RU97121232A - COMPOSITION FOR OXIDATION DYE OF KERATIN FIBERS AND COLOR METHOD USING THIS COMPOSITION - Google Patents
COMPOSITION FOR OXIDATION DYE OF KERATIN FIBERS AND COLOR METHOD USING THIS COMPOSITIONInfo
- Publication number
- RU97121232A RU97121232A RU97121232/14A RU97121232A RU97121232A RU 97121232 A RU97121232 A RU 97121232A RU 97121232/14 A RU97121232/14 A RU 97121232/14A RU 97121232 A RU97121232 A RU 97121232A RU 97121232 A RU97121232 A RU 97121232A
- Authority
- RU
- Russia
- Prior art keywords
- phenylenediamine
- para
- bis
- composition
- radical
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 35
- 102000011782 Keratins Human genes 0.000 title claims 7
- 108010076876 Keratins Proteins 0.000 title claims 7
- 239000000835 fiber Substances 0.000 title claims 7
- 230000003647 oxidation Effects 0.000 title 1
- 238000007254 oxidation reaction Methods 0.000 title 1
- 238000004043 dyeing Methods 0.000 claims 15
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims 14
- 239000002253 acid Substances 0.000 claims 13
- 150000003839 salts Chemical class 0.000 claims 13
- 239000011780 sodium chloride Substances 0.000 claims 13
- CBCKQZAAMUWICA-UHFFFAOYSA-N P-Phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims 9
- 239000000654 additive Substances 0.000 claims 8
- 230000000996 additive Effects 0.000 claims 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 8
- 125000000217 alkyl group Chemical group 0.000 claims 7
- 150000001875 compounds Chemical class 0.000 claims 7
- 125000005263 alkylenediamine group Chemical group 0.000 claims 6
- WZCQRUWWHSTZEM-UHFFFAOYSA-N M-Phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 claims 5
- 125000002091 cationic group Chemical group 0.000 claims 5
- -1 hydroxyethyl para-phenylenediamine Chemical compound 0.000 claims 5
- 239000007800 oxidant agent Substances 0.000 claims 4
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-Dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 claims 3
- 239000000975 dye Substances 0.000 claims 3
- 125000005843 halogen group Chemical group 0.000 claims 3
- 230000001590 oxidative Effects 0.000 claims 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- 239000000982 direct dye Substances 0.000 claims 2
- 229910052731 fluorine Inorganic materials 0.000 claims 2
- 239000011737 fluorine Substances 0.000 claims 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
- 229910052740 iodine Inorganic materials 0.000 claims 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 2
- 239000011630 iodine Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- NKNCGBHPGCHYCQ-UHFFFAOYSA-N (2,5-diaminophenyl)methanol Chemical compound NC1=CC=C(N)C(CO)=C1 NKNCGBHPGCHYCQ-UHFFFAOYSA-N 0.000 claims 1
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims 1
- CBWPAXKVACVBLU-UHFFFAOYSA-N 1,3-bis[4-amino-N-(2-hydroxyethyl)anilino]propan-1-ol Chemical compound C1=CC(N)=CC=C1N(CCO)CCC(O)N(CCO)C1=CC=C(N)C=C1 CBWPAXKVACVBLU-UHFFFAOYSA-N 0.000 claims 1
- ZOYYUUSGWBEYDY-UHFFFAOYSA-N 1-(4-aminoanilino)butan-2-ol Chemical compound CCC(O)CNC1=CC=C(N)C=C1 ZOYYUUSGWBEYDY-UHFFFAOYSA-N 0.000 claims 1
- KQGOJGSMIRVVJL-UHFFFAOYSA-N 1-N-methyl-4-N-[4-[4-(methylamino)anilino]butyl]benzene-1,4-diamine Chemical compound C1=CC(NC)=CC=C1NCCCCNC1=CC=C(NC)C=C1 KQGOJGSMIRVVJL-UHFFFAOYSA-N 0.000 claims 1
- GZVVXXLYQIFVCA-UHFFFAOYSA-N 2,3-dimethylbenzene-1,4-diamine Chemical compound CC1=C(C)C(N)=CC=C1N GZVVXXLYQIFVCA-UHFFFAOYSA-N 0.000 claims 1
