SG11201408134RA - Dual catalyst esterification - Google Patents
Dual catalyst esterificationInfo
- Publication number
- SG11201408134RA SG11201408134RA SG11201408134RA SG11201408134RA SG11201408134RA SG 11201408134R A SG11201408134R A SG 11201408134RA SG 11201408134R A SG11201408134R A SG 11201408134RA SG 11201408134R A SG11201408134R A SG 11201408134RA SG 11201408134R A SG11201408134R A SG 11201408134RA
- Authority
- SG
- Singapore
- Prior art keywords
- international
- ames
- catalyst
- rule
- free fatty
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/02—Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 25 September 2014 (25.09.2014) WIPOIPCT (10) International Publication Number WO 2014/150678 A1 (51) International Patent Classification: C09F 7/00 (2006.01) (21) International Application Number: (22) International Filing Date: (25) Filing Language: (26) Publication Language: PCT/US2014/023950 12 March 2014 (12.03.2014) English English (30) Priority Data: 61/800,986 15 March 2013 (15.03.2013) US (71) Applicant: RENEWABLE ENERGY GROUP, INC. [US/US]; 416 S. Bell Ave., Ames, IA 50010 (US). (72) Inventors: SLADE, David, A.; 2729 Northwood Dr, Ames, IA 50010 (US). ELLENS, Cody, J.; 323 SE Springwood Dr, Ankeny, IA (US). BROWN, Jared, N.; 2323 NW Cherry St., Ankeny, IA (US). POLLARD, An thony, J.S.; 719 Douglas Ave, Ames, IA 50010 (US). AL- BIN, Bradley, Neil; 3031 Bayberry RD, Ames, IA 50014 (US). (74) Agents: CARTER, Ryan, N. et al.; Nyemaster Goode, P.C., 625 First Street SE, Suite 400, Cedar Rapids, IA 52401 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available)'. AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available)'. ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Declarations under Rule 4.17: — of inventorship (Rule 4.17(iv)) Published: — with international search report (Art. 21(3)) — before the expiration of the time limit for amending the claims and to be republished in the event of receipt of amendments (Rule 48.2(h)) (54) Title: DUAL CATALYST ESTERIFICATION Fig. 1 100—» 105- 00 l> o © CJ (57) Abstract: Methods, processes, apparatus, equipment and systems are disclosed for converting carboxylic acids into esters by es - terification with alcohol and a dual catalyst. The method combines homogenous and heterogeneous a catalyst in one or more reactors to increase the conversion of carboxylic acids compared to using a homogenous and/or heterogeneous catalyst independently. The invention converts free fatty acids into esters by esterification with alcohol and a dual catalyst such that the reaction mixture contains sufficiently low free fatty acids and the amount of free fatty acids in the product stream leaving the process remains stable over time.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361800986P | 2013-03-15 | 2013-03-15 | |
PCT/US2014/023950 WO2014150678A1 (en) | 2013-03-15 | 2014-03-12 | Dual catalyst esterification |
Publications (1)
Publication Number | Publication Date |
---|---|
SG11201408134RA true SG11201408134RA (en) | 2015-01-29 |
Family
ID=51530177
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SG11201408134RA SG11201408134RA (en) | 2013-03-15 | 2014-03-12 | Dual catalyst esterification |
Country Status (11)
Country | Link |
---|---|
US (2) | US8957242B2 (en) |
EP (1) | EP2880112A4 (en) |
JP (1) | JP2015527335A (en) |
KR (1) | KR20150013877A (en) |
AU (1) | AU2014235751B2 (en) |
BR (1) | BR112015023555B1 (en) |
CA (1) | CA2877832C (en) |
MY (1) | MY171548A (en) |
SG (1) | SG11201408134RA (en) |
UY (1) | UY35404A (en) |
WO (1) | WO2014150678A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PT3011001T (en) * | 2013-06-19 | 2020-05-27 | Argent Energy Uk Ltd | Process and apparatus for purifying a fatty mixture and related products including fuels |
FR3059327B1 (en) * | 2016-11-25 | 2021-10-15 | Arkema France | ACID COMPOSITION FOR TREATMENT OF FATTY ACIDS |
EA039919B1 (en) * | 2017-09-26 | 2022-03-28 | Публичное акционерное общество "СИБУР Холдинг" | Method of preparing esters of terephthalic acid |
KR102111500B1 (en) * | 2019-10-08 | 2020-05-15 | 강용근 | Special additives for lubricating oil to improve extreme pressure and improve soot |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3501761A1 (en) | 1985-01-21 | 1986-07-24 | Henkel KGaA, 4000 Düsseldorf | METHOD FOR PRE-Esterification OF FREE FATTY ACIDS IN RAW FATS AND / OR OILS |
