SE527884C2 - Process for liquid expulsion from suspensions - Google Patents

Process for liquid expulsion from suspensions

Info

Publication number
SE527884C2
SE527884C2 SE0401234A SE0401234A SE527884C2 SE 527884 C2 SE527884 C2 SE 527884C2 SE 0401234 A SE0401234 A SE 0401234A SE 0401234 A SE0401234 A SE 0401234A SE 527884 C2 SE527884 C2 SE 527884C2
Authority
SE
Sweden
Prior art keywords
substance
dewatering
particulate form
process according
weight
Prior art date
Application number
SE0401234A
Other languages
Swedish (sv)
Other versions
SE0401234L (en
SE0401234D0 (en
Inventor
Arne Lindahl
Original Assignee
Arne Lindahl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arne Lindahl filed Critical Arne Lindahl
Priority to SE0401234A priority Critical patent/SE527884C2/en
Publication of SE0401234D0 publication Critical patent/SE0401234D0/en
Priority to JP2007513103A priority patent/JP2007536084A/en
Priority to CNA2005800185276A priority patent/CN1980865A/en
Priority to PCT/SE2005/000667 priority patent/WO2005108314A1/en
Priority to RU2006142558/15A priority patent/RU2006142558A/en
Publication of SE0401234L publication Critical patent/SE0401234L/en
Publication of SE527884C2 publication Critical patent/SE527884C2/en

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/18De-watering; Elimination of cooking or pulp-treating liquors from the pulp
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • C02F11/147Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using organic substances

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Treatment Of Sludge (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

This invention relates to a procedure concerning dewatering of suspensions, in particular, suspensions with a relatively low concentration of organic matter or having a dry solid content of less than 15 %. A distinguishing feature of this invention is that dewatering promoting agents are mixed simultaneously with the suspension as thickening occurs. Examples of materials that increases the concentration of organic matter are among others sawdust, synthetic materials that preferably consist of pulverous polyurethane, ground peat or alternatively ground bark. The weight proportion of the additives amounts to at least 5 weight­% and preferably to at least 10 weight-% of the total weight of the organic matter. The simultaneous dewatering and mixing is performed with the aid of known dewatering mechanisms. An example of this is the water extracting screw. After the partial dewatering the material is transferred to a press for further dewatering to solid contents above 45 %.

Description

527 884 Z En nackdel med manga apparater ar, att de utsätter materialet fiir krafiig kompression. *Om kan skada materialet, och delar av själva maskinutrusmingen. 527 884 Z A disadvantage of many devices is that they expose the material to excessive compression. * If can damage the material, and parts of the machine equipment itself.

Vad beträffar utrustningen skadas bla. viror och pressfiltar av för höga mekaniska tryck.As far as the equipment is concerned, among other things. wires and presses result from excessive mechanical pressures.

Förslitningen ökar och viran eller filten kan till och med gi av. Pressvalsama kan också ta skada. Dessutom erfordras det mera energi för varje höjning av arbetstrycket. Sekundlrt får en högre eriergitörbmkning negativ effekt på den yttre miljon eftersom det vanligtvis fordras insats av elektrisk energi, som i sin tur genereras genom fitrbranning av bl.a. fossila bränslen, vilka bl.a. alstrar koldioxid.Wear increases and the wire or fi lten can even give off. The press rollers can also be damaged. In addition, more energy is required for each increase in working pressure. Secondly, a higher energy output has a negative effect on the external million because it usually requires the input of electrical energy, which in turn is generated by burning, among other things. fossil fuels, which i.a. generates carbon dioxide.

Vidtörtjocknmgwslamfiinmmngwerkicenuifixgârdetwånstttömmammaterida orn torrsubstanshalten överstiger cirka 25 % (sällsynt). En annan nackdel med centrifuger ar deras relativt låga kapacitet i fiirening med hög investuingskostnad.Vidtörtjicknmgwslam fi inmmngwerkicenui fi xgârdetwånstttömmammaterida or the dry matter content exceeds about 25% (rare). Another disadvantage of centrifuges is their relatively low capacity in cleaning with high investment costs.

Skruvpressar ger relativt hoga torrsubstanshalter men har dock nackdelen av att vätskan, som pressas ut, innehåller mycket av det material som skall Rirtjockas. Detta berOI' P5 m WWW* harvåggarvilka arperforerademed relativt storahålellerslitsar.Screw presses give relatively high dry matter contents, but have the disadvantage that the liquid, which is pressed out, contains much of the material to be thickened. This is due to PW's WW5 * having walls which are relatively large or large slots.

