SE1551159A1 - A substance to be used in an absorption machine - Google Patents
A substance to be used in an absorption machine Download PDFInfo
- Publication number
- SE1551159A1 SE1551159A1 SE1551159A SE1551159A SE1551159A1 SE 1551159 A1 SE1551159 A1 SE 1551159A1 SE 1551159 A SE1551159 A SE 1551159A SE 1551159 A SE1551159 A SE 1551159A SE 1551159 A1 SE1551159 A1 SE 1551159A1
- Authority
- SE
- Sweden
- Prior art keywords
- compartment
- absorption machine
- machine according
- compartments
- lil
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B30/00—Heat pumps
- F25B30/04—Heat pumps of the sorption type
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/047—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for absorption-type refrigeration systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B15/00—Sorption machines, plants or systems, operating continuously, e.g. absorption type
- F25B15/02—Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B15/00—Sorption machines, plants or systems, operating continuously, e.g. absorption type
- F25B15/02—Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas
- F25B15/04—Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas the refrigerant being ammonia evaporated from aqueous solution
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B15/00—Sorption machines, plants or systems, operating continuously, e.g. absorption type
- F25B15/02—Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas
- F25B15/06—Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas the refrigerant being water vapour evaporated from a salt solution, e.g. lithium bromide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B17/00—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type
- F25B17/08—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type the absorbent or adsorbent being a solid, e.g. salt
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B37/00—Absorbers; Adsorbers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B49/00—Arrangement or mounting of control or safety devices
- F25B49/04—Arrangement or mounting of control or safety devices for sorption type machines, plants or systems
- F25B49/043—Operating continuously
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2315/00—Sorption refrigeration cycles or details thereof
- F25B2315/003—Hydrates for sorption cycles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/27—Relating to heating, ventilation or air conditioning [HVAC] technologies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/62—Absorption based systems
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Sorption Type Refrigeration Machines (AREA)
- Gas Separation By Absorption (AREA)
Description
[0008] Fig 2 shows a diagram from an experiment with discharging a system
with Li|-3H2O + NH3.
Description
[0009]|t is an object of the present invention to obviate at least some of the
disadvantages in the prior art and provide an improved substance for a
chemical heat pump.
[0010]ln a first aspect there is provided an absorption machine comprising at least
a first and a second compartment in fluid connection with each other, wherein
the first compartment comprises Lil-sHzO and wherein at least one of the first
compartment and the second compartment comprises NHs.
[0011]ln one embodiment both the first and second compartments are in heat
conducting connection with at least one surrounding system adapted to
transfer heat to and from said first and second compartments.
[0012]|n one embodiment the pressure can be regulated in at least one of said first
and second compartments. ln yet another embodiment the pressure can be
held higher in one of the at least two compartments compared to the other(s). lt
is conceived that the pressure regulation takes place with known methods such
including but not limited to valves, pressure reducing valves and pumps.
[0013]ln one embodiment the absorption machine is a chemical heat pump
working according to the absorption principle, including: a reactor part
comprising Li|-3H2O and arranged to be heated and cooled by an external
medium, an evaporator/condenser part containing the portion of the NH3 that
exists in a condensed state, and arranged to be heated and cooled by an
external medium, and a channel for the vapor phase of NH3, the channel
connecting the reactor part and the evaporator/ condenser part to each other.
[0014]ln one embodiment at least one of the first compartment and the second
compartment comprises particles. ln another embodiment at least one of the
first compartment and the second compartment comprises particles with a
maximum diameter in the range 1-100 nm. ln yet another embodiment at least
one of the first compartment and the second compartment comprises two
dimensional particles. Two dimensional particles include but are not limited to
particles of graphene, which extends mainly in two dimensions with the third
dimension being only one or a few atom Iayers. ln a further embodiment at
least one of the first compartment and the second compartment comprises
particles comprising graphene. Advantages of using particles is that the heat
conductivity is improved. The particles improve the heat transfer from the
solution of LiI-3H2O and/or NH3 to the wall enclosing the compartment.
