SG187156A1 - Maintaining antiwear performance and improving deposit formation resistance of turbine oils - Google Patents
Maintaining antiwear performance and improving deposit formation resistance of turbine oils Download PDFInfo
- Publication number
- SG187156A1 SG187156A1 SG2013004767A SG2013004767A SG187156A1 SG 187156 A1 SG187156 A1 SG 187156A1 SG 2013004767 A SG2013004767 A SG 2013004767A SG 2013004767 A SG2013004767 A SG 2013004767A SG 187156 A1 SG187156 A1 SG 187156A1
- Authority
- SG
- Singapore
- Prior art keywords
- range
- rdp
- alkyl
- turbine oil
- turbine
- Prior art date
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- 239000010723 turbine oil Substances 0.000 title claims abstract description 91
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 24
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 91
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 50
- 150000001412 amines Chemical class 0.000 claims abstract description 31
- 239000007866 anti-wear additive Substances 0.000 claims abstract description 29
- 239000000203 mixture Substances 0.000 claims description 67
- -1 diphenyl amines Chemical class 0.000 claims description 65
- 150000002148 esters Chemical class 0.000 claims description 54
- 125000000217 alkyl group Chemical group 0.000 claims description 48
- 238000012360 testing method Methods 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 31
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 30
- 229910052739 hydrogen Inorganic materials 0.000 claims description 27
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 25
- 239000004480 active ingredient Substances 0.000 claims description 23
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 21
- 239000002253 acid Substances 0.000 claims description 21
- 239000001257 hydrogen Substances 0.000 claims description 21
- 229910052698 phosphorus Inorganic materials 0.000 claims description 21
- 239000011574 phosphorus Substances 0.000 claims description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 20
- 229920005862 polyol Polymers 0.000 claims description 18
- 239000002199 base oil Substances 0.000 claims description 17
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 17
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 12
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
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- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- OWICEWMBIBPFAH-UHFFFAOYSA-N (3-diphenoxyphosphoryloxyphenyl) diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1)(=O)OC1=CC=CC=C1 OWICEWMBIBPFAH-UHFFFAOYSA-N 0.000 abstract description 7
- 238000009472 formulation Methods 0.000 description 32
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- 229910019142 PO4 Inorganic materials 0.000 description 20
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- 239000010705 motor oil Substances 0.000 description 13
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- 150000004982 aromatic amines Chemical class 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 5
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- 125000001931 aliphatic group Chemical group 0.000 description 4
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- 239000001177 diphosphate Substances 0.000 description 4
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- 125000001183 hydrocarbyl group Chemical group 0.000 description 4
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- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 3
- OILUAKBAMVLXGF-UHFFFAOYSA-N 3,5,5-trimethyl-hexanoic acid Chemical compound OC(=O)CC(C)CC(C)(C)C OILUAKBAMVLXGF-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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- 241000700159 Rattus Species 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 125000000732 arylene group Chemical class 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- MHPUGCYGQWGLJL-UHFFFAOYSA-N dimethyl pentanoic acid Natural products CC(C)CCCC(O)=O MHPUGCYGQWGLJL-UHFFFAOYSA-N 0.000 description 3
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- 238000004939 coking Methods 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical class CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- OQCGQYSHNVXOJM-UHFFFAOYSA-N dicyclohexyl decanedioate Chemical compound C1CCCCC1OC(=O)CCCCCCCCC(=O)OC1CCCCC1 OQCGQYSHNVXOJM-UHFFFAOYSA-N 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- HUDSKKNIXMSHSZ-UHFFFAOYSA-N dihexyl hydrogen phosphate Chemical class CCCCCCOP(O)(=O)OCCCCCC HUDSKKNIXMSHSZ-UHFFFAOYSA-N 0.000 description 1
- HTDKEJXHILZNPP-UHFFFAOYSA-N dioctyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCCCCCC HTDKEJXHILZNPP-UHFFFAOYSA-N 0.000 description 1
- VJHINFRRDQUWOJ-UHFFFAOYSA-N dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 description 1
- MZHWPEFVDZZOKM-UHFFFAOYSA-N dipentan-3-yl nonanedioate Chemical compound CCC(CC)OC(=O)CCCCCCCC(=O)OC(CC)CC MZHWPEFVDZZOKM-UHFFFAOYSA-N 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical class OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229940067592 ethyl palmitate Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000007688 immunotoxicity Effects 0.000 description 1
- 231100000386 immunotoxicity Toxicity 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 231100000037 inhalation toxicity test Toxicity 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-N isocaproic acid Chemical compound CC(C)CCC(O)=O FGKJLKRYENPLQH-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Chemical compound CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- CBFCDTFDPHXCNY-UHFFFAOYSA-N octyldodecane Natural products CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical group OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000002954 polymerization reaction product Substances 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001850 reproductive effect Effects 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000012974 tin catalyst Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- CAPOZRICGSDRLP-UHFFFAOYSA-N tris(2,3-dimethylphenyl) phosphate Chemical class CC1=CC=CC(OP(=O)(OC=2C(=C(C)C=CC=2)C)OC=2C(=C(C)C=CC=2)C)=C1C CAPOZRICGSDRLP-UHFFFAOYSA-N 0.000 description 1
- KOWVWXQNQNCRRS-UHFFFAOYSA-N tris(2,4-dimethylphenyl) phosphate Chemical compound CC1=CC(C)=CC=C1OP(=O)(OC=1C(=CC(C)=CC=1)C)OC1=CC=C(C)C=C1C KOWVWXQNQNCRRS-UHFFFAOYSA-N 0.000 description 1
- BOSMZFBHAYFUBJ-UHFFFAOYSA-N tris(4-methylphenyl) phosphate Chemical class C1=CC(C)=CC=C1OP(=O)(OC=1C=CC(C)=CC=1)OC1=CC=C(C)C=C1 BOSMZFBHAYFUBJ-UHFFFAOYSA-N 0.000 description 1
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical class [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/041—Mixtures of base-materials and additives the additives being macromolecular compounds only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
- C10M2207/2825—Esters of (cyclo)aliphatic oolycarboxylic acids used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
- C10M2207/2835—Esters of polyhydroxy compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/285—Esters of aromatic polycarboxylic acids
- C10M2207/2855—Esters of aromatic polycarboxylic acids used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
- C10M2215/065—Phenyl-Naphthyl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/066—Arylene diamines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
- C10N2040/13—Aircraft turbines
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The antiwear performance of turbine oils containing polymerized amine antioxidants and antiwear additives is maintained at or enhanced beyond the level as that of turbine oils containing monomeric amine antioxidants by employing as the antiwear additive a resorcinol bis(diphenylphosphate) (RDP). The deposit formation resistance performance of turbine oils containing monomeric and/or polymeric amine antioxidant is improved by employing RDP.
Description
MAINTAINING ANTIWEAR PERFORMANCE AND IMPROVING DEPOSIT
FORMATION RESISTANCE OF TURBINE OILS
[0001] The present disclosure relates to turbine oils containing antiwear additives and antioxidants and to the maintenance and/or improvement of the antiwear performance and the deposit formation resistance performance of such turbine oils.
[0002] Turbine oils, especially aviation jet engine oils, are complex liquid lubricants designed to function under extreme conditions of temperature, pressure and load. At such conditions the turbine oil experiences volatilization of vital components as well as a loss of the ability to control or inhibit wear of critical engine parts.
[0003] To control wear, the liquid lubricant typically employs additives specifically designed as antiwear additives. Typical turbine antiwear additives are addressed and described in the prior art.
[0004] EP 0,521,628 is directed to a combination of aryl phosphates useful as antiwear additives in fuels, lubricants and functional fluids which are subjected to high temperatures under actual service conditions. The combination of aryl phosphates is comprised of: (1) at least one oil-soluble aryl phosphate of the formula: (RO);PO wherein each R is, independently, phenyl or an alkyl-substituted phenyl group; and (2) at least one oil-soluble aryl phosphate of the formula:
Oo Oo
R— ot P—O—Ar—0O P — (OR), . "
OR wherein each R is, independently, phenyl or an alkyl-substituted phenyl group, Ar is m-phenylene or an alkyl-substituted m-phenylene group, and n is a number from 1 to 4, said combination containing from 2 to 30% by weight of component (1). When the above formula represents a mixture of the depicted polyphosphates, n is a whole or fractional number from 1 to 4, because n in that case represents the average composition of the mixture.
[0005] The lubricant compositions which can be benefitted by the use of the composition combination are lubricating oils of lubricating viscosity, including oils composed by volume of at least 50% up to and including 100% of one or more mineral oils or one or more synthetic ester oils.