Denvanligatypenavtrurnfiltergerenlitenfltrlustavmaterial. Med andraordarfiltratet relativt rent En väsentlig nackdel med trumfiltren ar emellertid den låga torrsubstanshalt dessa ger. Även efter komplettering av filtret med pressvalsar uppnås inte särskilt hög tonsubstarrshalt.The usual type of spinner is a small spoon material. In other words, the filtrate is relatively pure. However, a significant disadvantage of the drums is the low dry matter content they give. Even after supplementing the filter with press rollers, a very high tonnage content is not achieved.

Beskrivning av uppfinningen I enlighet med uppfinningen blandas suspensionen, som ska avvattnas, med ett fast ämne (harefier benämnd tillsatsmedel) i partikelform Sådana tillsatsrnedel utgörs bla. av polymerer som exempelvis polyuretan med låg densitet eller med en volymdensitet som är väsentligt lagre an l kg/dm”. Polyuretan är uppbyggd av karbamidsyraestrar (generell formel RQCONH; ). Etylesterformen kallas vanligen uretan Sådan uretan kan återvinnas från uttjant isoleringsmaterial fiin exempelvis gamla nys-och kylskåp. Inßm ramen för uppfinningen kan vidare tillsattes regenererad cellulosa ”WETIEK-shntf), sågspån, stärkelse, strâvaxter' som exempelvis rörflen och halm Även torv, bark och finflàrdelade strâvaxter kan tillsattes. Enligt en föredragen utfitringsforrn av uppfinningen ska tillsatsmedlet, rivas eller malas till relativt små partiklar eventuellt före uppdelning medelst fraktionering (sâllning) ßr anrikning av tillsatsmedlets finmaterial..Description of the invention In accordance with the invention, the suspension to be dewatered is mixed with a solid (hereinafter referred to as an additive) in particulate form. of polymers such as low-density polyurethane or with a bulk density significantly lower than 1 kg / dm ”. Polyurethane is composed of uric acid esters (general formula RQCONH;). The ethyl ester form is usually called urethane. In addition, within the scope of the invention, regenerated cellulose (WETIEK-shntf), sawdust, starch, straw plants such as straw and straw can also be added. Peat, bark and finely divided straw plants can also be added. According to a preferred embodiment of the invention, the additive should be grated or ground into relatively small particles, possibly before partitioning by means of fractionation (sieving) or enrichment of the fine material of the additive.

Tillsatsrnedlets avsedda partikelstorlek erhålls säkrast genom sållning i ett eller flera steg.The intended particle size of the additive is most safely obtained by sieving in one or more steps.

Således kan anvandas kanda sallanordningar såsom skaksåll, vibrationssåll eller sk. vindsikt. oo 0 oo nano o o o oo n c o O I I u n o a u c :noe u o U o o o I 0 role o o nu non nous Oo o IQ I ul O lo I I OOIIO OI I 527 884 3 Viktsandelen tillsatsmedel kan variera inom ett stort intervall. Ur ekonomisk synpunkt fitredras emellertid lagsta möjliga andel tillsatsmedel. För att ß efiekt krävs emellertid en viktsandel av minst 5 % och företrädesvis mera an 10 vikts-%.Thus, kanda saddle devices such as shaking sieve, vibration sieve or so-called can be used. wind visibility. oo 0 oo nano o o o oo n c o O I I u n o a u c: noe u o U o o o o I 0 role o o nu non nous Oo o IQ I ul O lo I I OOIIO OI I 527 884 3 The weight percentage of additives can vary within a large range. From an economic point of view, however, the lowest possible proportion of additives is tripled. However, for ß e fi ekt, a weight percentage of at least 5% and preferably more than 10% by weight is required.

I vissa fall kan det vara fördelaktigt att efter törtjockningen tillvaka briketter, granuler eller pellets. Därvid kan anvandas den metod som bla beskrivs i patentsbifien SE 9904313-5.In some cases, it may be advantageous to add briquettes, granules or pellets after the thickening of the cake. The method described in, among other things, patent application SE 9904313-5 can be used.

En väsentlig och kánnetecknande del av uppfinningen är att inblandningen av ovan beskrivna tillsatser sker i ett irrtegrerat steg med samtidig ßrtjockning. Darvid avses fisrljockning av vätskor som har en relativt låg koncentration (torrhalt) av substans, tex. slam.An essential and characteristic part of the invention is that the mixing of the additives described above takes place in an integrated step with simultaneous thickening. This refers to fi liquefaction of liquids which have a relatively low concentration (dry content) of substance, e.g. sludge.

Således avses att förtjoeka suspensioner med koneentrationer av fast material som ligger mellan 0,5 % och 15 %.Thus, it is intended to increase suspensions with concentrations of solid material between 0.5% and 15%.

