SE311642B - - Google Patents
Info
- Publication number
- SE311642B SE311642B SE7494/61A SE749461A SE311642B SE 311642 B SE311642 B SE 311642B SE 7494/61 A SE7494/61 A SE 7494/61A SE 749461 A SE749461 A SE 749461A SE 311642 B SE311642 B SE 311642B
- Authority
- SE
- Sweden
- Prior art keywords
- transition metal
- reduction
- ligand
- salt
- biphyllic
- Prior art date
Links
- 239000003446 ligand Substances 0.000 abstract 12
- 229910052723 transition metal Inorganic materials 0.000 abstract 10
- 150000003624 transition metals Chemical class 0.000 abstract 9
- 150000003839 salts Chemical class 0.000 abstract 8
- 229910052698 phosphorus Inorganic materials 0.000 abstract 6
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 abstract 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- 229910052783 alkali metal Inorganic materials 0.000 abstract 4
- -1 cycloaliphatic Chemical group 0.000 abstract 4
- 239000002609 medium Substances 0.000 abstract 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 3
- 150000001340 alkali metals Chemical class 0.000 abstract 3
- 229910052787 antimony Inorganic materials 0.000 abstract 3
- 229910052785 arsenic Inorganic materials 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 3
- 239000011574 phosphorus Substances 0.000 abstract 3
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 125000000962 organic group Chemical group 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 125000004437 phosphorous atom Chemical group 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 abstract 1
- PHJJWPXKTFKKPD-UHFFFAOYSA-N [Ni+3].[O-]P([O-])[O-] Chemical compound [Ni+3].[O-]P([O-])[O-] PHJJWPXKTFKKPD-UHFFFAOYSA-N 0.000 abstract 1
- NQCACSDIPTYDFO-UHFFFAOYSA-L [Rb+].[Rb+].[O-]S(=O)S([O-])=O Chemical compound [Rb+].[Rb+].[O-]S(=O)S([O-])=O NQCACSDIPTYDFO-UHFFFAOYSA-L 0.000 abstract 1
- 150000001242 acetic acid derivatives Chemical class 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000003842 bromide salts Chemical class 0.000 abstract 1
- 150000004648 butanoic acid derivatives Chemical class 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000003841 chloride salts Chemical class 0.000 abstract 1
- VCRXKVBLDRIWKL-UHFFFAOYSA-N cobalt triethyl phosphite Chemical compound C(C)OP(OCC)OCC.[Co] VCRXKVBLDRIWKL-UHFFFAOYSA-N 0.000 abstract 1
- 239000008139 complexing agent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000002391 heterocyclic compounds Chemical class 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000002823 nitrates Chemical class 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 150000007519 polyprotic acids Polymers 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/301—Organic compounds compounds not mentioned before (complexes) derived from metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
- C07F15/045—Nickel compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5045—Complexes or chelates of phosphines with metallic compounds or metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US44556A US3102899A (en) | 1960-07-22 | 1960-07-22 | Preparation of transition metal organic phosphite complexes |
US4607160A | 1960-07-29 | 1960-07-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
SE311642B true SE311642B (hr) | 1969-06-23 |
Family
ID=26721706
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SE7494/61A SE311642B (hr) | 1960-07-22 | 1961-07-20 | |
SE11744/62A SE307132B (hr) | 1960-07-22 | 1962-11-01 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SE11744/62A SE307132B (hr) | 1960-07-22 | 1962-11-01 |
Country Status (8)
Country | Link |
---|---|
US (1) | US3102899A (hr) |
BE (1) | BE606408A (hr) |
DE (2) | DE1468661A1 (hr) |
ES (1) | ES269264A1 (hr) |
FR (1) | FR1300404A (hr) |
GB (2) | GB988943A (hr) |
NL (3) | NL267290A (hr) |
SE (2) | SE311642B (hr) |
Families Citing this family (77)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3239566A (en) * | 1960-07-22 | 1966-03-08 | Shell Oil Co | Hydroformylation of olefins |
US3239571A (en) * | 1960-07-22 | 1966-03-08 | Shell Oil Co | Hydroformylation of olefins |
