SE0950705A2 - A device for the recovery of soluble salts - Google Patents
A device for the recovery of soluble saltsInfo
- Publication number
- SE0950705A2 SE0950705A2 SE0950705A SE0950705A SE0950705A2 SE 0950705 A2 SE0950705 A2 SE 0950705A2 SE 0950705 A SE0950705 A SE 0950705A SE 0950705 A SE0950705 A SE 0950705A SE 0950705 A2 SE0950705 A2 SE 0950705A2
- Authority
- SE
- Sweden
- Prior art keywords
- reactor
- electrodes
- insoluble chemical
- pair
- chemical complexes
- Prior art date
Links
- 150000003839 salts Chemical class 0.000 title claims abstract description 18
- 238000011084 recovery Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims abstract description 18
- 230000006698 induction Effects 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims abstract 13
- 238000001556 precipitation Methods 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 12
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 6
- 150000002500 ions Chemical class 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 239000003153 chemical reaction reagent Substances 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 239000011133 lead Substances 0.000 claims description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 4
- 238000001228 spectrum Methods 0.000 claims description 4
- 239000011135 tin Substances 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 3
- 230000002238 attenuated effect Effects 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000005345 coagulation Methods 0.000 claims description 3
- 230000015271 coagulation Effects 0.000 claims description 3
- 239000004571 lime Substances 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 241000143252 Idaea infirmaria Species 0.000 claims description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910003460 diamond Inorganic materials 0.000 claims description 2
- 239000010432 diamond Substances 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 230000003189 isokinetic effect Effects 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 239000000956 alloy Substances 0.000 claims 1
- 230000005611 electricity Effects 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 claims 1
- 238000002386 leaching Methods 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 230000005285 magnetism related processes and functions Effects 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 9
- 150000001805 chlorine compounds Chemical class 0.000 description 7
- 239000013535 sea water Substances 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000005684 electric field Effects 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 150000002823 nitrates Chemical class 0.000 description 4
- 238000001914 filtration Methods 0.000 description 3
- 238000005065 mining Methods 0.000 description 3
- 230000006911 nucleation Effects 0.000 description 3
- 238000010899 nucleation Methods 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 238000010612 desalination reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005189 flocculation Methods 0.000 description 2
- 230000016615 flocculation Effects 0.000 description 2
- 230000002262 irrigation Effects 0.000 description 2
- 238000003973 irrigation Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- -1 hydroxyl ions Chemical class 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/463—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/48—Devices for applying magnetic or electric fields
- C02F2201/483—Devices for applying magnetic or electric fields using coils
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
- Y02A20/138—Water desalination using renewable energy
- Y02A20/144—Wave energy
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Uppfinningen avser en anordning och processer för återvinning av lösliga salter genom att bilda olösliga kemiska föreningar med hjälp av kemiska, elektriska och magnetiska processer. Anordningen innefattar bland annat en reaktor, två elektrodpar kopplade till en magnetisk induktionskälla respektive en frekvensgenerator, ett spiralformat ledande element som genererar magnetiska fält, en fotonemittor och en fläkt, vilka producerar och tillför fotoniserad luft i reaktorn via en kapillär.The invention relates to a device and processes for recovering soluble salts by forming insoluble chemical compounds by means of chemical, electrical and magnetic processes. The device comprises, inter alia, a reactor, two electrode pairs connected to a magnetic induction source and a frequency generator, respectively, a helical conductive element generating magnetic fields, a photon emitter and a fan, which produce and supply photonized air into the reactor via a capillary.
Description
62096 CN 1131127 beskriver en process för att olösliggöra salter innefattade i en vätska genom tillsats av kemiska reagenser, såsom fosfat- och bariumsalter. 62096 CN 1131127 describes a process for insolubilizing salts contained in a liquid by the addition of chemical reagents, such as phosphate and barium salts.
