SA519410752B1 - Method for producing ethyleneamines - Google Patents

Method for producing ethyleneamines

Info

Publication number
SA519410752B1
SA519410752B1 SA519410752A SA519410752A SA519410752B1 SA 519410752 B1 SA519410752 B1 SA 519410752B1 SA 519410752 A SA519410752 A SA 519410752A SA 519410752 A SA519410752 A SA 519410752A SA 519410752 B1 SA519410752 B1 SA 519410752B1
Authority
SA
Saudi Arabia
Prior art keywords
catalyst
elements
active metals
amination
groups
Prior art date
Application number
SA519410752A
Other languages
Arabic (ar)
Inventor
ريجين هيلجا بيبينسى
باربارا بيكير
افا كوش
هيرمان لويكين
جوهان بيتير ميلدير
توماس هيديمان
Original Assignee
باسف اس اي
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by باسف اس اي filed Critical باسف اس اي
Publication of SA519410752B1 publication Critical patent/SA519410752B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C215/00—Compounds containing amino and hydroxy groups bound to the same carbon skeleton
    • C07C215/02—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C215/04—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated
    • C07C215/06—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated and acyclic
    • C07C215/08—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated and acyclic with only one hydroxy group and one amino group bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872—Details of the fluidised bed reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The invention relates to processes for preparing alkanolamines and ethyleneamines in the liquid phase, by reacting ethylene glycol and/or monoethanolamine with ammonia in the presence of an amination catalyst comprising one or more active metals selected from Sn and the elements of groups 8, 9, 10 and 11 of the Periodic Table of the Elements, wherein the amination catalyst is obtained by reductive calcination of a catalyst precursor. The catalyst precursor here is preferably prepared by contacting a conventional or catalytic support material with one or more soluble compounds of the active metals and optionally one or more soluble compounds of added catalyst elements. The present invention further relates to a process for preparing an amination catalyst comprising one or more active metals selected from Sn and the elements of groups 8, 9, 10 and 11 of the Periodic Table of the Elements, the amination catalyst being obtained by reductive calcination of a catalyst precursor, wherein the
SA519410752A 2017-06-09 2019-12-08 Method for producing ethyleneamines SA519410752B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP17175151 2017-06-09
PCT/EP2018/063589 WO2018224315A1 (en) 2017-06-09 2018-05-24 Method for producing ethyleneamines

Publications (1)

Publication Number Publication Date
SA519410752B1 true SA519410752B1 (en) 2022-07-16

Family

ID=59034559

Family Applications (1)

Application Number Title Priority Date Filing Date
SA519410752A SA519410752B1 (en) 2017-06-09 2019-12-08 Method for producing ethyleneamines

Country Status (7)

Country Link
US (1) US11214535B2 (en)
EP (1) EP3634934B1 (en)
JP (1) JP7105813B2 (en)
CN (1) CN110709380A (en)
BR (1) BR112019025307B1 (en)
SA (1) SA519410752B1 (en)
WO (1) WO2018224315A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112019025633B1 (en) * 2017-06-09 2023-05-09 Basf Se PROCESS FOR THE PREPARATION OF ALKANOLAMINES AND/OR ETHYLENEAMINES
WO2019081285A1 (en) 2017-10-27 2019-05-02 Basf Se Method for producing ethyleneamines
JP7268017B2 (en) 2017-10-27 2023-05-02 ビーエーエスエフ ソシエタス・ヨーロピア Method for producing ethyleneamine
CN116440893B (en) * 2022-01-06 2024-06-18 中国科学院大连化学物理研究所 Catalyst, preparation method thereof and application of catalyst in preparation of acetonitrile by ammonification and dehydrogenation of ethanol
WO2023135035A1 (en) 2022-01-14 2023-07-20 Basf Se Method for the manufacture or conversion of alkanolamines
WO2024002740A1 (en) 2022-06-29 2024-01-04 Basf Se Method for manufacture of ethyleneamines
WO2024002748A1 (en) 2022-06-29 2024-01-04 Basf Se Method for manufacture of ethyleneamines

