RU99119226A - 2,4-DIAMINO-1,3,5-TRIAZINES, METHOD FOR THEIR PRODUCTION AND THEIR APPLICATION AS HERBICIDES AND PLANT GROWTH REGULATORS - Google Patents

Claims (10)

1. The compounds of formula (I) and their salts

where R ¹ means alkyl with 1 to 6 carbon atoms, unsubstituted or substituted by one or more residues from the group including halogen, hydroxyl, cyano, nitro, thiocyanato, alkoxy with 1-4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, alkenyl with 2 to 4 carbon atoms, alkynyl with 2 to 4 carbon atoms, and unsubstituted or substituted phenyl, or unsubstituted or substituted phenyl,
R ² and R ³ independently of one another denote hydrogen, amino, alkylamino with 1 to 6 carbon atoms or dialkylamino with 1 to 6 carbon atoms in the alkyl part, a hydrocarbon residue or an oxygen-containing hydrocarbon residue, each with 1 to 10 carbon atoms, preferably with 1 to 6 carbon atoms, or a heterocyclic residue, an oxygen-containing heterocyclic residue or an amino-containing heterocyclic residue, each with 3 to 9 ring atoms and 1 to 3 heteroatoms from the group comprising nitrogen, oxygen and sulfur, each of the last five the tissue is unsubstituted or substituted, or the acyl residue, or
R ² and R ³ together with the nitrogen atom of the group NR ² R ³ means a 3-6-membered heterocyclic residue with 1-4 heteroatoms, and in addition to the nitrogen atom, further heteroatoms are optionally selected from the group of nitrogen, oxygen and sulfur, and the residue is unsubstituted or substituted;
R ⁴ is hydrogen, an amino group, an alkylamino group with 1 to 6 carbon atoms, a dialkylamino group with 1 to 6 carbon atoms in the alkyl part, a hydrocarbon residue or an oxygen-containing hydrocarbon residue, each with 1 to 10 carbon atoms, preferably 1 to 6 carbon atoms, or a heterocyclic residue, an oxygen-containing heterocyclic residue or an amino-containing heterocyclic residue, each with 3 to 9 ring atoms and 1 to 3 heteroatoms from the group including nitrogen, oxygen and sulfur, and each of the last five residues is unsubstituted or displacements or acyl residue;
R ⁵ and R ⁶ independently of one another denote halogen, nitro, cyano, thio-cyanato or a residue of the formula-X ¹ -A ¹ , where -X ¹ means a direct bond or divalently groups of the formula -O-, -S (O) _p -O-, -O-S (O) _p -, -CO-, -O-CO-, -CO-O-, -NR'-, -O-NR'-, -NR'-O-, - NR'-CO- or -CO-NR'-, and in formulas p represents 0, 1 or 2, R'-hydrogen, alkyl with 1-6 carbon atoms, phenyl, benzyl, cycloalkyl with 3-6 carbon atoms or alkanoyl with 1 to 6 carbon atoms, and A ¹ is hydrogen or a hydrocarbon residue or a heterocyclic residue, each of the last two residues being unsubstituted or substituted, or
R ⁵ and R ⁶ together represent an alkylene chain with 2 to 4 carbon atoms, unsubstituted or substituted by one or more residues from the group consisting of halogen, alkyl with 1 to 4 carbon atoms and an oxo group;
R ⁷ independently of other residues R ⁷ means halogen, nitro, cyano, thiocyanato or a residue of the formula -X ² A ² , where X ² means a direct bond or divalently group of the formula -O-, -S (O) _q -O-, - O-S (O) _q -, -CO-, -O-CO-, -CO-O-, -NR "-, -O-NR" -, -NR "-O-, -NR" -CO- or -CO-NR "-, and in the formulas, q means 0, 1 or 2, R" is hydrogen, alkyl with 1-6 carbon atoms, phenyl, cycloalkyl with 3-6 carbon atoms, and
A ¹ is hydrogen or a hydrocarbon residue or a heterocyclic residue, each of the last two residues is unsubstituted or substituted, or two adjacent radicals R ⁷ together denote a fused ring with 4-6 ring atoms that is carbocyclic or contains heteroatoms from the group including oxygen, sulfur and nitrogen, and which is unsubstituted or substituted by one or more residues from the group including halogen, alkyl with 1-4 carbon atoms and oxygen,
X means a group of the formula -O-, S (O) _r -, -NR * - or -N (O) -, moreover, r means 0, 1 or 2, R * is hydrogen or alkyl with 1 to 4 carbon atoms, and
n is 0, 1, 2, 3, 4 or 5,
with the exception of compounds of formula (I) and their salts,
a) where R ¹ is 1-haloethyl, 1-halogen-1-methyl-ethyl or 1-halogen-1-methyl-propyl, R ² , R ³ , R ⁴ , R ^{6 are} each hydrogen, R ⁵ is methyl, R ⁷ is alkyl with 1-4 carbon atoms, OCH ₃ or fluorine, and if n equals 2, both R ⁷ radicals have the same value, n is the number 0, 1 or 2, X is an oxygen atom, and
b) where R ¹ is alkyl with 1 to 10 carbon atoms, unsubstituted or substituted with 1 to 4 substituents from the group consisting of alkoxy with 1 to 4 carbon atoms and hydroxyl, R ² , R ³ , R ⁴ , R ⁶ means each hydrogen, R ⁵ is methyl, R ^{7 is} independent of other radicals R ⁷ means alkyl with 1-4 carbon atoms, OCH ₃ or halogen, n is the number 0, 1, 2, 3 or 4, and X is an oxygen atom. 2. The compounds of formula (I) and their salts according to claim 1, characterized in that R ¹ is alkyl with 1-4 carbon atoms, which is unsubstituted or substituted by one or more residues from the group comprising halogen, hydroxyl, alkoxy with 1 - 4 carbon atoms, alkylthio with 1-4 carbon atoms, alkylsulfonyl with 4-4 carbon atoms and phenyl, or phenyl, which is unsubstituted or substituted, R ² and R ³ independently of one another denote hydrogen, amino or alkylamino group with 1 to 4 atoms carbon, dialkylamino with 1 to 4 carbon atoms in the alkyl part, a hydrocarbon residue or a xyrocarbon residue, each with 1-6 carbon atoms, or a heterocyclic residue, an oxyheterocyclic residue or an amino heterocyclic residue, each of the last five residues is unsubstituted or substituted by one or more residues from the group comprising halogen, alkoxyl with 1-4 carbon atoms, haloalkoxy with 1 to 4 carbon atoms, alkylthio group with 1 to 4 carbon atoms, alkenyl with 2 to 4 carbon atoms, alkynyl with 2 to 4 carbon