SG11201806008PA - Hydrogenation treatment catalyst for hydrocarbon oil, method for producing the same, and hydrogenation treatment method - Google Patents

Hydrogenation treatment catalyst for hydrocarbon oil, method for producing the same, and hydrogenation treatment method

Info

Publication number
SG11201806008PA
SG11201806008PA SG11201806008PA SG11201806008PA SG11201806008PA SG 11201806008P A SG11201806008P A SG 11201806008PA SG 11201806008P A SG11201806008P A SG 11201806008PA SG 11201806008P A SG11201806008P A SG 11201806008PA SG 11201806008P A SG11201806008P A SG 11201806008PA
Authority
SG
Singapore
Prior art keywords
catalyst
mass
parts
hydrogenation treatment
carrier
Prior art date
Application number
SG11201806008PA
Inventor
Yusuke Matsumoto
Mitsunori Watabe
Midori Kobayashi
Original Assignee
Jgc Catalysts & Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2016087499A external-priority patent/JP6681259B2/en
Application filed by Jgc Catalysts & Chemicals Ltd filed Critical Jgc Catalysts & Chemicals Ltd
Publication of SG11201806008PA publication Critical patent/SG11201806008PA/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/051—Molybdenum
    • B01J27/0515—Molybdenum with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J35/30—
    • B01J35/60—
    • B01J35/615—
    • B01J35/647—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/08—Nitrates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof

Abstract

Provided is a hydrogenation treatment catalyst for hydrocarbon oil, which is excellent in desulfurization activity while maintaining industrially high productivity, and which can regenerate a high-performance catalyst. On a g -alumina carrier (a carrier of 100% g -alumina or an inorganic composite oxide carrier of g -alumina mixed with foreign element metals), for example, molybdenum and/or tungsten are/is loaded in an amount of 15 to 28 parts by mass in terms of oxide relative to 100 parts by mass of the catalyst, and cobalt and/or nickel are/is in an amount of 2 to 7 parts by mass in terms of oxide, and the content of carbon derived from an organic acid is 2.0 parts by mass or less on an elemental basis. The specific surface area of the catalyst is 180 to 320 m 2/g, and the mean pore size measured according to a mercury intrusion method is 50 to 110 Å. The ignition loss of the catalyst is 5.0% or less, and the nitrogen monoxide adsorption amount on the sulfurized catalyst is 8.0 ml/g or more.
SG11201806008PA 2016-02-01 2017-01-30 Hydrogenation treatment catalyst for hydrocarbon oil, method for producing the same, and hydrogenation treatment method SG11201806008PA (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2016017533 2016-02-01
JP2016087499A JP6681259B2 (en) 2016-04-25 2016-04-25 Hydroprocessing catalyst for hydrocarbon oil, method for producing the same, and hydroprocessing method
PCT/JP2017/003197 WO2017135193A1 (en) 2016-02-01 2017-01-30 Hydrotreating catalyst for hydrocarbon oil, method for producing hydrotreating catalyst, and hydrotreating method

Publications (1)

Publication Number Publication Date
SG11201806008PA true SG11201806008PA (en) 2018-08-30

Family

ID=59501033

Family Applications (3)

Application Number Title Priority Date Filing Date
SG11201806008PA SG11201806008PA (en) 2016-02-01 2017-01-30 Hydrogenation treatment catalyst for hydrocarbon oil, method for producing the same, and hydrogenation treatment method
SG10202007253YA SG10202007253YA (en) 2016-02-01 2017-01-30 Hydrogenation treatment catalyst for hydrocarbon oil, method for producing the same, and hydrogenation treatment method
SG10202007257QA SG10202007257QA (en) 2016-02-01 2017-01-30 Hydrogenation treatment catalyst for hydrocarbon oil, method for producing the same, and hydrogenation treatment method

Family Applications After (2)

Application Number Title Priority Date Filing Date
SG10202007253YA SG10202007253YA (en) 2016-02-01 2017-01-30 Hydrogenation treatment catalyst for hydrocarbon oil, method for producing the same, and hydrogenation treatment method
SG10202007257QA SG10202007257QA (en) 2016-02-01 2017-01-30 Hydrogenation treatment catalyst for hydrocarbon oil, method for producing the same, and hydrogenation treatment method

Country Status (4)

Country Link
KR (1) KR102608017B1 (en)
CN (1) CN108602055A (en)
SG (3) SG11201806008PA (en)
WO (1) WO2017135193A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111375438A (en) * 2018-12-29 2020-07-07 中国石油化工股份有限公司 Heavy oil hydrotreating catalyst carrier, catalyst and preparation method thereof
CN111375396B (en) * 2018-12-29 2022-06-07 中国石油化工股份有限公司 Hydrotreating catalyst carrier, catalyst and preparation method thereof
CN113562750B (en) * 2020-04-28 2023-05-09 中国石油化工股份有限公司 Pseudo-boehmite containing phosphorus and boron, preparation method thereof, alumina containing phosphorus and boron and application thereof
KR20230163761A (en) * 2022-05-24 2023-12-01 롯데케미칼 주식회사 Transition metal oxide composite and manufacturing method and the use thereof

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Also Published As

Publication number Publication date
KR102608017B1 (en) 2023-11-30
KR20180111815A (en) 2018-10-11
WO2017135193A1 (en) 2017-08-10
SG10202007253YA (en) 2020-09-29
SG10202007257QA (en) 2020-09-29
CN108602055A (en) 2018-09-28

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