SE446752B - COMPOSITION FOR TRANSFER OF HAIR AND WOOL - Google Patents
COMPOSITION FOR TRANSFER OF HAIR AND WOOLInfo
- Publication number
- SE446752B SE446752B SE7908700A SE7908700A SE446752B SE 446752 B SE446752 B SE 446752B SE 7908700 A SE7908700 A SE 7908700A SE 7908700 A SE7908700 A SE 7908700A SE 446752 B SE446752 B SE 446752B
- Authority
- SE
- Sweden
- Prior art keywords
- composition
- acetylethanolamine
- dyeing
- hair
- sulfur
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 41
- 210000002268 wool Anatomy 0.000 title claims description 4
- PVCJKHHOXFKFRP-UHFFFAOYSA-N N-acetylethanolamine Chemical compound CC(=O)NCCO PVCJKHHOXFKFRP-UHFFFAOYSA-N 0.000 claims description 25
- 238000004043 dyeing Methods 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 13
- 239000000975 dye Substances 0.000 claims description 11
- 210000004209 hair Anatomy 0.000 claims description 11
- 239000003973 paint Substances 0.000 claims description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 6
- 239000011593 sulfur Substances 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 4
- 229910001385 heavy metal Inorganic materials 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims description 3
- KKMOSYLWYLMHAL-UHFFFAOYSA-N 2-bromo-6-nitroaniline Chemical compound NC1=C(Br)C=CC=C1[N+]([O-])=O KKMOSYLWYLMHAL-UHFFFAOYSA-N 0.000 claims description 2
- 102000011782 Keratins Human genes 0.000 claims description 2
- 108010076876 Keratins Proteins 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 238000004040 coloring Methods 0.000 description 8
- 239000002657 fibrous material Substances 0.000 description 5
- 239000004753 textile Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000000118 hair dye Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- -1 wool and camouflage Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- HNLXNOZHXNSSPN-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCOCCOCCOCCO)C=C1 HNLXNOZHXNSSPN-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- RAUWPNXIALNKQM-UHFFFAOYSA-N 4-nitro-1,2-phenylenediamine Chemical compound NC1=CC=C([N+]([O-])=O)C=C1N RAUWPNXIALNKQM-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- 229920002466 Dynel Polymers 0.000 description 1
- 229920002821 Modacrylic Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000004161 brilliant blue FCF Substances 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- QVBODZPPYSSMEL-UHFFFAOYSA-N dodecyl sulfate;2-hydroxyethylazanium Chemical compound NCCO.CCCCCCCCCCCCOS(O)(=O)=O QVBODZPPYSSMEL-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229940098514 octoxynol-9 Drugs 0.000 description 1
- 229920002114 octoxynol-9 Polymers 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 235000012752 quinoline yellow Nutrition 0.000 description 1
- 229940051201 quinoline yellow Drugs 0.000 description 1
- FZUOVNMHEAPVBW-UHFFFAOYSA-L quinoline yellow ws Chemical compound [Na+].[Na+].O=C1C2=CC=CC=C2C(=O)C1C1=NC2=C(S([O-])(=O)=O)C=C(S(=O)(=O)[O-])C=C2C=C1 FZUOVNMHEAPVBW-UHFFFAOYSA-L 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Cosmetics (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Description
446 752 2 hos de färgade materialen mot blekning; i beständigheten hos de färgade materialen mot erosion av färg genom gnidning och lik- nande; i djupet för den färg som förlänas materialen som är förbundet med färgning; och/eller i effektiviteten och den lätthet med vilken färg förlänas materialen för deras färgning. 446 752 2 of the colored materials against bleaching; in the resistance of the colored materials to erosion of paint by rubbing and the like; in the depth of the color imparted to the materials associated with dyeing; and / or in the efficiency and ease with which paint is imparted to the materials for their dyeing.
Stora ansträngningar har nedlagts i eftersträvan att förbättra färgningen av fibermaterial. Kända medel för underlättande och förbättring av sådana färgningsförfaranden har emellertid en- dast haft tillfällig och/eller begränsad framgång. Sådana me- del har ofta visat sig dyrbara, endast framgångsrika för und- vikande av några av de föregående olägenheterna och/eller lämpliga endast med vissa typer av färgsystem.Great efforts have been made to improve the dyeing of fibrous materials. However, known agents for facilitating and improving such staining processes have had only temporary and / or limited success. Such agents have often proved costly, only successful in avoiding some of the foregoing disadvantages and / or suitable only with certain types of paint systems.
