SE7611274L - PROCEDURE TO REMOVE GAS SULFUR FROM GAS - Google Patents

PROCEDURE TO REMOVE GAS SULFUR FROM GAS

Info

Publication number
SE7611274L
SE7611274L SE7611274A SE7611274A SE7611274L SE 7611274 L SE7611274 L SE 7611274L SE 7611274 A SE7611274 A SE 7611274A SE 7611274 A SE7611274 A SE 7611274A SE 7611274 L SE7611274 L SE 7611274L
Authority
SE
Sweden
Prior art keywords
gas
stage
hydrogen sulfide
solution
carbon dioxide
Prior art date
Application number
SE7611274A
Other languages
Unknown language ( )
Swedish (sv)
Other versions
SE424815B (en
Inventor
K F Butwell
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/723,161 external-priority patent/US4093701A/en
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of SE7611274L publication Critical patent/SE7611274L/en
Publication of SE424815B publication Critical patent/SE424815B/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493Selection of liquid materials for use as absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1468Removing hydrogen sulfide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Industrial Gases (AREA)

Abstract

PROCESS FOR ACID GAS REMOVAL A continuous process for the selective absorption of hydrogen sulfide from a feed gas comprising an acid gas mixture of carbon dioxide and hydrogen sulfide is provided which comprises counter-currently contacting the feed gas with an aqueous alkanolamine solution in an absorption zone having from two to ten separate stages, contacting the feed gas in each stage with lean aqueous alkanolamine solution and withdrawing rich aqueous alkanolamine solution from the bottom of esch stage, in each stage maximizing the equilibrium approach between the hydrogen sulfide in the gas and liquid phases and minimizing the equilibrium approach between the carbon dioxide in the gas and liquid phases, and maintaining the rich solution loading in each stage within the range from about O.l to about 0.3 mole of acid gas per mole of alkanolamine. The absorption zone is operated in combination with a stripping zone to which rich aqueous alkanolamine solution is passed and in which lean solution is generated. The particular multi-stagP ~bsorption process of the invention allows for the recovery as stripping zone overhead of gaseous product in which the combined molar ratio of carbon dioxide to hydrogen sulfide is no greater than about 6. S P E C I F I C A T I O N
SE7611274A 1975-10-30 1976-10-11 PROCEDURE FOR CONTINUOUS SELECTIVE ABSORPTION OF SULFURS FROM A GAS MATERIAL SE424815B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US62721175A 1975-10-30 1975-10-30
US05/723,161 US4093701A (en) 1975-10-30 1976-09-17 Process for acid gas removal

Publications (2)

Publication Number Publication Date
SE7611274L true SE7611274L (en) 1977-05-01
SE424815B SE424815B (en) 1982-08-16

Family

ID=27090369

Family Applications (1)

Application Number Title Priority Date Filing Date
SE7611274A SE424815B (en) 1975-10-30 1976-10-11 PROCEDURE FOR CONTINUOUS SELECTIVE ABSORPTION OF SULFURS FROM A GAS MATERIAL

Country Status (25)

Country Link
JP (1) JPS5254680A (en)
AR (1) AR208638A1 (en)
AT (1) AT366929B (en)
BR (1) BR7607246A (en)
CA (1) CA1074534A (en)
CS (1) CS199650B2 (en)
DD (1) DD130570A5 (en)
DE (1) DE2649719C2 (en)
DK (1) DK490776A (en)
ES (1) ES452862A1 (en)
FI (1) FI763095A (en)
FR (1) FR2329328A1 (en)
GB (1) GB1561492A (en)
GR (1) GR63150B (en)
IN (1) IN146105B (en)
IT (1) IT1070933B (en)
MX (1) MX145154A (en)
MY (1) MY8100134A (en)
NL (1) NL186435C (en)
NO (1) NO763710L (en)
PH (1) PH14111A (en)
PT (1) PT65778B (en)
RO (1) RO72255A (en)
SE (1) SE424815B (en)
TR (1) TR19515A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53108880A (en) * 1977-03-05 1978-09-22 Idemitsu Kosan Co Ltd Washing method for gas with amine process
NL190316C (en) * 1978-03-22 1994-01-17 Shell Int Research METHOD FOR REMOVING ACID GASES FROM A GAS MIX
FR2439613A1 (en) * 1978-10-27 1980-05-23 Elf Aquitaine PROCESS FOR THE SELECTIVE EXTRACTION OF H2S FROM GAS MIXTURES CONTAINING CO2
US6395137B1 (en) * 1997-10-22 2002-05-28 Valmet Corporation Seal construction for a suction box in a suction roll in a paper/board machine
JP6117027B2 (en) 2013-07-04 2017-04-19 株式会社神戸製鋼所 Absorption method and apparatus using fine flow path
US9962644B2 (en) * 2015-12-28 2018-05-08 Exxonmobil Research And Engineering Company Process for increased selectivity and capacity for hydrogen sulfide capture from acid gases

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3563695A (en) * 1968-03-22 1971-02-16 Field And Epes Separation of co2 and h2s from gas mixtures
DE1903065A1 (en) * 1969-01-22 1970-08-27 Basf Ag Process for removing carbon dioxide from gas mixtures
NL168548C (en) * 1970-07-15 1982-04-16 Shell Int Research PROCESS FOR THE SELECTIVE REMOVAL OF HYDROGEN SULFUR FROM GASES CONTAINING SULFUR HYDROGEN AND CARBON DIOXIDE.
US4085192A (en) * 1973-05-11 1978-04-18 Shell Oil Company Selective removal of hydrogen sulfide from gaseous mixtures

Also Published As

Publication number Publication date
NO763710L (en) 1977-05-03
SE424815B (en) 1982-08-16
PT65778B (en) 1978-04-27
RO72255A (en) 1982-05-10
NL186435C (en) 1990-12-03
CS199650B2 (en) 1980-07-31
FR2329328B1 (en) 1980-06-13
AT366929B (en) 1982-05-25
MX145154A (en) 1982-01-12
JPS5254680A (en) 1977-05-04
NL7612016A (en) 1977-05-03
AR208638A1 (en) 1977-02-15
FR2329328A1 (en) 1977-05-27
GB1561492A (en) 1980-02-20
PT65778A (en) 1976-11-01
FI763095A (en) 1977-05-01
DD130570A5 (en) 1978-04-12
IT1070933B (en) 1985-04-02
TR19515A (en) 1979-06-27
CA1074534A (en) 1980-04-01
NL186435B (en) 1990-07-02
MY8100134A (en) 1981-12-31
PH14111A (en) 1981-02-26
DK490776A (en) 1977-05-01
JPS6111658B2 (en) 1986-04-04
BR7607246A (en) 1977-09-13
GR63150B (en) 1979-09-25
ES452862A1 (en) 1978-03-16
ATA805476A (en) 1981-10-15
DE2649719C2 (en) 1985-01-10
IN146105B (en) 1979-02-24
DE2649719A1 (en) 1977-05-12

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