RU99128077A - HIGH STRENGTH POLYMER COMPOSITION - Google Patents
HIGH STRENGTH POLYMER COMPOSITIONInfo
- Publication number
- RU99128077A RU99128077A RU99128077/04A RU99128077A RU99128077A RU 99128077 A RU99128077 A RU 99128077A RU 99128077/04 A RU99128077/04 A RU 99128077/04A RU 99128077 A RU99128077 A RU 99128077A RU 99128077 A RU99128077 A RU 99128077A
- Authority
- RU
- Russia
- Prior art keywords
- composition
- copolymers
- composition according
- block
- vinylarene
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims 2
- 229920001577 copolymer Polymers 0.000 claims 6
- 150000001993 dienes Chemical class 0.000 claims 6
- 239000004793 Polystyrene Substances 0.000 claims 4
- 229920001400 block copolymer Polymers 0.000 claims 4
- 229920002223 polystyrene Polymers 0.000 claims 4
- 229920005605 branched copolymer Polymers 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 1
- 125000002897 diene group Chemical group 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 229920005684 linear copolymer Polymers 0.000 claims 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
Claims (1)
(1) 30 - 95% полистирола,
(2) 70 - 5% композиции блоксополимеров виниларена и сопряженного диена,
причем сумма процентов (1) и (2) равна 100, высокопрозрачная композиция (2) по существу состоит из:
(2а) 30 - 60 мас.% сополимеров с линейной структурой;
(2б) 70 - 40 мас.% сополимеров с разветвленной структурой;
среднемассовая мол. мас. вышеописанной композиции (2) находится в интервале от 30000 до 400000, предпочтительно от 50000 до 200000.1. A highly transparent composition essentially consisting of:
(1) 30 to 95% polystyrene,
(2) 70 to 5% of the composition of block copolymers of vinylarene and conjugated diene,
wherein the sum of percent (1) and (2) is 100, the highly transparent composition (2) essentially consists of:
(2a) 30-60 wt.% Copolymers with a linear structure;
(2b) 70 to 40 wt.% Copolymers with a branched structure;
mass average mol. wt. the above composition (2) is in the range from 30,000 to 400,000, preferably from 50,000 to 200,000.
(2а) от 35 до 50% сополимеров с линейной структурой;
(2b) от 65 до 50% сополимеров с разветвленной структурой;
4. Композиция по п.1, в которой виниларен представляет собой стирол, а сопряженный диен представляет собой С4- или C5-диен.3. The composition according to claim 1, in which the composition (2) essentially consists of:
(2a) from 35 to 50% of linear copolymers;
(2b) from 65 to 50% of branched copolymers;
4. The composition of claim 1, wherein the vinylarene is styrene and the conjugated diene is a C 4 or C 5 diene.
(i) Сополимеры с линейной структурой (2а) имеют структуру типа В-Т-А;
(ii) Сополимеры с разветвленной структурой (2b) имеют общую формулу (I):
где А - поливинилареновый блок;
b - мономерное звено сопряженного диена;
Т - статистический сополимер, состоящий из виниларена и сопряженного диена;
х - число мономерных звеньев, которые образуют полидиеновый блок В;
В - полидиеновый блок;
n и m - число разветвлений сополимера, причем сумма n+m находится в пределах от 1 до 5;
В-Т-А - это частично блочный сополимер, привитый на полидиеновую функциональную группу -(-b-)х- или на диеновые звенья статистического сополимера Т.8. The composition according to claim 1, in which:
(i) Copolymers with a linear structure (2a) have a structure of type B-T-A;
(ii) Branched copolymers (2b) have the general formula (I):
where A is a polyvinylarene block;
b is the monomer unit of the conjugated diene;
T is a statistical copolymer consisting of vinylarene and a conjugated diene;
x is the number of monomer units that form the polydiene block B;
B is a polydiene block;
n and m are the number of branches of the copolymer, and the sum of n + m is in the range from 1 to 5;
B-T-A is a partially block copolymer grafted onto the polydiene functional group - (- b-) x - or onto the diene units of statistical copolymer T.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI98A002769 | 1998-12-22 | ||
IT1998MI002769A IT1304497B1 (en) | 1998-12-22 | 1998-12-22 | HIGH TRANSPARENCY POLYMERIC COMPOSITION. |
Publications (2)
Publication Number | Publication Date |
---|---|
RU99128077A true RU99128077A (en) | 2001-09-27 |
RU2237687C2 RU2237687C2 (en) | 2004-10-10 |
Family
ID=11381300
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU99128077A RU2237687C2 (en) | 1998-12-22 | 1999-12-22 | Polymeric composition with high transparency |
Country Status (18)
Country | Link |
---|---|
US (1) | US6867258B2 (en) |
EP (1) | EP1013712B1 (en) |
JP (1) | JP4672100B2 (en) |
AT (1) | ATE259859T1 (en) |
BG (1) | BG64287B1 (en) |
CA (1) | CA2292137C (en) |
CZ (1) | CZ300839B6 (en) |
DE (1) | DE69914869T2 (en) |
