SI9600307A - Ultrasonic precrystallizer - Google Patents

Ultrasonic precrystallizer Download PDF

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Publication number
SI9600307A
SI9600307A SI9600307A SI9600307A SI9600307A SI 9600307 A SI9600307 A SI 9600307A SI 9600307 A SI9600307 A SI 9600307A SI 9600307 A SI9600307 A SI 9600307A SI 9600307 A SI9600307 A SI 9600307A
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Prior art keywords
water
ultrasonic
recrystallizer
ultrasound
softening
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SI9600307A
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Slovenian (sl)
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Marjan Zupancic
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Marjan Zupancic
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Priority to SI9600307A priority Critical patent/SI9600307A/en
Publication of SI9600307A publication Critical patent/SI9600307A/en
Priority to PCT/SI1997/000026 priority patent/WO1998017584A1/en
Priority to AU43251/97A priority patent/AU4325197A/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/34Treatment of water, waste water, or sewage with mechanical oscillations
    • C02F1/36Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/10Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physical Water Treatments (AREA)

Abstract

The figure shows an ultrasound crystallizer in straight form showing the housing (1), the cover of the ultrasound generator (2), the ultrasound generator (3), the digital regulator (4) and the cover of the digital regulator (5). The ultrasound generator (3) emits high density energy which precludes the formation of calcareous deposits in pipelines and other equipment. A correct selection of an ultrasound frequency will further achieve a bacterial reduction in warm water systems and a sediment disinfection in treatment plants following anaerobic and aerobic fermentation processes.

Description

OPIS IZUMADESCRIPTION OF THE INVENTION

Področje tehnikeThe field of technology

Cevovodi; filtriranje; ultrazvočno čiščenje.Pipelines; filtering; ultrasonic cleaning.

Prikaz problemaView the problem

Trda voda ima različne količine prostih ionov kalcija in magnezija ter drugih nečistoč. Te se pri segrevanju vode v odvisnosti od temperature izločajo in vežejo v kristale, ki se nalagajo na površinah, ki so v stiku z vodo. Obloge najdemo tako predvsem na grelnih telesih, kolenih in podobnih cevnih elementih, skratka na površinah, ki imajo bodisi visoko temperaturo ali pa se tam nenadoma spremenijo pogoji delovanja. Med slednje prištevamo šobe, armature in podobne elemente, ki predstavljajo stik trde vode z okolico. Zaradi nalaganja kristalov na površine se zelo zmanjša izkoristek naprave, kvaliteta vode pa poslabša. Klasične metode filtriranja ali kemične obdelave so bodisi drage, bodisi neudobne (potrebna je menjava filtrov ipd.).Hard water has different amounts of free calcium and magnesium ions and other impurities. Depending on the temperature, these are separated and bind to crystals, which are deposited on surfaces that are in contact with water, depending on the temperature. The linings are found mainly on heaters, elbows and similar pipe elements, in short on surfaces that have either a high temperature or where operating conditions suddenly change. The latter include nozzles, fittings and similar elements that represent the contact of hard water with its surroundings. Due to the deposition of crystals on the surfaces, the efficiency of the device is greatly reduced and the water quality is deteriorated. The classic methods of filtering or chemical treatment are either expensive or inconvenient (changing filters, etc.) required.

Tehnični problem je torej preprečevanje spajanja ionov kalcija, magnezija in pospeševanje izločanja trdnih delcev iz tekočine na uporabniku prijazen, enostaven in ne predrag način.The technical problem, therefore, is to prevent the conjugation of calcium ions, magnesium and to accelerate the separation of particulate matter from the liquid in a user-friendly, simple and not expensive way.

