SG11201906175SA - Transalkylation process and catalyst composition used therein - Google Patents
Transalkylation process and catalyst composition used thereinInfo
- Publication number
- SG11201906175SA SG11201906175SA SG11201906175SA SG11201906175SA SG11201906175SA SG 11201906175S A SG11201906175S A SG 11201906175SA SG 11201906175S A SG11201906175S A SG 11201906175SA SG 11201906175S A SG11201906175S A SG 11201906175SA SG 11201906175S A SG11201906175S A SG 11201906175SA
- Authority
- SG
- Singapore
- Prior art keywords
- international
- applicant
- pct
- rule
- catalyst composition
- Prior art date
Links
- 238000010555 transalkylation reaction Methods 0.000 title abstract 6
- 239000003054 catalyst Substances 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical class CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical class CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 abstract 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- 150000001491 aromatic compounds Chemical class 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- 241000234282 Allium Species 0.000 abstract 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 abstract 1
- 230000029936 alkylation Effects 0.000 abstract 1
- 238000005804 alkylation reaction Methods 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- -1 for example Chemical class 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 230000008520 organization Effects 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
- C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/067—C8H10 hydrocarbons
- C07C15/073—Ethylbenzene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/085—Isopropylbenzene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 02 August 2018 (02.08.2018) WIP0 I PCT onion °nolo olomollm olo 1111111 ow (10) International Publication Number WO 2018/140149 Al (51) International Patent Classification: CO7C 6/12 (2006.01) (21) International Application Number: PCT/US2017/066633 (22) International Filing Date: 15 December 2017 (15.12.2017) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/450,122 25 January 2017 (25.01.2017) US 17161741.8 20 March 2017 (20.03.2017) EP (71) Applicant: EXXONMOBIL CHEMICAL PATENTS INC. [US/US]; 5200 Bayway Drive, Baytown, TX 77520 (US). (72) Inventors: LOVELESS, Brett, T.; 14005 N. Lake Branch Lane, Houston, TX 77044 (US). BEECKMAN, Jean, W.; 5431 The Bridle Path, Columbia, MD 21044 (US). OLIVERI, Christopher, G.; 14611 Wood Thorn Court, Humble, TX 77396 (US). WEIGEL, Scott, J.; 246 Elm Road, Allentown, PA 18104 (US). IDE, Matthew, S.; 1 Woods End Drive, Doylestown, PA 18902 (US). BAUM- RUCKER, Theresa, A.; 31210 Hollow Sage Lane, Spring, TX 77386 (US). (74) Agent: TYUS, Darryl, M. et al.; Exxonmobil Chemical Company, Law Department, P.O. Box 2149, Baytown, TX 77522-2149 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Declarations under Rule 4.17: as to applicant's entitlement to apply for and be granted a patent (Rule 4.1 7(ii)) as to the applicant's entitlement to claim the priority of the earlier application (Rule 4.1 7(iii)) Published: — with international search report (Art. 21(3)) (54) Title: TRANSALKYLATION PROCESS AND CATALYST COMPOSITION USED THEREIN (57) : The present disclosure relates to a process for producing a mono-alkylated aromatic compound, such as, for example, ethylbenzene or cumene, in which an alkylatable aromatic compound stream, such as, for example, benzene, and an alkylation agent stream, such as, for example, poly-ethylbenzene or poly-isopropylbenzene, are contacted in the presence of a trans alkylation catalyst and under at least partial liquid phase transalkylation conditions. The trans alkylation catalyst comprises a zeolite having a framework structure selected from the group consisting of FAU, BEA*, MOR, MWW and mixtures thereof. The zeolite has a silica- alumina molar ratio in a range of 10 to 15. The transalkylation catalyst composition has an external surface area/volume ratio in the range of 30 cm 1 to 85 cm 1.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762450122P | 2017-01-25 | 2017-01-25 | |
| EP17161741 | 2017-03-20 | ||
