SI9210125A - Process for the production of wood-fibre boards - Google Patents
Process for the production of wood-fibre boards Download PDFInfo
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- SI9210125A SI9210125A SI9210125A SI9210125A SI9210125A SI 9210125 A SI9210125 A SI 9210125A SI 9210125 A SI9210125 A SI 9210125A SI 9210125 A SI9210125 A SI 9210125A SI 9210125 A SI9210125 A SI 9210125A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
- B27N1/02—Mixing the material with binding agent
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Abstract
Description
OSTERREICHISCHE HIAG WERKE Gesellschaft m.b.H.OSTERREICHISCHE HIAG WERKE Gesellschaft m.b.H.
Postopek izdelave plošč iz lesnih vlakenThe process of making wood fiber boards
Izum se nanaša na postopek izdelave plošč iz lesnih vlaken, pri katerem je surovina podvržena razvlaknjenju, zatem se jo v pihalnem vodu olepi z vodno raztopino veziva in tako dobljeni olepljeni vlakninski material se po sušenju na potrebno preostalo vlažnost natrosi v proge ploskovnega nasutja in se ga pod tlakom in temperaturo stisne v plošče. Zlasti pa se izuma nanaša na tak postopek izdelave srednjegostih vlakninskih plošč (SGV plošč; nem. MDF - mitteldichte Faserplatten) in trdih vlakninskih plošč (TGV plošč; nem. HDF - Hartfaserplatten), ki vsebujejo zmanjšano količino veziva.The invention relates to a method of manufacturing wood fiber boards, in which the raw material is subjected to dehumidification, then it is glued in a blower line with an aqueous solution of binder and the resulting adhered fibrous material is then dried into the lines of planar fill after drying to the necessary residual humidity. under pressure and temperature squeezes into panels. In particular, the invention relates to such a process for making medium-sized fibreboards (SGV boards; MDF - mitteldichte Faserplatten) and hard fibreboards (TGV boards; German HDF - Hartfaserplatten) containing a reduced amount of binder.
Mehanske lastnosti plošč iz lesnih vlaken določa razen kakovosti operacije razvlaknjenja v pomembnem delu vezivo, uporabljeno za vezavo vlakninskega materiala. Pri tem je pod v preostalem konstantnimi pogoji povišanje mehanske trdnosti plošč zvezano z zvišanjem količine veziva, vloženega za vezanje vlakninskega materiala.The mechanical properties of the wood fiber boards are determined, in addition to the quality of the stretching operation, in a significant part by the binder used to bond the fiber material. Under the remaining constant conditions, an increase in the mechanical strength of the plates is related to an increase in the amount of binder introduced for bonding the fibrous material.
Ker pa vezivni material pri izdelavi vlakninskih plošč predstavlja bistveni stroškovni faktor, obstaja z vidika gospodarnosti izdelave vlakninskih plošč težnja po tem, da se vloži kar se da malo veziva. Nadalje se stremi za tem, da se količina veziva zmanjša iz razloga, da se zmanjša obremenitev okolja, ki ga predstavlja zlasti pri aminoplastičnih vezivih nastopajoče odcepljanje formaldehida. Pri običajnih postopkih za izdelavo plošč iz lesnih vlaken pa zmanjšanje količine vloženega veziva, kot že rečeno, vodi k padcu trdnosti tako narejenih plošč.However, since the binder material is a significant cost factor in the manufacture of fiber boards, there is a tendency to invest as little binder as possible in the cost-effectiveness of fiber board production. It further seeks to reduce the amount of binder in order to reduce the environmental burden of formaldehyde cleavage occurring in particular with aminoplastic binders. In conventional wood fiber board manufacturing processes, however, a decrease in the amount of binder put in, as mentioned above, leads to a decrease in the strength of the boards so made.