Enligt föreliggande uppfinning har det framkommit att inför- livning av N-acetyletanolamin i färgningskompositioner till- handahåller förbättrad och mera varaktig färgning än som hit- tills har erhållits, påskyndar frägningsförfarandet och/eller tillhandahåller färgade produkter med ökade och mera bestän- diga färger.According to the present invention, it has been found that incorporation of N-acetylethanolamine into coloring compositions provides improved and more durable coloring than has hitherto been obtained, accelerates the friction process and / or provides colored products with increased and more durable colors.
Föreliggande uppfinning har visat sig vara lämplig för hela det breda området av olika färgämnen inom denna teknik. Kompo- sitionen enligt uppfinningen användes för färgning av keratin- haltiga fibrer innefattande hår och ull och omfattar ett färg- system innehållande ett färgningsmedel som väljes bland den grupp som omfattar sura, basiska, direkta, svavel-, kyp-, leu- koestrar, azo-, acetat-, pigment-, tungmetallsalt/-svavelhaltig reducerande förening, oxidations- och oorganiska färgämnen och en vätskeformig dispergeringsvehikel därför, vilken komposition utmärkes av att kompositionen innehåller N-acetyletanolamin för att främja färgning av nämnda material.The present invention has been found to be suitable for the whole wide range of different dyes in this art. The composition of the invention is used for dyeing keratin-containing fibers comprising hair and wool and comprises a dyeing system containing a dyeing agent selected from the group comprising acidic, basic, direct, sulfur, quenching, leucoesters, azo , acetate, pigment, heavy metal salt / sulfur-containing reducing compound, oxidizing and inorganic dyes and a liquid dispersing vehicle therefor, which composition is characterized in that the composition contains N-acetylethanolamine to promote dyeing of said material.
N-acetyletanolamin har inom kosmetikatekniken varit känd som ett i hög grad effektivt konditioneringsmedel eller skötsel- hjälpmedel för hår, varvid det användes i stället för mineral- olje-derivat i schampon, sköljmedel, konditioneringsmedel och liknande, för att belägga håret så att håret ligger plant, icke är flygigt och har ett glänsande utseende. Man har emel- lertid tidigare icke insett att N-acetyletanolamin även kommer att tjänstgöra för att främja eller öka färgningen av hår. Ej 446 752 heller har man insett att denna effekt inträffar icke endast med hår utan även med andra fibermaterial och icke endast med konventionella hårfärgningssystem utan även med andra färg- system.N-acetylethanolamine has been known in the cosmetic art as a highly effective conditioner or care aid for hair, using instead of mineral oil derivatives in shampoos, rinses, conditioners and the like, to coat the hair so that the hair lies flat, not airy and has a shiny appearance. However, it has not previously been realized that N-acetylethanolamine will also serve to promote or increase the coloring of hair. Nor has it been realized that this effect occurs not only with hair but also with other fibrous materials and not only with conventional hair dyeing systems but also with other dyeing systems.
Förutom dess nyligen upptäckta egenskap eller funktion som ett färgningsökande medel fortsätter N-acetyletanolamin att till- handahålla de fördelar för vilka denna varit allmänt känd inom kosmetikaområdet. Dess närvaro i en färgningskomposition fortsätter följaktligen att tillhandahålla de borstnings- eller konditioneringsfunktioner för vilka den är känd. Före- liggande färgningskompositioner är därför förutom att de till- handahåller förbättrad färgning även mindre sträva i sina effekter på det material som färgas. Även om uppfinningen icke skall vara bunden till någon viss teori är det troligt att åtminstone ett av de sätt medelst vilka N-acetyletanolamin fungerar för att öka eller främja färgning är genom dess förmåga att förorsaka fiberexpansion i det material som behandlas. En sådan expansion av de indivi- duella fibrerna hos det material som färgas skulle kunna för- klara den förbättrade och påskyndade penetrationen av ett färgsystem in i materialet. Den kunde även förklara den iakt- tagna accelerationen och lättheten i förlänande av färgning och/eller förbättrad resistans hos det färgade materialet mot blekning eller förlust av färgning.In addition to its newly discovered property or function as a color enhancer, N-acetylethanolamine continues to provide the benefits for which it has been widely known in the cosmetics field. Accordingly, its presence in a coloring composition continues to provide the brushing or conditioning functions for which it is known. The present dyeing compositions are therefore, in addition to providing improved dyeing, also less strenuous in their effects on the material being dyed. Although the invention is not to be bound by any particular theory, it is likely that at least one of the ways in which N-acetylethanolamine acts to increase or promote staining is by its ability to cause fiber expansion in the material being treated. Such an expansion of the individual fibers of the dyed material could explain the improved and accelerated penetration of a dyeing system into the material. It could also explain the observed acceleration and ease of imparting dyeing and / or improved resistance of the dyed material to bleaching or loss of dyeing.