atoms, alkenyloxy with 2 to 4 carbon atoms, alkynyloxyl with 2 to 4 carbon atoms, hydroxyl, ami foot group, acylamino group, mono- and dialkylamino group with 1-4 carbon atoms in the alkyl part, nitro group, carboxyl, cyano group, azido group, alkoxycarbonyl with 1-4 carbon atoms in the alkoxy part, alkylcarbonyl with 1-4 carbon atoms in the alkyl part, formyl, carbamoyl, mono- and dialkylaminocarbonyl with 1-4 carbon atoms in the alkyl part, alkylsulfinyl with 1-4 carbon atoms, haloalkylsulfinyl with 1-4 carbon atoms, alkylsulfonyl with 1-4 carbon atoms, haloalkylsulfonyl with 1-4 carbon atoms and case of cyclical stop tkov and alkyl having 1 - 4 carbon atoms and haloalkyl with 1 - 4 carbon atoms, or acyl radical, or R ² and R ³ together with the nitrogen atom of the group NR ² R ³ is 3 - 6 membered heterocyclic radical with 1 - 2 heteroatoms, in addition to the nitrogen atom, if necessary, a further heteroatom is selected from the group of nitrogen, oxygen and sulfur, and the residue is unsubstituted or substituted by one or more residues from the group consisting of halogen, alkyl with 1 to 4 carbon atoms and an oxo group, R ⁴ is hydrogen, amino group, mono- or dialkylamino group with 1-6 carbon atoms in alkyl In part, a hydrocarbon residue or an oxygen-containing hydrocarbon residue, each with 1-6 carbon atoms, or a heterocyclic residue, an oxygen-containing heterocyclic residue or an amino-containing heterocyclic residue, each of the last five residues is unsubstituted or substituted by one or more residues from the group comprising halogen, alkoxy with 1 to 4 carbon atoms, haloalkoxy with 1 to 4 carbon atoms, alkylthio group with 1 to 4 carbon atoms, alkenyl with 2 to 4 carbon atoms, alkynyl with 2 to 4 carbon atoms, alke niloxyl with 2 to 4 carbon atoms, alkynyloxy with 2 to 4 carbon atoms, hydroxyl, amino group, acylamino group, mono- and dialkylamino group with 1 to 4 carbon atoms in the alkyl part, nitro group, carboxyl, cyano group, azido group, alkoxycarbonyl with 1 to 4 atoms carbon in the alkoxy part, alkylcarbonyl with 1-4 carbon atoms in the alkyl part, formyl, carbamoyl, mono- and dialkylaminocarbonyl with 1-4 carbon atoms in the alkyl part, alkylsulfinyl with 1-4 carbon atoms, haloalkylsulfinyl with 1-4 carbon atoms, alkylsulfonyl with 1 to 4 atoms and carbon, haloalkylsulfonyl with 1-4 carbon atoms, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxyl and, in the case of cyclic residues, and alkyl with 1-4 carbon atoms and haloalkyl with 1-4 carbon atoms, or acyl residue R ⁵ and R ⁶ independently of one another means halogen, nitro, cyano, thiocyanato or a residue of the formula —X ¹ -A ¹ , where X ¹ means a direct bond or divalently groups of the formula —O—, —S—, —CO—, —O — CO -, -CO-O-, -NR'-, -NR'-CO- or -CO-NR'-, and in the formulas R 'is hydrogen or alkyl with 1-6 carbon atoms, and where A ¹ is hydrogen or acyclic cue hydrocarbon residue with 1 to 6 carbon atoms, cyclic hydrocarbon residue with 3 to 6 carbon atoms or a heterocyclic residue with 3 to 6 ring atoms and 1 to 3 heteroatoms from the group including nitrogen, oxygen and sulfur, each of the last three residues is unsubstituted or substituted by one or more residues from the group comprising halogen, alkoxy with 1-4 carbon atoms, haloalkoxy with 1-4 carbon atoms, alkylthio group with 1-4 carbon atoms, alkenyl with 2-4 carbon atoms, alkynyl with 2-4 atoms carbon, alkenyloxy with 2 - 4 carbon atoms, alkynyloxy with 2-4 carbon atoms, hydroxyl, amino group, acylamino group, mono- and dialkylamino group with 1-4 carbon atoms in the alkyl part, cycloalkylamino group with 3-6 carbon atoms, nitro group, carboxyl, cyano group, azido group, unsubstituted or substituted heterocyclyl, alkoxycarbonyl with 1-4 carbon atoms in the alkoxy part, alkylcarbonyl with 1-4 carbon atoms in the alkyl part, formyl, carbamoyl, mono- and dialkylaminocarbonyl with 1-4 carbon atoms in the alkyl part, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy, unsubstituted or substituted phenylcarbonyl alkylsulfinyl with 1 to 4 carbon atoms, haloalkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, haloalkylsulfonyl with 1 to 4 carbon atoms and, in the case of cyclic residues, and alkyl with 1 to 4 carbon atoms and haloalkyl with 1 to 4 carbon atoms, or R ⁵ and R ⁶ together mean an alkylene chain with 2 to 4 carbon atoms, unsubstituted or substituted by one or more residues from the group comprising halogen, alkyl with 1 to 4 atoms carbon and oxog Upp, (R ⁷ ) _n n means residues R ⁷ that, if n = 2, 3, 4 or 5, are the same or different, and R ⁷ means halogen, nitro, cyano, thiocyanato or a residue of the formula -X ² A ² , where X ² means a direct bond or divalent group of the formula -O-, -S (O) _q -, -S (O) _q -O-, -OS (O) _q -, -CO-, -O-CO-, -CO-O-, -NR "-, -O-NR" -, -NR "-O-, -NR" -CO- or -CO-NR "-, moreover, in the formulas q - 0, 1, 2, and R "is hydrogen, alkyl with 1-6 carbon atoms, phenyl or cycloalkyl with 3-6 carbon atoms, and where A ² is hydrogen or alkyl with 1-6 carbon atoms, alkenyl with 2-6 carbon atoms, alkynyl with 2 - 6 carbon atoms, cycloalkyl with 3 - 6 carbon atoms, cyclo 3-6 carbon atoms, phenyl or heteroaryl, each of the last seven residues is unsubstituted or substituted by one or more residues from the group comprising halogen, hydroxyl, nitro, cyano, amino, acylamino, aminocarbonyl, mono- and dialkylamino with 1 to 4 carbon atoms in the alkyl part, mono- and dialkylamino-carbonyl with 1 to 4 carbon atoms in the alkyl part, cycloalkyl with 3 to 6 carbon atoms, cycloalkoxy with 3 to 6 carbon atoms, alkoxyl with 1 to 6 carbon atoms, alkylthio group with 1 to 6 carbon atoms, 1-6 carbon atoms, alkylcarbonyl 1-6 carbon atoms, alkoxycarbonyl 1-6 carbon atoms, alkylcarbonyloxy 1-6 