Da bi količino veziva zmanjšali, ne da bi škodovali trdnosti, so doslej poskušali z uporabo raznih aparaturnih posegov pri dodajanju veziva v pihalnem vodu doseči dobro porazdelitev lepila, t.j. doseči so hoteli kar se da veliko število zlepnih mest (točk), ki so merodajna za zlepno trdnost. Pri tem so se nadalje posluževali raztopin veziva z vsebnostjo trdne smole okoli 50 mas.%.In order to reduce the amount of binder without damaging the strength, it has hitherto been attempted to achieve a good distribution of adhesive by using various apparatus to add a binder in the blowing line. they wanted to reach as many points (points) as possible, which are crucial for the strength of the evil. The solutions of the binder with a solid resin content of about 50% by weight were further used.
Na področju plošč iz lesnih odrezkov so že opisali postopek z zmanjšano količino dodanega veziva, po katerem uporabljajo razredčeno raztopino veziva z vsebnostjo trdne smole v količini prednostno od 22 do 30 mas.% (EP-B 0 010 537). S tem postopkom se pride do enakomernejše porazdelitve veziva po odrezkih močno različne velikosti in s tem do prihranka na količini veziva. Vloženo surovino pri tem postopku najprej delijo na odrezke in jo zatem podvržejo sušenju do vlage v vrednosti prednostno manj kot 2%, preden jo olepijo z vodno raztopino določenega aminoplasta. Odrezke prevlečejo z lepilom v mešalniku za olepljanje. Razen tega raztopini veziva dodajajo sredstva za zgoščanje, kot so derivati celuloze, da se izognejo vdoru veziva v material odrezkov. Vlažnost olepljenega materiala odrezkov, ki jo držijo pod 12%, določajo s količino vode, nanesene na material odrezkov z raztopino veziva. Omenjena objava potemtakem zadeva postopek, ki je za izdelavo plošč iz odrezkov običajen in po katerem surovino najprej sušijo, zatem olepijo, izum pa se nanaša na suhe postopke izdelave vlakninskih plošč, pri katerih izhodiščni material najprej olepimo, nato sušimo.In the area of wood chip boards, a process with a reduced amount of added binder has already been described according to which a diluted binder solution with a solid resin content in an amount of preferably 22 to 30% by weight is used (EP-B 0 010 537). This process results in a more even distribution of the binder across sections of vastly different sizes and thus saves on the amount of binder. The raw material used in this process is first divided into chunks and then subjected to drying to a moisture content of preferably less than 2% before being bonded with an aqueous solution of a particular aminoplast. The slices are coated with glue in a blender mixer. In addition, thickening agents such as cellulose derivatives are added to the binder solution to prevent the binder from penetrating the material of the cuts. The moisture content of the adhered snippet material held below 12% is determined by the amount of water applied to the snippet material with a binder solution. The said publication therefore relates to a process which is customary for the manufacture of slabs of cuttings, after which the raw material is first dried, then glued, and the invention relates to dry processes for the manufacture of fibreboards, in which the starting material is first glued, then dried.
S tovrstnimi suhimi postopki doslej ni bilo moč izdelati vlakninskih plošč, ki imajo kljub malemu deležu veziva zadostno trdnost. Da so dosegli zadostno trdnost po veljavnih tehniških normah, so doslej morali pri vlakninskih ploščah (tako pri SGV ploščah kot tudi pri TGV ploščah) vgrajevati trdno smolo, katere delež je glede na a.s. (absolutno suhi) vlakninski material vedno znašal več kot 12 mas.%.Such dry processes have so far failed to produce fibreboards which, despite their low content of binder, have sufficient strength. In order to achieve sufficient strength according to the applicable technical standards, it has hitherto been necessary to install a solid resin in the fiber boards (both SGV and TGV boards), whose proportion is a.s. (absolutely dry) fibrous material always exceeded 12% by weight.