- BWAPJIHJXDYDPW-UHFFFAOYSA-N 2,5-dimethyl-p-phenylenediamine Chemical compound CC1=CC(N)=C(C)C=C1N BWAPJIHJXDYDPW-UHFFFAOYSA-N 0.000 claims 1
- KEEQZNSCYCPKOJ-UHFFFAOYSA-N 2,6-diethylbenzene-1,4-diamine Chemical compound CCC1=CC(N)=CC(CC)=C1N KEEQZNSCYCPKOJ-UHFFFAOYSA-N 0.000 claims 1
- MJAVQHPPPBDYAN-UHFFFAOYSA-N 2,6-dimethylbenzene-1,4-diamine Chemical compound CC1=CC(N)=CC(C)=C1N MJAVQHPPPBDYAN-UHFFFAOYSA-N 0.000 claims 1
- ZFFAFXDAFACVBX-UHFFFAOYSA-N 2-(2,4-diamino-5-methylphenoxy)ethanol Chemical compound CC1=CC(OCCO)=C(N)C=C1N ZFFAFXDAFACVBX-UHFFFAOYSA-N 0.000 claims 1
- WCPGNFONICRLCL-UHFFFAOYSA-N 2-(2,4-diaminophenoxy)ethanol Chemical compound NC1=CC=C(OCCO)C(N)=C1 WCPGNFONICRLCL-UHFFFAOYSA-N 0.000 claims 1
- KULOFVMDAJSPOK-UHFFFAOYSA-N 2-(2,5-diaminophenoxy)ethanol Chemical compound NC1=CC=C(N)C(OCCO)=C1 KULOFVMDAJSPOK-UHFFFAOYSA-N 0.000 claims 1
- HJXIRCMNJLIHQR-UHFFFAOYSA-N 2-N,2-N-dimethylbenzene-1,2-diamine Chemical compound CN(C)C1=CC=CC=C1N HJXIRCMNJLIHQR-UHFFFAOYSA-N 0.000 claims 1
- QSQJPVOCPBBFNL-UHFFFAOYSA-N 2-[2-amino-4-(methylamino)phenoxy]ethanol Chemical compound CNC1=CC=C(OCCO)C(N)=C1 QSQJPVOCPBBFNL-UHFFFAOYSA-N 0.000 claims 1
- BGRBURMLBAACID-UHFFFAOYSA-N 2-[4-amino-3-chloro-N-(2-hydroxyethyl)anilino]ethanol Chemical compound NC1=CC=C(N(CCO)CCO)C=C1Cl BGRBURMLBAACID-UHFFFAOYSA-N 0.000 claims 1
- KBHHZOYDILVUBF-UHFFFAOYSA-N 2-[4-amino-N-(2-hydroxyethyl)-3-methylanilino]ethanol Chemical compound CC1=CC(N(CCO)CCO)=CC=C1N KBHHZOYDILVUBF-UHFFFAOYSA-N 0.000 claims 1
- ISCYHXYLVTWDJT-UHFFFAOYSA-N 2-[4-amino-N-(2-hydroxyethyl)anilino]ethanol Chemical compound NC1=CC=C(N(CCO)CCO)C=C1 ISCYHXYLVTWDJT-UHFFFAOYSA-N 0.000 claims 1
- FLCAOAGLACNSPB-UHFFFAOYSA-N 2-[4-amino-N-[2-[4-amino-N-(2-hydroxyethyl)anilino]ethyl]anilino]ethanol Chemical compound C1=CC(N)=CC=C1N(CCO)CCN(CCO)C1=CC=C(N)C=C1 FLCAOAGLACNSPB-UHFFFAOYSA-N 0.000 claims 1
- MGLZGLAFFOMWPB-UHFFFAOYSA-N 2-chloro-1,4-phenylenediamine Chemical compound NC1=CC=C(N)C(Cl)=C1 MGLZGLAFFOMWPB-UHFFFAOYSA-N 0.000 claims 1
- FXFTWEVIIHVHDS-UHFFFAOYSA-N 2-fluorobenzene-1,4-diamine Chemical compound NC1=CC=C(N)C(F)=C1 FXFTWEVIIHVHDS-UHFFFAOYSA-N 0.000 claims 1
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 claims 1
- WNYJRJRHKRZXEO-UHFFFAOYSA-N 2-propan-2-ylbenzene-1,4-diamine Chemical compound CC(C)C1=CC(N)=CC=C1N WNYJRJRHKRZXEO-UHFFFAOYSA-N 0.000 claims 1
- JKZGDHJHXRRQKD-UHFFFAOYSA-N 3-(2,4-diaminophenoxy)propane-1,2-diol Chemical compound NC1=CC=C(OCC(O)CO)C(N)=C1 JKZGDHJHXRRQKD-UHFFFAOYSA-N 0.000 claims 1
- BNRMHEDSMWOIMC-UHFFFAOYSA-N 4-(2-aminoethoxy)benzene-1,3-diamine Chemical compound NCCOC1=CC=C(N)C=C1N BNRMHEDSMWOIMC-UHFFFAOYSA-N 0.000 claims 1
- POKISONDDBRXBK-UHFFFAOYSA-N 4-N,4-N,2-trimethylbenzene-1,4-diamine Chemical compound CN(C)C1=CC=C(N)C(C)=C1 POKISONDDBRXBK-UHFFFAOYSA-N 0.000 claims 1
- XBTWVJKPQPQTDW-UHFFFAOYSA-N 4-N,4-N-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(C)=C1 XBTWVJKPQPQTDW-UHFFFAOYSA-N 0.000 claims 1
- QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-N,4-N-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 claims 1
- UOWYGPTYSRURDP-UHFFFAOYSA-N 4-N,4-N-dipropylbenzene-1,4-diamine Chemical compound CCCN(CCC)C1=CC=C(N)C=C1 UOWYGPTYSRURDP-UHFFFAOYSA-N 0.000 claims 1
- ZWUNNXOYHZGABC-UHFFFAOYSA-N 4-N-(4-aminobutyl)benzene-1,4-diamine Chemical compound NCCCCNC1=CC=C(N)C=C1 ZWUNNXOYHZGABC-UHFFFAOYSA-N 0.000 claims 1