Fällningslösningarna separeras genom filtrering varvid vätskan - i detta fall vatten - får en minskad salthalt. I denna process används ej elektriska fält, magnetiska fält eller frekvenser och den kan ej bilda komplex.The precipitation solutions are separated by filtration, whereby the liquid - in this case water - has a reduced salt content. In this process, electric fields, magnetic fields or frequencies are not used and it cannot form complexes.
SAMMANDRAG Föreliggande uppfinning innefattar en process för bildning av olösliga kemiska föreningar i ett flytande medium genom fysisk stimuli. De bildade föreningarna kan vara oorganiska eller organiska, enkla eller komplexa. Det tekniska problem som föreliggande uppfinning löser är att omvandla salter med hög löslighet till olösliga föreningar, så att de kan separeras från vätskan för att utnyttja både de separerade salterna och den återstående renade vätskan.SUMMARY The present invention encompasses a process for the formation of insoluble chemical compounds in a liquid medium by physical stimuli. The compounds formed may be inorganic or organic, simple or complex. The technical problem solved by the present invention is to convert high solubility salts into insoluble compounds so that they can be separated from the liquid to utilize both the separated salts and the remaining purified liquid.
I ett enda steg eller reaktor sker reaktionsmekanismer och fysiska förändringar, såsom initial utfällning av komplex som tjänar som kärnor för efterföljande mekanismer för kärnbildning och adsorption av andra bildade species.In a single stage or reactor, reaction mechanisms and physical changes occur, such as the initial precipitation of complexes that serve as nuclei for subsequent mechanisms of nucleation and adsorption of other formed species.
Bildningen av dessa första fällningar beror på inverkan av ett elektriskt och magnetiskt fält som anbringas genom en ultrafiltrerad elektrisk ström som överförs via elektroder i tillägg till det joniska bidraget från en av elektroderna som fungerar som offer.The formation of these first precipitates is due to the action of an electric and magnetic field applied by an ultrafiltered electric current transmitted via electrodes in addition to the ionic contribution from one of the electrodes acting as a victim.
Därefter tillsätts en andra omgång av joner, vanligen aluminium, kalcium, järn, bly eller tenn för att bilda nya komplex med salterna som finns i vätskan. På detta vis ökar storleken av de först bildade kärnorna genom dessa nya komplex och i detta skede förekommer adsorption av andra bildade ickekomplexa salter. 62096 De olika komplexerna bildas genom selektiviteten i de processer som uppnås genom anbringande av elektromagnetisk vågfrekvens i radiovågspektratå vid frekvenser om 1 KHz till 2 MHz, med en utrustning som genererar elektromagnetiska vågor med olika geometri och frekvens.Then a second round of ions is added, usually aluminum, calcium, iron, lead or tin to form new complexes with the salts present in the liquid. In this way, the size of the first formed nuclei increases through these new complexes and at this stage adsorption of other formed non-complex salts occurs. 62096 The different complexes are formed by the selectivity of the processes achieved by applying electromagnetic wave frequency in radio wave spectra at frequencies of 1 KHz to 2 MHz, with equipment generating electromagnetic waves of different geometry and frequency.