Stanje tehnikeThe state of the art

Koncept mehčanja, čiščenja in separacije s pomočjo tlačnih valov je že znan, med drugim je opisan v US 3,992,288 kjer Kling navaja uporabo separacije predmetov ene specifične teže od predmetov druge, različne specifične teže tako, da predmeti z večjo specifično težo vsled delovanja ultrazvočnih valov migrirajo navzdol, medtem ko premeti z manjšo specifično težo vsled delovanja zakonov o ohranitvi migrirajo navzgor. Slabost opisanega stanja tehnike je v uporabi omenjenega za ločevanje trdnih delcev in ne za ločevanje ali čiščenje tekočin.The concept of softening, purifying, and separating by means of pressure waves is already known, inter alia, in U.S. Pat. No. 3,992,288, where Kling states the use of separation of objects of one specific gravity from objects of another, different specific gravity such that objects with greater specific gravity due to the action of ultrasonic waves downward, while lower specific gravity migrates upward due to the operation of conservation laws. The disadvantage of the prior art is in the use mentioned for separating solids and not for separating or purifying liquids.

Razen zvočnih valov je mogoče mehčanje trde vode doseči z uporabo magnetnih prekristalizatorjev, ki so podvrženi različnim vplivom in slabo delujejo predvsem pri različni kvaliteti vode, npr. pri vodi s koncentracijo silicija preko 40 ppm in železa preko 2 ppm.In addition to sound waves, hard water softening can be achieved by using magnetic recrystallizers that are subject to different influences and perform poorly especially in different water quality, e.g. for water with a concentration of silicon exceeding 40 ppm and iron exceeding 2 ppm.

Razen naštetega je mogoče mehčanje vode doseči s pomočjo kemijskih pripomočkov in dodatkov, ki pa zahtevajo uporabo katalizatorjev in reagentov, ki lahko v vodi pustijo svoje sledi ter ji tako spremenijo kvaliteto.Apart from the above, water softening can be achieved with the help of chemical aids and additives, which, however, require the use of catalysts and reagents, which can leave their marks in the water and thus change its quality.

Stanje tehnike zajema tudi US 4,244,749 kjer Sachs et. al. opisujejo uporabo ultrazvočnih transducerjev za čiščenje bioloških oblog na zunanji strani cevi s pomočjo kavitacije. Slabost opisanega stanja tehnike je v omejevanju uporabe na zunanjo stran cevi in na kavitacijo.The prior art also includes US 4,244,749 where Sachs et. al. describe the use of ultrasonic transducers to clean biological liners on the outside of the tube by cavitation. A disadvantage of the prior art is that it is limited to use on the outside of the tube and on cavitation.

Stanje tehnike zajema tudi US 4,320,528 kjer Scharton et al. predlagajo uporabo ultrazvoka za čiščenje korozijskih, oksidacijskih, sedimentacijskih in podobnih kemičnih produktov iz različnih delov toplotnih prenosnikov, predvsem iz težje dostopnih delov le-teh. Slabost opisanega stanja tehnike je v omejevanju uporabe tehnike na stacionarne obloge in aplikacije, povezane s toplotnimi prenosniki.The prior art also covers US 4,320,528 where Scharton et al. propose the use of ultrasound to clean corrosion, oxidation, sedimentation and similar chemical products from various parts of heat exchangers, in particular from more difficult to access parts. The disadvantage of the prior art is to limit the use of the technique to stationary liners and applications related to heat exchangers.

Stanje tehnike nadalje zajema US 4,727,734 kjer Kanazawa et al. opisujejo uporabo čistilnega mehanizma, delujočega na podlagi zračnih mehurčkov, ki so bodisi v sistem inducirani ali povzročeni zaradi uporabe ultrazvočnega generatorja. Slabost opisanega stanja tehnike je v uporabi metode v stacionarnih ali gibljivih rezervoarjih, ne pa v cevnih sistemih ter v omejevanju na čistilni efekt zračnih mehurčkov.The prior art further encompasses US 4,727,734 where Kanazawa et al. describe the use of an air-bubble-based cleaning mechanism, either induced or induced by the use of an ultrasonic generator. The disadvantage of the prior art is the use of the method in stationary or moving tanks, but not in pipe systems, and in limiting the cleaning effect of air bubbles.