US3239569A (en) * | 1960-07-22 | 1966-03-08 | Shell Oil Co | Hydroformylation of olefins |
US3239570A (en) * | 1960-07-22 | 1966-03-08 | Shell Oil Co | Hydroformylation of olefins |
US3274263A (en) * | 1961-08-30 | 1966-09-20 | Shell Oil Co | Process for olefin hydroformylation |
NL134286C (hr) * | 1962-01-23 | |||
US3311598A (en) * | 1963-02-05 | 1967-03-28 | Exxon Research Engineering Co | Process for hydroformylating an unsaturated hydrocarbon polymer |
US3310576A (en) * | 1963-02-05 | 1967-03-21 | Exxon Research Engineering Co | Hydroformylation catalyst and process relating thereto |
US3242171A (en) * | 1963-02-06 | 1966-03-22 | Du Pont | Complexes of organophosphorus fluorides with zerovalent transition metals |
US3374256A (en) * | 1963-08-16 | 1968-03-19 | Monsanto Res Corp | Complex phosphorus salts |
US3989675A (en) * | 1964-01-24 | 1976-11-02 | The Dow Chemical Company | Oxo process for producing an aldehyde |
US3354229A (en) * | 1964-01-28 | 1967-11-21 | Exxon Research Engineering Co | Oxonation of cyclododecatriene to c13 alcohol |
US3336387A (en) * | 1964-02-28 | 1967-08-15 | Shell Oil Co | Tertiary amine oxides |
US3258502A (en) * | 1964-05-18 | 1966-06-28 | Shell Oil Co | Polycyclic hydrocarbon production |
FR1458029A (fr) * | 1964-12-14 | 1966-11-04 | Shell Int Research | Procédé de préparation d'aldéhydes et d'alcools |
US3420898A (en) * | 1965-03-29 | 1969-01-07 | Shell Oil Co | Single stage hydroformylation of olefins to alcohols |
US3448157A (en) * | 1965-09-27 | 1969-06-03 | Shell Oil Co | Hydroformylation of olefins |
US3456017A (en) * | 1965-10-21 | 1969-07-15 | Shell Oil Co | Glycol production |
US3463819A (en) * | 1965-10-21 | 1969-08-26 | Shell Oil Co | Glycol production |
GB1127965A (en) * | 1965-11-26 | 1968-09-25 | Shell Int Research | Ditertiary phosphines and application thereof as catalyst components for alcohol production |
US3857900A (en) * | 1965-12-15 | 1974-12-31 | Ethyl Corp | Hydrogenation of aldehydes using triarylphosphine rhodium halogenoid catalysts |
US3448158A (en) * | 1966-01-28 | 1969-06-03 | Shell Oil Co | Hydroformylation of olefins |
US3515757A (en) * | 1966-04-01 | 1970-06-02 | Ethyl Corp | Organic compounds and processes |
US3363015A (en) * | 1966-04-04 | 1968-01-09 | Phillips Petroleum Co | Olefinic isomers and process for forming same |
US3363014A (en) * | 1966-04-04 | 1968-01-09 | Phillips Petroleum Co | Isomerization of olefinic hydrocarbons |
US3458550A (en) * | 1966-08-22 | 1969-07-29 | Union Carbide Corp | Ni ii tetracoordinate and pentacoordinate complexes of organo phosphorous esters as catalysts for the preparation of pentacyclo(8.2.1.1**4.7.0**2.9.0**3.8)tetra-deca-5,11-diene |
US3733361A (en) * | 1966-08-23 | 1973-05-15 | Gulf Research Development Co | Oxo process |
GB1141847A (en) * | 1966-08-24 | 1969-02-05 | Ici Ltd | Hydrogenation process |
US3511880A (en) * | 1966-09-16 | 1970-05-12 | Union Oil Co | Hydrocarbonylation process |
JPS516124B1 (hr) * | 1966-10-11 | 1976-02-25 | ||
US4482748A (en) * | 1967-05-29 | 1984-11-13 | Celanese Corporation | Hydrocarbonylation |
US3505408A (en) * | 1967-06-05 | 1970-04-07 | Union Carbide Corp | Hydroformylation of olefins |
US3499932A (en) * | 1967-06-15 | 1970-03-10 | Union Carbide Corp | Hydroformylation of polycyclic diolefins |
US3499933A (en) * | 1967-06-15 | 1970-03-10 | Union Carbide Corp | Hydroformylation of cyclic olefins |
US3527809A (en) * | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
JPS5127649B1 (hr) * | 1967-08-25 | 1976-08-13 | ||
GB1243189A (en) * | 1967-12-05 | 1971-08-18 | British Petroleum Co | Oxo process |
DE1939322B2 (de) * | 1968-08-02 | 1981-02-26 | Johnson, Matthey & Co., Ltd., London | Verfahren zur Hydroformylierung olefinisch ungesättigter Verbindungen |
US3857895A (en) * | 1969-05-12 | 1974-12-31 | Union Oil Co | Recovery of catalyst complexes |
GB1338237A (en) * | 1969-12-22 | 1973-11-21 | Union Carbide Corp | Hydroformylation process |
US3917661A (en) * | 1970-01-07 | 1975-11-04 | Union Carbide Corp | Hydroformylation of unsaturated organic compounds |
US3907847A (en) * | 1970-04-27 | 1975-09-23 | Ethyl Corp | Compound and method |