[0006] In forming the combination of aryl phosphates, use can be made of phenol and/or one or more alkyl phenols containing from 1 to 5 alkyl groups on the ring. Each alkyl group can contain up to about 18 carbon atoms provided the alkyl substituents do not sterically hinder the hydroxyl group to such an extent that the substituted phenol cannot undergo reaction to form the desired aryl phosphate.
[0007] The combination of aryl phosphates is reported to have excellent thermal stability at high temperatures, even as high as 400°C, compared to tri-n-octyl phosphate (TOP), tricresyl phosphate (TCP), tri-n-butoxy-ethyl phosphate (TBEP), and cresyl diphenyl phosphate (CDP).
[0008] When used as lubricating oil antiwear additive, the combination is employed in the range 0.005 to 20 wt% based on the total weight of the finished lubricant. The finished lubricant can contain additional additives, including ashless dispersants, zinc hydrocarbyl dithiophosphates, one or more oil-soluble sulfur-containing antiwear and/or extreme pressure agents.
[0009] U.S. Patent 5,560,849 is directed to improving the antiwear properties of synthetic ester lubricants intended for use at high temperatures (150 to 350°C) by adding to the lubricant a hydrocarbon-insoluble, synthetic ester-soluble, aryl diphosphate ester composition containing a major amount of an aryl diphosphate ester of the formula:
O 0 (RO); — P—0 — Ar— 0 — P (OR), wherein Ar is an unsubstituted or alkyl (C; to C;,)-substituted arylene and R is unsubstituted or alkyl (C, to Cy,)-substituted aryl.
[0010] The alkyl diphosphate ester exhibits high thermal stability, making it suitable for use as an antiwear additive in lubricants used at high temperature as a replacement for a tri-aryl phosphate ester (e.g., TCP).
[0011] The aryl diphosphate ester is employed in synthetic ester base stocks including polyol esters, diesters and phosphate esters in amounts in the range 0.1 to 10%, preferably 0.5 to 5%, based on the weight of the synthetic ester. Other additives may also be present in the synthetic ester lubricant and include lubricating agents, other antiwear additives, antioxidants, metal passivators, rust and/or corrosion inhibitors, viscosity index (VI) improvers, detergents/dispersants, defoamers/antifoamants, emulsion modifiers, seal swell agents, tackifiers, stabilizers, dyes and odor-masking agents. Antioxidants include hindered phenols, aromatic amines and zinc dialkyl/diaryl phosphate (ZDDP).
[0012] EP 0,612,837 is directed to a polyphenylene ether lubricant containing hydrocarbyl bis(dihydrocarbyl phosphate) compounds of the formula:
O O
(RO); — P—0 —A —0 — P(OR), wherein R is either unsubstituted or substituted hydrocarbyl alkyl or aryl group, A is a bridging group alkylene, haloalkylene, arylene, two arylene groups joined by a bridging group (e.g., -C(CHj), -SO, or —CO) or a bridging group containing biarylene, the di-phosphate compound being used as an antiwear additive in an amount in the range of about 0.1 to 10% by weight of the lubricating composition.
[0013] U.S. Published Application 2007/0179069 is directed to high temperature, stable lubricant compositions comprising at least one polyol polyester derived from the reaction product of a neopentyl polyol with 5,7, 7-trimethyl-2-(1,3,3-trimethylbutyl)-octanoic acid. This polyolester can be used in combination with other conventional polyolesters as well as in combination with other additives, including metal protecting additives such as t-butyl phenyl phosphate, mono-hexyl and di-hexyl phosphates, isopropylphenyl phosphates, tri-cresyl phosphates, tri-xylyl phosphates, di(n-octyl) phosphate, alkylated tri-phenyl phosphorothionate, tri-phenyl thiophosphate, benzotriazole, tolyltriazole and mixtures, derivatives and combinations thereof in amounts in the range of about 0.1 to 10%, preferably up to about 5%, by weight of the total composition.
[0014] Other lubricant additives include alkylated di-phenyl amines, nonylated di-phenylamine, styrenated di-phenyl amine and hindered alkyl phenols.
[0015] U.S. Patent 5,206,404 is directed to a composition of alkylated phenyl phosphate esters comprising 1 to 20 wt% tri-alkyl phenyl phosphate, 10 to 50 wt% di-alkyl phenyl mono-phenyl phosphate, 15 to 60 wt% mono-alkyl phenyl di-phenyl phosphate and less than 2 wt% tri-phenyl phosphate exhibiting a combination of excellent thermal, oxidative and hydrolytic stability.
Unexpectedly superior thermal and hydrolytic stability properties are obtained when the alkyl moiety is a tertiary alkyl, preferably a t-butyl moiety.
[0016] The phosphate esters are an ashless antiwear base stock of reduced volatility and find further use as a lubricant additive.
[0017] “Phosphate Reactions as Mechanisms of High Temperature
Lubrication”, Nagarajan, A. et al., NASA/TM-2006-213060, is directed to the study of the chemical vapor deposition of tert-butyl phenyl phosphate (TBPP) on cast iron. TBPP is reported as possessing superior oxidative, thermal and hydrolytic stability compared to other commercial phosphate ester products and can be an effective and highly stable antiwear additive in both petroleum and synthetic base stocks including polyesters, diesters and polyalphaolefins.
[0018] See also “Chemical Vapor Deposition Applications in Thin Film
Coatings for High Temperature Lubrication”, Nagarajan, A. et al., AIChE Annual
Meeting, Conference Proceedings, Cincinnati, Ohio, October 30-November 4, 2005 (564a/1-564a/11); and
[0019] “Vapor-Phase Lubrication: Reaction of Phosphate Ester Vapors with
Iron and Steel”, Johnson, D. W. et al., Chem Mater, 2002, 14, 3767-3775.
[0020] While tri-alkyl phenyl phosphates are useful as antiwear additives in polyester base turbine oil formulations containing monomeric amine antioxidants, their performance has been found to be no more beneficial than tri-cresyl phosphate when employed in turbine oil formulation containing polymeric amine antioxidants. In fact, their performance as antiwear additives is negatively impacted when employed in high performance turbine oil formulations containing polymeric amine antioxidants.
[0021] It would be an advance in turbine oil technology if a way could be found to retain high antiwear performance in turbine oil formulations containing polymeric amine antioxidants. It would also be an advance in turbine oil technology if a way could be found to improve the deposition formation resistance performance of turbine oils containing monomeric or polymeric amine antioxidants.
[0022] In one form of the present disclosure disclosed herein, there is provided a turbine oil exhibiting maintained or improved antiwear performance as specified in SAE specification AS 5780 comprising a synthetic ester base oil, one or more of a polymeric aminic antioxidant and RDP antiwear additive of the formula: 0 0
AAry— 0 P — © 0 P — O —fAry_ (RY), | RY. | (R),0 0 —tAry_ 0 —thr (R®),, n NRL. wherein R' is a C; to Cs alkyl group, x is an integer ranging from zero to 4, n is an integer ranging from 1 to 7, each Ar is independently phenyl or naphthyl, RA,
R®, R® and R® are the same or different C; to Cg alkyl groups or hydrogen and where any of R* to R” are other than hydrogen the corresponding 7%, 7° 7° and
ZP are the same or different and range from 1 to up to the available valence of each Ar group, the RDP being present in an amount in the range 0.01 to 10 wt% based on active ingredient and contributing from 500 to 6000 ppm phosphorus, wherein the antiwear performance of the turbine oil as measured by the Wedeven
Associates Machine (WAM) test ranges from greater than 23 to 30.
[0023] In another form of the present disclosure disclosed herein, there is provided a method for maintaining or enhancing the antiwear performance of a
High Performance Category turbine oil comprising a synthetic ester base oil, one or more of a polymeric aminic antioxidant and RDP antiwear additive of the formula: 0 0
ANY— 0 P — © 0 P — 0 —tAN_ (RY), Ry. | (R%),0 0 —tAN 0 —tAr (R®),, n Nw wherein R' is a C; to Cs alkyl group, x is an integer ranging from zero to 4, n is an integer ranging from 1 to 7, each Ar is independently phenyl or naphthyl, R*,
R®, R® and RP” are the same or different C; to Cg alkyl groups or hydrogen and where any of R* to R” are other than hydrogen the corresponding 7%, 7° 7° and
ZP are the same or different and range from 1 to up to the available valence of each Ar group, the RDP being present in an amount in the range 0.01 to 10 wt% based on active ingredient and contributing from 500 to 6000 ppm phosphorus, wherein the antiwear performance of the turbine oil as measured by the Wedeven
Associates Machine (WAM) test ranges from greater than 23 to 30.