Såsom redan har angetts är den kemiska kompositionen och meka- nismen för det färgsystem som använts i föreliggande komposi- tioner relativt oviktigt. Vilka som helst av de välkända sys- tement enligt den tidigare tekniken innefattande exempelvis oxidativa färgämnen, basiska färger och tungmetallsalt/svave1- haltiga reducerande blandningssystem såsom de som beskrives nedan kan utnyttjas.As already stated, the chemical composition and mechanism of the paint system used in the present compositions are relatively unimportant. Any of the well known prior art systems including, for example, oxidative dyes, basic dyes and heavy metal salt / sulfur-containing reducing mixing systems such as those described below may be utilized.
Dessa färgsystem enligt den tidigare tekniken uppgår normalt till ungefär 50 % och företrädesvis från ungefär l till 25 % 446 752 av den totala vikten av färgningskompositionen. De exakta proportionerna varierar emellertid från system till system och med deras avsedda användning på konventionellt sätt. De är ej heller kritiska för verkan av N-acetyletanolaminen.These prior art dyeing systems normally amount to about 50% and preferably from about 1 to 25% 446,752 of the total weight of the dyeing composition. However, the exact proportions vary from system to system and with their intended use in a conventional manner. They are also not critical to the action of the N-acetylethanolamine.
I föreliggande färgkompositioner (såsom.i den tidigare tekni- ken) tillhandahålles färgsystemet i en flytande dispergerings- vehikel för detta, vanligtvis vatten eller en vattenhaltig blandning. Detta erfordras icke eftersom icke-vattenhaltiga system innefattande alkohol, mineralolja och liknande kan an- vändas. Likaledes är blandade vattenhaltiga/vatten-oblandbara vätskeemulsioner lämpliga vehiklar för färgsystem i förelig- gande kompositioner.In the present paint compositions (as in the prior art) the paint system is provided in a liquid dispersing vehicle therefor, usually water or an aqueous mixture. This is not required as non-aqueous systems including alcohol, mineral oil and the like can be used. Likewise, mixed aqueous / water-immiscible liquid emulsions are suitable vehicles for paint systems in the present compositions.
N-acetyhæïmohmünen kan användas i nästan vilken som helst mängd; den omfattar emellertid wndigbüs fnàxungefär 1 till 25 %, företrädesvis l0 - 15 %, av den totala vikten av färgkompo- sitionen. Under det att dessa proportioner i allmänhet till- handahåller maximalt färgfrämjande kan ännu större mängder av N-acetyletanolamin finnas närvarande för det ytterligare ända- målet att tillhandahålla konditionering för det behandlade fibermaterialet, eller där N-acetyletanolaminen utgör en huvuddel, eller hela mängden, av själva vehikeln. Den mängd av N-acetyletanolamin som utnyttjas i vilken som helst given färgningskomposition kan följaktligen variera vidsträckt.The N-acetyhemimohmone can be used in almost any amount; however, it comprises wndigbüs fnàxunge about 1 to 25%, preferably 10 - 15%, of the total weight of the paint composition. While these proportions generally provide maximum color enhancement, even greater amounts of N-acetylethanolamine may be present for the additional purpose of providing conditioning for the treated fibrous material, or where the N-acetylethanolamine constitutes a major, or all, amount of the vehicle itself. Accordingly, the amount of N-acetylethanolamine used in any given coloring composition may vary widely.