Cilj predloženega izuma je, ustvariti uvodoma omenjeni postopek izdelave plošč iz lesnih vlaken, s katerim je dosegljiv, med drugim, še bolj izboljšan izkoristek veziva, uporabljenega za olepljenje vlakninskega materiala, tako da se da za dosego določene trdnosti plošče pri določenem vnaprej danem vlakninskem materialu delati z manj trdne smole kot doslej. Nadaljnji cilj predloženega izuma je, ustvariti tak postopek, ki bo izvedljiv brez spreminjanja principa aparaturnih naprav, kakršne so na voljo za izvedbo zgoraj omenjenih znanih postopkov, ali brez bistvenega spreminjanja časa, potrebnega za izvedbo postopka.It is an object of the present invention to provide the aforementioned process for the manufacture of wood fiber boards, by which, inter alia, the improved utilization of the binder used to adhere the fibrous material is achieved so that to achieve a certain strength of the plate at a predetermined fiber material work with less solid resin than before. It is a further object of the present invention to create such a process that will be practicable without altering the principle of apparatus devices such as are available to perform the above known procedures, or without substantially altering the time required to carry out the process.
Ta cilj je po izumu dosežen s tem, da olepljamo z raztopino z vsebnostjo trdne smole v količini od 20 do 35 mas.%, prednostno od 25 do 35 mas.%, in pri tem dodajamo vezivo v količini, ki znaša manj kot 10 mas.%, prednostno 7 do 9 mas.% trdne smole, vzeto glede na skupni, na a.s. stanje računani vlakninski material.This object of the invention is achieved by adhering to a solution having a solid resin content in an amount of from 20 to 35% by weight, preferably from 25 to 35% by weight, while adding a binder in an amount of less than 10% by weight .%, preferably 7 to 9% by weight of solid resin, taken as a total, per ac condition calculated fiber material.
Z uporabo, ki je značilna za izum, močno razredčenih vodnih raztopin veziva je možno po suhem postopku izdelovati plošče iz lesnih vlaken, katerih mehanske vrednosti zelo dobro ustrezajo zahtevam iz tehniških norm, pri čemer je v primerjavi s ploščami, izdelanimi po postopkovnem načinu iz vsakdanje tehnologije, hkrati omogočen pomemben prihranek na vezivu. Tako je po postopku po izumu možno izdelovati plošče iz lesnih vlaken z deležem trdne smole v vrednosti manj kot 10 mas.%, pa imajo zadostne trdnosti po veljavnih tehniških standardih.Using the characteristic of the invention, heavily diluted aqueous binder solutions, it is possible to dry wood fiber boards, whose mechanical values correspond very well to the requirements of the technical norms, in a dry process, in comparison with the plates made according to the process method from everyday life. technology, while allowing significant binder savings. Thus, according to the method of the invention, it is possible to produce wood fiber boards with a solid resin content of less than 10% by weight, having sufficient strength according to the applicable technical standards.
Z uporabo, kakršna je predvidena v postopku po izumu, močno razredčenih raztopin veziva očitno dobimo izjemno popolno oplaščenje vlakninskega gradiva z vezivom, s čimer se močno pomnožijo zlepne točke, ki so tako pomembne za vzpostavitev trdnosti v ploščah.Using the method of the present invention, the heavily diluted binder solutions obviously provide an extremely complete coating of the fiber material with the binder, thereby greatly multiplying the adhesion points that are so important for restoring the strength of the plates.
Nadaljnja prednost tega postopka je v tem, da z močnim razredčenjem vloženega veziva na olepljena vlakna izvajamo hladilni učinek, saj se del vode iz zmesi veziva takoj upari, s čimer se sistemu vlakna/vezivo kot celoti odtegne toplota. S tem se prepreči predčasna strditev veziva, nahajajočega se na olepljenih vlaknih, predčasna strditev pa bi prav tako utegnila imeti za posledico padec trdnosti plošče.A further advantage of this process is that a strong dilution of the embedded binder to the bonded fibers exerts a cooling effect, since part of the water from the binder mixture is immediately evaporated, thereby dissipating the fiber / binder system as a whole. This will prevent premature hardening of the binder located on the bonded fibers, and premature hardening could also result in a decrease in the strength of the panel.