- OAQDBKQAJRFJIY-UHFFFAOYSA-N 4-N-[2-(4-amino-N-ethyl-3-methylanilino)ethyl]-4-N-ethyl-2-methylbenzene-1,4-diamine Chemical compound C=1C=C(N)C(C)=CC=1N(CC)CCN(CC)C1=CC=C(N)C(C)=C1 OAQDBKQAJRFJIY-UHFFFAOYSA-N 0.000 claims 1
- BGGGDHXHMQFBGA-UHFFFAOYSA-N 4-[(2,4-diaminophenoxy)methoxy]benzene-1,3-diamine Chemical compound NC1=CC(N)=CC=C1OCOC1=CC=C(N)C=C1N BGGGDHXHMQFBGA-UHFFFAOYSA-N 0.000 claims 1
- MWKPYVXITDAZLL-UHFFFAOYSA-N 4-[3-(2,4-diaminophenoxy)propoxy]benzene-1,3-diamine Chemical compound NC1=CC(N)=CC=C1OCCCOC1=CC=C(N)C=C1N MWKPYVXITDAZLL-UHFFFAOYSA-N 0.000 claims 1
- AYAKPRUPZTWPLK-UHFFFAOYSA-N 4-ethoxy-6-methylbenzene-1,3-diamine Chemical compound CCOC1=CC(C)=C(N)C=C1N AYAKPRUPZTWPLK-UHFFFAOYSA-N 0.000 claims 1
- NQHVJMJEWQQXBS-UHFFFAOYSA-N 4-ethoxybenzene-1,3-diamine Chemical compound CCOC1=CC=C(N)C=C1N NQHVJMJEWQQXBS-UHFFFAOYSA-N 0.000 claims 1
- WERSDZKEJFOKJJ-UHFFFAOYSA-N 4-methoxy-5-methylbenzene-1,3-diamine Chemical compound COC1=C(C)C=C(N)C=C1N WERSDZKEJFOKJJ-UHFFFAOYSA-N 0.000 claims 1
- PSPYAOSEFGPDOA-UHFFFAOYSA-N 5-ethyl-4-methoxybenzene-1,3-diamine Chemical compound CCC1=CC(N)=CC(N)=C1OC PSPYAOSEFGPDOA-UHFFFAOYSA-N 0.000 claims 1
- MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophene Chemical compound OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 claims 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N Hydrogen peroxide - urea Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 125000005055 alkyl alkoxy group Chemical group 0.000 claims 1
- 150000001412 amines Chemical group 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- 125000002431 aminoalkoxy group Chemical group 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000004432 carbon atoms Chemical group C* 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 150000003840 hydrochlorides Chemical class 0.000 claims 1
- CPELXLSAUQHCOX-UHFFFAOYSA-N hydrogen bromide Chemical class Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims 1
- 125000005113 hydroxyalkoxy group Chemical group 0.000 claims 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl radical Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 claims 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
- 150000003892 tartrate salts Chemical class 0.000 claims 1
- 0 Cc1c(CS)cc(**)[s]1 Chemical compound Cc1c(CS)cc(**)[s]1 0.000 description 2
Claims (21)
где R1 представляет собой атом водорода или С1-С4 алкил-радикал;
R2 представляет собой атом водорода или алкил-радикал, который может быть замещен -CN - радикалом или аминогруппой, 4'-аминофенильный радикал или образует с R1 или атомом углерода бензольного кольца, несущего радикалы R3 и R4 необязательно оксигенированный и/или азотистый гетероцикл, который может быть замещен C1-C4 алкил-радикалом;
R3 и R4 которые могут быть одинаковыми или различными, представляют собой атом водорода, атом галогена, такой как бром, хлор, иод или фтор, C1-C4 алкил, C1-C4 алкоксирадикал или -CN радикал;
Х- представляет собой анион, предпочтительно выбираемый из хлорида, метилсульфата и ацетата,
В представляет собой группу, выбираемую из структур B1-B11
где R5 представляет собой C1-C4 алкил-радикал, R6 и R7, которые могут быть одинаковыми или различными, представляют собой атом водорода или C1-C4 алкил-радикал; когда R1 и R2 образуют азотистый гетероцикл или когда R3 и R4 представляют собой C1-C4 алкил-радикал или C1-C4 алкокси-радикал или когда R2 представляет собой 4'-аминофенильный радикал, тогда В может также представлять группу структуры B12