[0024] In yet another form of the present disclosure disclosed herein, there is provided a method for improving the resistance to deposit formation of turbine oil comprising a synthetic ester base oil, one or more polymeric or monomeric aromatic aminic antioxidants, and RDP antiwear additive of the formula:
0 0
ANY— 0 P — © 0 P — 0 —tAN_ (RY), | RI). | (R%),0 0 —tAI 0 —t (R®) , n Nr. wherein R' is a C; to Cs alkyl group, x is an integer ranging from zero to 4, n is an integer ranging from 1 to 7, each Ar is independently phenyl or naphthyl, R*,
RE, R® and RP are the same or different C, to Cg alkyl groups or hydrogen and where any of R* to R® are other than hydrogen the corresponding Z*, Z®, Z¢ and
ZP are the same or different and range from 1 to up to the available valence of each Ar group, the RDP being present in an amount in the range 0.01 to 10 wt% based on active ingredient and contributing from 500 to 6000 ppm phosphorus, wherein the resistance to deposit formation as measured by the Vapor Phase
Coker Test at 700°F of the turbine oil is at least 30 mg lower than the deposit formation of turbine oils containing the same ester base stock and aminic antioxidant. but containing tricresyl phosphate in place of the RDP.
[0025] All numerical values within the detailed description and the claims herein are modified by “about” or “approximately” the indicated value, and take into account experimental error and variations that would be expected by a person having ordinary skill in the art.
[0026] The present disclosure is directed to a method for maintaining or enhancing the antiwear performance as specified in SAE specification AS 5780 of
High Performance Category (HPC) turbine oils, especially gas turbine oils, particularly aviation turbine oils or jet engine oils containing polymerized amine antioxidants and to such turbine oils themselves and to a method for improving the deposit formation resistance performance of turbine oils containing monomeric aminic antioxidants (Standard Performance Category (SPC) turbine oils), or polymeric aminic antioxidants (HPC turbine oils).
[0027] Turbine oils in general are made up of a number of components which include the base oil, which is one or a mixture of synthetic esters such as polyol esters and diesters, antioxidants, antiwear agents, friction reducers, corrosion inhibitors, metal passivators, dispersants, and defoamants.
[0028] As the demands on the turbine oil increase in terms of load and temperature, HPC turbine oils are being formulated containing polymeric amine antioxidants to enhance oxidation stability. Most SPC oils contain monomeric amine antioxidants and most HPC oils contain polymeric amine antioxidant
[0029] However, it is desirable to not only improve the oxidation stability of such oils but to maintain and, if possible, enhance the load-bearing capacity and deposit formation resistance performance of such turbine oils.
[0030] The present disclosure is a method for maintaining or enhancing the antiwear/load-bearing performance of High Performance Category turbine oil containing polymeric amine antioxidant additives and phosphate-type antiwear agents and to a method for improving the deposit formation resistance performance of Standard Performance Category turbine oil containing monomeric amine antioxidant and phosphate ester-type antiwear agents and of High
Performance Category turbine oils containing polymeric amine antioxidants and phosphate ester-type antiwear agents by using as the antiwear agent an additive amount of a polyphosphate ester antiwear agent including resorcinol bis(diphenylphosphate) of the formula:
O 0
AAry— 0 P — © 0 P — 0 —tAry_
GOW RI). | (R%)0 0 —tAN 0 —fAr (R), n Nw). wherein R' is a C; to Cs alkyl group, x is an integer ranging from zero to 4, preferably zero to 2, more preferably zero, n is an integer ranging from 1 to 7, cach Ar is independently phenyl or naphthyl, R* R®, R® and R® are the same or different, selected from the group consisting of hydrogen, C; to Cg alkyl groups, preferably hydrogen and C, to Cs alkyl groups, and when any of R* to R® are other than hydrogen the corresponding 7", 78, 7° and Z° are the same or different, preferably the same, and range from 1 to up to the available valence of each Ar group, preferably 1 to 2, most preferably 1. The resorcinol bis(diphenylphosphate) additive will be designated herein as RDP.
[0031] The RDP is used in an amount in the range 0.01 to 10 wt% (active ingredient), preferably 0.1 to 5 wt% (active ingredient), more preferably 1 to 4 wt% (active ingredient), contributing from 500 to 6000 ppm phosphorus, preferably 1000 to 4000 ppm phosphorus, to the formulation.
[0032] The present disclosure is also directed to the HPC lubricant comprising the synthetic ester base stock, polymeric aminic antioxidant and the RDP antiwear additive.
[0033] It has been discovered that by replacing all or a portion, preferably all, of other phosphate-type antiwear agents such as the tri-cresyl phosphate currently used in turbine oils with RDP, when the antioxidant is one or more of a polymeric aminic antioxidant, the antiwear performance of the turbine oil is maintained or even enhanced as compared to the antiwear performance exhibited by turbine oils containing other phosphate-type antiwear additives such as tri-cresyl phosphate,
tri(tert-butyl phenyl)-phosphate or even IDP (4,4'-(isopropylidenediphenyl) bis(diphenyl phosphate), wherein the antiwear performance of such oils is degraded when the antioxidant is changed from monomeric aminic antioxidants to a polymeric aminic antioxidant. The deposit formation resistance performance of such oil is also superior to that of turbine oils containing the same ester base stock and polymeric aminic antioxidant but containing tricresyl phosphate in place of the RDP. In the Vapor Phase Coker Test at 700°F, the deposit formation resistance performance of HPC turbine oils containing RDP is 30 mg lower, or 40 mg lower, or 50 mg lower, or 60 mg lower, or 70 mg lower, that is better, than the performance of turbine oils containing the same ester base stock and polymeric aminic antioxidant but containing tricresyl phosphate in place of the RDP.
[0034] [It has also been discovered that the deposit formation resistance performance of turbine oils containing monomeric aminic antioxidant can also be improved by employing RDP, the deposit formation resistance performance being improved compared to the deposit formation performance exhibited by turbine oils containing the same base stock and monomeric aminic antioxidant but containing tricresyl phosphate in place of the RDP. The improvement is seen as a reduction in the deposits formed by at least 40 mg, or at least 60 mg, or at least 80 mg, or at least 100 mg, or at least 130 mg, compared to turbine oils containing the same ester base stock and monomeric aminic antioxidant but tricresyl phosphate in place of the RDP.
[0035] The antiwear performance of the turbine engine oils disclosed herein may be measured using the Wedeven Associates Machine (WAM) test, which is a required test for qualification of a turbine (jet) engine oil (scuffing load stage limit >= 15). The WAM test is described in details in the Examples section below.
The turbine engine oils disclosed herein yield WAM test values ranging from greater than 23 to 30, or greater than 24 to 30, or greater than 25 to 30, or greater than 26 to 30, or greater than 27 to 30.
[0036] Alternatively, the antiwear performance of the turbine engine oils disclosed herein may be measured using the 4-ball wear using ASTM D4172 as the screener test. The 4-ball wear test is described in details in the Examples section below. The turbine engine oils disclosed herein yield 4-ball wear test results of less than 0.55, or less than 0.50, or less than 0.45, or less than 0.40, or less than 0.35, or less than 0.30.
[0037] Turbine oils, e.g. gas turbine oils, aviation turbine oils and jet engine turbine oils, employ synthetic esters and especially polyol esters as base oils.
[0038] The synthetic ester which can be used as the base oil is formed by the esterification of an aliphatic monohydric or polyhydric alcohol with linear or branched carboxylic acids.
[0039] The synthetic esters employed as base oils for the turbine oil have kinematic viscosities at 100°C in the range of 2 to 12 mm®s, preferably 3 to 8 mm?/s, more preferably 4 to 6 mm?/s.
[0040] Monohydric alcohols suitable for making ester base stocks include methyl, butyl, isooctyl, didecyl and octadecyl alcohols. “Oxo” alcohols prepared by the reaction of olefins with carbon monoxide and hydrogen are suitable.
Neo-alcohols, i.e., alcohols having no hydrogens on the beta carbon atom, are preferred. ~~ Examples of such alcohols are 2,2,4-trimethyl-pentanol and 2,2-dimethyl propanol.
[0041] The polyhydric alcohols which can be reacted with the linear acid are, by way of example, polyols represented by the general formula:
R(OH),, wherein R is any aliphatic or cyclo-aliphatic hydrocarbyl group (preferably an alkyl) and = is at least 2. The hydrocarbyl group may contain from about 2 to about 20 or more carbon atoms, and the hydrocarbyl group may also contain substituents such as chlorine, nitrogen and/or oxygen atoms. The polyhydroxyl compounds generally may contain one or more oxyalkylene groups and, thus, the polyhydroxyl compounds include compounds such as polyetherpolyols. The number of carbon atoms (i.c., carbon number, wherein the term “carbon number” as used throughout this application refers to the total number of carbon atoms in either the acid or alcohol as the case may be) and number of hydroxyl groups contained in the polyhydroxyl compound used to form the carboxylic esters may vary over a wide range.