Under det att föreliggande uppfinning har beskrivits i stora drag i termer av i förväg framställda kompositioner som skall anbringas till det material som färgas behöver detta icke vara fallet. Föreliggande kompositioner kan även framställas på själva fibermaterialet, genom anbringning i följd av N-acetyl- etanolamin och av färgsystemet. Det är sålunda endast nödvän- digt att alla de väsentliga komponenterna hos färgningskompo- sitionen finnes närvarande på, eller i, det fibermaterial som färgas samtidigt för uppnående av de fördelaf"som"här"béskri- vits. 446 752 Uppfinningen åskâdliggöres närmare medelst följande exempel där ett flertal exempel på kompositioner enligt föreliggande uppfinning beskrives.While the present invention has been broadly described in terms of preformed compositions to be applied to the material being dyed, this need not be the case. The present compositions can also be prepared on the fibrous material itself, by sequential application of N-acetylethanolamine and by the dyeing system. Thus, it is only necessary that all the essential components of the dyeing composition be present on, or in, the fibrous material dyed simultaneously to achieve the benefits "described" herein. 446 752 The invention is further illustrated by the following examples. where several examples of compositions of the present invention are described.
Exempel l Vattenhaltiga färgningskompositioner av tvâ standardfärger, FD&C Blue nr l (i 0,25 viktprocent) och D&C Yellow nr 10 (i 0,75 viktprocent) användes i jämförande färgtester beträffande effekterna av N-acetyletanolamin. Parade prov av dessa två färgningskompositioner - ett jämförelseprov innehållande 0 % och ett prov innehållande 10 % av N-acetyletanolamin baserat på vikt - användes för jämförelsen.Example 1 Aqueous dye compositions of two standard colors, FD&C Blue No. 1 (in 0.25% by weight) and D&C Yellow No. 10 (in 0.75% by weight) were used in comparative color tests on the effects of N-acetylethanolamine. Paired samples of these two coloring compositions - a comparative sample containing 0% and a sample containing 10% of N-acetylethanolamine based on weight - were used for the comparison.
Bitar av olika textilier nedsänktes i de fyra testprovfärg- ningskompositionerna vid 60°C under l minut. Efter torkning jämfördes bitarna visuellt beträffande intensiteten av färg- ämnesfärgen. Resultaten visade flera fall i vilka N-acetyl- etanolaminen överraskande åstadkommer färgning (icke alla tex- tilmaterialen är normalt mottagare för dessa speciella färg- kompositioner) samt andra vari färgning var klart förbättrad jämförd med de resp. jämförelseproven. Textilierna som upp- visade ökningar i färgintensitet beroende på närvaron av N- acetyletanolaminen varierade brett i typer av fibrer, innefat- tande ull och kamull, rayon (varubeteckning AVRIL), viskos- rayon, silke, nylon, bomull, acetat, akrylnitril (ACRILAN), triacetat (ARNEL), akryl (CRESLAN, ORLON och ZEFRAN), poly- ester (DACRON, FORTREL och KODEL), olefin (HERCULON) och modakrylfibrer (VEREL och DYNEL).Pieces of different textiles were immersed in the four test sample dyeing compositions at 60 ° C for 1 minute. After drying, the pieces were visually compared for the intensity of the dye dye. The results showed several cases in which the N-acetylethanolamine surprisingly produces dyeing (not all textile materials are normally recipients of these particular dye compositions) and others in which dyeing was clearly improved compared to the resp. the comparative tests. The textiles which showed increases in color intensity due to the presence of the N-acetylethanolamine varied widely in types of fibers, including wool and camouflage, rayon (trade name AVRIL), viscose rayon, silk, nylon, cotton, acetate, acrylonitrile (ACRILAN ), triacetate (ARNEL), acrylic (CRESLAN, ORLON and ZEFRAN), polyester (DACRON, FORTREL and KODEL), olefin (HERCULON) and modacrylic fibers (VEREL and DYNEL).
Vid visuell undersökning visade sig bitar färgade i närvaro av N-acetyletanolamin även vara mera homogena i färg och mindre känsliga för flöden och strimbildning. N-acetyletanolaminen förbättrade sålunda fixeringen av färgen på textilierna.On visual inspection, pieces stained in the presence of N-acetylethanolamine were also found to be more homogeneous in color and less sensitive to flows and streaks. The N-acetylethanolamine thus improved the fixation of the color of the textiles.