Predloženi postopek po izumu lahko izvedemo brez bistvene spremembe postopkovne tehnike. Do olepljenja vlakninskega gradiva pride pri tem tik za izstopom gradiva iz stroja za razvlaknjenje (angl. refiner) v pihalnem vodu na običajen način.The present method of the invention can be carried out without substantially altering the procedural technique. The fiber material is peeled off just after the material is exited from the refiner in the blower line in the usual way.
Raztopini lepila dodajamo primerne trdilne snovi, kot naprimer amonijev klorid, amonijev fosfat, fosforno kislino, mravljinčjo kislino, za strditev uporabljenega veziva med operacijo prešanja v vročem, v količinah, kakršne so v tehniki znane, ki so odvisne od vsakokratnih pogojev naprave. Kot posebno prednosten se je izkazal tudi dodatek posebnega ojačevalca lepila na osnovi sulfonata lignina. Nadalje se lahko raztopini veziva dodajajo tudi še dodatni lovilci formaldehida, kot naprimer sečnina. Parafinska emulzija ali staljen parafin za dosego hidrofobnosti vlakninskih plošč pa se dodaja smotrno pred vstopom v refiner.Appropriate solids, such as ammonium chloride, ammonium phosphate, phosphoric acid, formic acid, are added to the adhesive solution to solidify the binder used during hot pressing operations, in amounts known in the art, which depend on the particular conditions of the device. The addition of a special lignin sulfonate based adhesive enhancer has also proved particularly advantageous. Further, additional formaldehyde traps such as urea may also be added to the binder solution. However, paraffin emulsion or molten paraffin to achieve the hydrophobicity of the fiber boards is added well before entering the refiner.
Vlakninsko gradivo, ki smo ga na zgoraj opisani način opremili z vezivom, nato na po sebi znan način osušimo do preostale vlage največ 12%, prednostno največ 10%, preden ga po raztrosenju v ploskovne proge enakomerne debeline stisnemo v plošče v običajnih prešah za prešanje v vročem.The fiber material, which was equipped with the binder as described above, is then dried in a known manner to a residual moisture content of not more than 12%, preferably not more than 10%, before being pressed into flat lines of uniform thickness by spreading them into plates in conventional presses in the hot.
Material lahko prešamo v plošče bodisi v običajnih stacionarnih prešah pri temperaturah od okoli 160 do 190 °C in tlakih tja do 35 bar ali v konti prešah pri temperaturah grelnih plošč tja do 235 °C in običajnih programih tlakov. Časi stiskanja pri postopku po izumu ustrezajo časom stiskanja, ki so se uporabljali tudi doslej.The material can be pressed into panels or in conventional stationary presses at temperatures from about 160 to 190 ° C and pressures down to 35 bar or in counter presses at temperatures up to 235 ° C and conventional pressure programs. The compression times of the process according to the invention correspond to the compression times that have been used so far.
Prednostna izvedbena oblika postopka po predloženem izumu obstaja v tem, da aminoplastično vezivo, ki je pripravljeno za uporabo, najprej razredčimo z vodo na koncentracijo trdne smole okoli 30 do 40 mas.% in potrebne dodatke, kot so trdilne snovi, ojačevalec lepila, lovilec formaldehida, v primerni vodni raztopini dodamo razredčeni raztopini veziva šele neposredno pred vstopom v pihalni vod preko mešalne proge.A preferred embodiment of the process of the present invention is that the ready-to-use aminoplastic binder is first diluted with water to a solid resin concentration of about 30 to 40 wt.% And the necessary additives such as solids, adhesive enhancer, formaldehyde trap , in a suitable aqueous solution, is added to the diluted binder solution only immediately before entering the blower line via the mixing line.
Izum bomo sedaj nadalje obrazložili na osnovi primerov, ne da bi se nanje omejevali.The invention will now be further explained on a case by case basis, without being limited thereto.