Stanje tehnike zajema tudi US 4,752,401, kjer Bodenstein predlaga čiščenje pitne vode ali tehniške vode v obtočni napravi, kjer prihaja voda v neposredni kontakt z ultravioletno lučjo. Pri tem uporablja tudi ultrazvočni generator, vendar se omejuje le načiščenje površine ultravioletne luči, ne pa tudi vode same, kar je glavna slabost opisanega stanja tehnike.The prior art also includes US 4,752,401, where Bodenstein proposes to purify drinking water or technical water in a recirculation device where the water comes in direct contact with the ultraviolet light. In doing so, it also uses an ultrasonic generator, but it only limits the cleaning of the surface of the ultraviolet light, but not the water itself, which is a major disadvantage of the prior art.

Stanje tehnike zajema tudi CA 583869, kjer Masri opisuje sistem čiščenja vode v obtoku s pomočjo ultrazvoka v mejah med 15 in 150 kHz za čas najmanj 12 sekund, kar pozvroča kavitacijo. Prav te omejitve so glavna slabost opisanega stanja tehnike.The state of the art is also covered by CA 583869, where Masri describes a circulating water purification system using ultrasound in the range of 15 to 150 kHz for a period of at least 12 seconds, which causes cavitation. These limitations are the main disadvantages of the prior art.

Stanje tehnike nadalje zajema US 5,059,331, kjer Goyal opisuje sistem filtriranja tekočine s pomočjo ultrazvočne energije in kombinacijo le-tega z efektom povratnega udarca vode. Poglavitna slabost opisanega stanja tehnike je v omejenosti na čiščenje oblog in to s potapljanjem elementa.The state of the art further covers US 5,059,331, where Goyal describes a fluid filtration system using ultrasonic energy and a combination thereof with the effect of water return shock. The main disadvantage of the prior art is that it is limited to the cleaning of the linings by immersing the element.

Stanje tehnike zajema tudi US 5,085,783, kjer Feke et. al. opisujejo separacijo delcev iz tekočine v podolgovati komori, skozi katero prehaja tekočino in v kateri deluje akustični val, s pomočjo katerega je mogoče delce voditi v en del komore, medtem ko teče tekočina v drugi del komore. Slabost omenjega stanja tehnike je v omejitvah glede oblike in uporabe tehnike ter v sami izvedbi naprave.The state of the art also covers US 5,085,783, where Feke et. al. describe the separation of particles from a fluid in an elongated chamber through which a fluid passes and in which an acoustic wave operates, through which the particles can be guided to one part of the chamber while the fluid flows into the other part of the chamber. The disadvantages of the prior art are in the limitations on the design and use of the technique and in the design of the device itself.

Stanje tehnike zajema tudi JP 1-301843, kjer Ushimaru et al. opisuje uporabo ultrazvočnega generatorja v tanku vode za odpravo nekaterih komponent, ki so nastale pri kloriranju vode. Slabost omenjenega stanja tehnike je v nujnosti uporabe vodnega tanka.The state of the art is also covered by JP 1-301843, where Ushimaru et al. describes the use of an ultrasonic generator in a water tank to eliminate some of the components that have arisen from the chlorination of water. The disadvantage of this prior art is the necessity of using a water tank.

Stanje tehnike zajema tudi US 5,466,367 kjer Coate et. al. opisujejo uporabo ultrazvoka za povzročitev koagulacije in precipitacije v industrijskih odplakah, kar je tudi glavna pomanjkljivost omenjenega stanja tehnike.The prior art also includes US 5,466,367 where Coate et. al. describe the use of ultrasound to induce coagulation and precipitation in industrial effluents, which is also a major drawback of the prior art.

Stanje tehnike končno zajema tudi JP 5-250537 in JP 6-028099 kjer Dokhu et al. opisujejo čiščenje predmetov s pomočjo ultrazvoka v več zaporednih korakih. Glavna pomanjkljivost omenjenega stanja tehnike je prav v omejitvi na čiščenje stacionarnih predmetov v vodnem rezervoarju.The prior art also includes JP 5-250537 and JP 6-028099 where Dokhu et al. describe the cleaning of objects by ultrasound in several consecutive steps. The main disadvantage of this state of the art is precisely the limitation to the cleaning of stationary objects in a water reservoir.