US3671560A (en) * | 1970-09-29 | 1972-06-20 | Phillips Petroleum Co | Manufacture of palladium or platinum-containing compounds |
US3692864A (en) * | 1970-09-30 | 1972-09-19 | Texaco Inc | Hydrogenation process utilizing homogeneous metal catalysts |
US3906015A (en) * | 1971-10-18 | 1975-09-16 | Du Pont | Carboalkoxylation and carboalkoxylation of olefins |
US3900526A (en) * | 1972-05-02 | 1975-08-19 | Phillips Petroleum Co | Selective removal of 1,2 polyenes and acetylenic compounds from conjugated-diene feed using a nickel, iron or cobalt arsenide catalyst |
US3915891A (en) * | 1972-05-05 | 1975-10-28 | Goodyear Tire & Rubber | Hydrogenation catalyst |
US3917677A (en) * | 1972-05-17 | 1975-11-04 | Monsanto Co | Production of carboxylic acid esters by hydroesterification |
US4028275A (en) * | 1973-01-24 | 1977-06-07 | Mitsui Mining & Smelting Co., Ltd. | Process for preparing catalytic materials for purifying exhaust gas and catalytic materials prepared thereby |
US3912785A (en) * | 1973-12-11 | 1975-10-14 | Chevron Res | Oxo-related reaction making triethanolmethane and 3-methylpentanediol-1,5 from hexenediols |
US4024197A (en) * | 1974-07-31 | 1977-05-17 | E. I. Du Pont De Nemours And Company | Production of butanediol |
US4133823A (en) * | 1975-02-28 | 1979-01-09 | Monsanto Company | Reaction products of metal oxides and salts with phosphorus compounds |
US4070403A (en) * | 1975-07-21 | 1978-01-24 | Uop Inc. | Catalytic hydroformylation process |
US4118408A (en) * | 1976-05-07 | 1978-10-03 | Phillips Petroleum Company | Organophosphorus nickel complexes and preparation thereof |
US4055582A (en) * | 1976-05-10 | 1977-10-25 | Phillips Petroleum Company | Synthesis of nickel and palladium organophosphorus complexes |
GB1565719A (en) * | 1976-12-30 | 1980-04-23 | Gen Electric | Process for preparing butanediols |
US4245115A (en) * | 1977-09-14 | 1981-01-13 | Mobil Oil Corporation | Selective carbonylation of olefinically unsaturated hydrocarbons using palladium-arsine or -stibine catalysts |
US4302401A (en) * | 1980-01-23 | 1981-11-24 | Exxon Research & Engineering Co. | Tetraalkyl phosphonium substituted phosphine and amine transition metal complexes |
US4267383A (en) * | 1979-05-04 | 1981-05-12 | Celanese Corporation | Hydrocarbonylation |
FR2459683A1 (fr) | 1979-06-22 | 1981-01-16 | Ugine Kuhlmann | Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene |
US4292437A (en) * | 1979-06-27 | 1981-09-29 | E. I. Du Pont De Nemours And Company | Preparation of isobutyric acid and esters |
JPS5850234B2 (ja) * | 1980-10-23 | 1983-11-09 | 三菱化学株式会社 | 第8族貴金属固体錯体の取得方法 |
JPS5841830A (ja) * | 1981-09-07 | 1983-03-11 | Nissan Chem Ind Ltd | オキソ法によるアルコ−ルの製造方法 |
US4416825A (en) * | 1982-02-23 | 1983-11-22 | E. I. Du Pont De Nemours & Co. | Preparation of zerovalent nickel complexes |
DE3371067D1 (en) * | 1982-06-11 | 1987-05-27 | Davy Mckee London | Hydroformylation process |
EP0096987B1 (en) * | 1982-06-11 | 1985-11-13 | DAVY McKEE (LONDON) LIMITED | Hydroformylation process |
US4450113A (en) * | 1982-08-09 | 1984-05-22 | Borg-Warner Chemicals, Inc. | Zerovalent nickel phosphite complexes |
US4451680A (en) * | 1982-10-21 | 1984-05-29 | Texaco Inc. | Alcohols prepared from olefins and synthesis gas |
US4469895A (en) * | 1982-10-21 | 1984-09-04 | Texaco Inc. | Process for preparing alcohols from olefins and synthesis gas |
US4451679A (en) * | 1982-10-21 | 1984-05-29 | Texaco Inc. | Alcohols and aldehydes prepared from olefins and synthesis gas |
DE3301591A1 (de) * | 1983-01-19 | 1984-07-19 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen hydroformylierung olefinisch ungesaettigter verbindungen |
US4737588A (en) * | 1984-12-28 | 1988-04-12 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
DE3625261A1 (de) * | 1986-07-25 | 1988-02-04 | Basf Ag | Verfahren zur kontinuierlichen hydroformylierung olefinisch ungesaettigter verbindungen |
DE3924720A1 (de) * | 1989-07-26 | 1991-01-31 | Basf Ag | Hydroformylierungsverfahren |
GB9119955D0 (en) * | 1991-09-18 | 1991-10-30 | Imperial College | Treatment of aqueous supplies containing organic material |