Möjliga användningsområden för denna teknik är, bland andra: O Avsaltning av havsvatten, utfällning av klorider och sulfater. o Borttagning av salter från surt vatten från gruvdrift. o Utfällning av salter från PLS-lösningar från gruvdrift. o Behandling av dricksvatten, utfällning av klorider och sulfater. o Behandlling av pannvatten och kylning, avlägsnande av sulfater och klorider. o Behandling av bevattningsresurser, utfällning av klorider och sulfater. o Behandling av bevattningsresurser, utfällning av fosfater och nitrater. o Behandling av avloppsvatten, utfällning av klorider, sulfater och fosfater. o Behandling av avloppsvatten, utfällning av nitrater och nitriter. o Göra salter olösliga itillverkningsprocesser av läkemedel och kemiska reagenseri allmänhet. o Utfällning av salter som förbehandling i ultrafiltrering och processer av omvänd OSmOS DTOCGSSGI". Även om dessa exempel kan vara de mest kända, kan många andra processer dra nytta av fördelarna med att olösliggöra vanligtvis lösliga salter och på detta vis optimera prestanda och/eller renhet hos de erhållna produkterna. Således, 62096 om en process använder en del av eller hela av tekniken av föreliggande uppfinning, omfattas denna av uppfinningen.Possible uses for this technology include, but are not limited to: O Desalination of seawater, precipitation of chlorides and sulphates. o Removal of salts from acidic water from mining. o Precipitation of salts from PLC solutions from mining. o Treatment of drinking water, precipitation of chlorides and sulphates. o Treatment of boiler water and cooling, removal of sulphates and chlorides. o Treatment of irrigation resources, precipitation of chlorides and sulphates. o Treatment of irrigation resources, precipitation of phosphates and nitrates. o Treatment of wastewater, precipitation of chlorides, sulphates and phosphates. o Treatment of wastewater, precipitation of nitrates and nitrites. o Make salts insoluble in manufacturing processes of drugs and chemical reagents in general. o Precipitation of salts as pretreatment in ultrafiltration and reverse OSmOS DTOCGSSGI processes ". Although these examples may be the best known, many other processes may benefit from the insolubilization of usually soluble salts and thus optimize performance and / or purity. Thus, if a process uses part or all of the technique of the present invention, it is encompassed by the invention.
Denna teknik använder sig av ultrafiltrerad likspänning, med en variabel våggeometri av sinustyp, dämpad sågtandspuls, fyrkantvågpuls samt en elektromagnetisk vågsignal av radiospektrum, som tillämpas genom ett par elektroder. Allt detta tillsammans kan förbättra utfällningsreaktionerna.This technology uses ultrafiltered DC voltage, with a sine wave variable wave geometry, attenuated sawtooth pulse, square wave pulse and a radio spectrum electromagnetic wave signal applied through a pair of electrodes. All this together can improve the precipitation reactions.
Dessutom behövs ett föredraget pH-intervall för nämnda utfällning, som bör ligga mellan pH 4 och pH 12. Emellertid kan processen ge goda resultat i vilket intervall som helst av pH-skalan. Senare finns ett skede av isokinetisk koagulation av de utfällda partiklarna, varvid denna koagulation är elektriskt assisterad. Den anbringade spänningen, motsvarande elektriska och magnetiska fält, är även inom ett intervall som bör ligga mellan en och etthundra volt, medan intensiteten av strömförbrukningen bör ligga mellan 'lOmA och 3A. Som nämnts ovan, är spänningen och den elektromagnetiska signalen anbringade genom elektroder som är nedsänkta i lösningen som skall behandlas. Materialet som används för att konstruera dessa elektroder varierar beroende på vattenkvaliteten. Dessa material kan vara: bly, platina, aluminium, koppar, kol, guld, tenn, zink, järn, titan, bor, nickel eller diamant.In addition, a preferred pH range is needed for said precipitation, which should be between pH 4 and pH 12. However, the process can give good results in any range of the pH scale. Later there is a stage of isokinetic coagulation of the precipitated particles, this coagulation being electrically assisted. The applied voltage, corresponding to electric and magnetic fields, is also in a range which should be between one and one hundred volts, while the intensity of the current consumption should be between '10mA and 3A. As mentioned above, the voltage and the electromagnetic signal are applied through electrodes immersed in the solution to be treated. The material used to design these electrodes varies depending on the water quality. These materials can be: lead, platinum, aluminum, copper, carbon, gold, tin, zinc, iron, titanium, boron, nickel or diamond.