ES (1) | ES2215361T3 (en) |
HR (1) | HRP990390B1 (en) |
HU (1) | HU224707B1 (en) |
IT (1) | IT1304497B1 (en) |
NO (1) | NO321515B1 (en) |
PL (1) | PL196195B1 (en) |
RU (1) | RU2237687C2 (en) |
SK (1) | SK285482B6 (en) |
TR (1) | TR199903203A3 (en) |
UA (1) | UA69384C2 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2739903C (en) | 2008-10-07 | 2016-12-06 | Ross Technology Corporation | Highly durable superhydrophobic, oleophobic and anti-icing coatings and methods and compositions for their preparation |
MX2012010669A (en) | 2010-03-15 | 2013-02-07 | Ross Technology Corp | Plunger and methods of producing hydrophobic surfaces. |
EP2678400A4 (en) | 2011-02-21 | 2015-11-18 | Ross Technology Corp | Superhydrophobic and oleophobic coatings with low voc binder systems |
EP2791255B1 (en) | 2011-12-15 | 2017-11-01 | Ross Technology Corporation | Composition and coating for superhydrophobic performance |
BR112014032676A2 (en) * | 2012-06-25 | 2017-06-27 | Ross Tech Corporation | elastomeric coatings that have hydrophobic and / or oleophobic properties |
WO2015041326A1 (en) * | 2013-09-20 | 2015-03-26 | Psジャパン株式会社 | Vinyl aromatic hydrocarbon polymer composition and method for producing vinyl aromatic hydrocarbon polymer composition |
TW201527067A (en) * | 2013-09-20 | 2015-07-16 | Ps Japan Corp | Extrude foam body and container |
JP6258088B2 (en) * | 2014-03-17 | 2018-01-10 | Psジャパン株式会社 | Biaxially stretched sheet |
JP6262577B2 (en) * | 2014-03-17 | 2018-01-17 | Psジャパン株式会社 | Biaxially stretched sheet |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5943059B2 (en) * | 1977-10-27 | 1984-10-19 | 新日鐵化学株式会社 | Styrenic resin composition with improved transparency |
DE3049186A1 (en) * | 1980-12-24 | 1982-07-29 | Basf Ag, 6700 Ludwigshafen | Biaxially drawn styrene!-butadiene! block copolymer foil prodn. - from linear or branched copolymer opt. mixed with polystyrene or polyphenylene oxide |
DE3816294A1 (en) | 1988-05-13 | 1989-11-23 | Basf Ag | TRANSPARENT, THERMOPLASTIC SHAPING MATERIAL, METHOD FOR THEIR PRODUCTION AND THEIR USE |
GB2232677B (en) | 1989-06-08 | 1993-06-30 | Labofina Sa | Polymeric material composition |
JP2986178B2 (en) * | 1990-06-04 | 1999-12-06 | 電気化学工業株式会社 | Block copolymer resin composition |
JP3103384B2 (en) * | 1991-02-15 | 2000-10-30 | 旭化成工業株式会社 | Block copolymer resin composition |
JPH0717809B2 (en) * | 1991-10-17 | 1995-03-01 | 旭化成工業株式会社 | Block copolymer resin composition |
JP3332281B2 (en) * | 1994-01-31 | 2002-10-07 | 電気化学工業株式会社 | Transparent high-strength resin composition |
US5596041A (en) | 1994-04-04 | 1997-01-21 | Japan Synthetic Rubber Co., Ltd. | Hydrogenated block copolymer and hydrogenated block copolymer compositon |
IT1269803B (en) * | 1994-05-20 | 1997-04-15 | Enichem Elastomers | HOT MELT ADHESIVE COMPOSITION FOR LABELS |
JPH0966554A (en) * | 1995-08-31 | 1997-03-11 | Daicel Chem Ind Ltd | Production of transparent styrenic sheet and film |
JPH09324084A (en) * | 1996-06-05 | 1997-12-16 | Denki Kagaku Kogyo Kk | Block copolymer resin composition, molded item, and its production |
DE19810141A1 (en) * | 1998-03-10 | 1999-09-16 | Basf Ag | Elastomeric polymer mixture with good tearing resistance and stiffness for fiber, film and molded article |
IT1302040B1 (en) * | 1998-09-04 | 2000-07-20 | Enichem Spa | HYDROGENATED BLOCK COPOLYMERS HAVING A PARTIALLY BRANCHED STRUCTURE. |
-
1998
- 1998-12-22 IT IT1998MI002769A patent/IT1304497B1/en active
-
1999
- 1999-12-15 BG BG104014A patent/BG64287B1/en unknown
- 1999-12-15 NO NO19996212A patent/NO321515B1/en not_active IP Right Cessation
- 1999-12-15 CA CA002292137A patent/CA2292137C/en not_active Expired - Lifetime
- 1999-12-16 ES ES99204355T patent/ES2215361T3/en not_active Expired - Lifetime
- 1999-12-16 DE DE69914869T patent/DE69914869T2/en not_active Expired - Lifetime
- 1999-12-16 EP EP99204355A patent/EP1013712B1/en not_active Expired - Lifetime
- 1999-12-16 AT AT99204355T patent/ATE259859T1/en active
- 1999-12-17 HR HR990390A patent/HRP990390B1/en not_active IP Right Cessation
- 1999-12-17 CZ CZ0461999A patent/CZ300839B6/en not_active IP Right Cessation
- 1999-12-20 UA UA99126957A patent/UA69384C2/en unknown
- 1999-12-21 PL PL337356A patent/PL196195B1/en unknown
- 1999-12-21 SK SK1831-99A patent/SK285482B6/en not_active IP Right Cessation
- 1999-12-21 HU HU9904690A patent/HU224707B1/en active IP Right Grant
- 1999-12-22 RU RU99128077A patent/RU2237687C2/en active
- 1999-12-22 TR TR1999/03203A patent/TR199903203A3/en unknown
- 1999-12-22 JP JP36530999A patent/JP4672100B2/en not_active Expired - Lifetime
-
2002
- 2002-09-23 US US10/251,854 patent/US6867258B2/en not_active Expired - Lifetime
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