US5364950A (en) * | 1992-09-29 | 1994-11-15 | Union Carbide Chimicals & Plastics Technology Corporation | Process for stabilizing phosphite ligands in hydroformylation reaction mixtures |
KR970703805A (ko) * | 1995-05-01 | 1997-08-09 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 | 막 분리방법(Membrane Separation) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE877598C (de) * | 1943-06-10 | 1953-05-26 | Basf Ag | Verfahren zur Herstellung von Alkoholen |
US2767082A (en) * | 1953-12-23 | 1956-10-16 | Chemical Construction Corp | Use of catalytic nucleating agents in the reduction of salts to metal |
-
0
- BE BE606408D patent/BE606408A/xx unknown
- NL NL146830D patent/NL146830C/xx active
-
1960
- 1960-07-22 US US44556A patent/US3102899A/en not_active Expired - Lifetime
-
1961
- 1961-07-20 GB GB859/63A patent/GB988943A/en not_active Expired
- 1961-07-20 DE DE19611468661 patent/DE1468661A1/de active Pending
- 1961-07-20 SE SE7494/61A patent/SE311642B/xx unknown
- 1961-07-20 FR FR868510A patent/FR1300404A/fr not_active Expired
- 1961-07-20 GB GB26417/61A patent/GB988941A/en not_active Expired
- 1961-07-20 ES ES0269264A patent/ES269264A1/es not_active Expired
- 1961-07-20 NL NL267290A patent/NL267290A/xx unknown
- 1961-07-20 DE DES74919A patent/DE1186455B/de active Pending
-
1962
- 1962-11-01 SE SE11744/62A patent/SE307132B/xx unknown
-
1971
- 1971-01-05 NL NL717100045A patent/NL146830B/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE1186455B (de) | 1965-02-04 |
NL7100045A (en) | 1971-05-25 |
NL267290A (hr) | |
GB988943A (en) | 1965-04-14 |
NL146830B (nl) | 1975-08-15 |
DE1468661A1 (de) | 1970-06-18 |
NL146830C (hr) | |
BE606408A (hr) | |
US3102899A (en) | 1963-09-03 |
FR1300404A (fr) | 1962-08-03 |
SE307132B (hr) | 1968-12-23 |
ES269264A1 (es) | 1962-04-16 |
GB988941A (en) | 1965-04-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
SE311642B (hr) | ||
Sievers et al. | Some metal chelates of ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, and triethylenetetraminehexaacetic acid | |
Wender et al. | The Chemistry of Metal Carbonyls. I. New Concepts Applied to Carbonyls of Cobalt | |
US4159999A (en) | Hydroformylation of olefins | |
KR840001119A (ko) | 하이드람포로밀화에 의한 알데히드의 제조방법 | |
GB1002429A (en) | Process for the preparation of alcohols | |
Basolo et al. | Mechanism of Substitution Reactions in Complex Ions. I. Kinetics of the Aquation and Hydrolysis of Some C-Substituted Acetatopentamminecobalt (III) Ions | |
EP0471583B1 (en) | Process for the preparation of salts of iron amino and hydroxy carboxylic acid complexes | |
ES385267A1 (es) | Procedimiento oxo para la obtencion de aldehidos y alcoho- les. | |
GB1464569A (en) | Process for production of p-nitrobenzoic acid | |
US3673250A (en) | Catalytic hydration of nitriles to produce amides | |
SE320355B (hr) | ||
US2861106A (en) | Process of preparing aldehydes or ketones by dehydrogenation of alcohols | |
GB827521A (en) | New organic copper compounds and solutions and mixtures containing the same, and processes for the preparation of such compounds | |
US3574734A (en) | Hydrogenation of unsaturated carboxylic acids | |
GB1324048A (en) | Process and catalyst for the polymerization of conjugated dienes | |
Phillips et al. | Reactions of nitrosonium salts with complexes of platinum | |
USRE28288E (en) | Table vi | |
GB1245036A (en) | Improvements in or relating to the preparation of catalysts | |
Kukushkin | Types of Reaction Undergone by Coordinated Ligands and the Factors Influencing the Change in Their Reactivity | |
US3068260A (en) | Glucoheptosaminic acid and derivatives thereof and their preparation | |
Al-Obadie et al. | Trismalonatocobaltates (III) | |
GB337409A (en) | Improvements in or relating to the manufacture of oxygenated organic compounds | |
GB827523A (en) | New organic copper compounds and solutions and mixtures containing the same, and processes for the preparation of such compounds | |
DE908969C (de) | Verfahren zur Herstellung von komplexen Salzen der Metallcarbonylwasserstoffsaeuren |