Hela processen för att bilda olösliga föreningar görs i en enda enhet, som består av flera element, nämligen: - en reaktor innehållande 1 par elektroder i olika utformning och olika tillverkningsmaterial, insatta längsmed sidan av reaktorn, placerade mitt emot varandra, ansluten till en strömkälla och en källa för magnetisk induktion som finns utanför anordningen, 62096 - ett andra par elektroder i annan utformning och annat tillverkningsmaterial, införda i reaktorn, placerade mitt emot varandra och bredvid det första elektrodparet, kopplande till en frekvensgenerator som finns utanför reaktorn, - ett spiralformat ledande element som finns utanför reaktorn och som är anslutet till strömkälla och en källa för magnetisk induktion, där ström flödar genom detta element vilket genererar specifika magnetfält, - tillförsel av fotonbehandlad luft producerad genom en luftpump och fotonsändare som förs in i reaktorn genom en kappillär placerad intill elektroden som är ansluten till strömkällans negativa pol så att kapillären hamnar så nära botten av reaktorn som möjligt, - en generator för elektriskt och magnetiskt fält samt en justerbar frekvensgenerator som finns utanför reaktorn, - en paddelomrörare med reglerbar hastighet som är placerad i mitten av reaktorn.The whole process of forming insoluble compounds is done in a single unit, which consists of several elements, namely: - a reactor containing 1 pair of electrodes in different designs and different manufacturing materials, inserted along the side of the reactor, placed opposite each other, connected to a power source and a source of magnetic induction located outside the device, 62096 - a second pair of electrodes of a different design and manufacturing material, inserted into the reactor, placed opposite each other and next to the first pair of electrodes, connecting to a frequency generator located outside the reactor, - a helical format conductive elements located outside the reactor and connected to a power source and a source of magnetic induction, where current flows through this element generating specific magnetic fields, - supply of photon-treated air produced by an air pump and photon transmitters introduced into the reactor through a capillary located next to the electrode connected to the power source negative pole so that the capillary ends up as close to the bottom of the reactor as possible, - an electric and magnetic field generator and an adjustable frequency generator located outside the reactor, - an adjustable speed paddle stirrer located in the center of the reactor.
Dessutom kan alla processer utföras i andra faciliteter med mer än en enhet.In addition, all processes can be performed in other facilities with more than one unit.
Utfällningsprocessen inkluderar bestämda tryck- och temperaturvärden inom intervallen 1 och 10 bar respektive 0 till 90°C. Detta beror på att utfällningsprocessen är baserad på en koncentration, vilket innebär en förskjutning av jämviktskonstanten vilken tillåter övermättning. Temperatureffekten påverkar reaktionskinetiken vilket ökar utfällningsprocessen eftersom de molekylära kollisionerna accelererar och därmed ökar den kinetiska konstanten. Tillämpning av yttre tryck leder till samma resultat. Ett tydligt exempel av detta är utfällningen av jarosit, vars bildning ej är 62096 möjlig under normala förhållanden och följaktligen är tillämpningen av dessa variabler är nödvändig.The precipitation process includes determined pressure and temperature values in the ranges of 1 and 10 bar and 0 to 90 ° C, respectively. This is because the precipitation process is based on a concentration, which means a shift of the equilibrium constant which allows supersaturation. The temperature effect affects the reaction kinetics, which increases the precipitation process because the molecular collisions accelerate and thus increase the kinetic constant. Application of external pressure leads to the same result. A clear example of this is the precipitation of jarosit, the formation of which is not possible under normal conditions and consequently the application of these variables is necessary.
KoRT FIGURFÖRTECKNING Figur 1 visar uppfinningens delar och deras sammankopplingar DETALJERAD BESKRIVNING AV UPPFINNINGEN Processen sker i ett enda steg, i en anordning som innefattar en reaktor (1) som innehåller ett par elektroder (2 och 3) anslutna till en strömkälla och en källa för magnetisk induktion (4) och ett andra par elektroder (5 och 6) anslutna till en frekvensgenerator (7). En ström av fotonbehandlad luft innehållande ozon och oxidantfria radikaler förs in i reaktorn via en luftpump (9) som cirkulerar luften genom en fotongenerator (10). Därtill, omger ett spiralformat ledande element (11) reaktorns utsida, genom vilken en ström cirkulerar som genererar specifika magnetfält.BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 shows the parts of the invention and their interconnections DETAILED DESCRIPTION OF THE INVENTION The process takes place in a single step, in a device comprising a reactor (1) containing a pair of electrodes (2 and 3) connected to a current source and a magnetic source. induction (4) and a second pair of electrodes (5 and 6) connected to a frequency generator (7). A stream of photon-treated air containing ozone and oxidant-free radicals is introduced into the reactor via an air pump (9) which circulates the air through a photon generator (10). In addition, a helical conductive element (11) surrounds the outside of the reactor, through which a current circulates which generates specific magnetic fields.