Exempel 2 En hårfärgningskomposition framställdes som hade följande sam- mansättning: 446 752 6 Vismutcitrat 0,50 % Trietanolamin 3,00 % Alkohol 10,00 % Svavel, utfälld 0,50 % Oktoxynol-9(TRITON X-100) 0,10 % N-acetyletanolamin 15,00 % Vatten 70,80 % Parfym 0,10 % Kompositionen framställdes på konventionellt sätt, varvid N- acetyletanolaminen (varubeteckning ACETAMIDE MEA) tillsattes efter smmanfiüfing ærde ætka ingredienserna. För testning av denna komposition doppades bitar av blekt här in i kompositio- nen, avlägsnades, skakades för avlägsnande av överskott av komposition och fick därefter torka över natten vid rumstempe- ratur. Efter torkning visade sig håret ha förändrats från sin ursprungliga blonda färg till en brun nyans. Upprepade dag- liga behandlingar under en veckas period gav en ökande djupare och mörkt färgad brun nyans av hög varaktighet.Example 2 A hair dye composition was prepared having the following composition: 446,752 Bismuth citrate 0.50% Triethanolamine 3.00% Alcohol 10.00% Sulfur, precipitated 0.50% Octoxynol-9 (TRITON X-100) 0.10% N-acetylethanolamine 15.00% Water 70.80% Perfume 0.10% The composition was prepared in a conventional manner, the N-acetylethanolamine (trade name ACETAMIDE MEA) being added after adding the ingredients. To test this composition, pieces of bleach here were dipped into the composition, removed, shaken to remove excess composition and then allowed to dry overnight at room temperature. After drying, the hair turned out to have changed from its original blonde color to a brown shade. Repeated daily treatments for a one-week period resulted in an increasingly deeper and dark-colored brown shade of high duration.
Exempel 3 En hårfärgningskomposition framställdes som hade följande sam- mansättning: Parafenylendiaminsulfat 5,00 % Resorcinol 1,00 % Alkohol 13,00 % N-acetyletanolamin 10,00 % Oljesyra 0,40 % Ammoniak (25 % lösning) 10,00 % Vatten 63,60 % Kompositionen framställdes på konventionellt sätt och användes med en peroxidframkallare. Vid testning på blekta bitar av hår gav den en mörk svart färgning. 446 752 Exemgel 4 En semi-permanent färg och schampo framställdes som hade föl- jande sammansättning: Monoetanolaminlaurylsulfat 20,00 % Etylenglykolmonostearat 3,00 % P-nitro-o-fenylendiamin 1,50 % Dietanolaminkokosnötfettsyror 3,00 % N-acetyletanolamin 7,00 % Vatten 65,50 % Vid användning vid schamponering av hår iakttogs en intensi- fierad färgning med ökad beständighet mot erosion av färgnin- gen genom avgnidning.Example 3 A hair dye composition was prepared having the following composition: Paraphenylenediamine sulfate 5.00% Resorcinol 1.00% Alcohol 13.00% N-acetylethanolamine 10.00% Oleic acid 0.40% Ammonia (25% solution) 10.00% Water 63.60% The composition was prepared in a conventional manner and used with a peroxide developer. When tested on bleached pieces of hair, it gave a dark black coloration. 446 752 Example gel 4 A semi-permanent dye and shampoo were prepared which had the following composition: Monoethanolamine lauryl sulphate 20.00% Ethylene glycol monostearate 3.00% P-nitro-o-phenylenediamine 1.50% Dietanolamine coconut fatty acids 3.00% N-acetylethanolamine 7, 00% Water 65.50% When used for shampooing hair, an intensified coloring with increased resistance to erosion of the coloring by rubbing was observed.