Kombinationen av momenten blandning och fllrtjockning kan utfliras med hjälp av kande maskiner. Således kan användas skruvurvattnare med kärna eller urvattnare utan kärna, som transporterar vatska och substans med hjalp av en spiral. I princip omges skruven eller spiralen av ett rör med öppningar på sin marttelyta. Mantelytans utsida eller insida kan vara bekladd med en vira av plast eller stål. Ytterligare alternativ utgör avvattnare med roterande paddlar eller pinnar ansluinatill en eentrumaxel. »_~. . *LLJJ lflll' :LSU ~_ Fiberslam i suspensionsform fiån ett pappersbntks bioreningssteg iördes till en skruvurvattnare vars mantelyta hade hål med diametern 0,2 mm. Därvid avñrdes vatten via mantelytanshål. Dettarestilteradeieniörtjoekningfrâningáendekonoentrationav 1,3 % till 12,6 %.The combination of blending and thickening steps can be performed using known machines. Thus, screw cores with a core or cores without a core can be used, which transport liquid and substance by means of a spiral. In principle, the screw or spiral is surrounded by a tube with openings on its mart surface. The outside or inside of the mantle surface can be covered with a plastic or steel wire. Additional alternatives are dewaterers with rotating paddles or sticks attached to a single-drum shaft. »_ ~. . * LLJJ l fl ll ': LSU ~ _ Fiber sludge in suspension form bio from a paper belt bio-purification stage was fed to a screw drain whose surface had holes with a diameter of 0.2 mm. Water was drained via the mantle surface holes. This results in an increase in concentration from 1.3% to 12.6%.

Filtratet, som rann ut genom skruvpressens hål, visade sig innehålla en icke önskad koncentration av torrslrbstans. Således innehöll filtratet 3 gem torrstibstans per liter vätska.The filtrate, which flowed out through the holes of the screw press, was found to contain an undesired concentration of dry slurry. Thus, the filtrate contained 3 g of dry powder per liter of liquid.

Det i skruvpressen Rårtjoekade fiberslammet fördes vidare till en press, som finns närmare beskriven i patentskrifien 0004557-2. Efter pressning erhölls en avvattning som resulterade i en torrhalt av 17,6 %. ri xem i Fiberslam i suspensionsform fiin ett pappersbmks bioreningssteg fördes, som vid exemplet iörtjockrxing enligtkándtelmkfill enskmvurvattnarevarsmantelytahadehalmeddiametern 0,2 mm. Vid inleppet av skruvurvattnaren tilliördes spin från ett sågverk 527 884 *i Sågspånet var en fialction av sållat sågspån. Det sñllade sågspånet hade en vilrtsandel av 64 % finfi-alrtion, som per definition passerade ett sáll med hålstorleken 2 mm. Sagspånet hade en tolrhalt av 43 %.The sludge in the screw press Rårtjoekade was passed on to a press, which is described in more detail in patent specification 0004557-2. After pressing, a dewatering was obtained which resulted in a dry content of 17.6%. In the form of a suspension in Fiberslam in suspension form, a bio-purification step was carried out, which in the example of thickening according to the known standard single-wave water had a mantle surface with a diameter of 0.2 mm. At the inlet of the screw waterer, spin from a sawmill 527 884 * was added in The sawdust was an ction alction of screened sawdust. The sieve sawdust had a wild share of 64% fi n al- alrtion, which by definition passed a sieve with a hole size of 2 mm. The sawdust had a customs content of 43%.