Nämnda element är anslutet till en strömkälla och en källa för magnetisk induktion (4) som genererar ström. Allt rörs om av en mekanisk eller magnetisk omrörare (8), och en kemisk reagens tillsätts för att tillhandahålla de joner som ej finns i vätskan och som är nödvändiga för att fullständiggöra de önskade olösliga komplexen. l de flesta fall är kalcium- och hydroxyljoner i otillräcklig mängd, så företrädesvis används kalk som enda reagens.Said element is connected to a current source and a source of magnetic induction (4) which generates current. Everything is stirred by a mechanical or magnetic stirrer (8), and a chemical reagent is added to provide the ions which are not in the liquid and which are necessary to complete the desired insoluble complexes. In most cases, calcium and hydroxyl ions are insufficient, so preferably lime is used as the sole reagent.
ExEMPEL1: Om vi tar exemplet med tillämpning av processen för avsaltning av havsvatten, är mekanismen som används följande: 62096 Först anbringas en luftblandning som passerar genom fotoner och denna anbringas sedan direkt på havsvattnet. De erhållna kemiska reaktionerna är: 1 , f* ~ šßfthñzafizïtš? “i 293% gfàšë 205- Ovanstående reaktion tillämpas tills pH > 9.8 enheter. Det elektriska fältet appliceras genom aluminiumelektroder som ger en andra elektrolytisk reaktion, som är: .ašfieifiåfrs + ag- Aluminiumet reagerar med OH-jonerna och bildar den första kärnbildningen baserad påföljande reaktion: så” + aozfuíáztafij; När aluminiumhydroxidkärnorna bildats, doseras kalciumhydroxiden och en radiofrekvens med en våglängd om 1,8 MHz anbringas, och sedan bildas följande utfällningsreaktion av sulfat, klorider och fosfater: scafl + aseë-Pf + zaâçasjzemílcaiaä :(5993 (omm in; ages? , j, _ , 3 êfaí” + 2:3 ~E- ZÅštIQI-Iljz -l- QHZÛ -š šífägø- fagššzfšgflííššfjl: Kit Efgøßï Sfiß” -l- 310953 í- QHW-g-fifaflšäügg QH Alternativt kan jonisk koppar bildas genom att, parallellt med bildandet av joniskt aluminium, använda på ett par kopparelektroder för att först bilda reaktionen: Ca” + 26' Nitratet fångas upp från mediet baserat följande reaktioner: czfl s me; ästšraz), fi: å* e eH-eïcura-H), 62096 Med detta och i föregående radiofrekvensmedium och fält bildas följande reaktion: :ica-ia t» zšac; + zcia-amstievogzasarem, Följaktligen har klorider, sulfater, fosfater och nitrater fällts ut. Borttagandet av anjoner innebär avlägsnandet av aluminium, koppar och kalcium. Varje fällning som bildas har en hög adsorptionsförmåga av tungmetaller.EXAMPLE 1: Taking the example of applying the seawater desalination process, the mechanism used is as follows: 62096 First, an air mixture passing through photons is applied and this is then applied directly to the seawater. The chemical reactions obtained are: 1, f * ~ šßfthñza fi zïtš? In 293% gfàšë 205- The above reaction is applied until pH> 9.8 units. The electric field is applied through aluminum electrodes which give a second electrolytic reaction, which is: .aš fi ei fi åfrs + ag- The aluminum reacts with the OH ions and forms the first nucleation based