carbon atoms, cycloalkylcarbonyl 3-6 carbon atoms, phenyl, phenoxy, phenylcarbonyl, phenoxycarbonyl, phenylcarbonyl, phenylcarbonyl, phenylcarbonyl, phenoxycarbonyl, phenylcarbonyl, phenoxycarbonyl, phenylcarbonyl, phenylcarbonyl, phenoxycarbonyl heterocyclylalkyl with 1 to 6 carbon atoms in the alkyl part, and, in the case of cyclic residues, and alkyl with 1 to 6 carbon atoms, each of the last 20 residues unsubstituted or substituted by one or more residues from the group consisting of halogen, hydroxyl, amino, di alkylamino with 1-4 carbon atoms in the alkyl part, nitro, cyano, alkoxy with 1-4 carbon atoms, alkylthio group with 1-4 carbon atoms, alkylsulfonyl with 1-4 carbon atoms, haloalkoxy with 1-4 carbon atoms and, in the case of cyclic residues, and alkyl with 1 to 4 carbon atoms and haloalkyl with 1-4 carbon atoms, or two adjacent residues R ⁷ together mean a fused ring with 4 to 6 ring atoms, which is carbocyclic or contains 1 to 3 heteroatoms from the group including oxygen, sulfur and nitrogen and which unsubstituted or substituted by one or several residues from the group including halogen, alkyl with 1-4 carbon atoms and an oxo group, X is a group of the formula -O-, -S (O) _r - or -NR * -, where r is 0, 1 or 2, and R * is hydrogen or alkyl with 1 to 4 carbon atoms, and n is 0, 1, 2, 3, 4, or 5,
while the heterocyclyl in the residues contains 3 to 9 ring atoms, preferably 3 to 6 ring atoms, in particular 5 or 6 ring atoms, and 1 to 3 heteroatoms from the nitrogen, oxygen and sulfur groups. 3. The compounds of formula (I) and their salts according to claim 1 or 2, characterized in that R ¹ - alkyl with 1 to 4 carbon atoms, which is unsubstituted or substituted by one or more residues from the group including halogen, hydroxyl, alkoxyl with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms and phenyl, or phenyl, which is unsubstituted or substituted by one or more residues from the group including halogen, alkyl with 1 to 4 carbon atoms, haloalkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, haloalkoxy with 1 to 4 carbon atoms, alkylthio group with 1 to 4 carbon atoms Erode, nitro, cyano, alkylcarbonyl with 1 - 2 carbon atoms in the alkyl moiety, formyl, carbamoyl, mono- and dialkylaminocarbonyl with 1 - 2 carbon atoms in the alkyl part and alkylsulfonyl with 1 - 4 carbon atoms, R ² and R ³ independently from each other means hydrogen, amino group, formyl, aminocarbonyl, alkyl with 1-4 carbon atoms, cyanoalkyl with 1-4 carbon atoms, alkylamino group with 1-4 carbon atoms, dialkylamino group with 1-4 carbon atoms in the alkyl part, haloalkyl with 1 - 4 carbon atoms, hydroxyalkyl with 1 to 4 carbon atoms, alko xyalkyl with 1-4 carbon atoms in the alkoxy part and 1-4 carbon atoms in the alkyl part, haloalkoxyalkyl with 1 to 4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, alkenyl with 2-6 carbon atoms, haloalkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms, haloalkynyl with 2 to 6 carbon atoms, alkylaminoalkyl with 1 to 4 carbon atoms in each alkyl part, dialkylaminoalkyl with 1 to 4 carbon atoms in each alkyl part, cycloalkylaminoalkyl with 3 - 6 carbon atoms in the cycloalkyl part and 1 to 4 atom amides of carbon in the alkyl part, cycloalkyl with 3-6 carbon atoms, heterocyclylalkyl with 3-6 carbon atoms in the heterocyclic part and 1-4 carbon atoms in the alkyl part, with the cyclic groups in the last three residues unsubstituted or substituted by one or several residues from the group containing alkyl with 1-4 carbon atoms, halogen and cyano group, or alkanolamine group with 1-6 carbon atoms, N-alkanoyl-N-alkylamino group with 1-6 carbon atoms in the alkanoyl part and 1 to 4 carbon atoms in the alkyl part, alkanoyl amino alkyl from 1 - 6 carbon atoms in the alkanoyl part and 1 to 4 carbon atoms in the alkyl part, N-alkanoyl-N-alkylaminoalkyl with 1 to 6 carbon atoms in the alkanoyl part and 1 to 4 carbon atoms in each alkyl part, phenyl, phenoxy, phenylcarbonyl, phenyl hydroxycarbonyl, phenylcarbonylalkyl with 1-4 carbon atoms, alkoxycarbonylalkyl with 1-4 carbon atoms in the alkoxy part and 1-4 carbon atoms in the alkyl part, alkylaminocarbonylalkyl with 1-4 carbon atoms in each alkyl part, alkylcarbonyl with 1-4 carbon atoms in the alkyl part, alkoxycarbonyl with 1-4 carbon atoms in the alkoxy part, alkylaminocarbonyl with 1-4 carbon atoms in the alkyl part, dialkylaminocarbonyl with 1-4 carbon atoms in the alkyl part, phenoxyalkyl with 1-4 carbon atoms, phenylalkyl with 1-4 carbon atoms, heterocyclyl, a heterocyclylamino group, a heterocyclyloxy group, a heterocyclyl thio group, or one of the 21 last residues that is substituted in the acyclic part or cyclic part by one or more residues from the group consisting of halogen, nitro, cyano, alkoxy of 1-4 carbon atoms, alkyl thio group with 1-4 carbon atoms, haloalkoxy with 1-4 carbon atoms, formyl, alkylcarbonyl with 1-4 carbon atoms and, in the case of cyclic residues, and alkyl with 1-4 carbon atoms and haloalkyl with 1-4 carbon atoms, or R ² and R ³ together with the nitrogen atom of the group NR ² R ³ means a 3-6-membered heterocyclic residue with 1 to 2 heteroatoms, and besides the nitrogen atom, a further heteroatom, if necessary, is selected from the group of nitrogen, oxygen and sulfur, and the residue is unsubstituted or substituted by one or more residues from the group comprising halogen, alk sludge with 1-4 carbon atoms and oxo group, R ⁴ - hydrogen, amino group, formyl, aminocarbonyl, alkyl with 1-4 carbon atoms, cyanoalkyl with 1-4 carbon atoms, alkylamino group with 1-4 carbon atoms, dialkylamino group with 1-4 carbon atoms in the alkyl part, haloalkyl with 1 to 4 carbon atoms, hydroxyalkyl with 1 to 4 carbon atoms, alkoxyalkyl with 1 to 