Kot ena od bistvenih sestavin obstoječega stanja tehnike je uporabljen ultrazvočni generator. To je naprava, ki spreminja vnešeno energijo, kije bodisi električna, bodisi mehanska, bodisi kaka druga oblika energije v tlačne valove, ki se manifestirajo kot zvok visokih frekvenc, imenovan ultrazvok. Ultrazvočni generator je opisan, bodisi direktno, bodisi z pomočjo referenc, v zgoraj opisanih patentnih prijavah, kijih v tem delu inkorporiramo kot referenco.An ultrasonic generator is used as one of the essential components of the current state of the art. It is a device that converts the input energy, which is either electrical, mechanical, or some other form of energy into pressure waves that manifest as high-frequency sound, called ultrasound. The ultrasonic generator is described, either directly or by reference, in the patent applications described above, which are incorporated herein by reference.

Opis nove rešitveDescription of the new solution

Predmet predstavljenega izuma je ultrazvočni prekristalizator, ki uspešno rešuje probleme, prisotne v obstoječem stanju tehnike. Bistven del predmeta izuma je ultrazvočni generator, ki zaradi velike specifične energije preprečuje spajanje ionov kalcija in magnezija v topli vodi in s tem nastajanje apnenčastih oblog v cevovodih in na drugi opremi.The object of the present invention is an ultrasonic recrystallizer that successfully solves problems present in the prior art. An essential part of the object of the invention is an ultrasonic generator, which, due to its high specific energy, prevents the coupling of calcium and magnesium ions in warm water and thus the formation of limestone deposits in pipelines and other equipment.

Ultrazvočni generator (3) je pritrjen na ohišje prekristalizatorja (1), ki ga vgradimo v cevovod, pri čemer je lahko ohišje razen v ravni tudi v kotni izvedbi, izvedljiva pa je tudi kombinacija z merilnikom pretoka ali kalorimetrom. Ultrazvočni generator (3) je zaščiten s pokrovom (2). Na pokrov je pritrjen digitalni regulator (4) za reguliranje frekvence in jakosti ultrazvoka, ki ga generira ultrazvočni regulator (3). Tudi digitalni regulator (4) je zaščiten s pokrovom digitalnega regulatorja (5).The ultrasonic generator (3) is attached to the recrystallizer housing (1), which is installed in the pipeline, the housing can be except in straight line and angular, and a combination with a flowmeter or calorimeter is feasible. The ultrasonic generator (3) is protected by a cover (2). A digital controller (4) is mounted on the cover to control the frequency and volume of the ultrasound generated by the ultrasonic controller (3). The digital controller (4) is also protected by the cover of the digital controller (5).

Predmet izuma je mogoče uporabiti v napravah za pripravo pitne vode, centralnega ogrevanja in vseh drugih napravah, v katerih se zaradi povišane temperature v vodi izločajo apnenčaste obloge. Ob tem pa z uporabo ultrazvočnega prekristalizatorja ne vplivamo na kvaliteto vode, hkrati pa je naprava sama za okolje neškodljiva.The object of the invention can be used in installations for the preparation of drinking water, central heating and any other device in which limestone deposits are eliminated due to the elevated temperature in the water. At the same time, the use of an ultrasonic recrystallizer does not affect the quality of the water, and at the same time the device is environmentally friendly.