subsequent reaction: so “+ aozfuíázta fi j; When the aluminum hydroxide nuclei are formed, the calcium hydroxide is metered in and a radio frequency with a wavelength of 1.8 MHz is applied, and then the following precipitation reaction of sulphate, chlorides and phosphates is formed: sca fl + aseë-Pf + zaâçasjzemílcaiaä: (5993, omm in; _, 3 êfaí ”+ 2: 3 ~ E- ZÅštIQI-Iljz -l- QHZÛ -š šífägø- fagššzfšg fl ííššfjl: Kit Efgøßï S fi ß” -l- 310953 í- QHW-g- fi fa fl šäütt kopp QH Alternativ with the formation of ionic aluminum, used on a pair of copper electrodes to first form the reaction: Ca '+ 26' The nitrate is captured from the medium based on the following reactions: cz fl s me; ästšraz), fi: å * e eH-eïcura-H), 62096 With this and in the preceding radio frequency medium and field the following reaction is formed:: ica-ia t »zšac; + zcia-amstievogzasarem, Consequently, chlorides, sulfates, phosphates and nitrates have precipitated. The removal of anions means the removal of aluminum, copper and calcium. Each precipitate formed has a high adsorption capacity of heavy metals.
Dessa bildade olösliga föreningar är vanligtvis mikro-fällningar som behöver växa. För att få igång tillväxten induceras en flockning genom att tillsätta en polymer och sedan separation genom dekantering och sedan genom filtrering.These formed insoluble compounds are usually micro-precipitates that need to grow. To initiate growth, flocculation is induced by adding a polymer and then separation by decantation and then by filtration.
Följande tabell visar de drift- och doseringsförhållanden genom vilka erfarenheten med havsvatten från San Antonio (Region V, Chile) utarbetades.The following table shows the operating and dosing conditions through which the experience with seawater from San Antonio (Region V, Chile) was developed.
Intensitet av aluminium 5 mps 1 2 intensitet av koppar 0,1 amps 3 Spänning 0,62 Volt 4 Tid 60 minuter 5 A1 massa 1.679 mg 6 Cu massa 1 19 mg 7 Dos av luft 1,5 Umin 8 Dos av kalk 17,5 g/ L 9 Radiofrekvens 1,5 MHz 10 Tillämpad puls dämpad sågvåg 11 Provvolym 0,75 L 12 Dos av aluminiumoxid 4,85 g/ L 13 Total energi 3,1 Watts-h Följande tabell visar de uppnådda verkningsgraderna vid avlägsnandet av salt från havsvattnet. Tabellen visar kolumnen obehandlad, som anger kvaliteten på havsvattnet. Kolumnen Behandlad anger värdet efter flockning och filtrering genom sand och kol. Kolumnen % Avlägsnad anger det erhållna värdet.Intensity of aluminum 5 mps 1 2 Intensity of copper 0.1 amps 3 Voltage 0.62 Volt 4 Time 60 minutes 5 A1 mass 1,679 mg 6 Cu mass 1 19 mg 7 Dose of air 1.5 Umin 8 Dose of lime 17.5 g / L 9 Radio frequency 1.5 MHz 10 Applied pulse attenuated saw wave 11 Sample volume 0.75 L 12 Dose of alumina 4.85 g / L 13 Total energy 3.1 Watts-h The following table shows the efficiencies achieved in removing salt from the sea water. The table shows the column untreated, which indicates the quality of the seawater. The Treated column indicates the value after flocculation and filtration through sand and coal. The% Removed column indicates the value obtained.