PRIMER 1EXAMPLE 1
Za izdelavo srednjegostih vlakninskih plošč (SGV plošč) smo uporabili vlakninsko gradivo, ki smo ga v stroju za razvlaknitev (refinerju) pridobili na po sebi znan način iz na drobno nasekane borovine. V pihalni vod, po katerem se vlakninsko gradivo odvaja iz refinerja, smo tik po izstopu iz refinerja dozirano vnesli zmes, ki je vsebovala vezivo. To zmes, ki vsebuje vezivo, smo takole sestavili:For the production of medium-sized fiber boards (SGV panels), we used fiber material, which was obtained in a well-known way from finely chopped pines in a refiner. Immediately after leaving the refiner, a mixture containing the binder was dosed into the blowing line through which the fibrous material was discharged from the refiner. We have assembled this binder containing compound as follows:
V mešalni posodi smo aminoplastično El lepilo za izdelavo vlakninskih plošč (HIACOLL MDF 15) razredčili z vodo na koncentracijo 33 mas.% trdne smole. V drugi mešalni posodi smo pripravili raztopino 30 mas.% sečnine, 10 mas.% amonijevega klorida in 2 mas.% fosforne kisline. S pomočjo dozirnih črpalk smo obe raztopini preko statičnega mešala združili v takem razmerju, da je končno dobljena raztopina lepila vsebovala koncentracijo 28,3 mas.% trdne smole. To raztopino lepila smo vlakninskemu gradivu dodali v tolikšni količini, da smo dobili faktor olepljenjaIn the mixing vessel, the aminoplastic El fiber board adhesive (HIACOLL MDF 15) was diluted with water to a concentration of 33% by weight of solid resin. A solution of 30% by weight of urea, 10% by weight of ammonium chloride and 2% by weight of phosphoric acid was prepared in another mixing vessel. With the aid of the dosing pumps, the two solutions were combined in a static mixer in such a proportion that the final adhesive solution contained a concentration of 28.3% by weight of solid resin. This adhesive solution was added to the fiber material in such a quantity that the adhesive factor was obtained
8,2 mas.% trdne smole, vzeto glede na absolutno suho (a.s.) vlakno. Olepljeno zmes vlaken smo zatem na znan način osušili na preostalo vlago 10 mas.%, oblikovali v ravninsko nasutje enakomerne debeline in v grelni preši pod vplivom tlaka in temperature stisnili v SGV ploščo. Tako izdelana plošča je zelo dobro odgovarjala zahtevam industrijske norme za SGV plošče (normirani tip MDF [=SGVj, vsebnost formaldehida A razred).8.2% by weight of solid resin, taken with respect to absolute dry (a.s.) fiber. The adhered fiber mixture was then dried in a known manner to a residual moisture content of 10% by weight, formed into a planar fill of uniform thickness and pressed into a SGV plate under the influence of pressure and temperature. The plate produced in this way was very well suited to the requirements of the industry standard for SGV panels (standard type MDF [= SGVj, formaldehyde content A class).