Predmet izuma je mogoče priključiti kjerkoli v sistemu, najustreznejša pa se zdi priključitev na dovod hladne vode tik pred napravo za proizvodnjo tople vode ali pa na dovod pitne vode v objekt, tako da imajo vsi porabniki na razpolago mehčano vodo. Mogoče pa je priključiti predmet izuma tudi neposredno v vse vrste naprav za proizvodnjo tople in vroče vode. Nadalje je ultrazvok mogoče s posebno oblikovanim zaslonom usmeriti na željeno mesto ob upoštevanju dejstva, da je vpadni kot zvoka na zaslon enak odbojnemu.The object of the invention can be connected anywhere in the system, but the most appropriate seems to be the connection to the cold water supply directly in front of the hot water production plant or to the drinking water supply to the facility so that all consumers have soft water at their disposal. However, it is also possible to connect the object of the invention directly to all types of hot and hot water production plants. Furthermore, ultrasound can be directed with a specially designed screen to the desired location, taking into account the fact that the incident angle of sound to the screen is equal to the reflectance.

Za uspešno delovanje izuma je potrebna pravilna izbira frekvence ultrazvoka, ki je odvisna od velikosti naprave in od oddaljenost le-te do končnih porabnikov, to je grelnih elementov in šob, na katerih obloge najpogosteje nastajajo. S pravilno izbiro in spreminjanjem frekvence je razen mehčanja vode mogoče doseči še:Successful operation of the invention requires the correct choice of ultrasound frequency, which depends on the size of the device and the distance from the device to the end users, that is, the heating elements and nozzles on which the lining is most commonly formed. By properly selecting and changing the frequency, in addition to water softening, you can achieve:

- dezinfekcijo bakterij v toplovodnih sistemih, tako da termična dezinfekcija ni potrebna;- bacterial disinfection in hot water systems so that thermal disinfection is not required;

- zmanjšanje porabe pralnega praška, ker ultrazvok pripomore k razgradnji umazanije;- reducing the consumption of washing powder because ultrasound helps to break down dirt;

- zmanjšanje uporabe čistil na sanitarni in drugi opremi, ker se na njej ne nabirajo apnenčaste obloge;- reducing the use of cleaners on sanitary and other equipment as no limestone deposits are accumulated on it;

- dezinfekcijo mulja v čistilnih napravah po končani anaerobni in aerobni fermentaciji.- disinfection of sludge in treatment plants after anaerobic and aerobic fermentation has been completed.

Z vgradnjo predmeta izuma v zajetjih in črpališčih za pitno vodo je mogoče nadomestiti kloriranje vode, saj ultrazvok uniči bakterije, prisotne v vodi.By incorporating the subject matter of the invention into drinking water wells and pumping stations, chlorination of water can be substituted as ultrasound destroys the bacteria present in the water.

Prav tako je mogoče po obodu posameznega ohišja vgraditi večje število ultrazvočnih generatorjev.A number of ultrasonic generators can also be installed around the perimeter of each enclosure.

Opis skic izumaDescription of the sketches of the invention

Na skici 1 je prikazana izvedba ultrazvočnega prekristalizatorja v ravni izvedbi in sicer je vidno ohišje prekristalizatorja (1), pokrov ultrazvočnega generatorja (2), ultrazvočni generator (3), digitalni regulator (4) in pokrov digitalnega regulatorja (5).Figure 1 shows an embodiment of the ultrasonic recrystallizer in a flat design, showing the recrystallizer housing (1), the cover of the ultrasonic generator (2), the ultrasonic generator (3), the digital controller (4) and the cover of the digital controller (5).

Claims (12)