4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, haloalkoxyalkyl with 1 to 4 carbon atoms in alkoxy part and 1 to 4 carbon atoms in the alkyl part, alkenyl with 2 to 6 atom amides of carbon, haloalkenyl with 2-6 carbon atoms, alkynyl with 2-6 carbon atoms, haloalkynyl with 2-6 carbon atoms, alkylaminoalkyl with 1-4 carbon atoms in each alkyl part, dialkylaminoalkyl with 1-4 carbon atoms in each alkyl part , cycloalkylaminoalkyl with 3 to 6 carbon atoms in the cycloalkyl part and 1 to 4 carbon atoms in the alkyl part, cycloalkyl with 3 to 6 carbon atoms, heterocyclylalkyl with 3 to 6 carbon atoms in the heterocyclyl part and 1 to 4 carbon atoms in the alkyl part, and cyclic groups in the last three x residues are unsubstituted or substituted by one or more residues from the group comprising alkyl with 1-4 carbon atoms, halogen and cyano group, or alkanolamine group with 1-6 carbon atoms, N-alkanoyl-N-alkylamino group with 1-6 carbon atoms in the alkanoyl part and 1 to 4 carbon atoms in the alkyl part, alkanoylaminoalkyl with 1 to 6 carbon atoms in the alkanoyl part and 1 to 4 carbon atoms in the alkyl part, N-alkanoyl-N-alkylaminoalkyl with 1 to 6 carbon atoms in the alkanoyl part and 1 to 4 carbon atoms in each alkyl part, phenyl, phenoxy, enylcarbonyl, phenoxycarbonyl, phenylcarbonylalkyl with 1-4 carbon atoms, alkoxycarbonylalkyl with 1-4 carbon atoms in the alkoxy part and 1-4 carbon atoms in the alkyl part, alkylaminocarbonylalkyl with 1-4 carbon atoms in each alkyl part, alkylcarbonyl with 1-4 carbon atoms carbon in the alkyl part, alkoxycarbonyl with 1-4 carbon atoms in the alkoxy part, alkylaminocarbonyl with 1-4 carbon atoms in the alkyl part, dialkylaminocarbonyl with 1-4 carbon atoms in the alkyl part, phenoxy alkyl with 1-4 carbon atoms, phenylalkyl 1 to 4 carbon atoms, heterocyclyl, heterocyclylamino group, heterocyclyloxy, heterocyclylthio group, or one of the 21 last residues that is substituted in the acyclic part or, preferably, in the cyclic part, by one or more residues from the group consisting of halogen, nitro, cyano, alkyl, alkyl, alkyl. 4 carbon atoms, alkoxy with 1-4 carbon atoms, alkylthio group with 1-4 carbon atoms, haloalkyl with 1-4 carbon atoms, haloalkoxy with 1-4 carbon atoms, formyl, alkylcarbonyl with 1-4 carbon atoms, alkoxycarbonyl with 1 to 4 carbon atoms and, in the case of cyclic residues, and alkyl with 1 to 4 carbon atoms and haloalkyl with 1 to 4 carbon atoms, R ⁵ and R ⁶ independently of one another denote hydrogen, halogen, hydroxyl, amino, nitro, formyl , aminocarbonyl, carboxyl, cyano, thiocyanato, alkyl with 1-4 carbon atoms, cyanoalkyl with 1-4 carbon atoms, alkoxy with 1-4 carbon atoms, alkylamino group with 1-4 carbon atoms, dialkylamino group with 1-4 carbon atoms in alkyl parts, haloalkyl with 1-4 carbon atoms, hydroxyalkyl with 1-4 carbon atoms Ordine, alkoxyalkyl with 1 to 4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, haloalkoxyalkyl with 1 to 4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, an alkylthio group with 1 to 4 carbon atoms, halo alkylthio group with 1-4 carbon atoms, alkenyl with 2-6 carbon atoms, haloalkenyl with 2-6 carbon atoms, alkynyl with 2-6 carbon atoms, haloalkynyl with 2-6 carbon atoms, alkylaminoalkyl with 1-4 carbon atoms in each alkyl part, dialkylaminoalkyl with 1 to 4 carbon atoms in each th alkyl part, cycloalkylaminoalkyl with 3 to 6 carbon atoms in the cycloalkyl part and 1 to 4 carbon atoms in the alkyl part, cycloalkyl with 3 to 6 carbon atoms, heterocyclylalkyl with 1 to 4 carbon atoms in the alkyl part and 3 to 6 ring members, and cyclic groups in the last three residues are unsubstituted or substituted by one or more residues from the group comprising alkyl with 1-4 carbon atoms, halogen and cyano group, or alkanoylamino group with 1-6 carbon atoms, N-alkanoyl-N-alkylamino group with 1-6 atoms carbon in alkanoyl parts and 1 to 4 carbon atoms in the alkyl part, alkanoylaminoalkyl with 1 to 6 carbon atoms in the alkanoyl part and 1 to 4 carbon atoms in the alkyl part, N-alkanoyl-N-alkylaminoalkyl with 1 to 6 carbon atoms in the alkanoyl part and 1 - 4 carbon atoms in each alkyl part, phenyl, phenoxy, phenylcarbonyl, phenoxycarbonyl, phenylcarbonylalkyl with 1-4 carbon atoms, alkoxycarbonylalkyl with 1-4 carbon atoms in the alkoxy part and 1-4 carbon atoms in the alkyl part, alkylaminocarbonylalkyl with 1-4 atoms carbon in each alkyl part, and lkylcarbonyl with 1-4 carbon atoms, alkoxycarbonyl with 1-4 carbon atoms, alkylaminocarbonyl with 1-4 carbon atoms, dialkylaminocarbonyl with 1-4 carbon atoms in the alkyl part, phenoxy alkyl with 1-4 carbon atoms, phenylalkyl with 1-4 carbon atoms , heterocyclyl, heterocyclylamino group, heterocyclyloxy, heterocyclylthio group or one of the 21 last residues that is substituted in the acyclic or cyclic part by one or more residues from the group consisting of halogen, nitro, cyano, alkoxy with 1 to 4 atoms carbonate, alkylthio group with 1-4 carbon atoms, haloalkoxy with 1-4 carbon atoms, formyl, alkylcarbonyl with 1-4 carbon atoms, alkoxycarbonyl with 1-4 carbon atoms and, in the case of cyclic residues, and alkyl with 1-4 carbon atoms and haloalkyl with 1 to 4 carbon atoms, or R ⁵ and R ⁶ together mean an alkylene chain with 2 to 4 carbon atoms, which is unsubstituted or substituted by one or more residues from the group containing halogen, alkyl with 1 to 4 carbon atoms and an oxo group, (R ⁷⁾ _{n n} means the residues R ⁷ which, if n = 2, 3, 4 or 5 identical or once ichny, and R ⁷ is halogen, hydroxyl, amino, nitro, formyl, aminocarbonylalkyl with 1 - 4 carbon atoms, carboxyl, cyano, thiocyanato group or an alkyl group having 1 - 6 carbon atoms, alkoxy having 1 - 6 carbon atoms, alkylthio with 1 to 6 