnu sa používajú aj z tohto dôvodu v technike odpadových vôd, pretože týmto spôsobom sa môžu ľahko vyrobiť bezpečné, samotesniace spoje medzi hladkými rúrami. K tomu pristupuje ešte ďalšia prednosť, že rúry 10 a 11 vyhotovené kontinuálnym postupom sa môžu položiť ako rúry z jedného kusa bez toho, aby boli potrebné zvláštne kolená alebo iné pripojovacie časti, aby sa rúry mohli položiť do požadovanej polohy. Je teda potrebné urobiť spoje len na miestach vstupu a výstupu medzi rúrami.Crosslinked polyolefin pipes are also used for this reason in sewage technology, since in this way safe, self-sealing joints between smooth pipes can be easily produced. A further advantage is that pipes 10 and 11 made by a continuous process can be laid in one piece without the need for special elbows or other connecting parts so that the pipes can be laid in the desired position. It is therefore only necessary to make connections at the inlet and outlet points between the pipes.

Claims (11)

PATENTOVÉ NÁROKYPATENT CLAIMS 1. Spôsob výroby zvierajúceho spoja pozostávajúceho z konca (4) rúry (3), zo zosieťovaného polyoleflnu a spojovacej časti (1) s povrchovou štruktúrou, pri ktorom koniec (4) rúry (3) zo zosieťovaného polyoleflnu, ktorý má vnútorný priemer menší ako je vonkajší priemer spojovacej časti (1), rozšírený pomocou rozpínacieho tmu, pri teplote okolia na vnútorný priemer, ktorý je väčší ako je vonkajší priemer spojovacej časti (1) a po odstránení rozpínacieho tmu sa ešte rozšírený koniec (4) rúry (3) a spojovacia časť (1) na seba nastrčia a potom sa zmraštením rozšíreného konca (4) rúry spolu spoja, vyznačujúci sa t ý m , že sa koniec (4) rúry vybaví zvierajúcim krúžkom (5) vytvoreným z materiálu, pri teplote okolia rozšíriteľným a samovoľne pretvarovateľným a spolu so zvierajúcim krúžkom (5) sa samovoľným pretvarovaním pri teplote okolia pevne a tesne spojí s pripojovacou časťou (1).Method for producing a clamping joint comprising an end (4) of a cross-linked polyolefin tube and a connecting portion (1) having a surface structure, wherein the end (4) of cross-linked polyolefin tube having an inner diameter less than the outer diameter of the connecting part (1) is widened by means of expanding darkness at ambient temperature to an inner diameter which is larger than the outer diameter of the connecting part (1) and after removal of the expanding darkness the end (4) of the pipe (3) is the coupling part (1) is pushed together and then shrunk together by shrinking the expanded pipe end (4), characterized in that the pipe end (4) is provided with a clamping ring (5) made of material expandable and spontaneously at ambient temperature By means of a deformable and together with a clamping ring (5), it is firmly and tightly connected to the connecting part (1) by spontaneous deformation at ambient temperature. 2. Spôsob, podľa nároku 1, vyznačujúci sa t ý m , že zvierajúci krúžok (5) pozostáva zo zosieťovaného polyoleflnu.Method according to claim 1, characterized in that the clamping ring (5) consists of crosslinked polyolefin. 3. Spôsob, podľa nároku 1. alebo 2, vyznačujúci sa tým, že sa rozšírený koniec (4) rúry zmraští na koncovú časť (2) pripojovacej časti (1) vybavenej na vonkajšom obvode povrchovou štruktúrou.Method according to claim 1 or 2, characterized in that the widened pipe end (4) shrinks to the end part (2) of the connecting part (1) provided on the outer periphery with a surface structure. 4. Spôsob, podľa nároku 3, vyznačujúci sa t ý m , že povrchová štruktúra sa vytvorí zo zosilnenej, ku koncu sa zužujúcej koncovej časti (2).Method according to claim 3, characterized in that the surface structure is formed from a thickened end-tapered end portion (2). 5. Potrubný spoj v tvare zvierajúceho spoja pozostávajúci z pripojovacej časti (1) s povrchovou štruktúrou a z5. Clamping joint pipe connection consisting of a connecting part (1) with a surface structure and SK 282175 Β6 konca (4) rúry (3) zo zosieťovaného polyolefínu, ktorý má vnútorný priemer menší ako je vonkajší priemer pripojovacej časti (1), pričom pri teplote okolia rozšírení koniec (4) rúry (3) je samovoľným pretvarovaním spojený s pripojovacou časťou (1), v y z n a č u j ú c i sa tým, že rúrový koniec (4) je vybavený zvierajúcim krúžkom (5) z materiálu, pri teplote okolia rozšíriteľným a samovoľne sa pretvarovateľným.2826 the end (4) of the cross-linked polyolefin pipe (3) having an inner diameter smaller than the outer diameter of the connecting part (1), the end (4) of the pipe (3) being spontaneously deformed to the connecting part (1), characterized in that the pipe end (4) is provided with a clamping ring (5) of a material, extensible at ambient temperature and self-deformable. 6. Potrubný spoj, podľa nároku 5, vyznačujúci sa t ý m , že zvierajúci krúžok (5) pozostáva z rovnakého materiálu ako rúra (3).Pipe joint according to claim 5, characterized in that the clamping ring (5) consists of the same material as the pipe (3). 7. Potrubný spoj, podľa nároku 5 alebo 6, v y z n a čujúci sa tým, že povrchová štruktúra je vytvorená na koncovej časti (2) pripojovacej časti (1) a cez jej vonkajší obvod prečnieva.Pipe joint according to claim 5 or 6, characterized in that the surface structure is formed on the end portion (2) of the connecting portion (1) and overlaps over its outer periphery. 8. Potrubný spoj, podľa nároku 7, vyznačujúci sa t ý m , že povrchová štruktúra je vytvorená zo zosilnenej, ku koncu sa zužujúcej koncovej časti (2).Pipe joint according to claim 7, characterized in that the surface structure is formed from a thickened end-tapered end portion (2). 9. Potrubný spoj v tvare zvieracieho spoja pozostávajúci z prvého rúrového konca (11) prvej rúry (10) zo zosieťovaného polyolefínu a z druhého rúrového konca (13) druhej rúry (12) zo zosieťovaného polyolefínu, ktorý má vnútorný priemer menší ako je vonkajší priemer prvého rúrového konca (11), pričom pri teplote okolia rozšírení rúrový koniec (13) je samovoľným pretvarovaním spojený s prvý rúrovým koncom (11), v y z n a č u j ú c i sa tým, že druhý rúrový koniec (13) je vybavený zvierajúcim krúžkom vytvoreným s materiálu, pri teplote okolia rozšíriteľným a samovoľne späť pretvarovateľným .A clamp-like pipe joint comprising a first pipe end (11) of a first crosslinked polyolefin pipe (10) and a second pipe end (13) of a second crosslinked polyolefin pipe (12) having an inner diameter smaller than the outer diameter of the first a pipe end (11), wherein at the ambient temperature of the extension the pipe end (13) is spontaneously connected to the first pipe end (11), characterized in that the second pipe end (13) is provided with a clamping ring formed of material , at ambient temperature expandable and self-deformable. 10. Potrubný spoj, podľa nároku 9, vyznačujúci sa t ý m , že zvierajúci krúžok (5) pozostáva z rovnakého materiálu ako je druhá rúra (12).Pipe joint according to claim 9, characterized in that the clamping ring (5) consists of the same material as the second pipe (12). 11. Potrubný spoj, podľa nároku 9 alebo 10, vyznačujúci sa tým, že prvá a druhá rúra (10,12) sú vytvorené ako hladké rúry.A pipe joint according to claim 9 or 10, characterized in that the first and second pipes (10, 12) are formed as plain pipes.
SK215-94A 1991-08-31 1992-08-21 Pipe junction and method for production of pipe junctions from polyolefin SK282175B6 (en)