где R5 имеет такие же значения, какие определены выше для структур В1-В11; и по крайней мере один окислитель.1. Composition for oxidative dyeing of keratin fibers, in particular, human keratin fibers, for example, hair, ready for use, characterized in that in an environment suitable for dyeing, it includes the following ingredients: at least one oxidation base selected from a pair -phenylenediamine and bis (phenyl) alkylenediamine and their acid additive salts, at least one paint-forming component, selected from meta-phenylenediamine and their acid additive salts, at least one direct cationic dye b, selected from compounds of formula I
where R 1 represents a hydrogen atom or a C 1 -C 4 alkyl radical;
R 2 represents a hydrogen atom or an alkyl radical which may be substituted with a -CN - radical or amino group, a 4'-aminophenyl radical or forms with a R 1 or a carbon atom of the benzene ring bearing the radicals R 3 and R 4 optionally oxygenated and / or a nitrogenous heterocycle that may be substituted by a C 1 -C 4 alkyl radical;
R 3 and R 4 which may be the same or different, represent a hydrogen atom, a halogen atom such as bromine, chlorine, iodine or fluorine, C 1 -C 4 alkyl, C 1 -C 4 alkoxy radical or -CN radical;
X - is an anion, preferably selected from chloride, methyl sulfate and acetate,
B is a group selected from structures B1-B11
where R 5 represents a C 1 -C 4 alkyl radical, R 6 and R 7 , which may be the same or different, represent a hydrogen atom or a C 1 -C 4 alkyl radical; when R 1 and R 2 form a nitrogenous heterocycle, or when R 3 and R 4 are a C 1 -C 4 alkyl radical or a C 1 -C 4 alkoxy radical, or when R 2 is a 4'-aminophenyl radical, then B may also represent group structure B12
where R 5 has the same meanings as defined above for structures B1-B11; and at least one oxidizing agent.
где R8 представляет собой атом водорода, C1-C4 алкил-, C1-C4 моногидроксиалкил-, C2-C4 полигидроксиалкил-, фенил-, 4'-аминофенил- или (C1-C4)алкокси(C1-C4)алкил-радикал;
R9 представляет собой атом водорода или C1-C4 алкил-, C1-C4 моногидроксиалкил- или C2-C4 полигидроксиалкил-радикал;
R10представляет собой атом водорода, атом галогена, такой как хлор, бром, иод или фтор, C1-C4 алкил-, C1-C4 моногидроксиалкил-, C1-C4 гидроксиалкокси-, C1-C4 мезиламиноалкокси-, C1-C4 карбамоиламиноалкокси- или C1-C4 ацетиламиноалкокси-радикал;
R11 представляет собой атом водорода или C1-C4 алкил-радикал.2. The composition according to p. 1, characterized in that the para-phenylenediamine selected from compounds of formula II and their acid additive salts
where R 8 represents a hydrogen atom, C 1 -C 4 alkyl-, C 1 -C 4 monohydroxyalkyl-, C 2 -C 4 polyhydroxyalkyl, phenyl, 4'-aminophenyl- or (C 1 -C 4 ) alkoxy ( A C 1 -C 4 ) alkyl radical;
R 9 represents a hydrogen atom or a C 1 -C 4 alkyl, C 1 -C 4 monohydroxyalkyl or C 2 -C 4 polyhydroxyalkyl radical;
R 10 represents a hydrogen atom, a halogen atom, such as chlorine, bromine, iodine or fluorine, C 1 -C 4 alkyl-, C 1 -C 4 monohydroxyalkyl, C 1 -C 4 hydroxyalkoxy, C 1 -C 4 mesylaminoalkoxy -, C 1 -C 4 carbamoylaminoalkoxy- or C 1 -C 4 acetylaminoalkoxy-radical;
R 11 represents a hydrogen atom or a C 1 -C 4 alkyl radical.