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, cycloalkyl with 1 to 6 carbon atoms, alkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms, cycloalkylalkyl with 3 to 6 carbon atoms in the cycloalkyl part and 1 - 4 carbon atoms in the alkyl part, cycloalkylalkenyl with 3 to 6 carbon atoms in c the clooyl part and 1 to 4 carbon atoms in the alkenyl part, cycloalkylalkynyl with 3 to 6 carbon atoms in the cycloalkyl part and 1 to 4 carbon atoms in the alkynyl part, alkylcarbonyl with 1 to 6 carbon atoms, cycloalkoxyl with 3 to 6 carbon atoms, cycloalkylcarbonyl with 3 to 6 carbon atoms, alkoxycarbonyl with 1 to 6 carbon atoms, alkylcarbonyloxy with 1 to 6 carbon atoms, alkylcarbonylalkyl with 1 to 6 carbon atoms in each alkyl part, alkoxycarbonylalkyl with 1 to 6 carbon atoms in the alkoxy part and 1 to 6 carbon atoms in the alkyl part and alkylcarbonyloxyalkyl with 1 to 6 carbon atoms in each alkyl part, cycloalkoxyalkyl with 1 to 6 carbon atoms in the cycloalkoxy part and 1 to 4 carbon atoms in the alkyl part, cycloalkylcarbonylalkyl with 3 to 6 carbon atoms in the cycloalkyl part and 1 to 4 carbon atoms in the alkyl part, monoalkylamino group with 1-6 carbon atoms, dialkylamino group with 1-4 carbon atoms in the alkyl part, alkanoylamino group with 1-6 carbon atoms, N-alkanoyl-N-alkylamino group with 1-6 carbon atoms in the alkanoyl part and 1 - 4 carbon atoms in a the acid part, alkanolamine alkyl with 1-6 carbon atoms in the alkanoyl part and 1-4 carbon atoms in the alkyl part or N-alkanoyl-N-alkylaminoalkyl with 1-6 carbon atoms in the alkanoyl part and 1-4 carbon atoms in each alkyl part, each of the last 26 residues in the acyclic part or in the cyclic part is replaced by one or more residues from the group including halogen, nitro, amino, aminoalkyl with 1-4 carbon atoms, mono- and dialkylaminoalkyl with 1-4 carbon atoms in each alkyl part , hydroxyl, qi nogroup, alkoxy with 1-4 carbon atoms, alkylthio group with 1-4 carbon atoms, haloalkoxy with 1-4 carbon atoms, alkylcarbonyl with 1-4 carbon atoms, alkoxycarbonyl with 1-4 carbon atoms and, in the case of cyclic residues, and alkyl with 1 - 4 carbon atoms and haloalkyl with 1 - 4 carbon atoms, or phenyl, phenoxy, phenylthio, phenylcarbonyl, phenoxycarbonyl, phenylcarbonyloxy, phenylsulfonyl, phenoxyalkyl with 1 - 6 carbon atoms, fenilkarbonilalkil with 1 - 6 carbon atoms, feniloksikarbonilalkil 1 - 6 carbon atoms, phenylcarbonyl textiles with 1-4 carbon atoms, phenylalkyl with 1-6 carbon atoms, phenylalkenyl with 1-6 carbon atoms, phenylalkynyl with 1-6 carbon atoms, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylsulfonyl, cycloalkyls, heterocyclics, heterocyclylthio, heterocyclylsulfonyl, heterocyclics, heterocyclyl, heterocyclyl one of the last 20 residues, which is substituted by one or several residues from the group including halogen, hydroxyl, nitro, cyano, alkyl with 1-6 carbon atoms, alkoxy with 1-6 carbon atoms, alkylthio group with 1-6 carbon atoms, alkyls lfonil with 1 - 4 carbon atoms, haloalkyl with 1 - 6 carbon atoms and haloalkoxy with 1 - 6 carbon atoms, or two adjacent residues R ⁷ together represent prikondensirovanny ring having 4 - 6 ring atoms which is carbocyclic or contains 1 - 3 heteroatoms from the group comprising oxygen, sulfur and nitrogen, and which is unsubstituted or substituted by one or more residues from the group including halogen, alkyl with 1-4 carbon atoms and an oxo group, X is a group of the formula -O-, -S- or -NR * -, where R * is hydrogen or alkyl with 1-4 carbon atoms, and n is 0, 1, 2, 3, 4, or 5,
while heterocyclyl in the residues contains 3 to 9 ring atoms and 1 to 3 heteroatoms from the nitrogen, oxygen and sulfur groups. 4. The compounds of formula (I) and their salts according to one of claims 1 to 3, characterized in that R ¹ is alkyl with 1 to 4 carbon atoms, haloalkyl with 1 to 4 carbon atoms, hydroxyalkyl with 1 to 4 carbon atoms, alkoxyalkyl with 1-4 carbon atoms in the alkoxy part and 1-4 carbon atoms in the alkyl part or benzyl, R ² and R ³ independently of each other mean hydrogen, amino group, formyl, alkyl with 1-4 carbon atoms, alkoxyalkyl with 1 - 4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, alkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms , alkylaminoalkyl with 1-4 carbon atoms in each alkyl part, dialkylaminoalkyl with 1-4 carbon atoms in each alkyl part or phenyl, phenylalkyl with 1-4 carbon atoms or phenoxycarbonyl or one of the last three residues, which in the phenyl part is mono- three times substituted by residues from the group consisting of halogen, alkyl with 1-4 carbon atoms, alkoxy with 1-4 carbon atoms and alkoxycarbonyl with 1-4 carbon atoms, or R ² and R ³ together with the nitrogen atom of the group NR ² R ³ mean 3 - 6-membered heterocyclic residue with 1 to 2 heteroatoms, etc. than the addition to the nitrogen atom is available if necessary a further heteroatom selected from nitrogen and oxygen, and the residue is unsubstituted or substituted by one or more radicals from the group consisting of halogen, alkyl having 1 - 4 carbon atoms and an oxo group, R ⁴ - hydrogen, amino, formyl, alkyl with 1-4 carbon atoms, dialkylamino group with 1-4 carbon atoms in the alkyl part, alkoxyalkyl with 1-4 carbon atoms in the alkoxy part and 1-4 carbon atoms in the alkyl part, alkenyl with 2-6 carbon atoms, alkynyl with 2 - 6 carbon atoms, dialkylamino kil with 1-4 carbon atoms in each alkyl part, phenyl, phenoxyalkyl with 1-4 carbon atoms, phenylalkyl with 1-4 carbon atoms, phenoxycarbonyl, phenylaminocarbonyl or one of the last five residues, which in the phenyl part is mono-up to three times substituted by residues from the group comprising alkyl with 1-4 carbon atoms, alkoxy with 1-4 carbon atoms