[0042] The following alcohols are particularly useful as polyols: 2-¢thyl-1,3-hexanediol, 2-propyl-3,3-heptanediol, 2-butyl-1,3-butanediol, 2,4-dimethyl-1,3-butanediol, neopentyl glycol, 2,2-dimethylol butane, trimethylol ethane, trimethylol propane, trimethylol butane, mono-pentaerythritol, technical grade pentaerythritol, di-pentaerythritol, tri-pentaerythritol, ethylene glycol, propylene glycol and polyalkylene glycols (e.g., polyethylene glycols, polypropylene glycols, polybutylene glycols, etc., and blends thereof such as polymerized mixture of ethylene glycol and propylene glycol). Mixtures of such alcohols may also be used.
[0043] The carboxylic acid reactant used to produce the synthetic polyol ester base oil is selected from aliphatic monocarboxylic acids or a mixture of aliphatic monocarboxylic acids and aliphatic dicarboxylic acids. The carboxylic acids contain from 4 to 20 carbon atoms and includes the straight and branched chain aliphatic acids. The aliphatic chain may include aryl substituents. Mixtures of acids may be used.
[0044] The carboxylic acid used is a branched or linear C4 to Cy carboxylic acid.
[0045] The branched acid is preferably a mono-carboxylic acid which has a carbon number in the range between about C, to Cy, more preferably about Cs to
Co wherein methyl or ethyl branches are preferred. The mono-carboxylic acid is preferably at least one acid selected from the group consisting of: 2,2-dimethylpropionic acid (neopentanoic acid), neoheptanoic acid, neooctanoic acid, neononanoic acid, isohexanoic acid, neodecanoic acid, 2-ethylhexanoic acid (2EH), 3,5,5-trimethylhexanoic acid (TMH), isoheptanoic acid, isooctanoic acid, isononanoic acid and isodecanoic acid. One especially preferred branched acid is 3,5,5-trimethylhexanoic acid. The term “neo” as used herein refers to a trialkyl acetic acid, i.e. an acid which is triply substituted at the alpha carbon with alkyl groups. These alkyl groups are equal to or greater than CHj, as shown in the general structure set forth herebelow:
R, Oo
R,— C— C—OH
Rs; Alpha Carbon wherein Ry, R; and Rj; are greater than or equal to CH; and not equal to hydrogen.
[0046] 3,5,5-trimethylhexanoic acid has the structure set forth herebelow:
CH, CH, Oo
CH; — C — CH,— CH —CH, — C— OH
CH,
[0047] The mono-carboxylic linear acids are any linear saturated alkyl carboxylic acid having a carbon number in the range between about C4 to Cy, preferably Cs to Cy.
[0048] Some examples of linear acids include butyric, valeric, sebacic, azelaic, suberic, succinic, adipic, oxalic, malonic, glutaric, pentadecanedicarboxylic, diglycolic, thidiglycolic, acetic, propionic, lauric, palmitic, pimilic, n-hexanoic, n-heptanoic, n-octanoic, n-nonanoic, and n-decanoic acids and mixtures thereof.
[0049] Examples of suitable ester base oils are ethyl palmitate, ethyl laurate, butyl stearate, di-(2-ethylhexyl) sebacate, di(2-ethylhexyl) azealate, ethyl glycol dilaurate, di-(2-ethylhexyl) phthalate, di-(1,3-methylbutyl) adipate, di-(1-ethylpropyl) azelate, diisopropyloxylate, dicyclohexyl sebacate, glycerol tri-n-heptoate, di(undecyl) azelate, and tetracthylene glycol di-(2-ethyl caproate), and mixtures thereof.
[0050] If it is desired to form a complex alcohol ester or complex acid ester, then the synthetic ester can also include a polybasic acid selected from the group consisting of: any C, to Cy, polybasic acids, e.g. adipic, azelaic, sebacic and dodecanedioic acids.
[0051] Other preferred polyol ester base oils are those ones prepared from technical pentaerythritol and a mixture of linear and branched C, to C,, carboxylic acids. Technical pentaerythritol is a mixture which includes about 85 to 92% monopentaerythritol and 8 to 15% dipentaerythritol. A typical commercial technical pentaerythritol contains about 88% monopentaerythritol having the formula:
CH,OH
HOH,C — C — CH,0OH
CH,OH and about 12% of dipentaerythritol having the formula:
Te CH,OH
HOH,C—C —C —0—C — C—CH,0OH I
Hy Hy
CH,OH CH,OH
The technical pentaerythritol may also contain some tri- and tetrapentaerythritol that is normally formed as by-products during the manufacture of technical pentaerythritol.
[0052] The preparation of esters from alcohols and carboxylic acids can be accomplished using conventional methods and techniques known and familiar to those skilled in the art. In general, the monohydric alcohol or polyhydric alcohol, e.g. technical pentaerythritol, is heated with the desired carboxylic acid or mixture of acids either neat or in the presence of a solvent such as an aromatic hydrocarbon and optionally in the presence of catalyst such as, e.g. titanium, zirconium and tin catalysts such as titanium, zirconium or tin alcohalates, carboxylates and chelates, HCl, HF, HBr, H,SO,, BF;, etc., see for example U.S.
Patent 3,038,859 and U.S. Patent 3,121,109.
[0053] Generally, a slight excess of acid is employed to force the reaction to completion to produce a fully esterified product. Water is removed during the reaction and any excess acid is then stripped from the reaction mixture. The esters of technical pentaerythritol may be used without further purification or may be further purified using conventional techniques such as distillation or other methods known to those of skill in the art.
[0054] Other polyol esters useful as turbine oil base oils are those made by synthesizing the polyol esters from a polyol and a branched or linear carboxylic acid in such a way that it has a substantial amount of unreacted hydroxyl groups; that is, the product is not fully esterified. The presence of the unreacted hydroxyl group in the ester is believed to allow this “high” hydroxyl ester to exhibit increased thermal/oxidation stability, as measured by high pressure differential scanning calorimetry (HPDSC). It is believed the presence of the unreacted hydroxyl group provides a pathway capable of scavenging alkoxide and alkyl peroxide radicals formed in the turbine oil during use, such scavenging thereby reducing the rate at which oxidation degradation can occur.
[0055] The high hydroxyl polyester is the reaction product of a linear or branched alcohol and at least one branched and/or linear carboxylic acid, the resulting synthetic ester having a hydroxyl number between 5 to 180 depending on the acid and polyol used (e.g. 1 to 25% unconverted hydroxyl groups, based on the total amount of hydroxyl groups in the branched or linear alcohol), preferably between about 5 to 100 (e.g. 1 to 15% unconverted hydroxyl groups), more preferably between 10 to 80 (e.g. 2 to 10% unconverted hydroxyl groups).
[0056] Hydroxyl number measures the free hydroxyl groups by determining the amount of acetic anhydride that the sample will react with under certain conditions. Anhydride is introduced in excess with the sample. Once the reaction is complete, the remaining anhydride is determined by titration with a base solution. The hydroxyl number is reported as milligrams of KOH/gram of sample. A standard method for measuring hydroxyl number is detailed by the
American Oil Chemist’s Society as A.O.C.S. Cd. 13-60. For highly converted esters, e.g. 99% or more conversion to ester (almost no unreacted hydroxyl groups), the hydroxyl number is generally less than or equal to 5.
[0057] In the case of both the fully esterified ester and the ester containing free hydroxyl groups, the alcohols and acids employed can be the same, the only difference in the products being, as previously indicated, that in one instance the product is fully esterified and in the other the product has free hydroxyl groups.
[0058] Mixtures of fully esterified synthetic esters and of synthetic esters containing free hydroxyl groups can also be used.
[0059] Esters suitable for use as base stocks for turbine oils are esters of monocarboxylic acids having three to twelve carbons and polyalcohols such as pentaerythritol, dipentaerythritol and trimethylolpropane. Examples of these esters are pentaerythrityl tetrabutyrate, pentaerythrityl tetravalerate, pentaerythrityl tetracaproate, pentaerythrityl dibutyratedicaproate, pentaerythrityl butyratecaproate divalerate, pentaerythrityl butyrate trivalerate, pentaerythrityl butyrate tricaproate, pentaerythrityl tributyratecaproate, mixed C4- to
Cio-saturated fatty acid esters of pentaerythritol, dipentaerythrityl hexavalerate, dipentaerythrityl hexacaproate, dipentaerythrityl hexaheptoate, dipentaerythrityl hexacaprylate, dipentaerythrityl tributyrate tricaproate, dipentaerythrityl trivalerate trinonylate, dipentaerythrityl mixed hexaesters of C4 to Cy fatty acids and trimethylolpropane heptylate. Pentaerythrityl esters of mixtures of C4 to Cy, acids are excellent base oils and are commercially available from Hercules
Chemical Company.
