SE545216C2 - Method for increasing the starch content in potato - Google Patents

Method for increasing the starch content in potato

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Publication number
SE545216C2
SE545216C2 SE1930398A SE1930398A SE545216C2 SE 545216 C2 SE545216 C2 SE 545216C2 SE 1930398 A SE1930398 A SE 1930398A SE 1930398 A SE1930398 A SE 1930398A SE 545216 C2 SE545216 C2 SE 545216C2
Authority
SE
Sweden
Prior art keywords
potato
potassium
starch
solution
crops
Prior art date
Application number
SE1930398A
Other languages
Swedish (sv)
Other versions
SE1930398A1 (en
Inventor
Hugo Hjelm
Martina Håkansson
Slawomir Michalek
Original Assignee
Perstorp Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Perstorp Ab filed Critical Perstorp Ab
Priority to SE1930398A priority Critical patent/SE545216C2/en
Priority to PCT/SE2020/051085 priority patent/WO2021118426A1/en
Publication of SE1930398A1 publication Critical patent/SE1930398A1/en
Publication of SE545216C2 publication Critical patent/SE545216C2/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D1/00Fertilisers containing potassium
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C23/00Distributing devices specially adapted for liquid manure or other fertilising liquid, including ammonia, e.g. transport tanks or sprinkling wagons
    • A01C23/04Distributing under pressure; Distributing mud; Adaptation of watering systems for fertilising-liquids
    • A01C23/047Spraying of liquid fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C9/00Fertilisers containing urea or urea compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/02Formic acid
    • C07C53/06Salts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G22/00Cultivation of specific crops or plants not otherwise provided for
    • A01G22/25Root crops, e.g. potatoes, yams, beet or wasabi
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M7/00Special adaptations or arrangements of liquid-spraying apparatus for purposes covered by this subclass
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M7/00Special adaptations or arrangements of liquid-spraying apparatus for purposes covered by this subclass
    • A01M7/0025Mechanical sprayers
    • A01M7/0032Pressure sprayers
    • A01M7/0042Field sprayers, e.g. self-propelled, drawn or tractor-mounted
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • C05G5/23Solutions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Soil Sciences (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)
  • Preparation Of Fruits And Vegetables (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

The present invention refers to a method for increasing the starch content in agricultural crops, said method comprising the step of applying a solution comprising 0.2 - 4.0 % by weight of potassium formate to said crops, wherein said solution is applied to said crops by foliar application.