and alkoxycarbonyl with 1-4 carbon atoms, R ⁵ and R ⁶ independently of one another denote hydrogen, alkyl with 1-4 carbon atoms, cycloalkyl with 3 to 6 carbon atoms, alkoxyalkyl with 1 to 4 carbon atoms in alk xyl part and 1 to 4 carbon atoms in the alkyl part, alkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms, dialkylaminoalkyl with 1 to 4 carbon atoms in each alkyl part, phenyl, phenoxyalkyl with 1 to 4 carbon atoms, phenylalkyl with 1-4 carbon atoms, phenoxycarbonyl, phenylaminocarbonyl or one of the last three residues, which in the phenyl part is mono-to three-fold substituted by residues from the group including halogen, alkyl with 1-4 carbon atoms, alkoxyl with 1-4 carbon atoms and alkoxycarbonyl with 1 to 4 carbon atoms, or R ⁵ and R ⁶ in place means an alkylene chain with 2 to 4 carbon atoms, unsubstituted or substituted by one or more residues from the group consisting of halogen, alkyl with 1 to 4 carbon atoms and an oxo group, (R ⁷ ) _n n means R ⁷ residues, which, if n = 2, 3, 4 or 5 are the same or different, and R ⁷ means halogen, hydroxyl, amino group, nitro group, formyl, aminocarbonyl, carboxyl, cyano group, thiocyanato group, alkyl with 1-6 carbon atoms, alkoxyl with 1-4 atoms carbon, haloalkyl with 1-4 carbon atoms, haloalkoxy with 1-4 carbon atoms, hydroxyalkyl with 1 - 4 carbon atoms, hydroxyalkoxy with 1-4 carbon atoms, alkoxyalkyl with 1-4 carbon atoms in the alkoxy part and 1-4 carbon atoms in the alkyl part, alkoxyalkoxy with 1-4 carbon atoms in each alkoxy part, 1-4 halogen alkoxyalkyl carbon in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, haloalkoxyalkoxy with 1-4 carbon atoms in each alkoxy part, cycloalkyl with 3-6 carbon atoms, halocycloalkyl with 3-6 carbon atoms, alkenyl with 2-6 carbon atoms, haloalkenyl with 2 to 6 carbon atoms yes, alkynyl with 2-6 carbon atoms, haloalkynyl with 2-6 carbon atoms, alkylcarbonyl with 1-4 carbon atoms, haloalkylcarbonyl with 1-4 carbon atoms, cycloalkyloxy with 3-6 carbon atoms, halo-cycloalkyloxy with 3-6 carbon atoms, cycloalkylcarbonyl with 3-6 carbon atoms, halo-cycloalkylcarbonyl with 3-6 carbon atoms, alkoxycarbonyl with 1-4 carbon atoms, haloalkoxycarbonyl with 1-4 carbon atoms, alkylcarbonyloxyl with 1-4 carbon atoms, haloalkylcarbonyloxyl with 1-4 carbonyl atoms and carbonyl atoms with 1-4 carbon atoms, haloalkylcarbonyloxycarbonyl with 1-4 carbon atoms with 1-4 carbon atoms, haloalkylcarbonyloxycarbonyl with 1-4 carbon atoms with 1-4 carbon atoms, haloalkylcarbonyloxycarbonyl with 1-4 carbon atoms with 1-4 carbon atoms, haloalkylcarbonyloxycarbonyl with 1-4 carbon atoms and carbon atoms of 1-4 carbon atoms, haloalkylcarbonylcarboxylic carbonyl with 1-4 carbon atoms with 1-4 carbon atoms 1 to 4 atoms carbon in each alkyl part, alkoxycarbonylalkyl with 1 to 4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, alkylcarbonyloxyalkyl with 1 to 4 carbon atoms in each alkyl part, alkylthio group with 1 to 4 carbon atoms, alkyl alkyl group with 1 - 4 carbon atoms, alkylamino group with 1-4 carbon atoms, dialkylamino group with 1-4 carbon atoms in the alkyl part, alkanolamine group with 1-6 carbon atoms, N-alkanoyl-N-alkylamino group with 1-6 carbon atoms in the alkanoyl part and 1 - 4 carbon atoms in alk the flax part, alkanoyl amino alkyl with 1 to 6 carbon atoms in the alkanoyl part and 1 to 4 carbon atoms in the alkyl part, N-alkanoyl-N-alkylaminoalkyl with 1 to 6 carbon atoms in the alkanoyl part and 1 to 4 carbon atoms in each alkyl part, or phenyl, phenoxy, phenylcarbonyl, phenoxycarbonyl, phenylcarbonyloxy, phenoxy alkyl with 1-4 carbon atoms, phenylcarbonylalkyl with 1-4 carbon atoms, phenylalkyl with 1-4 carbon atoms, phenylalkenyl with 2-6 carbon atoms, phenylalkynyl with 2-6 atom, carbon, heterocyclyl, heterocyclyloxy, heterocycly thio group, heterocyclylamino group, heterocyclylalkyl with 1-6 carbon atoms, or one of the last 15 residues, which is substituted in the cyclic part by one or more residues from the group including halogen, hydroxyl, nitro, alkyl with 1-4 carbon atoms, alkoxy with 1 - 4 carbon atoms, alkylthio group with 1-4 carbon atoms, haloalkyl with 1-4 carbon atoms and haloalkoxy with 1-4 carbon atoms, or two adjacent R ⁷ together denote a fused ring with 4-6 ring atoms, which is carbocyclic or contains heteroatoms from the group comprising oxygen, sulfur and nitrogen, and which is unsubstituted or substituted by one or more residues from the group including halogen, alkyl with 1 to 4 carbon atoms and an oxo group, X is a group of the formula -O- or -NR * -, where R * is hydrogen or methyl, and n is 0, 1, 2, 3, 4, or 5,
while heterocyclyl in the residues contains 3 to 9 ring atoms and 1 to 3 heteroatoms from the nitrogen, oxygen and sulfur groups. 5. The compounds of formula (I) and their salts according to one of claims 1 to 4, characterized in that R ¹ is alkyl with 1 to 4 carbon atoms, haloalkyl with 1 to 4 carbon atoms, hydroxyalkyl with 1 to 4 carbon atoms or alkoxyalkyl with 1 to 4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, R ² and R ³ independently of one another denote hydrogen, amino, formyl or alkyl with 1 to 4 carbon atoms, or R ² and R ³ together with the nitrogen atom of the group NR ² R ³ means 4 - 6-membered heterocyclic residue, which in addition to the nitrogen atom as a heteroatom may contain further a heteroatom from the group of nitrogen and oxygen, R ⁴ is hydrogen or alkyl with 1 to 4 carbon atoms, R ⁵ is hydrogen, alkyl with 1 to 4 carbon atoms, alkenyl with 2 to 4 carbon atoms, alkynyl with 2 to 4 carbon atoms, cycloalkyl with 3-6 carbon atoms or alkoxyalkyl with 1-4 carbon atoms in the alkoxy part and 1-4 carbon atoms in the alkyl part or phenyl, and R ⁶ is hydrogen, alkyl with 1-4 carbon atoms, alkenyl