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3137730A (en) 1960-04-12 1964-06-16 Allied Chem Production of ethylenediamine
DE1172268B (en) 1962-02-21 1964-06-18 Basf Ag Process for the production of diamines
US4123462A (en) 1976-01-07 1978-10-31 Union Carbide Corporation Amination process using nickel-rhenium catalysts
SE461095B (en) 1983-09-09 1990-01-08 Berol Kemi Ab AMINING PROCEDURE USING A RUTENIUM DOPPED NICKEL AND / OR COVOLT CATALYST
US4653677A (en) 1985-04-16 1987-03-31 The Dow Chemical Company Vessel having a molten material outlet
US4806690A (en) * 1985-05-13 1989-02-21 The Dow Chemical Company Method of producing amines
US5817593A (en) 1995-06-02 1998-10-06 The Dow Chemical Company Catalyst and process for producing amines
DE19644107A1 (en) * 1996-10-31 1998-05-07 Basf Ag Catalysts for the amination of alkylene oxides, alcohols, aldehydes and ketones
DE19645047A1 (en) * 1996-10-31 1998-05-07 Basf Ag Catalysts for the amination of alkylene oxides, alcohols, aldehydes and ketones
WO2000006756A1 (en) 1998-07-28 2000-02-10 E.I. Du Pont De Nemours And Company Sulfur metabolism enzymes
EP1106600B1 (en) 1999-12-06 2004-08-04 Basf Aktiengesellschaft Process for the preparation of amines
DE102004023529A1 (en) 2004-05-13 2005-12-08 Basf Ag Process for the continuous production of an amine
JP4938802B2 (en) 2006-02-14 2012-05-23 ビーエーエスエフ ソシエタス・ヨーロピア Process for producing ethyleneamine and ethanolamine from monoethylene glycol (MEG)
JP4761461B2 (en) * 2006-06-07 2011-08-31 旭化成ケミカルズ株式会社 Nb-based oxide catalyst and method for producing unsaturated compound using the same
EP2061747B1 (en) 2006-07-14 2013-04-17 Basf Se Method for producing an amine
JP5637684B2 (en) 2006-07-14 2014-12-10 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Method for producing amine
JP4985773B2 (en) 2007-07-09 2012-07-25 富士通株式会社 User authentication device, user authentication method, and user authentication program
EP2225027B1 (en) 2007-12-21 2012-05-23 Basf Se Method for producing an amine
WO2009080510A1 (en) 2007-12-21 2009-07-02 Basf Se Method for the production of an amine
ATE553844T1 (en) 2007-12-21 2012-05-15 Basf Se METHOD FOR PRODUCING AN AMINE
EP2346602B1 (en) 2008-09-19 2014-03-19 Basf Se Method for the continuous production of an amine using an aluminium-copper catalyst
CN102639231B (en) 2009-12-03 2014-12-10 巴斯夫欧洲公司 Catalyst and method for producing an amine
CN102781571B (en) 2009-12-03 2015-06-17 巴斯夫欧洲公司 Catalyst and method for producing an amine
CN102190588A (en) 2010-03-16 2011-09-21 张家港惠尔化学科技有限公司 Method for preparing ethylenediamine from glycol and ammonia
CN102233272A (en) 2010-04-22 2011-11-09 张家港惠尔化学科技有限公司 Catalyst for preparing ethylene diamine through amination of ethylene glycol and preparation method thereof
CN103945935B (en) * 2011-11-17 2016-10-19 巴斯夫欧洲公司 Produce the method containing Sn catalyst
BR112019025633B1 (en) * 2017-06-09 2023-05-09 Basf Se PROCESS FOR THE PREPARATION OF ALKANOLAMINES AND/OR ETHYLENEAMINES

Also Published As

Publication number Publication date
EP3634934A1 (en) 2020-04-15
BR112019025307B1 (en) 2023-05-09
US20200102262A1 (en) 2020-04-02
US11214535B2 (en) 2022-01-04
BR112019025307A2 (en) 2020-06-23
EP3634934B1 (en) 2022-04-06
CN110709380A (en) 2020-01-17
WO2018224315A1 (en) 2018-12-13
JP7105813B2 (en) 2022-07-25
JP2020522547A (en) 2020-07-30

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