Description

The present invention refers to a method for increasing the starch content in potato, said method comprising the step of applying an aqueous solution comprising 0-2-4-.0 0.8 -2.2 % by weight of potassium formate to said crops, wherein said solution is applied to said crops by foliar application.
BACKGROUND OF THE INVENTION Starch provides almost three-quarters of the nutritional energy consumed by mankind. It is also widely used in phannaceuticals, textiles, the paper industry, drilling fluids, biodegradable plastics and gypsum binders.
Starch is extracted from a wide range of agricultural crops. These include maize, wheat, potato and cassava (also known as manioc in some regions) and to a lesser extent from rice, barley and sorghum. Colder climates favor potato growing and cassava is cultivated in the tropics, while grain varieties are grown all over the world.
Potato starch is extracted from the tubers of Solanum tuberosum, which was first cultivated around ad 200 in Peru. Potato starch is mainly produced in Europe. Many types of potatoes are grown; for the production of potato starch, potato varieties with high starch content and high starch yields are selected. The cultivation of potatoes for starch mainly takes place in Germany, the Netherlands, China, Japan, France, Denmark, and Poland, but also in Sweden, Finland, Austria, the Czech Republic, Ukraine, Canada, and India. Starch is typically isolated from cull potatoes, surplus potatoes, and waste streams from potato processing. However, there are special cultivars developed for starch manufacture. These starch cultivars contain roughly about % per weight of starch.
The cells of the root tubers of the potato plant contain starch grains (leucoplasts). To extract the starch, the potatoes are crushed and the starch grains are released from the destroyed cells. The starch is then washed out and dried to powder.
Marked amendments Potato starch is a very refined starch, containing minimal protein and fat. This gives the powder a clear white colour, and the cooked starch typical characteristics of neutral taste, good clarity, high binding strength, long texture and a minimal tendency to foaming or yellowing of the solution. Potato starch contains approximately 800 ppm phosphate bound to the starch; this increases the viscosity and gives the solution a slightly anionic character, a low gelatinisation temperature of approximately 60 °C, and high swelling power. These typical properties are used in food and technical applications.
With a growing population in the world, the demand of agricultural crops and the products manufactured therefrom, such as starch, is expected to increase in the future. Therefore it is desirable to increase the efficiency of starch production by developing a method for increasing the starch content of agricultural crops.
Fertilizers are commonly used for growing all crops, with application rates depending on the soil fertility, usually as measured by a soil test and according to the need of the particular crop. Many sources of fertilizers exist, both natural and industrially produced. Fertilizers in general provide (in varying proportions) three macronutrients; nitrogen, phosphorous and potassium, three secondary nutrients; calcium, magnesium and sulfur and micronutrients like copper, iron, molybdenum, zinc and boron.
Fertilizers are classified in several ways, they are classified according to whether they provide a single nutrient or if they provide two or more nutrients (multinutrient fertilizers). A very common type of multinutrient fertilizers are the NPK fertilizers, providing a mixture of the macronutrients nitrogen, phosphorous and potassium. There are also organic fertilizers, which are usually recycled plant- or animal-derived matter.
Potassium is one of the major nutrients required by all crops and is present in large quantities in the plant in the form of the cation K+. Potassium is considered second only to nitrogen, when it comes to nutrients needed by plants and it affects the plant shape, size, color, taste and other measurements attributed to healthy produce. Potassium increases crop yield and improves quality. It is required for numerous plant growth processes, as potassium is fundamental to many Marked amendments metabolic processes through the activation of a large number of enzymes required for chemical reactions in plants. The potassium changes the physical shape of the enzyme molecule, exposing the appropriate chemical active sites for reaction. Potassium also neutralizes various organic anions and other compounds within the plant, helping to stabilize the pH-value between 7 and 8, which is an optimum for most enzyme reactions.