with 2-4 carbon atoms , alkynyl with 2 to 4 carbon atoms, cycloalkyl with 3 to 6 carbon atoms or alkoxyalkyl with 1 to 4 carbon atoms in the alkoxy part and 1 to 4 atoms carbon in the alkyl part or phenyl, or R ⁵ and R ⁶ together mean an alkylene chain with 2-4 carbon atoms, R ⁷ - independently of each other halogen, hydroxyl, amino, nitro, formyl, carboxyl, cyano, alkyl with 1 - 6 carbon atoms, alkoxy with 1-4 carbon atoms, haloalkyl with 1-4 carbon atoms, haloalkoxy with 1-4 carbon atoms, hydroxyalkyl with 1-4 carbon atoms, hydroxyalkoxy with 1-4 carbon atoms, alkoxyalkyl with 1-4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, haloalkoxyalkyl with 1 - 4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, halogenyl alkoxyalkoxy with 1 to 4 carbon atoms in the alkyl part and 1 to 4 carbon atoms in the alkoxy part, alkoxyalkoxy with 1 to 4 carbon atoms in each alkoxy part, cycloalkyl with 3-6 carbon atoms, halocycloalkyl with 3-6 carbon atoms, alkenyl with 2-6 carbon atoms, haloalkenyl with 2-6 carbon atoms, alkynyl with 2-6 carbon atoms, haloalkynyl with 2-6 carbon atoms, alkylcarbonyl with 1 - 4 carbon atoms, haloalkylcarbonyl with 1 to 4 atoms carbon, alkoxycarbonyl with 1-4 carbon atoms, haloalkoxycarbonyl with 1-4 carbon atoms, alkylcarbonyloxy with 1-4 carbon atoms, haloalkylcarbonyloxy with 1-4 carbon atoms, alkylcarbonylalkyl with 1-4 carbon atoms in each alkyl part, alkylthio group with 1 - 4 carbon atoms, haloalkylthio group with 1-4 carbon atoms, alkylamino group with 1-4 carbon atoms, dialkylamino group with 1-4 carbon atoms in the alkyl part, phenyl, phenoxy, phenylcarbonyl, phenoxycarbonyl, phenylcarbonyloxy, phenoxyalkyl with 1-4 carbon atoms yes, phenylcarbonylalkyl with 1-4 carbon atoms, phenylalkyl with 1-4 carbon atoms, phenylalkenyl with 2-4 carbon atoms, phenylalkynyl with 2-4 carbon atoms, heterocyclyl, heterocyclyloxy, heterocyclylthio group, I’ll be a the cyclic part is substituted with one or more residues from the group consisting of halogen, alkyl with 1-4 carbon atoms, alkoxy with 1-4 carbon atoms, haloalkyl with 1-4 carbon atoms and halo-alkoxy with 1-4 carbon atoms, and heterocyclyl in residues has 3 to 6 ring atoms and 1 to 3 heteroatoms from the nitrogen and oxygen groups, or two adjacent residues R ⁷ together mean a fused ring with 4 to 6 ring atoms that is carbocyclic or contains heteroatoms from the group including oxygen and nitrogen, and which is unsubstituted or substituted by one or more residues from the group comprising alkyl with 1 to 4 carbon atoms, X is a group of the formula —O— or —NH—, and n is 0, 1, 2, 3, 4 or 5. 6. The compounds of formula (I) and their salts according to one of paragraphs.1 to 5, characterized in that a1) R ¹ is a haloalkyl with 1 to 6 carbon atoms, R ² , R ³ , R ⁴ , R ⁶ means each hydrogen , R ⁵ is methyl n is 3, 4 or 5, X is an oxygen atom, and (R ⁷ ) _n n means residues R ⁷ that are the same or different, and R ⁷ means halogen, hydroxyl, amino, nitro, formyl, carboxyl, cyano, alkyl with 1-6 carbon atoms, alkoxy with 1-4 carbon atoms, haloalkyl with 1-4 carbon atoms, haloalkoxy with 1-4 carbon atoms, hydroxyalkyl with 1-4 carbon atoms, hydroxyalkoxy with 1-4a carbon ohms, alkoxyalkyl with 1 to 4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, haloalkoxyalkyl with 1 to 4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, haloalkyloxyalkoxy with 1 to 4 carbon atoms in the alkyl part and 1 to 4 carbon atoms in the alkoxy part, alkoxyalkoxy with 1 to 4 carbon atoms in each alkoxy part, cycloalkyl with 3 to 6 carbon atoms, halo-cycloalkyl with 3 to 6 carbon atoms, alkenyl with 2 to 4 carbon atoms, haloalkenyl with 2 to 4 carbon atoms, alc Nile with 2-4 carbon atoms, haloalkynyl with 2-4 carbon atoms, alkylcarbonyl with 1-4 carbon atoms, alkoxycarbonyl with 1-4 carbon atoms, alkylcarbonyloxy with 1-4 carbon atoms, alkylcarbonylalkyl with 1-4 carbon atoms in each alkyl parts, alkylthio group with 1 to 4 carbon atoms, alkylamino group with 1 to 4 carbon atoms, dialkylamino group with 1 to 4 carbon atoms in the alkyl part or phenyl, phenoxy, phenylcarbonyl, phenoxycarbonyl, phenylcarbonyloxy, phenoxyalkyl with 1 to 4 carbon atoms, phenylcarbonylalkyl, - 4 carbon atoms , phenylalkyl with 1-4 carbon atoms or one of the last 8 residues, which in the phenyl part is replaced by one or more residues from the group including halogen, alkyl with 1-4 carbon atoms, alkoxyl with 1-4 carbon atoms, haloalkyl with 1 - 4 carbon atoms and haloalkoxy with 1-4 carbon atoms, or two adjacent residues R ⁷ together mean a fused ring with 4-6 ring atoms, which is carbocyclic or contains heteroatoms from the group comprising oxygen and nitrogen, and which is unsubstituted or substituted by one or several kimi radicals from the group consisting of alkyl having 1 - 4 carbon atoms, or a2) R ¹ - haloalkyl with 1 - 6 carbon atoms, R ^2, R ^3, R ^4, R ⁶ are each hydrogen, R ⁵ - methyl n - number 1 or 2, X is an oxygen atom, (R ⁷ ) nn means residues R ⁷ that, if n = 2, are the same, and R ⁷ means chlorine, bromine, iodine, hydroxyl, amino, nitro, formyl, carboxyl, cyano, alkoxy with 2 to 4 carbon atoms, methyl, which is substituted by one or more residues from the group including chlorine, bromine and iodine, haloalkyl with 2 to 4 carbon atoms, haloalkoxy with 1 to 4 carbon atoms Ordine, hydroxyalkyl with 1-4 carbon atoms, hydroxyalkoxy with 1-4 carbon atoms, alkoxyalkyl with 1-4 carbon atoms in the alkoxy part and 1-4 carbon atoms in the alkyl part, haloalkoxyalkyl with 1 to 4 carbon atoms in the alkoxy part and 1 - 4 carbon atoms in the alkyl part, haloalkyloxyalkoxy with 1 to 4 carbon atoms in the alkyl part and 1 to 4 carbon atoms in the alkoxy part, alkoxyalkoxy with 1 to 4 carbon atoms in each alkoxy