где Z1 и Z2 которые могут быть одинаковые или различные, представляют собой гидроксильный радикал или группу NHR15, где R15 представляет атом водорода или C1-C4 алкил-радикал;
R12 представляет атом водорода или C1-C4 алкил-, C1-C4 моногидроксиалкил- или C2-C4 полигидроксиалкил-радикал или C1-C4 аминоалкил-радикал, где аминный остаток может быть замещен;
R13 и R14, которые могут быть одинаковые или различные, представляют собой атом водорода или галогена или C1-C4 алкил-радикал,
Y представляет собой радикал, взятый из группы, состоящей из следующих радикалов -(СН2)n ; - (СН2)m - О - (СН2)m; - (СН2)m - СНОН - (CН2)m; и
где n - целое число от 0 до 8 включительно и m - целое число от 0 до 4 включительно.4. The composition according to p. 1, characterized in that the bis (phenyl) alkylenediamines are selected from compounds of the formula III and their acid additive salts
where Z 1 and Z 2 which may be the same or different, represent a hydroxyl radical or a group NHR 15 , where R 15 represents a hydrogen atom or a C 1 -C 4 alkyl radical;
R 12 represents a hydrogen atom or a C 1 -C 4 alkyl, C 1 -C 4 monohydroxyalkyl or C 2 -C 4 polyhydroxyalkyl radical or a C 1 -C 4 aminoalkyl radical, where the amine residue may be substituted;
R 13 and R 14 , which may be the same or different, represent a hydrogen or halogen atom or a C 1 -C 4 alkyl radical,
Y represents a radical taken from the group consisting of the following radicals - (CH 2 ) n ; - (CH 2 ) m - O - (CH 2 ) m ; - (CH 2 ) m - CHOH - (CH 2 ) m ; and
where n is an integer from 0 to 8 inclusive and m is an integer from 0 to 4 inclusive.
где R16 представляет атом водорода или C1-C4 алкил-, C1-C4 моногидроксиалкил- или C2-C4 полигидроксиалкил-радикал;
R17 и R18, которые могут быть одинаковые или различные, представляют собой атом водорода или C1-C4 алкил-, C1-C4 моногидроксиалкил- или C2-C4 полигидроксиалкил-радикал;
R19 представляет собой атом водорода, C1-C4 алкилкокси-, C1-C4 аминоалкокси-, C1-C4 моногидроксиалкокси- или C2-C4 полигидроксиалкокси- или 2,4-диаминофеноксиалкокси-радикал.6. Composition according to any one of the preceding paragraphs, characterized in that the meta-phenylenediamines are selected from compounds of the formula IV and their acid addition salts:
where R 16 represents a hydrogen atom or a C 1 -C 4 alkyl, C 1 -C 4 monohydroxyalkyl or C 2 -C 4 polyhydroxyalkyl radical;
R 17 and R 18 , which may be the same or different, represent a hydrogen atom or a C 1 -C 4 alkyl, C 1 -C 4 monohydroxyalkyl or C 2 -C 4 polyhydroxyalkyl radical;
R 19 represents a hydrogen atom, a C 1 -C 4 alkyl alkoxy, C 1 -C 4 aminoalkoxy, C 1 -C 4 monohydroxyalkoxy or C 2 -C 4 polyhydroxyalkoxy or 2,4-diaminophenoxy alkoxy radical.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9615894A FR2757387B1 (en) | 1996-12-23 | 1996-12-23 | KERATINIC FIBER OXIDATION DYE COMPOSITION AND DYEING METHOD USING THE SAME |
FR9615894 | 1996-12-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
RU97121232A true RU97121232A (en) | 1999-08-27 |
RU2177305C2 RU2177305C2 (en) | 2001-12-27 |
Family
ID=9499037
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU97121232/14A RU2177305C2 (en) | 1996-12-23 | 1997-12-22 | Composition for oxidizing coloring of keratin fibers and coloring method with application of said composition |