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EP91114686A EP0530387B2 (en) 1991-08-31 1991-08-31 Pipeline connection and method of manufacturing pipeline connections made of polyolefine
PCT/EP1992/001923 WO1993005332A1 (en) 1991-08-31 1992-08-21 Pipe joint and process for producing pipe joints made of polyolefin

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SK21594A3 (en) 1994-08-10
NO940672D0 (en) 1994-02-25
EP0530387B1 (en) 1995-11-02
NO940672L (en) 1994-02-25
ES2081406T5 (en) 2000-01-16
CZ286291B6 (en) 2000-03-15
PT100823B (en) 2001-05-31
HK100096A (en) 1996-06-14
GR3032196T3 (en) 2000-04-27
HUT69886A (en) 1995-09-28
ATE129795T1 (en) 1995-11-15
JPH06509994A (en) 1994-11-10
KR100250347B1 (en) 2000-04-01
HU215296B (en) 1998-11-30
AU2440192A (en) 1993-04-05
PT100823A (en) 1994-05-31
FI940864A0 (en) 1994-02-24
IL102958A0 (en) 1993-01-31
IL102958A (en) 1995-07-31
CA2116561A1 (en) 1993-03-18
FI940864A (en) 1994-02-24
PL170053B1 (en) 1996-10-31
EP0530387A1 (en) 1993-03-10
CZ32294A3 (en) 1994-05-18
WO1993005332A1 (en) 1993-03-18
TR27381A (en) 1995-02-01
JP3223977B2 (en) 2001-10-29
DK0530387T4 (en) 2000-04-17
GR3018275T3 (en) 1996-02-29
DE59106833D1 (en) 1995-12-07
NZ244134A (en) 1994-07-26
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KR940702257A (en) 1994-07-28
DK0530387T3 (en) 1996-03-04
HU9400390D0 (en) 1994-05-30
NO311952B1 (en) 2002-02-18
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EP0530387B2 (en) 1999-10-06
ES2081406T3 (en) 1996-03-01

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