The majority of the plant"s total potassium requirement is needed for the essential role of maintaining the water content of plant cells. Plants depend upon potassium to regulate the opening and closing of stomata, the pores through which leaves exchange carbon dioxide, water vapor and oxygen with the atmosphere. Proper functioning of stomata are essential for photosynthesis, water and nutrient transport, and plant cooling. If potassium supply is inadequate, the stomata become sluggish - slow to respond - and water vapor is lost. As a result, plants with an insufficient supply of potassium are much more susceptible to water stress.
Potassium has a complex role in photosynthesis, the critical process for plants to convert energy from the sun into chemical energy, in the form of sugars, required for growth and ultimately yield. These sugars contain carbon derived from carbon dioxide from the atmosphere that enters the plant through the stomata. So, the role of potassium in the regulation of stomatal opening is also important for efficient photosynthesis by controlling the movement of carbon dioxide into the leaves. Potassium also has an impact on the production of ATP (adenosine triphosphate), which is the plant"s initial high-energy product from the photosynthesis. When plants are deficient in potassium the rate of photosynthesis is reduced and hence the rate of ATP production is also reduced, slowing down all the processes dependent on ATP in the plant.
Potassium is also important for the transport of sugars, water and nutrients in the plant, for helping plants to resist lodging, for plant disease and pest resistance and for the plant's frost tolerance. Potassium is required for every major step in protein synthesis. Where potassium levels in the plant are low, protein synthesis can be reduced despite an abundance of available nitrogen.
The enzyme responsible for synthesis of starch (starch synthetase) is activated by potassium. Thus, with inadequate potassium, the level of starch declines while soluble carbohydrates and nitrogen compounds accumulate. Photosynthetic activity also affects the rate of sugar formation Marked amendments for ultimate starch production. Under high potassium levels, starch is efficiently moved from sites of production to storage organs.
Field crops normally absorb the majority of nutrients from the soil through root absorption, but above ground plant Structures, especially leaves, are capable of absorbing limited amounts of some nutrients. Because of this, most supplemental nutrients supplied to crops as fertilizer are applied to the soil, and soluble nutrients in the soil contact root hair surfaces, where they are absorbed into the roots and transferred to other parts of the growing plant for metabolic use.
However, leaves and also to a lesser degree stems, and flowering plant tissues, can absorb limited amounts of nutrients. Foliar fertilization is the application of foliar sprays of one or more mineral nutrients to plants to supplement traditional soil applications of fertilizers. The fertilizer is sprayed directly onto the leaves of the plant and the plant absorbs essential elements through their leaves. Foliar feeding of a plant does not replace traditional soil fertilization, it rather complements traditional fertilization.
If only very small amounts of a micronutrient are required by a crop, foliar application may be more effective than traditional soil application. Also, if it is noted that a crop suffers from a deficiency of a particular nutrient, foliar application is a fast and effective Way to try to treat that particular deficiency.
The present invention has revealed a new situation where a small foliar application of potassium formate quite unexpectedly gives an increase in the starch content of agricultural crops, despite the fact that soil fertilization, including enough potassium according to recommendations, has already been applied.
Marked amendments DETAILED DESCRIPTION OF THE INVENTION With a constantly growing population in the world, we need to improve at all stages of the value chain for food production around the world. A more sustainable and yet more efficient agriculture is one part of this complex picture. One way to accomplish this is to develop methods for how to increase the content of specific nutrients in crops.
The present invention refers to a method for increasing the starch content in potato crop, said method comprising the step of applying a solution comprising 0.8 - 2.2 % by weight, of potassium formate to said crops, wherein said solution is applied to said crops by foliar application. Comprehensive field trials have revealed that a relatively small addition of potassium, in the form of potassium formate and applied by foliar application, gives both a higher content of starch and a higher yield in different cultivars of potato.