Country Status (21)
Country | Link |
---|---|
US (1) | US5879412A (en) |
EP (1) | EP0852135B2 (en) |
JP (1) | JP2954122B2 (en) |
KR (1) | KR100260452B1 (en) |
CN (1) | CN1119987C (en) |
AR (1) | AR010701A1 (en) |
AT (1) | ATE179325T1 (en) |
AU (1) | AU694083B1 (en) |
BR (1) | BR9706312A (en) |
CA (1) | CA2223722C (en) |
CZ (1) | CZ291830B6 (en) |
DE (1) | DE69700200T2 (en) |
DK (1) | DK0852135T3 (en) |
ES (1) | ES2134056T5 (en) |
FR (1) | FR2757387B1 (en) |
GR (1) | GR3030246T3 (en) |
HU (1) | HU220160B (en) |
MX (1) | MX199537B (en) |
PL (1) | PL188879B1 (en) |
RU (1) | RU2177305C2 (en) |
ZA (1) | ZA9711308B (en) |
Families Citing this family (45)
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FR2769213B1 (en) * | 1997-10-03 | 1999-12-17 | Oreal | KERATIN FIBER DYEING COMPOSITION AND DYEING METHOD USING THE SAME |
PT999823E (en) * | 1997-10-22 | 2004-11-30 | Oreal | THERMAL FIBER TISSUE COMPOSITION AND DYEING PROCESS USING THIS COMPOSITION |
FR2776923B1 (en) | 1998-04-06 | 2003-01-10 | Oreal | DYE COMPOSITION FOR KERATINIC FIBERS WITH CATIONIC DIRECT DYE AND SUBSTANTIVE POLYMER |
FR2778845B1 (en) * | 1998-05-25 | 2001-05-04 | Oreal | DYE COMPOSITION FOR KERATINIC FIBERS WITH CATIONIC DIRECT DYE AND SUBSTANTIVE POLYMER |
FR2779054B1 (en) * | 1998-05-26 | 2001-06-29 | Oreal | KERATINIC FIBER OXIDATION DYE COMPOSITION AND DYEING METHOD USING THE SAME |
FR2779056B1 (en) * | 1998-05-28 | 2001-09-07 | Oreal | DYE COMPOSITION FOR KERATINIC FIBERS WITH CATIONIC DIRECT DYE AND POLYOL OR POLYOL ETHER |
FR2779055B1 (en) * | 1998-05-28 | 2001-05-04 | Oreal | DIRECT DYE COMPOSITION FOR KERATINIC FIBERS WITH CATIONIC DIRECT DYE AND POLYOL AND / OR POLYOL ETHER |
FR2780880B1 (en) * | 1998-07-09 | 2001-08-10 | Oreal | DYE COMPOSITION FOR KERATINIC FIBERS WITH CATIONIC DIRECT DYE AND THICKENER POLYMER |
FR2780881B1 (en) * | 1998-07-09 | 2001-08-10 | Oreal | DYE COMPOSITION FOR KERATINIC FIBERS WITH CATIONIC DIRECT DYE AND THICKENER POLYMER |
FR2780883B1 (en) * | 1998-07-09 | 2001-04-06 | Oreal | DYE COMPOSITION FOR KERATINIC FIBERS WITH CATIONIC DIRECT DYE AND THICKENER POLYMER |
FR2788432B1 (en) | 1999-01-19 | 2003-04-04 | Oreal | USE FOR THE DIRECT DYEING OF KERATINIC FIBERS FROM A COMBINATION OF TWO CATIONIC DYES |
HUP0204268A2 (en) | 2000-01-19 | 2003-04-28 | Artec Systems Group, Inc. | One-step bleach and coloring composition for hair and method of using same |
US6547834B1 (en) | 2000-03-17 | 2003-04-15 | Kao Corporation | Hair dye composition |
JP2001261535A (en) | 2000-03-17 | 2001-09-26 | Kao Corp | Hair dyeing agent composition |
JP4150484B2 (en) | 2000-03-17 | 2008-09-17 | 花王株式会社 | Hair dye composition |
JP2001288054A (en) * | 2000-04-07 | 2001-10-16 | Kao Corp | Hair dye |
JP4150485B2 (en) | 2000-04-07 | 2008-09-17 | 花王株式会社 | Hair dye composition |
JP4150488B2 (en) | 2000-04-07 | 2008-09-17 | 花王株式会社 | Hair dye composition |
FR2807650B1 (en) * | 2000-04-18 | 2002-05-24 | Oreal | KERATIN FIBER OXIDATION DYE COMPOSITION COMPRISING 1- (4-AMINOPHENYL) -PYRROLIDINE AND A PARTICULAR DIRECT DYE |
JP2002012533A (en) * | 2000-06-27 | 2002-01-15 | Kao Corp | Hair dye composition |
JP4139552B2 (en) * | 2000-06-27 | 2008-08-27 | 花王株式会社 | Hair dye composition |
JP2002012526A (en) * | 2000-06-27 | 2002-01-15 | Kao Corp | Hair dye composition |
