RU95105445A - Pyrimidine compounds, method of their synthesis, pesticide composition, method of struggle against pests - Google Patents

Pyrimidine compounds, method of their synthesis, pesticide composition, method of struggle against pests

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Publication number
RU95105445A
RU95105445A RU95105445/04A RU95105445A RU95105445A RU 95105445 A RU95105445 A RU 95105445A RU 95105445/04 A RU95105445/04 A RU 95105445/04A RU 95105445 A RU95105445 A RU 95105445A RU 95105445 A RU95105445 A RU 95105445A
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RU
Russia
Prior art keywords
hydrogen
alkyl
halogen
alkoxy
synthesis
Prior art date
Application number
RU95105445/04A
Other languages
Russian (ru)
Inventor
Манро Дейвид
Gb]
Дейвис Ройстон
Энн Дэй Джанет
Энн Уилкин Жаклин
Уэйкфилд Вуд Уильям
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL)
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL), Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL)
Publication of RU95105445A publication Critical patent/RU95105445A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/48—Two nitrogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/52—Two oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/58—Two sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/60—Three or more oxygen or sulfur atoms

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Veterinary Medicine (AREA)
  • Agronomy & Crop Science (AREA)
  • Medicinal Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Public Health (AREA)
  • General Chemical & Material Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

FIELD: organic chemistry, heterocyclic compounds. SUBSTANCE: product: pyrimidine compounds of the formula (I) where Xand Xeach means oxygen; S(O), at n = 0, 1 or 2; or CO, CHor NR where R means hydrogen or alkyl; Rand Reach means hydrogen or halogen; Rand Reach means hydrogen, cyano, nitro, alkyl, haloidalkyl, alkoxy, alkylthio, amino, mono- or dialkylamino, alkoxyalkyl, halogenhydroxyalkyl or alkoxycarbonyl; Rand Reach means hydrogen, chlorine, alkyl, haloidalkyl, haloidalkenyl, haloidalkynyl, haloidalkoxy, haloidalkoxycarbonyl, haloidalkylthio, haloidalkoxyalkyl, haloidalkylsulfinyl or haloidalkylsulfonyl, nitro or cyano-group; Rand Reach means hydrogen, halogen, alkyl or alkoxy; Rmeans hydrogen, halogen, cyano, alkyl, haloidalkyl, alkoxy, alkylthio, alkylsulfinyl or phenyl; and Rmeans hydrogen or when Rmeans hydrogen, alkyl; at condition that each phenyl is unsubstituted or at least one of Rand Ris not hydrogen. Synthesized compounds show pesticide activity and method of its synthesis. EFFECT: improved method of synthesis.

Claims (1)

Пиримидиновые соединения формулы (1) в которой X1 и X2 каждый представляют кислород; S(O)n, при n = 0,1 или 2; или СО, CH2 или NR, при R являющимся водородом или алкилом, R1 и R10 каждый является водородом или галогеном, R2 и R9 каждый является водородом, галогеном, циано, нитро, алкилом, галоалкилом, алкокси, алкилтио, амино, моно- или ди-алкиламино, алкоксиалкилом, галоалкоксиалкилом или алкоксикарбонилом, R3 и R8 каждый представляет водород, хлор, алкил, галоалкил, галоалкенил, галоалкинил, галоалкокси, галоалкоксикарбонил, галоалкилтио, галоалкоксиалкил, галоалкилсульфинил или галоалкилсульфонил, нитро или циано; R4 и R7 каждый представляет водород, галоген, алкил или алкокси; R5 представляет водород, галоген, циано, алкил, галоалкил, алкокси, алкилтио, алкилсульфинил или финил; и R6 является водородом или, когда R5 представляет водород, алкилом; при условии, что либо каждый фенил является незамещенным либо по крайней мере один из R3 и R8 не является водородом, обладающие полезной пестицидной активностью, а также способ его получения.Pyrimidine compounds of formula (1) in which X 1 and X 2 each represent oxygen; S (O) n , for n = 0.1 or 2; or CO, CH 2 or NR, with R being hydrogen or alkyl, R 1 and R 10 are each hydrogen or halogen, R 2 and R 9 are each hydrogen, halogen, cyano, nitro, alkyl, haloalkyl, alkoxy, alkylthio, amino mono- or di-alkylamino, alkoxyalkyl, haloalkoxyalkyl or alkoxycarbonyl, R 3 and R 8 each represents hydrogen, chloro, alkyl, haloalkyl, haloalkenyl, haloalkynyl, haloalkoxy, haloalkoxycarbonyl, haloalkylthio, haloalkoxyalkyl, haloalkyl-alkaloalkyl, haloalkyl-alkaloalkyl; R 4 and R 7 each represents hydrogen, halogen, alkyl or alkoxy; R 5 represents hydrogen, halogen, cyano, alkyl, haloalkyl, alkoxy, alkylthio, alkylsulfinyl or vinyl; and R 6 is hydrogen or, when R 5 is hydrogen, alkyl; with the proviso that either each phenyl is unsubstituted or at least one of R 3 and R 8 is not hydrogen, possessing useful pesticidal activity, as well as a method for its preparation.
RU95105445/04A 1992-07-17 1993-07-15 Pyrimidine compounds, method of their synthesis, pesticide composition, method of struggle against pests RU95105445A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP92306600.5 1992-07-17
EP92306600 1992-07-17