The BBCH-scale is used to identify the phenological development stages of plants. BBCH-scales have been developed for a range of crop species where similar growth stages of each plant are given the same code. The BBCH-scale for potato thus identifies the phenological growth stages of a potato (Solanum tuberosum). The scale starts with stage O, which is sprouting/germination, continues with stage 1: leaf development, stage 2: formation of basal side shoots below and above soil surface (main stem), stage 3: main stem elongation (crop cover), stage 4: tuber formation, stage 5: inflorescence (cyme) emergence, stage 6: flowering, stage 7: development of fruit, stage 8: ripening of fruit and seed and finally stage 9: senescence. The first digit of the scale refers to the principal growth stage and the second digit refers to the secondary growth stage. In the context of the present invention, phenological growth stages are equal to phenological development stages according to the BBCH-scale for potato.
Marked amendments According to one embodiment of the present invention, the solution comprising potassium forrnate is applied to the potato crops during phenological growth stages 1-4. According to a preferred embodiment of the present invention, said solution is applied to said potato crops during phenological growth stages 21- During the work leading to the present invention, foliar application of potassium in three different forms has been tested, besides potassium fonnate both potassium nitrate and potassium chloride were tested and evaluated (see Embodíment Example I). These tests clearly show that it is specifically the foliar application of potassium fonnate that gives the increased starch content in the potato crops. The other two forrns of potassium give varying results, sometimes performing worse than the control sample.
The solution applied by foliar application to the crops may in addition to potassium fonnate comprise other substances that are beneficial for the growth and development of the crop. Such substances can for example be urea, phosphorus, magnesium, calcium, manganese and/or zinc.
The foliar application of the potassium forrnate solution is preferably performed with a field crop sprayer and at an application rate of 50 - 500 liters/ha (1 ha = 10 000 m2).
The solution comprising potassium forrnate is applied to the crops at one single occasion or at several occasions, preferably at 1-3 separate occasions and with at least three days between each occasion.
The present invention is illustrated in the below Embodíment Examples, which are to be construed as merely illustrative and not limiting in any way.
Marked amendments EMBODIMENT EXAMPLES List of examples, tables and figures illustrating the invention; -Example 1: Effect of foliar application of different forms of potassium on starch concentration and fresh tuber yield in two different potato cultivars -Example 2: Effect of foliar application with potassium formate on starch concentration and fresh tuber yield in 12 different potato cultivars -Table 1. Chemical plant protection agents against Weeds and Colorado beetle applied.
-Figure 1 a - d: Starch content in potato cultivars Jelly and Bellarosa, potassium supplied in three different forms, growing seasons 2017 and -Figure 2 a - d: Fresh tuber yield in potato cultivars Jelly and Bellarosa, potassium supplied in three different forms, growing seasons 2017 and -Figure 3. Starch content in 12 different potato cultivars, treated according to the method of the present invention vs. control plants.
-Figure 4. Fresh tuber yield in 12 different potato cultivars, treated according to the method of the present invention vs. control plants.
Example 1: Effect of foliar application of different forms of potassium on starch concentration and fresh tuber víeld in two different potato cultivars Field experiments were conducted at three fields in the Lublin area in Poland during two separate growing seasons (2017 and 2018). Two different potato cultivars, Jelly and Bellarosa, were used. The tubers were planted with a row space of 63 cm and with 48 000 plants per hectare. The plot area was 15 m2 and with four replicates for each treatment. The sizes of the seed tubers were between 30-40 mm. The in-row seed spacing was 30 cm. The experimental field was ploughed in autumn and tilted two times before planting in spring. Mineral fertilizers - ammonium nitrate (N), and Polifoska® (N, P, K) were spread in spring prior to potato planting and were incorporated into the soil by a harrow. The total amount of fertilizer applied to all fields was 196 kg N, 63 kg P, 168 kg K, 30 kg Mg and 47 kg S per hectare.Marked amendments Three different forms of potassium were applied at a concentration of 1% by weight, by foliar application: potassium nitrate (KNOg), potassium chloride (KCI) and potassium fonnate (PoF o). Both potato cultivars were treated at the same time, using 250 liters/ha (250 liters for 10 000 m2) of liquid spray (readymade solution). All treatments were sprayed three times. At spraying the later cultivar (Jelly) was on stage II (vegetative growth) and the early cultivar (Bellarosa) was on stage III (tuber initiation). Control fields were sprayed with only water. The pH value of the water used for spraying and preparing solution Was 6.8-7.2. The application Was done using a 5- liter sprayer . The temperature of the solution was below 20°C and it was applied after sunset.