JP4150489B2 (en) * | 2000-06-27 | 2008-09-17 | 花王株式会社 | Hair dye composition |
JP4150487B2 (en) | 2000-06-27 | 2008-09-17 | 花王株式会社 | Hair dye composition |
DE10045856A1 (en) * | 2000-09-14 | 2002-03-28 | Henkel Kgaa | Colorant for keratin fibers, useful for coloring fur, wool, feathers and especially human hair, contains benzo(b)furan-3-one or benzo(b)thiophen-3-one derivative(s) and reactive carbonyl or methine-active compound(s) |
ES2269481T3 (en) * | 2000-10-12 | 2007-04-01 | Ciba Specialty Chemicals Holding Inc. | METHOD FOR STAINING FIBERS CONTAINING KERATIN. |
FR2817466B1 (en) * | 2000-12-04 | 2004-12-24 | Oreal | OXIDATION DYE COMPOSITION FOR KERATINIC FIBERS COMPRISING AN ASSOCIATIVE POLYMER AND A NACRANT AGENT |
FR2817467B1 (en) * | 2000-12-04 | 2003-01-10 | Oreal | DYE COMPOSITION FOR KERATINIC FIBERS COMPRISING AN ASSOCIATIVE POLYMER AND A POLYMER WITH ACRYLAMIDE PATTERNS, DIALKYLDIALLYLAMMONIUM HALIDE AND VINYL CARBOXYLIC ACID |
BR0207949A (en) * | 2001-03-08 | 2004-07-27 | Ciba Sc Holding Ag | Porous Material Staining Method |
FR2822695B1 (en) | 2001-04-02 | 2003-07-25 | Oreal | NOVEL TINCTIRIAL COMPOSITION FOR DYEING KERATINIC FIBERS COMPRISING A PARTICULAR CATIONIC AZO DYE |
FR2822697B1 (en) * | 2001-04-02 | 2003-07-25 | Oreal | NEW DYE COMPOSITION FOR DYEING KERATIN FIBERS COMPRISING A PARTICULAR CATIONIC AZO DYE |
FR2822693B1 (en) * | 2001-04-02 | 2003-06-27 | Oreal | NOVEL TINCTORIAL COMPOSITION FOR DYEING KERATINIC FIBERS COMPRISING A PARTICULAR CATIONIC AZO DYE |
FR2822694B1 (en) * | 2001-04-02 | 2005-02-04 | Oreal | NOVEL TINCTORIAL COMPOSITION FOR DYEING KERATIN FIBERS COMPRISING A PARTICULAR CATIONIC AZOIC COLORANT |
FR2822698B1 (en) * | 2001-04-03 | 2006-04-21 | Oreal | NEW DYE COMPOSITION FOR DYEING KERATIN FIBERS COMPRISING A DICATIONIC MONOAZO DYE |
FR2833837B1 (en) * | 2001-12-21 | 2005-08-05 | Oreal | COMPOSITION FOR KERATIN FIBER OXIDATION DYE COMPRISING COLZA OXYETHYLENE FATTY ACID AMIDE |
EP1352632A1 (en) * | 2002-04-08 | 2003-10-15 | Kao Corporation | Hair dye composition |
EP1352631A1 (en) * | 2002-04-08 | 2003-10-15 | Kao Corporation | Hair dye composition |
US20030233713A1 (en) * | 2002-04-11 | 2003-12-25 | Quinn Francis Xavier | Kit for dyeing keratin fibers |
DE10229420A1 (en) * | 2002-06-29 | 2004-01-29 | Henkel Kgaa | Process for the gentle oxidative coloring of hair |
DE10260834A1 (en) * | 2002-12-23 | 2004-07-01 | Henkel Kgaa | New coupler components |
BRPI0417719A (en) * | 2003-12-19 | 2007-04-03 | Ciba Sc Holding Ag | method of coloring with buffered diazotized compound and coupling component |
FR2879922B1 (en) * | 2004-12-23 | 2007-03-02 | Oreal | NOVEL METHOD FOR WASHING COLORED KERATINOUS FIBERS WITH A COMPOSITION COMPRISING A PARTICULAR NON-IONIC SURFACTANT AND USE FOR PROTECTING COLOR |
EP1780764A1 (en) | 2005-11-01 | 2007-05-02 | FEI Company | Stage assembly, particle-optical apparatus comprising such a stage assembly, and method of treating a sample in such an apparatus |
DE102010042696A1 (en) * | 2010-10-20 | 2012-04-26 | Henkel Ag & Co. Kgaa | Dicationic 4-aza-1-azoniabicyclo [2.2.2] octanes and agents for coloring keratinous fibers |
IT201900008040A1 (en) | 2019-06-04 | 2020-12-04 | Pool Service S R L | Composition in gel for oxidation coloring hair and other keratin fibers, and related coloring method |