[0015]Further aspects and embodiments are defined in the appended claims,
which are specifically incorporated herein by reference.
[O016]One advantage is that an absorption machine such as a chemical heat
pump using Lil-3H2O + NH3 can be made smaller and lighter with the same
power. Further AT can be improved. The vapor pressure in the system can be
kept relatively high.
[O017]Before the invention is disclosed and described in detail, it is to be
understood that this invention is not limited to particular compounds,
configurations, method steps, substrates, and materials disclosed herein as
such compounds, configurations, method steps, substrates, and materials may
vary somewhat. lt is also to be understood that the terminology employed
herein is used for the purpose of describing particular embodiments only and is
not intended to be limiting since the scope of the present invention is limited
only by the appended claims and equivalents thereof.
[O018]lt must be noted that, as used in this specification and the appended claims,
the singular forms “a”, “an” and “the” include plural referents unless the context
clearly dictates otherwise.
[0019] lf nothing else is defined, any terms and scientific terminology used herein
are intended to have the meanings commonly understood by those of skill in
the art to which this invention pertains.
[O020]For absorption machines in general utilizing both NH3 and water it is a
problem that water follows with NH3 when the mixture is heated and the water
following the NHg constitutes a problem. ln the present invention this is solved
by using Li|-3H2O to which NH3 is absorbed. The vapor pressure for Lil-3H2O +
NH3 is depicted in Fig 1 and as can be seen a considerable AT can be
achieved. With 4 M of NH3 the AT is close to 70°C and with 1.77 M close to
120°C.
[0021]The solution of Lil-3H2O and NHs does comprise water, but in this
environment water has such a low vapor pressure so that the amount of water
following NH3 during heating does not affect the performance to any notable
degree. Further this water goes back together with NH3 during discharging.
[0022]Temperature stability tests have given that a temperature of 200°C does not
affect the stability of the system.
[O023]Fig 2 discloses a diagram from a discharge where Lil-3H2O is kept at about
60°C while stirred with a magnetic stirrer while NH3 is taken up from an
insulated compartment. The NH3 is a free fluid in the insulated compartment,
i.e. a reactor. lt can be seen that the cooling capability is high.
[0024]Since NH3 is miscible with water it is conceived that some of the NHs may
form a solution with accessible H20 molecules from Lil-3H2O.
[0O25]ln order to check for the presence of crystals a solution of Lil-3H2O and NHs
with 2.55 M NH3 was put in a glass flask on an ice bath at ambient pressure.
No crystallization could be detected. ln another experiment 100g of Lil-3H2O
was put in a flask and NH3 was added to a pressure of 80 mbar corresponding
to 1.77 M NH3. The solution was cooled on ice, but no crystallization could be
Seen.
[O026]|n order to investigate the stability the following test was performed: 100g
Lil-3H2O was mixed with 4 moles NH3. This was heated during stirring in an
evaporator connected to a condenser. The condenser was kept a room
temperature (about 20°C). The temperature in the evaporator was increased to
200°C at a pressure of 6.3 bar. At this temperature and pressure a valve
between the evaporator and the condenser was closed and the reactor was
allowed to cool to room temperature. The condenser was cooled with ice to O°C
and the pressure was 4.3 bar. NH3 from the condenser was removed and
replaced with new NH3. This was also cooled with ice to O°C and the pressure
was still 4.3 bar. This shows that the condenser after uptake of NH3 from the
condenser at 200°C has not received any water.
[0027]A|l the described alternative embodiments above or parts of an embodiment
can be freely combined without departing from the inventive idea as long as the
combination is not contradictory.
[O028]Other features and uses of the invention and their associated advantages
will be evident to a person skilled in the art upon reading the description and
the examples.