Publications (1)

Publication Number Publication Date
RU95105445A true RU95105445A (en) 1996-10-27

Family

ID=8211436

Family Applications (1)

Application Number Title Priority Date Filing Date
RU95105445/04A RU95105445A (en) 1992-07-17 1993-07-15 Pyrimidine compounds, method of their synthesis, pesticide composition, method of struggle against pests

Country Status (27)

Country Link
US (1) US5707995A (en)
EP (1) EP0650482B1 (en)
JP (1) JP3353895B2 (en)
KR (1) KR950702541A (en)
CN (1) CN1087085A (en)
AT (1) ATE206404T1 (en)
AU (1) AU671845B2 (en)
CA (1) CA2140346A1 (en)
CZ (1) CZ282275B6 (en)
DE (1) DE69330882T2 (en)
DK (1) DK0650482T3 (en)
EG (1) EG20267A (en)
ES (1) ES2164666T3 (en)
GE (1) GEP19981224B (en)
HU (1) HUT70086A (en)
IL (1) IL106324A (en)
MD (1) MD1154F2 (en)
OA (1) OA10124A (en)
PL (6) PL173467B1 (en)
PT (1) PT650482E (en)
RU (1) RU95105445A (en)
SG (1) SG49712A1 (en)
SK (1) SK279516B6 (en)
TR (1) TR26781A (en)
TW (1) TW234077B (en)
WO (1) WO1994002470A1 (en)
ZA (1) ZA935155B (en)

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CN109721548B (en) * 2017-10-31 2020-11-13 南通泰禾化工股份有限公司 Preparation method of azoxystrobin
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Also Published As

Publication number Publication date
SG49712A1 (en) 1998-06-15
IL106324A (en) 1998-09-24
ZA935155B (en) 1994-06-20
PL173717B1 (en) 1998-04-30
OA10124A (en) 1996-12-18
ATE206404T1 (en) 2001-10-15
PL307131A1 (en) 1995-05-02
ES2164666T3 (en) 2002-03-01
WO1994002470A1 (en) 1994-02-03
TW234077B (en) 1994-11-11
PL173066B1 (en) 1998-01-30
PL173091B1 (en) 1998-01-30
PL173467B1 (en) 1998-03-31
DE69330882T2 (en) 2002-04-11
JPH07508999A (en) 1995-10-05
HUT70086A (en) 1995-09-28
PL173021B1 (en) 1998-01-30
CZ282275B6 (en) 1997-06-11
AU4570093A (en) 1994-02-14
US5707995A (en) 1998-01-13
CN1087085A (en) 1994-05-25
AU671845B2 (en) 1996-09-12
EP0650482A1 (en) 1995-05-03
IL106324A0 (en) 1993-11-15
PT650482E (en) 2002-03-28
SK279516B6 (en) 1998-12-02
DE69330882D1 (en) 2001-11-08
DK0650482T3 (en) 2001-12-03
KR950702541A (en) 1995-07-29
GEP19981224B (en) 1998-02-11
EP0650482B1 (en) 2001-10-04
MD950235A (en) 1997-10-31
CZ3095A3 (en) 1995-09-13
JP3353895B2 (en) 2002-12-03
SK3295A3 (en) 1995-05-10
EG20267A (en) 1998-05-31
CA2140346A1 (en) 1994-02-03
PL173056B1 (en) 1998-01-30
TR26781A (en) 1995-05-15
MD1154F2 (en) 1999-02-28

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