EP0454719B1 (en) | 1989-01-17 | 1996-06-05 | Davy Process Technology Limited | A continuous process for the production of carboxylic acid esters |
EP0854131B1 (en) | 1996-07-18 | 2003-03-19 | Toray Industries, Inc. | Process for the preparation of alkyl carboxylates |
US5719311A (en) | 1996-11-19 | 1998-02-17 | Industrial Technology Research Institute | Catalytic processes for esterification of carboxylic acids |
US6175037B1 (en) * | 1998-10-09 | 2001-01-16 | Ucb, S.A. | Process for the preparation of (meth)acrylate esters and polyester (meth)acrylates using microwave energy as a heating source |
EP0995738A1 (en) * | 1998-10-19 | 2000-04-26 | Ucb, S.A. | Process for the preparation of (meth)acrylate esters and polyester (meth)acrylates |
US6355817B1 (en) | 2000-07-15 | 2002-03-12 | Exxonmobil Chemical Patents Inc. | Optimized catalyst addition to enhance esterification catalyst performance |
US20050274065A1 (en) * | 2004-06-15 | 2005-12-15 | Carnegie Mellon University | Methods for producing biodiesel |
JP2009513771A (en) * | 2005-10-26 | 2009-04-02 | サンパイン・アクチボラゲット | Automotive fuel and fine chemicals obtained from crude tall oil |
JP5154015B2 (en) | 2005-12-20 | 2013-02-27 | 花王株式会社 | Process for producing fatty acid alkyl ester and glycerin |
US7550614B2 (en) | 2006-11-13 | 2009-06-23 | Rohm And Haas Company | Method for esterification of free fatty acids in triglycerides |
JP2008231345A (en) * | 2007-03-23 | 2008-10-02 | Bio Energies Japan Kk | Method for producing biodiesel fuel |
US8070836B2 (en) | 2007-10-16 | 2011-12-06 | Wayne State University | Combined homogeneous and heterogeneous catalytic transesterification process for biodiesel production |
DE102007052065A1 (en) | 2007-10-30 | 2009-05-07 | Bayer Technology Services Gmbh | Continuous process for heterogeneously catalyzed esterification of fatty acids |
BRPI0818795A8 (en) | 2007-10-30 | 2016-04-26 | Bayer Technology Services Gmbh | PROCESS FOR THE HETEROGENICLY CATALYZED ESTERIFICATION OF FATTY ACIDS |
DE102009031054A1 (en) * | 2009-06-30 | 2011-01-13 | Clariant International Ltd. | Continuous process for the preparation of esters of aromatic carboxylic acids |
DE102009031053A1 (en) * | 2009-06-30 | 2011-01-13 | Clariant International Ltd. | Continuous process for the preparation of esters of aliphatic carboxylic acids |
US20110054200A1 (en) | 2009-09-01 | 2011-03-03 | Catilin, Inc. | Systems and Processes for Biodiesel Production |
WO2011033346A1 (en) | 2009-09-15 | 2011-03-24 | Council Of Scientific & Industrial Research | A process for conversion of low cost and high ffa oils to biodiesel |
-
2014
- 2014-03-11 US US14/203,885 patent/US8957242B2/en active Active
- 2014-03-12 EP EP14770799.6A patent/EP2880112A4/en not_active Withdrawn
- 2014-03-12 AU AU2014235751A patent/AU2014235751B2/en active Active
- 2014-03-12 KR KR1020147035947A patent/KR20150013877A/en not_active Application Discontinuation
- 2014-03-12 SG SG11201408134RA patent/SG11201408134RA/en unknown
- 2014-03-12 WO PCT/US2014/023950 patent/WO2014150678A1/en active Application Filing
- 2014-03-12 MY MYPI2015002378A patent/MY171548A/en unknown
- 2014-03-12 BR BR112015023555-7A patent/BR112015023555B1/en active IP Right Grant
- 2014-03-12 CA CA2877832A patent/CA2877832C/en active Active
- 2014-03-12 JP JP2015524517A patent/JP2015527335A/en active Pending
- 2014-03-13 UY UY0001035404A patent/UY35404A/en not_active Application Discontinuation
-
2015
- 2015-02-16 US US14/623,026 patent/US20150158806A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
BR112015023555A2 (en) | 2020-03-10 |
JP2015527335A (en) | 2015-09-17 |
US20140275612A1 (en) | 2014-09-18 |
EP2880112A4 (en) | 2016-05-18 |
CA2877832C (en) | 2016-02-02 |
US20150158806A1 (en) | 2015-06-11 |
AU2014235751B2 (en) | 2015-10-15 |
UY35404A (en) | 2014-10-31 |
MY171548A (en) | 2019-10-17 |
CA2877832A1 (en) | 2014-09-25 |
EP2880112A1 (en) | 2015-06-10 |
AU2014235751A1 (en) | 2015-01-22 |
WO2014150678A1 (en) | 2014-09-25 |
KR20150013877A (en) | 2015-02-05 |
BR112015023555B1 (en) | 2022-05-17 |
US8957242B2 (en) | 2015-02-17 |
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