Claims (5)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US95199878A | 1978-10-20 | 1978-10-20 | |
| US3754779A | 1979-05-11 | 1979-05-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE7908700L SE7908700L (en) | 1980-04-21 |
| SE446752B true SE446752B (en) | 1986-10-06 |
Family
ID=26714239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE7908700A SE446752B (en) | 1978-10-20 | 1979-10-19 | COMPOSITION FOR TRANSFER OF HAIR AND WOOL |
Country Status (20)
| Country | Link |
|---|---|
| AR (1) | AR226829A1 (en) |
| AT (1) | AT386834B (en) |
| AU (1) | AU528723B2 (en) |
| BR (1) | BR7906765A (en) |
| CA (1) | CA1141505A (en) |
| CH (1) | CH659359GA3 (en) |
| DE (1) | DE2942376C2 (en) |
| DK (1) | DK149582C (en) |
| FI (1) | FI67578C (en) |
| FR (1) | FR2439223A1 (en) |
| GB (1) | GB2036093B (en) |
| GR (1) | GR82354B (en) |
| IE (1) | IE49088B1 (en) |
| IT (1) | IT1124611B (en) |
| LU (1) | LU81791A1 (en) |
| NL (1) | NL180773C (en) |
| NO (1) | NO152176C (en) |
| NZ (1) | NZ191878A (en) |
| PT (1) | PT70321A (en) |
| SE (1) | SE446752B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2499852A1 (en) * | 1981-02-19 | 1982-08-20 | Rocador Sa | N-HYDROXYETHYLACETAMIDE DRUG FOR THE TREATMENT OF SEBORRHEA DISEASES ON HUMAN SCALP LEATHER |
| US4583986A (en) * | 1981-07-20 | 1986-04-22 | Combe Incorporated | Catalyzed bismuth dye system for human hair |
| DE3929333A1 (en) * | 1989-09-04 | 1991-03-07 | Henkel Kgaa | EQUALIZING OXIDATION HAIR COLORING AGENTS |
| US6440175B1 (en) * | 2001-06-28 | 2002-08-27 | Stanley, Iii Virgil E. | Hair coloring kit |
-
1979
- 1979-10-09 GR GR60224A patent/GR82354B/el unknown
- 1979-10-12 FI FI793179A patent/FI67578C/en not_active IP Right Cessation
- 1979-10-15 LU LU81791A patent/LU81791A1/en unknown
- 1979-10-16 PT PT70321A patent/PT70321A/en unknown
- 1979-10-17 NL NLAANVRAGE7907668,A patent/NL180773C/en not_active IP Right Cessation
- 1979-10-17 AU AU51860/79A patent/AU528723B2/en not_active Ceased
- 1979-10-18 GB GB7936256A patent/GB2036093B/en not_active Expired
- 1979-10-18 NZ NZ191878A patent/NZ191878A/en unknown
- 1979-10-18 IT IT26585/79A patent/IT1124611B/en active
- 1979-10-19 SE SE7908700A patent/SE446752B/en not_active IP Right Cessation
- 1979-10-19 CH CH943079A patent/CH659359GA3/fr unknown
- 1979-10-19 IE IE2004/79A patent/IE49088B1/en not_active IP Right Cessation
- 1979-10-19 BR BR7906765A patent/BR7906765A/en not_active IP Right Cessation
- 1979-10-19 DK DK442879A patent/DK149582C/en active
- 1979-10-19 AR AR278563A patent/AR226829A1/en active
- 1979-10-19 FR FR7926081A patent/FR2439223A1/en active Granted
- 1979-10-19 NO NO793373A patent/NO152176C/en unknown
- 1979-10-19 DE DE2942376A patent/DE2942376C2/en not_active Expired
- 1979-10-19 AT AT0682179A patent/AT386834B/en not_active IP Right Cessation
- 1979-10-22 CA CA000338092A patent/CA1141505A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB2036093A (en) | 1980-06-25 |
| DE2942376A1 (en) | 1980-04-30 |
| DK149582C (en) | 1987-02-09 |
| FI67578B (en) | 1984-12-31 |
| IE49088B1 (en) | 1985-07-24 |
| AU5186079A (en) | 1980-04-24 |
| IT1124611B (en) | 1986-05-07 |
| DK149582B (en) | 1986-08-04 |
| AU528723B2 (en) | 1983-05-12 |
| AT386834B (en) | 1988-10-25 |
| FR2439223A1 (en) | 1980-05-16 |
| IE792004L (en) | 1980-11-11 |
| AR226829A1 (en) | 1982-08-31 |
| ATA682179A (en) | 1988-03-15 |
| PT70321A (en) | 1979-11-01 |
| NO152176B (en) | 1985-05-06 |
| NO793373L (en) | 1980-04-22 |
| FI793179A7 (en) | 1980-04-21 |
| FR2439223B1 (en) | 1984-06-29 |
| NL7907668A (en) | 1980-04-22 |
| SE7908700L (en) | 1980-04-21 |
| NO152176C (en) | 1985-08-14 |
| BR7906765A (en) | 1980-09-09 |
| LU81791A1 (en) | 1980-01-24 |
| NL180773B (en) | 1986-11-17 |
| FI67578C (en) | 1985-04-10 |
| NL180773C (en) | 1987-04-16 |
| CA1141505A (en) | 1983-02-22 |
| DE2942376C2 (en) | 1983-02-03 |
| IT7926585A0 (en) | 1979-10-18 |
| DK442879A (en) | 1980-04-21 |
| GR82354B (en) | 1984-12-13 |
| NZ191878A (en) | 1981-05-15 |
| GB2036093B (en) | 1982-10-27 |
| CH659359GA3 (en) | 1987-01-30 |
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