Chemical plant protection agents against weeds and Colorado beetle were applied according to Table I below.
Treatment Product Active ingredient Producer Dose Herbicides Arcade 880 EC Prosulfocarb 800 g Syngenta Poland 4.0 l/ha + Metribuzin g/kg Fusilade Forte 150 Fluazifop-p-butyl Syngenta 2.0 l/ha EC 150 g/l Insecticides Decis Mega SOEW Deltamethrin 50 g/l Bayer SAS France 0.5 l/ha Nurelle D 550 EC Chloropiryphos 500 Dow AgroSciences 0.6 l/ha g/l + cyperrnethrine 50 g/l Table I. Measurements When all plants reached physiological maturity the total yield of potato tubers and the content of starch in the potato tubers were determined. Starch content was determined by the gravimetric method proposed by Reimann and Parow from 10 randomly selected plants in each plot. The method according to Reimann and Parow was used among others in research of Taulbert and Smith (1975), Affleck et al. (2012), Brazinskiene et al. (2014), Pszcólkowski et al. (2014) and described by Intemational Starch Institute in Denmark. Total fresh tuber yield was recorded for each treatment in all the replications and data was presented as ton per hectare.
Marked amendments BQLILL The starch content in the two different potato cultivars (Jelly and Bellarosa), with potassium supplied in different forms, are shown in Figure 1 a - d -below (data from growing seasons 2017 and 20 1 8): Starch content (%) Jelly, 2017 Starch content (%) Jelly,14,13,12,5 13/511,5 12,Control Control KNOSïaffih C0f1ï@nï(%) BGHHFOSH, 2017 Starch content (%) Bellarosa,12,8 12,6 12,4 12,12 11,8 11,6 11,4 11,COHUO! Control KNOMarked amendments The Fresh tuber yield in the two different potato cultivars (Jelly and Bellarosa) with potassium supplied in different forms, are shown in Figure 2 a - d below (data from growing seasons 2017 and 2018): Fresh tuber yield (t/ha), JellyFresh tuber yield (t/ha), JellyControl Control KNOFre-Sh ïUbef Yield (ï/hê), BGHGTOSH 2017 Fresh tuber yield (t/ha), Bellarosa41 37 39 3535 33 33 31 31 2927 I 27 25Control Control pl Ål ~/ w/ Marked amendments Example 2: Effect of foliar application with potassium formate on starch concentratíon and fresh tuber víeld ín 12 different potato cultivars Field experiments Were conducted in the same way as described in Experiment 1, but with potassium foimate (1% by Weight) as the only treatment tested. 12 different potato cultivars were tested and the tests Were conducted during the growing season 2018, in the Lublin area in Poland. Five of the cultivars were special cultivars developed for starch manufacture. Controls Were sprayed with only water.
Results The starch content in 12 different potato cultivars from growing season 2018 are shown in Figure 3 below: Starch content (%) different cultivars 26 24 22 18 16 14Control I PoFoMarked amendments The fresh tuber yield in 12 different potato cultivars from growing season 2018 are shown in Figure 4 below: Fresh tuber yield (t/ha), 12 different potato cultivars It is clear from Example 1 that it is the specific application of potassium formate that gives an increased starch content in the crops. For the potato cultivar Jelly, the starch content is on average more than 1 percent point higher where potassium formate is applied, compared to both the control and to the cases Where potassium is applied in other forms. lt can also be seen in Example 1 that the fresh tuber yield is highest where potassium fonnate has been applied (both potato cultivars, both seasons). Addition of potassium in all three forms (KNOg, KCl and PoFo) gives an increase in fresh tuber yield. However, it is only the specific application of potassium formate that gives an increased starch content compared to the control in all cases.Marked amendments In Example 2, the method of the present invention is tested on a Wide range of potato cultivars, both starch cultivars and potato for consumption. In all cases does the method according to the present invention give an increase both in starch content and in fresh tuber yield, compared to the control.
An increase in starch content of about 1 percent point may sound like a modest increase. However, if the actual increase in starch/ha, considering both the increase in starch content and the increase in fresh tuber yield is calculated, it becomes apparent that the gain for the individual potato fanner can become considerable.
For example, by applying the method according to the present invention, the average starch increase (calculated for the five starch cultivars in Example 2) is about 960 kg extra starch/ha, or an increase of 11.4 % in starch content, compared to the control. For an individual farrner, growing starch potato on 20 ha land, this will mean an increased yield of about 19.2 tons of starch/harvest. This implies that the method according to the present invention has a great potential of contributing to a more efficient starch production in the future. 13