PATENTNI ZAHTEVKIPATENT APPLICATIONS 1. Ultrazvočni prekristalizator, uporabljen za mehčanje, filtriranje in drugačno mehansko in/ali ionsko obdelavo vode ali druge tekočine, značilen po tem, da je na ohišje prekristalizatorja (1) pritrjen ultrazvočni generator (3), ki je zaščiten s pokrovom (2).An ultrasonic recrystallizer for softening, filtering and other mechanical and / or ionic treatment of water or other liquid, characterized in that an ultrasonic generator (3) is attached to the housing of the recrystallizer (3), which is protected by a lid (2) . 2. Predmet po zahtevku 1, značilen po tem, da regulacijo frekvence in jakosti ultrazvoka vObject according to claim 1, characterized in that the control of the frequency and intensity of ultrasound in izvajamo z digitalnim regulatorjem (4), ki je pritrjen na ali povezan z ultrazvočnim generatorjem in zaščiten s pokrovom digitalnega regulatorja (5).is performed with a digital controller (4) that is attached to or connected to an ultrasonic generator and protected by a cover of the digital controller (5). 3. Ultrazvočni prekristalizator, uporabljen za mehčanje, filtriranje in drugačno mehansko in/ali ionsko obdelavo vode ali druge tekočine, značilen po tem, da je izveden tik pred vstopom v napravo ali naprave za proizvodnjo tople ali vroče vode.3. An ultrasonic recrystallizer used for the softening, filtering and other mechanical and / or ionic treatment of water or other liquid, characterized in that it is carried out immediately before entering the device or devices for the production of hot or hot water. 4. Ultrazvočni prekristalizator, uporabljen za mehčanje, filtriranje in drugačno mehansko in/ali ionsko obdelavo vode ali druge tekočine, značilen po tem, da je izveden neposredno v napravah za proizvodnjo tople ali vroče vode.4. An ultrasonic recrystallizer used for the softening, filtering and other mechanical and / or ionic treatment of water or other liquid, characterized in that it is carried out directly in hot or hot water production plants. 5. Ultrazvočni prekristalizator, uporabljen za mehčanje, filtriranje in drugačno mehansko in/ali ionsko obdelavo vode ali druge tekočine, značilen po tem, da je izveden tako, da je mogoče ultrazvok s pomočjo zaslona usmerjati na željeno mesto.5. Ultrasonic recrystallizer used for softening, filtering and other mechanical and / or ionic treatment of water or other liquid, characterized in that it is designed so that the ultrasound can be directed to the desired location by means of a screen. 6.1 Ultrazvočni prekristalizator, uporabljen za mehčanje, filtriranje in drugačno mehansko6.1. Ultrasonic recrystallizer used for softening, filtering and other mechanical means J in/ali ionsko obdelavo vode ali druge tekočine, značilen po tem, da je izveden tako, da omogoča dezinfekcijo vode oziroma uničuje bakterije v njej.J and / or ion treatment of water or other liquid, characterized in that it is designed to disinfect the water or destroy the bacteria in it. 7. Predmet po zahtevkih 1 do 6, značilen po tem, daje izveden v povezavi z merilnikom pretoka.The item according to claims 1 to 6, characterized in that it is made in conjunction with a flowmeter. 8. Predmet po zahtevkih 1 do 6, značilen po tem, da je izveden v povezavi s kalorimetrom.The item according to claims 1 to 6, characterized in that it is made in conjunction with a calorimeter. 9. Predmet po zahtevkih 1 do 6, značilen po tem, da je izveden v kotni izvedbi.The item according to claims 1 to 6, characterized in that it is made in an angular manner. 10. Predmet po zahtevkih 1 do 6, značilen po tem, da je izveden v ravni izvedbi.The item according to claims 1 to 6, characterized in that it is made in a straight embodiment. A''A '' 11. Predmet po zahtevkih 1 do 6, značilen po tem, da uničuje bakterije v mulju v čistilnih napravah po končani fermentaciji.The object of claims 1 to 6, characterized in that it destroys the bacteria in the sludge in the treatment plants after fermentation is complete. 12. Predmet po zahtevkih 1 do 11, značilen po tem, da več ultrazvočnih generatorjev vgradimo po obodu ohišja.The item according to claims 1 to 11, characterized in that several ultrasonic generators are installed around the circumference of the housing.
SI9600307A 1996-10-18 1996-10-18 Ultrasonic precrystallizer SI9600307A (en)

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SI9600307A SI9600307A (en) 1996-10-18 1996-10-18 Ultrasonic precrystallizer
PCT/SI1997/000026 WO1998017584A1 (en) 1996-10-18 1997-09-16 Ultrasound treatment device for water or other fluid
AU43251/97A AU4325197A (en) 1996-10-18 1997-09-16 Ultrasound treatment device for water or other fluid

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WO1998017584A1 (en) 1998-04-30

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