PRIMER 2EXAMPLE 2
Vlakninsko gradivo iz prvega primera smo na po sebi znan način olepili z naslednjo zmesjo, ki je vsebovala vezivo:The fiber material from the first example was in a known manner glued to the following mixture containing the binder:
V mešalni posodi smo zmešali 1.000 kg HIACOLL MDF 15, 100 kg raztopine sečnine (40 mas.%) in 1.000 1 vode, tako da je koncentracija trdne smole te zmesi znašala 31,4 mas.%. V drugi mešalni posodi smo zmešali 100 kg ojačevalca lepila HIACOLL K1215 in 165 1 vode. Omenjeni raztopini smo preko dozirnih črpalk in statičnega mešala zmešali v tako razmerje zmesi, da je končno dobljena koncentracija trdne smole v zmesi znašala 27,0 mas.%. To zmes smo na vlakninsko gradivo nanašali v količini, da smo dobili faktor olepljenja 7,5 mas.%, vzeto na a.s. vlakninsko gradivo. Po osušitvi na okoli 10% preostale vlage, oblikovanju ravninskega nasutja enakomerne debeline in prešanju v vročem smo dobili SGV ploščo, kije v vseh vrednostih preizkušanja zelo dobro odgovarjala normiranemu tipu MDF (=SGV), vsebnost formaldehida A razred po industrijski normi za MDF (=SGV) plošče.1,000 kg of HIACOLL MDF 15, 100 kg of urea solution (40% by weight) and 1,000 1 of water were mixed in the mixing vessel so that the solid resin concentration of this mixture was 31.4% by weight. In a second mixing bowl, 100 kg of HIACOLL K1215 adhesive enhancer and 165 l of water were mixed. The solutions were mixed through a metering pump and a static mixer in such a mixture ratio that the final solid resin concentration in the mixture was 27.0% by weight. This mixture was applied to the fiber material in an amount to obtain a peel factor of 7.5% by weight taken on a.s. fiber material. After drying to about 10% residual moisture, forming a planar fill of uniform thickness, and pressing in hot, an SGV plate was obtained which, in all test values, corresponded very well to the standard MDF type (= SGV), the formaldehyde content of A grade according to the industry standard for MDF (= SGV) panels.
PRIMER 3EXAMPLE 3
Pri Primeru 3 gre za primerjalni primer.Example 3 is a comparative example.
Za olepljenje vlakninskega gradiva, ki smo ga izvedli tako, kot je opisano v Primeru 1 in 2, smo uporabili raztopino lepila naslednje sestave:To adhere the fiber material, which was carried out as described in Examples 1 and 2, we used an adhesive solution of the following composition:
HIACOLL MDF-12 raztopina sečnine (40 mas.%)HIACOLL MDF-12 urea solution (40% by weight)
1.000 kg 150 kg raztopina amonijevega klorida (15 mas.%) 40 kg voda kg1,000 kg 150 kg ammonium chloride solution (15% by weight) 40 kg water kg
Ta raztopina lepila po svoji sestavi ustreza stanju tehnike. Ima koncentracijo trdne smole v vrednosti 53,2 mas.%. Za dosego mehanskih vrednosti MDF (=SGV) plošče, narejene z uporabo te raztopine, torej vrednosti, kakršne za MDF (=SGV) plošče predpisujejo industrijske norme, smo morali na 1.000 kg a.s. vlakninskega gradiva vgraditi 235 kg raztopine lepila, kar ustreza faktorju olepljanja 12,5 mas.%, vzeto na a.s. vlakninsko gradivo.This adhesive solution in its composition corresponds to the state of the art. It has a solid resin concentration of 53.2% by weight. In order to achieve the mechanical values of MDF (= SGV) panels made using this solution, ie the values prescribed by industry standards for MDF (= SGV) panels, we had to per 1,000 kg a.s. to incorporate 235 kg of adhesive solution into the fibrous material, which corresponds to the adhesive factor of 12.5% by weight taken on a.s. fiber material.