[0060] If desired the synthetic esters, e.g. fully esterified and/or esters containing free hydroxyl groups, can be further used with other base stocks such as mineral oil, highly refined mineral oil, polyalpha olefins, polyalkylene glycols, phosphate esters, silicone oils, other polyol esters, as well as hydrocarbon oils made by hydrodewaxing/hydroisomerizing waxy feeds such as hydrodewaxed/hydroisomerized slack wax or Fischer-Tropsch synthesis waxes.
[0061] It is preferred, however, that the synthetic ester be it a fully esterified material or an ester containing free hydroxyl groups either be used individually or only in the mixture of two or more esters.
[0062] Monomeric amine antioxidants are unsubstituted or hydrocarbon-substituted diphenyl amines, unsubstituted or hydrocarbyl-
substituted phenyl naphthyl amines and unsubstituted or hydrocarbyl-substituted phenothiazines wherein the hydrocarbyl-substituted group is styrene or a C; to Cy alkyl group, preferably a C, to Cy alkyl group, more preferably a C4 to Cy alkyl group. Other monomeric aryl amines have been described in the patent literature.
[0063] Polymeric amine antioxidants are the polymerization reaction products of one or more substituted or hydrocarbyl-substituted diphenyl amines, one or more unsubstituted or hydrocarbyl-substituted phenyl naphthyl amines or both one or more of unsubstituted or hydrocarbyl-substituted diphenylamine with one or more unsubstituted or hydrocarbyl-substituted phenyl naphthylamine. A representative schematic is presented below: 2 R2 (R )y ( )y
H and
H
NH
HN
RS a b ®) @ ®h, © wherein (a) and (b) each range from zero to 10, preferably zero to 5, more preferably zero to 3, most preferably 1 to 3, provided (a) + (b) is at least 2; for example:
(RY), (Ry R), RR),
NH NH or HN NH or 3 3 (R%) (RY (RY), (R by q q (A) (B) 2
NH NH or NH NH NH
R), R), R), (RY, R),
Cc ©) ©) wherein R? is a styrene or C; to Cs alkyl, Risa styrene or C; to Cj alkyl, Risa styrene or C, to Cs alkyl, preferably R; is a C; to Cs alkyl, Rj is a C; to Cy alkyl,
Ry is a Cy to Cs alkyl, more preferably R, is a C4 to C10 alkyl, Rs is a C4 to C10 alkyl and Ry is a C4 to C10 alkyl, p, gq and y individually range from O to up to the valence of the aryl group to which the respective R groups are attached, preferably at least one of p, q and y range from 1 to up to the valence of the aryl group to which the respective R group(s) are attached, more preferably p, q and y each individually range from at least 1 to up to the valence of the aryl group to which the respective R groups are attached.
[0064] Other more extensive oligomers are within the scope of this disclosure, but materials of formulae A, B, C and D are preferred.
[0065] The polymeric amine antioxidant may contain nonpolymerized aryl amine antioxidant starting materials as a result of the preparation procedure.
Additional monomeric amine antioxidants may be added to the lubricant to impart desired properties. Examples of monomeric amine antioxidants include but are not limited to diphenyl amine, alkylated diphenyl amines, styrenated diphenyl amines, phenyl-N-naphthyl amine, alkylated phenyl-N-naphthyl amines, styrenated phenyl-N-naphthyl amines, phenothiazine, alkylated phenothiazine, and styrenated phenothiazine. Other antioxidants such as hindered phenols and zinc dithiophosphates can also be added to the lubricant in addition to the polymerized amine antioxidant.
[0066] The polymeric amine antioxidant is present in an amount in the range 0.5 to 10 wt% (active ingredient), preferably 2 to 5 wt% (active ingredient) of polymerized aminic antioxidant exclusive of any unpolymerized aryl amine which may be present or any added antioxidants.
[0067] The method for maintaining or enhancing the antiwear performance of a turbine oil and improving the deposition formation resistance performance of a turbine oil containing polyol ester base stock and polymeric amine antioxidant is the use of a RDP antiwear additive of the formula:
Oo Oo
AAry— 0 P — © 0 P — O —fAry_ (RY), | RY. | (R),0 0 —tAN 0 —tAr (R®),, n NRL.
wherein R' is a C; to Cs alkyl group, x is an integer ranging from zero to 4, preferably zero to 2, more preferably zero, n is an integer ranging from 1 to 7, each Ar is independently phenyl or naphthyl, R* R® R and R® are the same or different C, to Cg alkyl groups, preferably hydrogen and C; to Cs alkyl groups, and 7", 75, Z¢ and Z° are the same or different, preferably the same, and range from 1 to up to the available valence of each Ar group, preferably 1 to 2, most preferably 1.
[0068] The RDP is used in an amount in the range 0.01 to 10 wt% (active ingredient), preferably 0.1 to 5 wt% (active ingredient), more preferably 1 to 4 wt% (active ingredient), contributing from 500 to 6000 ppm phosphorus, preferably 1000 to 4000 ppm phosphorus to the formulation.
[0069] The RDP can be employed in combination with the standard, typical antiwear additive such as tri-cresyl phosphate, tri(tert-butyl phenyl) phosphate and even IDP, but it is preferred that the RDP be used as a total replacement of any such other antiwear additives.
[0070] RDP not only exhibits enhanced antiwear performance/antiwear performance retention in the presence of polymeric amine antioxidant, which the other antiwear additives don’t, but the published literature also indicates it is not toxic, see e.g. Henrich, R. etal., “Two Generation Oral (Diet) Reproductive
Toxicity Study of Resorcinol Bis-Diphenylphosphate (Fyrolflex RDP) in Rats”,
International Journal of Toxicology, 19: 243-255, 2000; Ryan, B. M. etal., “Development Toxicity Study of Orally Administered Resorcinol
Bis-Diphenylphosphate (RDP) in Rats”, International Journal of Toxicology, 19: 257-264, 2000; Sherwood, R. L. et al., “Immunotoxicity Evaluation of Resorcinol
Bis-Diphenylphosphate (Fyrolflex RDP) in B6 C3F1 Mice”, International Journal of Toxicology, 19: 265-275, 2000; Henrich, T. etal., “Twenty-Eight Day
Nose-Only Inhalation Study of Resorcinol Bis-Diphenylphosphate (Fyrolflex
RDP) in Rats”, International Journal of Toxicology, 19: 223-231; and
Freudenthal, R.I. etal, “Comparative Metabolism and Toxicokinetics of "C-Resorcinol Bis-Diphenylphosphate (RDP) in the Rat, Mouse and Monkey”,
International Journal of Toxicology, 19: 233-242, 2000.
[0071] The turbine oils benefitted by the present method include turbine oils further containing additive amounts of any of the additives common to turbine oil formulations including by way of example and not limitation corrosion inhibitors such as combinations of one or more dicarboxylic acids and a linear or branched alkyl or alkenyl succinic acid/anhydride ester or hemiester or hydroxylated derivative of such esters or hemiesters or linear or branched alkyl or alkenyl-substituted succinimides or amino-substituted succinimides, as well as other antioxidants including phenolic and monomeric aminic antioxidants, extreme pressure additives, antifoamants, detergents, hydrolytic stabilizers, metal deactivators, rust inhibitors, colorants, odorants, deodorants, viscosity modifiers, viscosity index improvers, etc. as desired by the practitioner.
[0072] The following are examples of the present disclosure and are not to be construed as limiting.
[0073] The different phosphate esters evaluated in the following Examples are presented below in Table 1:
_04 -
Table 1
I I
PhO
RDP Sr 0 O——P—10Ph n=1to7 PhO
OPh n
IDP 9 I n=1to7 ol 0 0——P—0Ph pro”
OPh n 0 t-Bu-TPP | —\ Bu with varying amount of p 0 X unbutylated triphenyl phosphate \ / (TPP) 3 =
Tricresyl Phosphate (TCP) P © \~
HCN / 3
CH4 0 ==
Trixylyl Phosphate (TXP)
P Oo \
HCN / 3
[0074] The polyol ester oils used as base stocks in the formulations evaluated in the following Example are presented and identified below in Table 2:
Table 2
Jet Ester 1:
PE / di-PE ester of i-Cs, n-Cs, C-, Cg and Cg acids
Jet Ester 2:
PE / di-PE ester of i-Cs, n-Cs, C; and Cy acids
Jet Ester 3:
PE / di-PE ester of n-Cs, n-C4, Cg and C,, acids wherein PE / di-PE means technical grade pentaerythritol containing a mixture of mono-pentaerythritol and di-pentaerythritol.