Claims (2)

1.A method for increasing the starch content in potato crop, said method comprising the step of applying a solution comprising 0.8 -
2.2 % by weight of potassium fonnate to said crops, wherein said solution is applied to said crops by foliar application. The method according to claim 1 characterized in , that said solution is applied to said potato crops during phenological growth stages 1- The method according to claim 2 characterized in, that said solution is applied to said potato crops during phenological growth stages 21- The method according to any of the claims 1 - 3 characterized in that, said solution is applied to said potato crops at an application rate of 50-500 liters/ha. The method according to any of the claims l - 4 characterized in, that said solution is applied to said potato crops with a field crop sprayer. The method according to any of the claims 1 - 5 characterized in, that said solution is applied to said potato crops at 1-3 separate occasions and that there is at least three days between each occasion. The method according to any of the claims 1 - 6 characterized in, that said solution comprises at least one additional substance, wherein said additional substance is selected from the group consisting of urea, phosphorous, magnesium, calcium, manganese and/or zinc. ll
SE1930398A 2019-12-11 2019-12-11 Method for increasing the starch content in potato SE545216C2 (en)

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SE1930398A SE545216C2 (en) 2019-12-11 2019-12-11 Method for increasing the starch content in potato
PCT/SE2020/051085 WO2021118426A1 (en) 2019-12-11 2020-11-12 Method for increasing the starch content in agricultural crops

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SE545216C2 true SE545216C2 (en) 2023-05-30

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CN103875409A (en) * 2014-03-20 2014-06-25 长沙环境保护职业技术学院 Potato fertility improving method for carrying out straw field changing and returning on newly-prepared farmland
EP2896286A1 (en) * 2013-12-16 2015-07-22 Associazione Marsicana Produttori Patate Societa Cooperativa Agricola Method for increasing the content of useful components in edible plants
CN105837330A (en) * 2016-04-05 2016-08-10 宁夏共享生物化工有限公司 Humic acid-containing water-soluble fertilizer specially used for melons and fruits, and preparation method thereof
WO2017040938A1 (en) * 2015-09-03 2017-03-09 Nachurs Alpine Solutions, Corp. Fertilizer with organic potassium salts
CN108101669A (en) * 2018-02-08 2018-06-01 王连祥 A kind of enhancing stress resistance of plant multielement organic water-soluble fertilizer and preparation method thereof
CN110483208A (en) * 2019-08-08 2019-11-22 陕西海德尔生物科技有限责任公司 A kind of organic water-soluble chitosan multi-Functional Fertilizers

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EP3222584A1 (en) * 2016-03-21 2017-09-27 Tessenderlo Chemie NV Method for producing soluble potassium sulfate
CN108997043A (en) * 2018-08-16 2018-12-14 什邡市长丰化工有限公司 One kind is containing humic acid water-soluble fertilizer and preparation method thereof
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4507142A (en) * 1982-12-30 1985-03-26 Arcadian Corporation, Inc. Alpha-oximino alkanoic acid containing foliar fertilizers to increase yield of crop plants
EP2896286A1 (en) * 2013-12-16 2015-07-22 Associazione Marsicana Produttori Patate Societa Cooperativa Agricola Method for increasing the content of useful components in edible plants
CN103875409A (en) * 2014-03-20 2014-06-25 长沙环境保护职业技术学院 Potato fertility improving method for carrying out straw field changing and returning on newly-prepared farmland
WO2017040938A1 (en) * 2015-09-03 2017-03-09 Nachurs Alpine Solutions, Corp. Fertilizer with organic potassium salts
CN105837330A (en) * 2016-04-05 2016-08-10 宁夏共享生物化工有限公司 Humic acid-containing water-soluble fertilizer specially used for melons and fruits, and preparation method thereof
CN108101669A (en) * 2018-02-08 2018-06-01 王连祥 A kind of enhancing stress resistance of plant multielement organic water-soluble fertilizer and preparation method thereof
CN110483208A (en) * 2019-08-08 2019-11-22 陕西海德尔生物科技有限责任公司 A kind of organic water-soluble chitosan multi-Functional Fertilizers

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