[O029]lt is to be understood that this invention is not limited to the particular
embodiments shown here. The embodiments are provided for illustrative
purposes and are not intended to limit the scope of the invention since the
scope of the present invention is limited only by the appended claims and
equivalents thereof.
Claims (9)
1. Absorptionsmaskin innefattande åtminstone en första och en andra avdelning i fluidanslutning med varandra, varvid den första avdelningen innefattar Lil-3H2O och varvid åtminstone en av den första avdelningen och den andra avdelningen innefattar NHs.
2. Absorptionsmaskin enligt krav 1, varvid båda de första och andra avdelningarna är i värmeledande anslutning med åtminstone ett omgivande system anpassat att överföra värme till och från nämnda första och andra avdelningar.
3. Absorptionsmaskin enligt något av kraven 1-2, varvid trycket kan regleras i åtminstone en av nämnda första och andra avdelningar.
4. Absorptionsmaskin enligt något av kraven 1-3, varvid trycket kan hållas högre i en av nämnda åtminstone två avdelningar jämfört med de(n) andra.
5. Absorptionsmaskin enligt något av kraven 1-4, varvid absorptionsmaskinen är en kemisk värmepump som arbetar enligt absorptionsprincipen, innefattande: en reaktordel innefattande Lil-3H2O och anordnad att värmas och kylas av ett externt medium, en förångar/kondensator-del innefattande delen med NHe, som existerar i ett kondenserat tillstånd, och anordnad att värmas och kylas av ett externt medium, och en kanal för ångfasen hos NHa, varvid kanalen ansluter reaktordelen och förångar/kondensator-delen till varandra.
6. Absorptionsmaskin enligt något av kraven 1-5, varvid åtminstone en av den första avdelningen och den andra avdelningen innefattar partiklar.
7. Absorptionsmaskin enligt något av kraven 1-6, varvid åtminstone en av den första avdelningen och den andra avdelningen innefattar partiklar med en maximal diameter i intervallet 1-100 nm.
8. Absorptionsmaskin enligt något av kraven 1-7, varvid åtminstone en av den första avdelningen och den andra avdelningen innefattar tvådimensionella partiklar.
9. Absorptionsmaskin enligt nàgot av kraven 1-8, varvid åtminstone en av den första avdelningen och den andra avdelningen innefattar partiklar innefattande grafen.
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE1551159A SE538922C2 (sv) | 2015-09-10 | 2015-09-10 | A substance to be used in an absorption machine |
CN201680046665.3A CN107923670A (zh) | 2015-09-10 | 2016-09-12 | 用于吸收机的混合物 |
JP2018512389A JP2018526610A (ja) | 2015-09-10 | 2016-09-12 | 吸収装置に使用される混合体 |
CA2995023A CA2995023A1 (en) | 2015-09-10 | 2016-09-12 | A mixture to be used in an absorption machine |
US15/758,218 US20180252448A1 (en) | 2015-09-10 | 2016-09-12 | A mixture to be used in an absorption machine |
BR112018001248A BR112018001248A2 (pt) | 2015-09-10 | 2016-09-12 | mistura a ser usada em uma máquina de absorção |
AU2016319305A AU2016319305A1 (en) | 2015-09-10 | 2016-09-12 | A mixture to be used in an absorption machine |
PCT/EP2016/071421 WO2017042383A1 (en) | 2015-09-10 | 2016-09-12 | A mixture to be used in an absorption machine |
EP16766521.5A EP3347655A1 (en) | 2015-09-10 | 2016-09-12 | A mixture to be used in an absorption machine |