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LU53050A1 (en) * | 1967-02-22 | 1968-08-27 | ||
US3524842A (en) * | 1967-08-04 | 1970-08-18 | Durand & Huguenin Ag | Water-soluble cationic phenylazo-naphthol dyestuffs containing a quaternary ammonium group |
US3985499A (en) * | 1971-06-04 | 1976-10-12 | L'oreal | Diazamerocyanines for dyeing keratinous fibers |
CA1021324A (en) * | 1971-06-04 | 1977-11-22 | Gerard Lang | Tinctorial compositions for keratinic fibres and new diaza-merocyanines entering these compositions |
LU71015A1 (en) * | 1974-09-27 | 1976-08-19 | ||
FR2421607A1 (en) * | 1978-04-06 | 1979-11-02 | Oreal | TWO-STAGE KERATINIC FIBER DYING PROCESS BY PH VARIATION |
FR2586913B1 (en) * | 1985-09-10 | 1990-08-03 | Oreal | PROCESS FOR FORMING IN SITU A COMPOSITION CONSISTING OF TWO SEPARATELY PACKED PARTS AND DISPENSING ASSEMBLY FOR THE IMPLEMENTATION OF THIS PROCESS |
LU86903A1 (en) * | 1987-05-29 | 1989-01-19 | Oreal | USE AS A COUPLER OF 2,4-DIAMINO-1,3-DIMETHOXYBENZENE OR ONE OF ITS SALTS, IN ASSOCIATION WITH OXIDATION DYE PRECURSORS, FOR DYEING HUMAN HAIR, HAIR DYE COMPOSITION CONTAINING SAID COUPLER AND METHOD FOR PREPARING THE COUPLER |
TW311089B (en) † | 1993-07-05 | 1997-07-21 | Ciba Sc Holding Ag | |
TW325998B (en) * | 1993-11-30 | 1998-02-01 | Ciba Sc Holding Ag | Dyeing keratin-containing fibers |
DE59510884D1 (en) † | 1994-11-03 | 2004-04-29 | Ciba Sc Holding Ag | Cationic imidazole azo dyes |
DE19515903C2 (en) * | 1995-04-29 | 1998-04-16 | Wella Ag | Means and methods for oxidative coloring of hair |
DE69728038T2 (en) † | 1996-04-25 | 2005-02-17 | L'oreal | Process for dyeing keratin fibers with dye precursors of oxidation dyes and powdered direct dyes |
-
1996
- 1996-12-23 FR FR9615894A patent/FR2757387B1/en not_active Expired - Fee Related
-
1997
- 1997-11-27 ES ES97402864T patent/ES2134056T5/en not_active Expired - Lifetime
- 1997-11-27 AT AT97402864T patent/ATE179325T1/en not_active IP Right Cessation
- 1997-11-27 DE DE69700200T patent/DE69700200T2/en not_active Expired - Lifetime
- 1997-11-27 EP EP97402864A patent/EP0852135B2/en not_active Expired - Lifetime
- 1997-11-27 DK DK97402864T patent/DK0852135T3/en active
- 1997-12-09 AU AU47630/97A patent/AU694083B1/en not_active Ceased
- 1997-12-16 MX MX9710190A patent/MX199537B/en unknown
- 1997-12-17 ZA ZA9711308A patent/ZA9711308B/en unknown
- 1997-12-17 CZ CZ19974078A patent/CZ291830B6/en not_active IP Right Cessation
- 1997-12-19 US US08/994,446 patent/US5879412A/en not_active Expired - Lifetime
- 1997-12-22 JP JP9353835A patent/JP2954122B2/en not_active Expired - Fee Related
- 1997-12-22 CA CA002223722A patent/CA2223722C/en not_active Expired - Fee Related
- 1997-12-22 KR KR1019970071966A patent/KR100260452B1/en not_active IP Right Cessation
- 1997-12-22 HU HU9702529A patent/HU220160B/en not_active IP Right Cessation
- 1997-12-22 RU RU97121232/14A patent/RU2177305C2/en not_active IP Right Cessation
- 1997-12-22 AR ARP970106103A patent/AR010701A1/en unknown
- 1997-12-22 CN CN97120860A patent/CN1119987C/en not_active Expired - Fee Related
- 1997-12-22 PL PL97323985A patent/PL188879B1/en not_active IP Right Cessation
- 1997-12-22 BR BR9706312A patent/BR9706312A/en not_active Application Discontinuation
-
1999
- 1999-05-19 GR GR990401339T patent/GR3030246T3/en unknown
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