[0075] Three different polymeric amine antioxidants were evaluated for their effect on WAM performance in the Examples presented. The specific polymeric amine antioxidant used is identified in each Example.
[0076] Two of the three polymeric amine antioxidants were prepared according to the teachings of U.S. 3,573,206. Polymeric Antioxidant 1 and polymeric
Antioxidant 2 were prepared by combining Cg-alkylated phenyl-a-naphthylamine and dioctyldiphenyl amine in a 3-to-2 ratio oligomerized to different degrees through the use of various amounts of alkyl peroxide. Polymeric Antioxidant 3 is a polymerized aryl amine commercially available from R.T. Vanderbilt as
Vanlube 9317. The treat rates of the antioxidants were adjusted based on the variations in percent active ingredient of the antioxidants to achieve an active ingredient treat level in each formulation of 2.8 wt% (active ingredient).
[0077] Two series of turbine engine oils were formulated, one series being a
Standard Performance Category (SPC) turbine (jet) engine oil and the second being a High Performance Category (HPC) turbine (jet) engine oil.
[0078] The definitions and criteria for certification of commercial jet oils as
SPC and HPC are given in the SAE specification AS5780. This specification defines basic physical, chemical and performance limits for 5 ¢St grades of gas turbine engine lubricating oils used in aero- and aero-derived marine and industrial applications, along with standard test methods and requirements for laboratories performing them. It also defines the quality control requirements to assure batch conformance and materials traceability, and the procedures to manage and communicate changes in oil formulation and brand.
[0079] These two series of turbine (jet) engine oils are provided in Table 3 and
Table 4:
Table 3
Standard Performance Category (SPC) Turbine (Jet) Oils
ARP 1231 | | 1 1 1 - mop 1 1202] -1 1 1 1 - anime et) Ep] which 11.8% is TPP eenesnme ee) op pl oo] which 6.6% is TPP ernest) op po] which 4.2% is TPP
F. 82% TCP/18% TX | | | | | | 28 | -
G.Durad12scrcpy | | | | | | | 3 emai ey | per fe
Increase at 218C
TAN at 218C
Table 4
High Performance Category (HPC) Turbine (Jet) Oils
STs | oosa | 050 | 0
Polymeric Antioxidant
MealPasivatr | 006 | 006 | 006 | 006 | 006 | 006 | 000
Arr Te por © poe [TT 1 1 1
C. Butylated triphenyl phosphate of 2.54 which 11.8% is TPP
D. Butylated triphenyl phosphate of 2.61 which 6.6% is TPP
E. Butylated triphenyl phosphate of 2.38 which 4.2% is TPP
F520 TCP/15% TXP 1 1 1 1 [ow —]
G Dud 135 (ICP) — 1 TT 1 1 To]
Phosphorus (ppm) 1910 1810 1830 1990
Oxidation & Corrosion Viscosity 13.0 26.8 20.7 26.2 28.7 19.7 18.1
Increase at 218C
Oxidation & Corrosion Viscosity 3.32 4.14 5.42 6.29 6.36 1.84 1.54
TAN at 218+A2C
VPC at 700F, mg deposits 1382 | 1319 143.6
D4172, 4-ball wear scar diameter, 0.36 0.44 0.54 0.51 0.54 0.51 mm
[0080] Because the additive being replaced is an antiwear additive, the antiwear performance of the turbine engine oils was determined using the
Wedeven Associates Machine (WAM) which is a required test for qualification of a turbine (jet) engine oil (scuffing load stage limit > = 15).
[0081] The WAM test employs a ball-on-disk machine that undergoes a progressive loading until a scuffing failure occurs in the lubricated contact zone.
Test conditions are selected to mimic the loading and roll-to-slide ratios encountered in the Ryder Gear Test described in Federal Test Method Standard 791C, Methods of Testing Lubricants, Liquid Fuels, and Related Products; Test
Method 6508 Load-Carrying Capacity of Lubricating Oils (Ryder Gear Machine).
The test equipment and procedure, which were employed and followed in conducting the following examples, are described in Aerospace Information Letter (AIR) 4978, Temporary Methods for Assessing the Load Carrying Capacity of
Aircraft Propulsion System Lubricating Oils. The paper is available from the
Society of Automotive Engineers.
[0082] As shown in Table 3, the WAM for the SPC turbine oil containing RDP (A) and the IDP (B) in combination with monomeric amine antioxidant outperformed the three formulations containing butylated triphenyl phosphate, as well as the two formulations containing tri-cresyl phosphate.
[0083] In Table 4, the WAM results for the HPC turbine oil shows, however, that whereas in the HPC turbine oil which contains a polyamine antioxidant, the antiwear performance of the IDP formulation, of the three butylated triphenyl phosphate formulations and the two tricresyl phosphate formulations were all lower than for SPC turbine oils containing comparable phosphate in a monoamine antioxidant formulation, unexpectedly the HPC turbine oil formulation containing the RDP in combination with polymeric aminic antioxidant exhibited a WAM load stage rating not only higher than that of the other HPC formulations but also higher than that of the SPC turbine oil similarly containing the RDP antiwear additive but in combination with the monomeric amine antioxidant.
[0084] Testing has shown the reproducibility of the WAM test to be +/- approximately 1.5 load stages.
[0085] The O&C test results in Tables 3 and 4 were obtained using test
FTM 5308 at 218°C.
[0086] Table 3 demonstrates that of the SPC turbine oil formulations the formulation containing RDP exceeded all others in terms of resistance to viscosity increase and tan increase.
[0087] Table 4 shows that of the HPC turbine oils, the formulation containing
RDP (Blend A) exhibited lower viscosity and TAN increase than any of the other formulations except for Blends F and G, which contained tricresyl phosphate.
[0088] The VPC test results for Tables 3 and 4 were obtained using the Vapor
Phase Coker (VPC) test at 700°F.
[0089] The VPC Test is described in Aerospace Recommended Practice (ARP) 5921 Vapor Phase Coking. This ARP, still in draft form, is available from
Mr. James McDonnell, Fuel & Lubricants Division, Naval Air Systems
Command, 22229 Elmer Road, Patuxent River, MD 20670, U.S.A.
[0090] Tables 3 and 4 both show that the formulations containing RDP exhibited results superior to that of the reference turbine oils which contained tricresyl phosphate antiwear additive.
[0091] Tables 3 and 4 compare the Thin Film Oxidation results for seven SPC turbine oils and for seven HPC turbine oils. The Thin Film Oxidation Test is described in Deposit Forming Tendencies of High-Temperature Lubricants, E. A.
Oberright, S. J. Leonard and H. L. Hepplewhite, ASLE Transations 1964 7(1), 64- 72. As can be seen, of the HPC turbine oil formulations tested the formulations containing the RDP met or exceeded the oxidation performance of the other formulations.
[0092] Table 4 presents the 4-ball wear test results for the HPC turbine oils.
The 4-ball wear test results were secured using ASTM D4172 as the screener test.
While all formulations exceeded the performance of Blend G which employed conventional commercial tricresyl phosphate, again the formulation containing the
RDP greatly exceeded the performance of the other formulations.
[0093] In Table 5 the effect, if any, of different ester base stocks on the WAM performance of formulated oils containing RDP and polymeric aminic antioxidant was determined. It was found that the identity of the ester base stock does not materially affect WAM results.
Table 5
Component (wt%) | Esterl | Bsterd | Esterd oroe
JetBster2 | | 9106
JetBster3 | | | 91.06
Metal Passivators | 0.06 | 006 | 006 2060 | 2020 | 2050 75
[0094] Table 6 investigates the effect, if any, that different polymeric aminic antioxidants have on the WAM performance of formulated oils containing RDP:
Table 6
Component, wt% | Antioxidant 1 | Antioxidant 2 | Antioxidant 3 91.06 91.06 92.46
Antioxidant 1 | 7 |] | 00
Antioxidant2 | | 7 | 00
Antioxidant3 | | | 56
Metal Passivators | 0.06 | 006 | 006
Phosphorus (ppm) 2050 2020 2010 773 7633
[0095] From Table 6 it is seen that the type of polymeric aminic antioxidant used in the formulation does not materially affect the WAM results.