| PCT/US2017/066633 WO2018140149A1 (en) | 2017-01-25 | 2017-12-15 | Transalkylation process and catalyst composition used therein |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SG11201906175SA true SG11201906175SA (en) | 2019-08-27 |
Family
ID=60888762
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SG11201906175SA SG11201906175SA (en) | 2017-01-25 | 2017-12-15 | Transalkylation process and catalyst composition used therein |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20200385322A1 (en) |
| EP (1) | EP3573942B1 (en) |
| JP (1) | JP6914362B2 (en) |
| KR (1) | KR102315640B1 (en) |
| CN (1) | CN110214131B (en) |
| CA (1) | CA3049411C (en) |
| ES (1) | ES2902875T3 (en) |
| RU (1) | RU2753341C2 (en) |
| SG (1) | SG11201906175SA (en) |
| ZA (1) | ZA201904080B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11739274B2 (en) | 2019-08-20 | 2023-08-29 | Exxon Mobil Technology and Engineering Company | Metal-organic framework catalysts and their use thereof in catalytic cracking |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2075467C1 (en) * | 1990-12-17 | 1997-03-20 | Дзе Дау Кемикал Компани | Process for preparing ethylbenzene or cumene |
| US6936744B1 (en) * | 2000-07-19 | 2005-08-30 | Exxonmobil Chemical Patents, Inc. | Alkylaromatics production |
| US20020042548A1 (en) * | 2001-07-11 | 2002-04-11 | Dandekar Ajit B. | Process for producing cumene |
| RU2246474C1 (en) * | 2003-11-24 | 2005-02-20 | Иванова Ирина Игоревна | Method for preparing alkylated polycyclic aromatic hydrocarbons |
| US6894201B1 (en) * | 2003-12-19 | 2005-05-17 | Uop Llc | Process and apparatus for the removal of nitrogen compounds from a fluid stream |
| CN101151230B (en) * | 2005-03-31 | 2012-10-03 | 埃克森美孚化学专利公司 | A process of using a high activity catalyst for the transalkylation of aromatics |
| SG172597A1 (en) * | 2006-05-24 | 2011-07-28 | Exxonmobil Chem Patents Inc | Monoalkylated aromatic compound production |
| GB0806422D0 (en) | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
| US20080171902A1 (en) * | 2007-01-12 | 2008-07-17 | Deng-Yang Jan | Aromatic Transalkylation Using a Y-85 Zeolite |
| US20080171649A1 (en) * | 2007-01-12 | 2008-07-17 | Deng-Yang Jan | Modified Y-85 and LZ-210 Zeolites |
| WO2008088962A1 (en) * | 2007-01-12 | 2008-07-24 | Uop Llc | Y-85 and modified lz-210 zeolites |
| US7517825B2 (en) * | 2007-01-12 | 2009-04-14 | Uop Llc | Aromatic transalkylation using a LZ-210 zeolite |
| US7737314B2 (en) * | 2007-02-12 | 2010-06-15 | Exxonmobil Chemical Patents Inc. | Production of high purity ethylbenzene from non-extracted feed and non-extracted reformate useful therein |
| US9365469B2 (en) * | 2011-09-14 | 2016-06-14 | Uop Llc | Process for transalkylating aromatic hydrocarbons |
| WO2014182294A1 (en) * | 2013-05-08 | 2014-11-13 | Badger Licensing Llc | Aromatics alkylation process |
| US9744530B2 (en) * | 2013-05-09 | 2017-08-29 | Exxonmobil Chemical Patents Inc. | Treatment of aromatic alkylation catalysts |
-
2017
- 2017-12-15 KR KR1020197021669A patent/KR102315640B1/en active IP Right Grant
- 2017-12-15 US US16/472,610 patent/US20200385322A1/en not_active Abandoned
- 2017-12-15 RU RU2019126013A patent/RU2753341C2/en active
- 2017-12-15 JP JP2019560040A patent/JP6914362B2/en active Active
- 2017-12-15 ES ES17823004T patent/ES2902875T3/en active Active
- 2017-12-15 CA CA3049411A patent/CA3049411C/en active Active
- 2017-12-15 CN CN201780084450.5A patent/CN110214131B/en active Active
- 2017-12-15 SG SG11201906175SA patent/SG11201906175SA/en unknown
- 2017-12-15 EP EP17823004.1A patent/EP3573942B1/en active Active
-
2019
- 2019-06-24 ZA ZA2019/04080A patent/ZA201904080B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP6914362B2 (en) | 2021-08-04 |
| KR102315640B1 (en) | 2021-10-21 |
| KR20190095465A (en) | 2019-08-14 |
| CN110214131B (en) | 2022-08-09 |
| RU2019126013A3 (en) | 2021-02-26 |
| US20200385322A1 (en) | 2020-12-10 |
| RU2753341C2 (en) | 2021-08-13 |
| JP2020505455A (en) | 2020-02-20 |
| ES2902875T3 (en) | 2022-03-30 |
| CA3049411A1 (en) | 2018-08-02 |
| RU2019126013A (en) | 2021-02-26 |
| ZA201904080B (en) | 2020-12-23 |
| EP3573942B1 (en) | 2021-12-01 |
| EP3573942A1 (en) | 2019-12-04 |
| CA3049411C (en) | 2021-02-16 |
| CN110214131A (en) | 2019-09-06 |
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