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Application Number | Priority Date | Filing Date | Title |
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AT0027891A AT403023B (en) | 1991-02-08 | 1991-02-08 | METHOD FOR PRODUCING WOOD FIBER PANELS |
YU12592 | 1992-02-07 |
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SI9210125A true SI9210125A (en) | 1995-04-30 |
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EP (1) | EP0570435B1 (en) |
CN (1) | CN1063837A (en) |
AT (1) | AT403023B (en) |
AU (1) | AU1225692A (en) |
DE (1) | DE59202092D1 (en) |
DK (1) | DK0570435T3 (en) |
ES (1) | ES2074874T3 (en) |
IE (1) | IE67381B1 (en) |
NZ (1) | NZ241508A (en) |
PT (1) | PT100106A (en) |
SI (1) | SI9210125A (en) |
TR (1) | TR26826A (en) |
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JP2774068B2 (en) * | 1994-08-19 | 1998-07-09 | 光洋産業株式会社 | Hot-press forming method of aggregate |
IL139932A0 (en) * | 1998-08-05 | 2002-02-10 | Fraunhofer Ges Forschung | Method for producing medium density fibre panels |
DE10249581A1 (en) * | 2002-10-24 | 2004-05-13 | Kronotec Ag | support plate |
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AT366960B (en) * | 1978-06-02 | 1982-05-25 | Oesterr Hiag Werke Ag | METHOD FOR PRODUCING WOOD CHIPBOARDS |
DE3025522A1 (en) * | 1980-07-05 | 1982-02-18 | Basf Ag, 6700 Ludwigshafen | Formaldehyde-free wood material prodn. - with thermosetting binder mixt. contg. aq. epoxy! resin dispersion and aq. poly:amine-amide! dispersion |
DE3042813A1 (en) * | 1980-11-13 | 1982-06-09 | Basf Ag, 6700 Ludwigshafen | METHOD FOR PRODUCING AMINOPLASTIC CONDENSATES |
US4407771A (en) * | 1982-04-26 | 1983-10-04 | The Celotex Corporation | Blow line addition of isocyanate binder in fiberboard manufacture |
DE3609506A1 (en) * | 1985-03-25 | 1986-10-30 | Koppers Co., Inc., Pittsburgh, Pa. | Process for producing a composition from cellulose particles and resin for the production of fibre boards |
DK77287D0 (en) * | 1987-02-16 | 1987-02-16 | Novopan Traeindustri | CHEWING PLATE AND PROCEDURES FOR PRODUCING THEREOF |
ATE98922T1 (en) * | 1989-03-20 | 1994-01-15 | Medite Europ | DEVICE AND PROCESS FOR THE MANUFACTURE OF SYNTHETIC PANELS INCLUDING FIRE RESISTANT PANELS. |
-
1991
- 1991-02-08 AT AT0027891A patent/AT403023B/en not_active IP Right Cessation
-
1992
- 1992-02-02 CN CN92100691A patent/CN1063837A/en active Pending
- 1992-02-03 NZ NZ241508A patent/NZ241508A/en unknown
- 1992-02-05 TR TR00130/92A patent/TR26826A/en unknown
- 1992-02-06 ZA ZA92874A patent/ZA92874B/en unknown
- 1992-02-07 DE DE59202092T patent/DE59202092D1/en not_active Revoked
- 1992-02-07 ES ES92903957T patent/ES2074874T3/en not_active Expired - Lifetime
- 1992-02-07 IE IE920406A patent/IE67381B1/en not_active IP Right Cessation
- 1992-02-07 PT PT100106A patent/PT100106A/en not_active Application Discontinuation
- 1992-02-07 SI SI9210125A patent/SI9210125A/en unknown
- 1992-02-07 EP EP92903957A patent/EP0570435B1/en not_active Revoked
- 1992-02-07 WO PCT/AT1992/000016 patent/WO1992013688A1/en not_active Application Discontinuation
- 1992-02-07 DK DK92903957.6T patent/DK0570435T3/en active
- 1992-02-07 AU AU12256/92A patent/AU1225692A/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
IE920406A1 (en) | 1992-08-12 |
ZA92874B (en) | 1992-11-25 |
WO1992013688A1 (en) | 1992-08-20 |
IE67381B1 (en) | 1996-03-20 |
AU1225692A (en) | 1992-09-07 |
AT403023B (en) | 1997-10-27 |
CN1063837A (en) | 1992-08-26 |
DK0570435T3 (en) | 1995-09-11 |
ATA27891A (en) | 1992-11-15 |
ES2074874T3 (en) | 1995-09-16 |
EP0570435A1 (en) | 1993-11-24 |
TR26826A (en) | 1994-08-12 |
PT100106A (en) | 1993-03-31 |
EP0570435B1 (en) | 1995-05-03 |
NZ241508A (en) | 1994-05-26 |
DE59202092D1 (en) | 1995-06-08 |
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