Kloridcr mg/L 19.500 2.650 86,4% Sulfater mg/L 2.850 327 88,5% 62096 Nitrater mg/L 220 25 88,6% Fosfater mg/L 78 5 916% Exempel 2: Ett annat exempel på saltutfällning är olösliggörande av sulfater i gruvdriftsvatten.Chloride mg / L 19,500 2,650 86.4% Sulfates mg / L 2,850 327 88.5% 62096 Nitrates mg / L 220 25 88.6% Phosphates mg / L 78 5 916% Example 2: Another example of salt precipitation is the insolubilization of sulphates in mining waters.
För detta togs ett prov från Collahuasi-gruvans vatten med en ursprunglig halt av sulfater om 5.200 mg/L.For this, a sample was taken from the water of the Collahuasi mine with an initial sulphate content of 5,200 mg / L.
Det använda komplexet var utfällningen, såsom natrlumjarosit. šffläzsíïflehtfilih] Element M kan vara natrium eller kalium. För detta har vi använt följande mekanism.The complex used was the precipitate, such as sodium lumenite. šf fl äzsíï fl eht fi lih] Element M can be sodium or potassium. For this we have used the following mechanism.
Först anbringas en luftblandning som får passera genom fotoner och som sedan appliceras direkt på havsvattnet. De erhållna reaktionerna är: ššyåvêfišfi 22,625 -šøz effich eaffe eefi- Föregående reaktion tillämpas tills pH > 9,8 enheter. Det elektriska fältet anbringas genom aluminumelektroder, vilket ger en andra elektrolytisk reaktion vilken är: .âsníeästfi + så' Aluminiumet reagerar med OH-jonerna och bildar den första kärnbildningen baserad på följande reaktion: egt* + sofz-fíílåzrafr), Vid jämvikt bildas aluminiumhydroxidkärnor och som sedan fälls ut som jarosit i mediet med radiofrekvens och elektriskt fält. 62096 išßêäá Efe aa šfí* -l- Záålflêfílg ~E 259; -l- åšfi-i- åflÅåQSQQÉIIQHR] Driftsförhållandena är: Pl intensitet av amps aluminium Spänning Volt Tid minuter Al-massa mg Dos av lufi 11min Radiofrekvens MHz Tillämpad puls sågvåg Provvolym L Total energi Watts-h KW \OGO\IG\UI-BUJN De uppnådda resultaterna är: Sulfater mg/L På detta vis kan olika olösliga element formas för att minska salterna. 10First, an air mixture is applied which is allowed to pass through photons and which is then applied directly to the seawater. The reactions obtained are: ššyåvê fi š fi 22,625 -šøz effich eaffe eefi- The previous reaction is applied until pH> 9.8 units. The electric field is applied by aluminum electrodes, which gives a second electrolytic reaction which is: .sníeäst fi + so 'The aluminum reacts with the OH ions and forms the first nucleation based on the following reaction: egt * + sofz-fíílåzrafr), At equilibrium aluminum hydroxide nuclei are formed which then precipitates as jarosit in the medium with radio frequency and electric field. 62096 išßêäá Efe aa šfí * -l- Záål fl êfílg ~ E 259; -l- åš fi- i- å fl ÅåQSQQÉIIQHR] The operating conditions are: Pl intensity of amps aluminum Voltage Volt Time minutes Al-mass mg Dose of lu fi 11min Radio frequency MHz Applied pulse saw wave Sample volume L Total energy Watts-h KW \ OGO \ IG \ UI-BUJN The results obtained are: Sulfates mg / L In this way, various insoluble elements can be formed to reduce the salts. 10
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| CL2008002879A CL2008002879A1 (en) | 2008-09-26 | 2008-09-26 | Device for the formation of insoluble chemical compounds in a liquid medium comprising a) a reactor containing a pair of electrodes and a second pair of electrodes, b) spiral-shaped conductor element, c) blower pump and photon emitter, d) generator of an electric / magnetic field, e) agitation medium; and method. |
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| CN108854798A (en) * | 2018-09-03 | 2018-11-23 | 上海卉沛生物科技有限公司 | A kind of radio frequency emulsifying device used for cosmetic |
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