Vid fiirsolcet erhölls en överraskande bra blandning mellan spin och fiberslamsuspensionen. Ännu mera överraskande var den efiektiva iïntjockning inblandningen av sågspånet resulterade i. Således erhölls en torrhalt av 24 % på prover uttagna fiin skruvurvattnarens utlopp. Vrktsandelen sågspån i sfickprover uttagna under sex timmar visade sig ligga på ett medelvärde av 41 % och med en spridning av i 3 vikts-%. Dettabetyder, att under det initiala skedet inuti skruvurvattnaren var torrhalten temporärt ca 14 %. Med andra ord höjdes torrhalten från ca 14 % till 24 % beroende på avvattrringsefiekteir som sådan Enmmnposiüvefiektvaranfiltraasommmutfiánshuvwvatmarenvarövenaskmde rent. Denna observation bekrafiades av att filtratet vid analys visade sig innehalla endast 0,8 gram torrsubstans per liter vätska Det i slcruvpressen fibrtjockade fiberslammet fiårdes vidare till samma press, som användes vid uttöringsexemplet enligt kand teknik. Trots relativt hög torrhalt (24 %) in till pressen erhölls etteverraskandestortflöde avvattenfiánpressen Dessutomvarfilnatetidetnärrnaste hinfllklmgvikabehafladæavaufilnnetmdeenmbstmshahwmdastmugrmpahtm vatten. Beroende på det relativt goda vatskeflödet fián pressen erhölls en så hög torrhalt som 51,2 %.At fi irsolcet, a surprisingly good mixture was obtained between spin and fi berslam suspension. Even more surprising was the effective thickening the mixture of sawdust resulted in. Thus, a dry matter content of 24% was obtained on samples taken from the outlet of the screw drain. The weight content of sawdust in sack samples taken during six hours was found to be at an average value of 41% and with a spread of 3% by weight. This means that during the initial stage inside the screw drain, the dry matter content was temporarily about 14%. In other words, the dry matter content was increased from about 14% to 24% depending on the dewatering property as such. This observation was confirmed by the fact that the filtrate during analysis was found to contain only 0.8 grams of dry matter per liter of liquid. Despite a relatively high dry matter content (24%) in to the press, a surprisingly large fl wasted dewatering was obtained without the press. Due to the relatively good water fl fate fi without the press, a dry matter content as high as 51.2% was obtained.

Fördelar Eftersom det år möjligt, att uppnå högre torrsubstansltalt med hjälp av uppfinningen kan sparas energi. Varje form av energibesparing resulterar dessutom i battre miljö eftersom fiirbrukningen av energigenererande fossila bränslen kan reduceras. Darfiir kan bland annat utsläppen av koldioxid reduceras på ett signifikant sätt. Teoretiskt medßr en reducering av varannan med 1 m” per :en tomma sam en minskning av romioxiaham (cos) man sa 200 kg. Enligt uppfinningen kan vattenhalten reduceras med ca 3 m: (ton) pertontorrtankt slam Med andra ord resulterar uppfinningen i en minskning av miljostörande CO; med ca 600 kgpertonslam Barai Sverige produceras ea200.000torrtankt slamper årmed ett vatteninnehåll av l million m3 (ton). Vid firll tillämpning av uppfinningen är de t möjligt att minska CO-z-trtsläppet med drygt 100.000 ton per år.Advantages Since it is possible to achieve higher dry matter numbers with the help of the invention, energy can be saved. In addition, any form of energy saving results in a better environment as the use of energy-generating fossil fuels can be reduced. Among other things, carbon dioxide emissions can be reduced in a significant way. Theoretically, a reduction of every other by 1 m ”per: an empty sam means a reduction of romioxiaham (cos) one said 200 kg. According to the invention, the water content can be reduced by about 3 m: (tonnes) perton dry tank sludge In other words, the invention results in a reduction of environmentally damaging CO; with about 600 kg pertons sludge Barai Sweden produces ea200,000 dry tank sludge per year with a water content of 1 million m3 (tons). With the application of the invention, it is not possible to reduce CO-z wood emissions by just over 100,000 tonnes per year.

Claims (1)