KR1020187007093A KR20180051532A (ko) | 2015-09-10 | 2016-09-12 | 흡수기에 사용되는 혼합물 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE1551159A SE538922C2 (sv) | 2015-09-10 | 2015-09-10 | A substance to be used in an absorption machine |
Publications (2)
Publication Number | Publication Date |
---|---|
SE1551159A1 true SE1551159A1 (sv) | 2017-02-14 |
SE538922C2 SE538922C2 (sv) | 2017-02-14 |
Family
ID=56940030
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SE1551159A SE538922C2 (sv) | 2015-09-10 | 2015-09-10 | A substance to be used in an absorption machine |
Country Status (10)
Country | Link |
---|---|
US (1) | US20180252448A1 (sv) |
EP (1) | EP3347655A1 (sv) |
JP (1) | JP2018526610A (sv) |
KR (1) | KR20180051532A (sv) |
CN (1) | CN107923670A (sv) |
AU (1) | AU2016319305A1 (sv) |
BR (1) | BR112018001248A2 (sv) |
CA (1) | CA2995023A1 (sv) |
SE (1) | SE538922C2 (sv) |
WO (1) | WO2017042383A1 (sv) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3283215B1 (en) * | 2015-04-16 | 2020-02-19 | SaltX Technology AB | Material for a chemical heat pump |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3312077A (en) * | 1964-03-17 | 1967-04-04 | Robertshaw Controls Co | Absorption refrigeration system |
US5547600A (en) * | 1995-05-05 | 1996-08-20 | Carrier Corporation | Absorption refrigeration system working fluid with molybdate, borate, silicate inhibitor blend |
JP2835945B2 (ja) * | 1996-02-26 | 1998-12-14 | 中国電力株式会社 | 吸収冷凍機 |
US5946937A (en) * | 1998-01-14 | 1999-09-07 | Gas Research Institute | Dual loop triple effect absorption chiller utilizing a common evaporator circuit |
CN1252516A (zh) * | 1998-10-22 | 2000-05-10 | 潘卫东 | 一种吸收式制冷方法及其系统 |
SE515688C2 (sv) * | 1998-12-18 | 2001-09-24 | Suncool Ab | Kemisk värmepump samt förfarande för kylning och/eller uppvärmning |
US7434411B2 (en) * | 2003-12-15 | 2008-10-14 | Drost Kevin M | Droplet desorption process and system |
SE535301C2 (sv) * | 2011-03-02 | 2012-06-19 | Climatewell Ab Publ | Salt överdraget med nanopartiklar |
CN102679617B (zh) * | 2012-06-21 | 2014-07-02 | 山东大学 | 一种压缩驱动吸附制冷方法及热泵系统 |
-
2015
- 2015-09-10 SE SE1551159A patent/SE538922C2/sv not_active IP Right Cessation
-
2016
- 2016-09-12 BR BR112018001248A patent/BR112018001248A2/pt not_active Application Discontinuation
- 2016-09-12 WO PCT/EP2016/071421 patent/WO2017042383A1/en active Application Filing
- 2016-09-12 JP JP2018512389A patent/JP2018526610A/ja active Pending
- 2016-09-12 AU AU2016319305A patent/AU2016319305A1/en not_active Abandoned
- 2016-09-12 CN CN201680046665.3A patent/CN107923670A/zh active Pending
- 2016-09-12 US US15/758,218 patent/US20180252448A1/en not_active Abandoned
- 2016-09-12 CA CA2995023A patent/CA2995023A1/en not_active Abandoned
- 2016-09-12 KR KR1020187007093A patent/KR20180051532A/ko unknown
- 2016-09-12 EP EP16766521.5A patent/EP3347655A1/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
CA2995023A1 (en) | 2017-03-16 |
US20180252448A1 (en) | 2018-09-06 |
AU2016319305A1 (en) | 2018-04-26 |
BR112018001248A2 (pt) | 2018-09-18 |
WO2017042383A1 (en) | 2017-03-16 |
EP3347655A1 (en) | 2018-07-18 |
JP2018526610A (ja) | 2018-09-13 |
CN107923670A (zh) | 2018-04-17 |
KR20180051532A (ko) | 2018-05-16 |
SE538922C2 (sv) | 2017-02-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
NUG | Patent has lapsed |