part, cycloalkyl with 3 to 6 carbon atoms, halogencycloalkyl with 3 to 6 carbon atoms, alc Nile with 2-4 carbon atoms, haloalkenyl with 2-4 carbon atoms, alkynyl with 2-4 carbon atoms, haloalkynyl with 2-4 carbon atoms, alkylcarbonyl with 1-4 carbon atoms, alkoxycarbonyl with 1-4 carbon atoms, alkylcarbonyloxy with 1 to 4 carbon atoms, alkylcarbonylalkyl with 1 to 4 carbon atoms in each alkyl part, an alkylthio group with 1 to 4 carbon atoms, a haloalkylthio group with 1 to 4 carbon atoms, an alkylamino group with 1 to 4 carbon atoms, a dialkylamino group with 1 to 4 carbon atoms in the alkyl part or phenyl, phenoxy, phenylcarbonyl, fe Noxicarbonyl, phenylcarbonyloxy, phenoxyalkyl with 1-4 carbon atoms, phenylcarbonylalkyl with 1-4 carbon atoms, phenylalkyl with 1-4 carbon atoms or one of the last 8 residues, which in the phenyl part is replaced by one or more residues from the group that includes halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, haloalkyl with 1 to 4 carbon atoms and haloalkoxy with 1 to 4 carbon atoms, or two adjacent residues R ⁷ together mean a fused ring with 4 to 6 ring atoms, which is carbocyclic or contains 1 or 2 hetero atoms from the group consisting of oxygen and nitrogen and which is unsubstituted or substituted by one or more radicals selected from the group consisting of alkyl having 1 - 4 carbon atoms, or a3) R ¹ - haloalkyl with 1 - 6 carbon atoms, R ² , R ³ , R ⁴ , R ⁶ mean each hydrogen, R ⁵ - methyl n - number 2, X - oxygen atom, (R ⁷ ) n means two residues R ⁷ , and both residues R ⁷ are different in structure and have the indicated above under a1) value, or two adjacent residues R ⁷ together represent a ring having prikondensirovanny 4 - 6 ring atoms which is karbotsikliches them or contains 1 or 2 hetero atoms from the group consisting of oxygen and nitrogen and which is unsubstituted or substituted by one or more radicals selected from the group consisting of alkyl having 1 - 4 carbon atoms, or b1) R ¹ - alkyl group with 1 - 6 carbon atoms, which is unsubstituted or substituted by 1-4 substituents from the group comprising alkoxy with 1-4 carbon atoms and hydroxyl, R ² , R ³ , R ⁴ , R ⁶ means each hydrogen, R ⁵ - methyl n - number 1, 2, 3 or 4, X is an oxygen atom, (R ⁷ ) _n n means residues R ⁷ that, if n = 2, 3 or 4, are the same or different, and R ⁷ means hydroxyl, amino, n itro group, formyl, carboxyl, cyano group, alkoxy with 1-4 carbon atoms, haloalkyl with 1-4 carbon atoms, haloalkoxy with 1-4 carbon atoms, hydroxyalkyl with 1-4 carbon atoms, hydroxyalkoxy with 1-4 carbon atoms, alkoxyalkyl with 1 to 4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, haloalkoxyalkyl with 1 to 4 carbon atoms in the alkoxy part and 1 to 4 carbon atoms in the alkyl part, haloalkyloxyalkoxy with 1 to 4 carbon atoms in the alkyl part and 1 - 4 carbon atoms in the alkoxy part, alc xyalkoxy with 1 to 4 carbon atoms in each alkoxy part, cycloalkyl with 3 to 6 carbon atoms, halo-cycloalkyl with 3 to 6 carbon atoms, alkenyl with 2 to 4 carbon atoms, haloalkenyl with 2 to 4 carbon atoms, alkynyl with 2 to 4 atoms carbon, haloalkynyl with 2 to 4 carbon atoms, alkylcarbonyl with 1 to 4 carbon atoms, alkoxycarbonyl with 1 to 4 carbon atoms, alkylcarbonyloxy with 1 to 4 carbon atoms, alkylcarbonylalkyl with 1 to 4 carbon atoms in each alkyl part, alkylthio group with 1 - 4 carbon atoms, haloalkylthio group with 1 to 4 carbon atoms ode, alkylamino group with 1-4 carbon atoms, dialkylamino group with 1-4 carbon atoms in the alkyl part or phenyl, phenoxyl, phenylcarbonyl, phenoxycarbonyl, phenylcarbonyloxy, phenoxy alkyl with 1-4 carbon atoms, phenylcarbonylalkyl with 1-4 carbon atoms, phenylalkyl 1 to 4 carbon atoms or one of the last 8 residues, which in the phenyl part is substituted by one or more residues from the group including halogen, alkyl with 1 to 4 carbon atoms, alkoxyl with 1 to 4 carbon atoms, haloalkyl with 1 to 4 carbon atoms and haloalkoxy with 1 - 4 atoms carbon atoms or two adjacent residues R ⁷ together mean a fused ring with 4-6 ring atoms, which is carbocyclic or contains 1 or 2 heteroatoms from the group comprising oxygen and nitrogen, and which is unsubstituted or substituted by one or several residues from the group including alkyl with 1 to 4 carbon atoms. 7. The method of obtaining compounds of General formula (I) and their salts according to one of paragraphs.1 to 6, characterized in that a) a compound of formula (II)
R ¹ -Fu
where Fu means a functional group present in residues such as carboxylic ester, ortho ester of carboxylic acid, carboxylic acid chloride, carboxylic acid amide, carboxylic anhydride, and trifluoromethyl,
subjected to interaction with biguanidine formula (III) or its acid additive salt

or b) the compound of formula (IV)

where Z ¹ is a replaceable residue or a removable group, is subjected to interaction with a suitable amine of the formula (V) or its acid additive salt

moreover, residues R ¹ to R ⁷ and X, as well as n, indicated in formulas (II), (III), (IV) and (V), as well as n, have the meaning indicated in formula (I)  8. A herbicidal or plant growth regulating agent, characterized in that it contains one or more compounds of formula (I) or their salts in accordance with one of the preceding claims 1 to 6, as well as standard aids in the field of plant protection for making preparations.  9. A method of controlling weeds or regulating the growth of plants, characterized in that an effective amount of one or more compounds of formula (I) or their salts according to one of claims 1 to 6 is applied to plants, plant seeds or a sown area.  10. The use of compounds of formula (I) or their salts according to one of paragraphs.1 - 6 as herbicides and regulating plant growth.