1. 527 884 5 Patentkrav Förfarande avseende vätskeutdrivning fiån suspensioner med relativt låg koncentration av organiskt material, som exempelvis slam från reningsverk eller fiberslam från massa-och pappersbruk kännetecknat av att samtidigt med vätskeutdrivningen i ett avvattningsorgan, som innefattar en rörlig maskindel såsom en skruv, pinnar eller paddlar tillförs ett torrhaltshöj ande ämne i partikelform, vilket ämne därvid blandas med suspensionen, varefter blandningen förs till ärmu ett avvattrnirigssteg som innefattar en press. Förfarande enligt krav 1 känneteclmat av att ämnet i partikelform består av sågspån. F örfarande enligt krav 1 kännetecknat av att ämnet i partikelforrn består av syntetiskt material och företrädesvis innehåller polyuretan. Förfarande enligt krav l kñnnetecknat av att ämnet i partikelforrn består av bark. Förfarande enligt krav 1 kännetecknat av att ämnet i partikelform består av torv. Förfarande enligt krav 1 kännetecknat av att ämnet i partikelform består av rörflen. Förfarande enligt krav 1 kännetecknat av att ämnet i partikelform består av halm. Förfarande enligt ett eller flera av krav 1-7 kännetecknat av att sågspån, syntetiskt material, bark, rörflen, halm och/eller torv i partikelform valfiitt blandas med varandra. Förfarande enligt krav 1-7 kännetecknat av att viktsandelen av ämnet i panikelforrn uppgår till mer än 10 vikts-% av totala vikten organiskt material.A process for liquid expulsion from suspensions with a relatively low concentration of organic material, such as sludge from sewage treatment plants or sludge from pulp and paper mills, characterized in that at the same time as the liquid expulsion in a dewatering means comprising a movable machine part such as a screw, sticks or paddles are added to a dry matter raising substance in particulate form, which substance is then mixed with the suspension, after which the mixture is passed to a drainage step which comprises a press. Process according to Claim 1, characterized in that the blank in particulate form consists of sawdust. Process according to Claim 1, characterized in that the substance in the particulate form consists of synthetic material and preferably contains polyurethane. Process according to Claim 1, characterized in that the substance in the particulate form consists of bark. Process according to Claim 1, characterized in that the substance in particulate form consists of peat. Process according to Claim 1, characterized in that the substance in particulate form consists of the tube. Process according to Claim 1, characterized in that the substance in particulate form consists of straw. Method according to one or more of Claims 1 to 7, characterized in that sawdust, synthetic material, bark, pipes, straw and / or peat in particulate form are optionally mixed with one another. Process according to Claims 1 to 7, characterized in that the proportion by weight of the substance in the panicle form amounts to more than 10% by weight of the total weight of organic material.
SE0401234A 2004-05-10 2004-05-10 Process for liquid expulsion from suspensions SE527884C2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
SE0401234A SE527884C2 (en) 2004-05-10 2004-05-10 Process for liquid expulsion from suspensions
JP2007513103A JP2007536084A (en) 2004-05-10 2005-05-08 Suspension dewatering method
CNA2005800185276A CN1980865A (en) 2004-05-10 2005-05-08 Procedure for dewatering of suspensions
PCT/SE2005/000667 WO2005108314A1 (en) 2004-05-10 2005-05-08 Procedure for dewatering of suspensions
RU2006142558/15A RU2006142558A (en) 2004-05-10 2005-05-08 SUSPENSION DEHYDRATION METHOD

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE0401234A SE527884C2 (en) 2004-05-10 2004-05-10 Process for liquid expulsion from suspensions

Publications (3)

Publication Number Publication Date
SE0401234D0 SE0401234D0 (en) 2004-05-10
SE0401234L SE0401234L (en) 2005-11-11
SE527884C2 true SE527884C2 (en) 2006-07-04

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SE0401234A SE527884C2 (en) 2004-05-10 2004-05-10 Process for liquid expulsion from suspensions

Country Status (5)

Country Link
JP (1) JP2007536084A (en)
CN (1) CN1980865A (en)
RU (1) RU2006142558A (en)
SE (1) SE527884C2 (en)
WO (1) WO2005108314A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012024888A1 (en) 2012-12-19 2014-06-26 Institut za okoljevarstvo in senzorje, d.o.o. Method and device for dewatering waste sludge
CN105384322A (en) * 2015-07-02 2016-03-09 江苏鑫中恒水工业装备有限公司 Sludge drying and sewage treatment method
WO2017219131A1 (en) * 2016-06-23 2017-12-28 Fpinnovations Enhancing dewatering of biosolid slurries using an acid and lignocellulosic materials
CN109574446A (en) * 2018-12-14 2019-04-05 上海交通大学 A method of improving dewatering performance of sludge using ozone/coagulant/hydrophobic polyurethane
SE2050328A1 (en) * 2020-03-25 2021-04-27 Valmet Oy Method for utilizing sludges from wood pulping
CN111499148B (en) * 2020-05-13 2021-01-29 扬州纪扬机械设备有限公司 Equipment for separating sludge and sewage

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2831384A1 (en) * 1978-07-17 1980-01-31 Weiss Geb Kg FILTER TOOLS FOR TREATMENT OF SUSPENSIONS, ESPECIALLY COMMUNAL, INDUSTRIAL AND OTHER SLUDGE FOR THE FOLLOWING DRAINAGE
JPS60147299A (en) * 1984-01-09 1985-08-03 Ebara Infilco Co Ltd Sludge dehydration method and apparatus thereof
SE523787C2 (en) * 2002-01-23 2004-05-18 Arne Lindahl Process for draining liquid from difficult dewatered materials
JP2018032707A (en) * 2016-08-24 2018-03-01 トヨタ自動車株式会社 Rectangular wire for forming reactor coil

Also Published As

Publication number Publication date
WO2005108314A1 (en) 2005-11-17
CN1980865A (en) 2007-06-13
SE0401234L (en) 2005-11-11
JP2007536084A (en) 2007-12-13
SE0401234D0 (en) 2004-05-10
RU2006142558A (en) 2008-06-20

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