[0096] Table 7 presents the compositional profiles and deposit formation resistance performance as determined by VPC testing of HPC turbine oils made using different polyol ester base oils in combination with polymeric aminic antioxidants and RDP compared to turbine oils containing the same ester base stocks and antioxidants but containing tricresyl phosphate in place of the RDP.
Table 7
Component, wt% | Blend X, | Blend X3 Blend Y, | Blend Yi | Blend Yo
Ref. X Ref. Y petbster2 | 1 1 | ss19 | 87.61 | 87.03
PetBster3 | 9153 | 906 J o0s3 | 1 1
Polymeric 7 7 7
Antioxidant,
Polymeric io, | | | fw fu] on [Metal Passivator | 0.06 | 0.06 | 006 | 005 | 005 | 005 | 0.05
Rop | 14 J 233 | | 175 | 233 | 291
Duadt2screp) | | |] 24 1 fF 1 1
Durad 120XC 3 (TCP/TXP)
Phosphorus (ppm) deposits
[0097] The different blends contained different amounts of RDP. The amounts of RDP added to blends X, and Xp were sufficient to provide amounts of phosphorus equal to 75% (Blend X,) and 125% (Blend Xp) of the amount of phosphorus contained in Ref. X contributed by the Durad 125 (TCP). Blends Ya,
Ys and Yc, respectively contained sufficient RDP to provide amounts of phosphorus equal to 75% (Blend Yj4), 100% (Blend Yp) and 125% (Blend Y¢) of the amount of phosphorus contained in Ref. Y contributed by the Durad 120XC (TCP/TXP). From Table 7 it is seen that the different blends containing the RDP exhibited from about 40 to 70 mg less deposits in the VPC test than the TCP- containing formulations.
[0098] Table 8 presents the compositional profile and deposit formation resistance performance of SPC turbine oils made using Jet Ester 1 in combination with a monomeric aminic antioxidant and RDP compared to turbine oil containing the same ester base stock and antioxidant but containing tricresyl phosphate in place of the RDP.
Table 8
ROP | 17s [29 | 00
Durad 120XC(TCP/TXP) | | | 3
[0099] It is seen that the amounts of RDP added to the different blends in
Table 8 varied from blend to blend. The amount of RDP added to Blend Z, was an amount sufficient to provide an amount of phosphorus equal to 75% of the amount of phosphorus contained in Ref. Z contributed by the Durad 120XC (TCP/TXP) while Blend Zg contained sufficient RDP to equal 125% of the amount of phosphorus contained in Ref.Z contributed by the Durad 120XC (TCP/TXP).
[00100] From Table 8 it is seen that the formulations containing the RDP exhibited deposit formation resistance performance superior to that of the reference formulation containing TCP, producing from about 100 to 135 mg less deposits in the VPC test than the TCP-containing formulation.
[00101] Applicants have attempted to disclose all embodiments and applications of the disclosed subject matter that could be reasonably foreseen. However, there may be unforeseeable, insubstantial modifications that remain as equivalents.
While the present disclosure has been described in conjunction with specific, exemplary embodiments thereof, it is evident that many alterations, modifications, and variations will be apparent to those skilled in the art in light of the foregoing description without departing from the spirit or scope of the present disclosure.
Accordingly, the present disclosure is intended to embrace all such alterations, modifications, and variations of the above detailed description.
[00102] All patents, test procedures, and other documents cited herein, including priority documents, are fully incorporated by reference to the extent such disclosure is not inconsistent with this disclosure and for all jurisdictions in which such incorporation is permitted.
[00103] When numerical lower limits and numerical upper limits are listed herein, ranges from any lower limit to any upper limit are contemplated.
Claims (25)
- CLAIMS:I. A turbine oil exhibiting maintained or improved antiwear performance as specified in SAE specification AS 5780 comprising a synthetic ester base oil, one or more of a polymeric aminic antioxidant and RDP antiwear additive of the formula: 0 0 AAry— 0 P — © 0 P — O —fAry_ (RY), RY. | (R%),0 0 —tArd 0 —tar (R®),, hn ~ (R),c wherein R' is a C, to Cs alkyl group, x is an integer ranging from zero to 4, n is an integer ranging from 1 to 7, each Ar is independently phenyl or naphthyl, R*, R®, R® and R® are the same or different C; to C5 alkyl groups or hydrogen and where any of R* to R” are other than hydrogen the corresponding 7%, 78,7 and ZP are the same or different and range from 1 to up to the available valence of each Ar group, the RDP being present in an amount in the range 0.01 to 10 wt% based on active ingredient and contributing from 500 to 6000 ppm phosphorus, wherein the antiwear performance of the turbine oil as measured by the Wedeven Associates Machine (WAM) test ranges from greater than 23 to 30.
- 2. The turbine oil of claim 1 wherein the synthetic ester base oil is a diester or a polyolester.
- 3. The turbine oil of claim 1 wherein the one or more polymeric aminic antioxidants is the polymerized reaction product of one or more diphenyl amines, one or more phenyl naphthyl amines or both one or more diphenyl amines with one or more phenyl naphthyl amines.
- 4. The turbine oil of claim 3 wherein the one or more polymeric amine antioxidant is the reaction product of: 2 R2 rR), ( )y H and H NH NH R3 RY), (@ RY), (b) wherein (a) and (b) each range from zero to 10 provided (a) + (b) is at least 2, R> is styrene or a C; to Cj alkyl, R? is styrene or a C; to Cs alkyl, R*is styrene or a C; to Cy alkyl, p, g and vy individually range from zero to up to the valence of the aryl group to which the respective R groups are attached.
- 5. The turbine oil of claim 1 wherein in the RDP additive » ranges from zero to 2, RA, RE, R® and RP are the same or different and are selected from hydrogen and C, to Cs alkyl, and Z*, 7°, 7° and Z are the same or different and range from 1 to 2.
- 6. The turbine oil of claim 5 wherein the RDP is present in an amount in the range 0.1 to 5 wt% based on active ingredient contributing 1000 to 4000 ppm phosphorus.
- 7. The turbine oil of claim 1, 2, 3, 4, 5 or 6 wherein the polymeric aminic antioxidant is present in an amount in the range 0.5 to 10 wt% based on active ingredient.
- 8. The turbine oil of claim 1, 2, 3, 4, 5 or 6 further containing additive amounts of corrosion inhibitors, extreme pressure additives, antifoamants, detergents, hydrolytic stabilizers, metal deactivators, rust inhibitors, colorants, odorants, deodorants, viscosity modifiers, viscosity index improvers, phenolic antioxidants and monomeric aminic antioxidants.
- 9. A method for maintaining or enhancing the antiwear performance of a High Performance Category turbine oil comprising a synthetic ester base oil, one or more of a polymeric aminic antioxidant and RDP antiwear additive of the formula: 0 0 ANY— 0 P — © 0 P — 0 —tArN_ (RY), | RI). | (RO), 0 —tAN 0 —tAr (R®),, n ~ (R°),c wherein R' is a C; to Cs alkyl group, x is an integer ranging from zero to 4, n is an integer ranging from 1 to 7, each Ar is independently phenyl or naphthyl, RY, R®, R® and R® are the same or different C; to C5 alkyl groups or hydrogen and where any of R* to R” are other than hydrogen the corresponding Z*, Z®, Z© and ZP are the same or different and range from 1 to up to the available valence of each Ar group, the RDP being present in an amount in the range 0.01 to 10 wt% based on active ingredient and contributing from 500 to 6000 ppm phosphorus, wherein the antiwear performance of the turbine oil as measured by the Wedeven Associates Machine (WAM) test ranges from greater than 23 to 30.
- 10. The method of claim 9 wherein the synthetic ester base stock is a diester or a polyol ester.
- 11. The method of claim 9 wherein the one or more polymeric aminic antioxidant is the polymerized reaction product of one or more diphenyl amines, one or more phenyl naphthyl amines or both one or more diphenyl amines with one or more phenyl naphthyl amines.
- 12. The method of claim 9 wherein the one or more polymeric aminic antioxidants is the reaction product of: 2 R2 (R )y ( )y H and H NH NH R3 RY), (@ RY), (b) wherein (a) and (b) each range from zero to 10 provided (a) + (b) is at least 2, R> is styrene or a C; to Cj alkyl, R? is styrene or a C; to Cs alkyl, R*is styrene or a C; to Cy alkyl, p, g and vy individually range from zero to up to the valence of the aryl group to which the respective R groups are attached.
- 13. The method of claim 9 wherein in the RDP antiwear additive x ranges from zero to 2, RA, RE, R® and RP are the same or different and are selected from hydrogen and C, to Cs alkyl groups, and Z*, Z®, Z© and Z” are the same or different and range from 1 to 2.
- 14. The method of claim 9 wherein the RDP is used in an amount in the range 0.1 to 5 wt% based on active ingredient contributing 1000 to 4000 ppm phosphorus.
- 15. The method of claim 9, 10, 11, 12, 13 or 14 wherein the polymeric aminic antioxidant is employed in an amount in the range 0.5 to 10 wt% based on active ingredient.
- 16. The method of claim 9, 10, 11, 12, 13 or 14 wherein the turbine oil further contains additive amounts of corrosion inhibitors, extreme pressure additives, antifoamants, detergents, hydrolytic stabilizers, metal deactivators, rust inhibitors, colorants, odorants, deodorants, viscosity modifiers, viscosity index improvers, phenolic antioxidants and monomeric aminic antioxidants.
- 17. A method for improving the resistance to deposit formation of turbine oil comprising a synthetic ester base oil, one or more polymeric or monomeric aromatic aminic antioxidants, and RDP antiwear additive of the formula: 0 0 ANY— 0 P — © 0 P — 0 —tAN_ (RY), | RI). | (R%),0 0 —tAN 0 —tar (R®) , n N (Rc wherein R' is a C; to Cs alkyl group, x is an integer ranging from zero to 4, n is an integer ranging from 1 to 7, each Ar is independently phenyl or naphthyl, R*, R®, R® and R® are the same or different C; to C5 alkyl groups or hydrogen and where any of R* to R” are other than hydrogen the corresponding Z*, Z®, Z© and ZP are the same or different and range from 1 to up to the available valence of each Ar group, the RDP being present in an amount in the range 0.01 to 10 wt% based on active ingredient and contributing from 500 to 6000 ppm phosphorus, wherein the resistance to deposit formation as measured by the Vapor Phase Coker Test at 700° F of the turbine oil is at least 30 mg lower than the deposit formation of turbine oils containing the same ester base stock and aminic antioxidant. but containing tricresyl phosphate in place of the RDP.
- 18. The method of claim 17 wherein the turbine oil is a Standard Performance Category (SPC) turbine oil wherein the antioxidant is one or more monomeric aminic antioxidants.
- 19. The method of claim 17 wherein the turbine oil is a High Performance Category (HPC) turbine oil wherein the antioxidant is one or more polymeric aminic antioxidants.
- 20. The method of claim 19 wherein the one or more polymeric aminic antioxidant is the polymerized reaction product of one or more diphenyl amines, one or more phenyl naphthyl amines or both one or more diphenyl amines with one or more phenyl naphthyl amines.
- 21. The method of claim 19 wherein the one or more polymeric aminic antioxidants is the reaction product of:2 R2 (R7), (R) y H and H NH NH RS a b ®)y © ry, © wherein (a) and (b) each range from zero to 10 provided (a) + (b) is at least 2, R’ is styrene or a C; to Cj alkyl, R? is styrene or a C; to Cy alkyl, R*is styrene or a C; to Cy alkyl, p, g and vy individually range from zero to up to the valence of the aryl group to which the respective R groups are attached.
- 22. The method of claim 17, 18, 19, 20 or 21 wherein in the RDP antiwear additive x ranges from zero to 2, R*, RE, R® and RP are the same or different and are selected from hydrogen and C; to Cs alkyl groups, and Z*, Z®, 7% and ZP are the same or different and range from 1 to 2.
- 23. The method of claim 17, 18, 19, 20 or 21 wherein the RDP is used in an amount in the range 0.1 to 5 wt% based on active ingredient contributing 1000 to 4000 ppm phosphorus.
- 24. The method of claim 19, 20 or 21 wherein the polymeric aminic antioxidant is employed in an amount in the range 0.5 to 10 wt% based on active ingredient.
- 25. The method of claim 17, 18, 19, 20 or 21 wherein the synthetic ester is selected from the group consisting of a mixture of monopentaerythritol/dipentaerythritol esters of i-Cs, n-Cs, C; and Cy acids, or a mixture of monopentaerythritol/dipentaerythritol esters of n-Cs, n-C,, Cg and Cj acids.
Applications Claiming Priority (3)
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US36812710P | 2010-07-27 | 2010-07-27 | |
US13/190,977 US8623795B2 (en) | 2010-07-27 | 2011-07-26 | Method for maintaining antiwear performance of turbine oils containing polymerized amine antioxidants and for improving the deposit formation resistance performance of turbine oils containing monomeric and/or polymeric antioxidants |
PCT/US2011/045474 WO2012015878A1 (en) | 2010-07-27 | 2011-07-27 | Maintaining antiwear performance and improving deposit formation resistance of turbine oils |
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EP (1) | EP2598490B1 (en) |
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CN102796599B (en) * | 2012-07-30 | 2014-09-03 | 新疆福克油品股份有限公司 | Preparation method of synthetic steam turbine oil |
US10604720B2 (en) * | 2015-07-07 | 2020-03-31 | Exxonmobil Research And Engineering Company | Method and composition for preventing or reducing engine knock and pre-ignition in high compression spark ignition engines |
US20190093040A1 (en) | 2017-09-22 | 2019-03-28 | Exxonmobil Research And Engineering Company | Lubricating oil compositions with viscosity and deposit control |
US20200199480A1 (en) | 2018-12-19 | 2020-06-25 | Exxonmobil Research And Engineering Company | Lubricating oil compositions with antioxidant formation and dissipation control |
WO2020132164A1 (en) | 2018-12-19 | 2020-06-25 | Exxonmobil Research And Engineering Company | Lubricating oil compositions with viscosity control |
US20230242830A1 (en) * | 2020-05-20 | 2023-08-03 | Nyco | Use of oils comprising non-neurotoxic anti-wear additives |
US11230683B2 (en) * | 2020-05-20 | 2022-01-25 | Nyco | Use of oils comprising non-neurotoxic anti-wear additives |
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US3038859A (en) | 1959-06-24 | 1962-06-12 | Sinclair Refining Co | Ester based lubricant composition containing phenothiazine and aminoquinoline |
US3121109A (en) | 1960-11-23 | 1964-02-11 | Sinaclair Res Inc | Ester interchange of aliphatic dicarboxylic acid diesters using titanium polymer catalysts |
US3573206A (en) | 1966-03-28 | 1971-03-30 | Mobil Oil Corp | Lubricant compositions |
US4780229A (en) | 1984-10-01 | 1988-10-25 | Akzo America Inc. | High temperature polyol ester/phosphate ester crankcase lubricant composition |
JP3199844B2 (en) | 1991-06-14 | 2001-08-20 | エチル・ペトロリアム・アデイテイブズ・インコーポレーテツド | Organic phosphates and their production |
US5344468A (en) | 1991-06-14 | 1994-09-06 | Ethyl Petroleum Additives, Inc. | Organic phosphates and their use as wear inhibitors |
US5206404A (en) | 1992-04-27 | 1993-04-27 | Fmc Corporation | Triaryl phosphate ester composition and process for its preparation |
EP0612837A1 (en) | 1993-01-06 | 1994-08-31 | Akzo Nobel N.V. | Polyphenylene ether lubricant containing hydrocarbyl bis(dihydrocarbylphosphate) compound |
US5560849A (en) * | 1994-12-23 | 1996-10-01 | Fmc Corporation | Synthetic ester lubricant having improved antiwear properties |
FR2847596B1 (en) | 2002-11-21 | 2005-08-19 | Demeter Technologie Sa | PROCESS FOR THE MANUFACTURE, IN PARTICULAR COLD, OF A COATED, AND COATED OBTAINED BY CARRYING OUT SAID METHOD |
EP1734103A4 (en) | 2004-03-25 | 2009-05-06 | Nippon Oil Corp | Lubricating oil composition for industrial machinery and equipment |
US7799101B2 (en) | 2004-09-29 | 2010-09-21 | Chemtura Corporation | Stabilized lubricant compositions |
US7579306B2 (en) | 2005-03-02 | 2009-08-25 | Chemtura Corporation | Method for improving the oxidative stability of industrial fluids |
WO2007089835A2 (en) | 2006-01-30 | 2007-08-09 | Inolex Investment Corp. | Improved high temperature lubricant compositions |
US7863227B2 (en) * | 2006-03-31 | 2011-01-04 | Exxonmobil Research And Engineering Company | High performance lubricant containing high molecular weight aromatic amine antioxidant and low boron content dispersant |
US20090253597A1 (en) | 2008-03-31 | 2009-10-08 | Exxonmobil Research And Engineering Company | Lubricant composition with improved varnish deposit resistance |
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2011
- 2011-07-26 US US13/190,977 patent/US8623795B2/en not_active Expired - Fee Related
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