RU97119736A - NANO-EMULSION BASED ON AMPHIPHIL NON-ION AND CATION LIPIDS AND ITS APPLICATION - Google Patents

NANO-EMULSION BASED ON AMPHIPHIL NON-ION AND CATION LIPIDS AND ITS APPLICATION

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Publication number
RU97119736A
RU97119736A RU97119736/04A RU97119736A RU97119736A RU 97119736 A RU97119736 A RU 97119736A RU 97119736/04 A RU97119736/04 A RU 97119736/04A RU 97119736 A RU97119736 A RU 97119736A RU 97119736 A RU97119736 A RU 97119736A
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RU
Russia
Prior art keywords
paragraphs
emulsion according
amphiphilic
emulsion
carbon atoms
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RU97119736/04A
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Russian (ru)
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RU2141813C1 (en
Inventor
Рестль Серж
Кове-Мартэн Даниель
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Л'Ореаль
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Priority claimed from FR9613978A external-priority patent/FR2755853A1/en
Priority claimed from FR9703281A external-priority patent/FR2755854B1/en
Application filed by Л'Ореаль filed Critical Л'Ореаль
Publication of RU97119736A publication Critical patent/RU97119736A/en
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Publication of RU2141813C1 publication Critical patent/RU2141813C1/en

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Claims (13)

1. Эмульсия масло-в-воде, глобулы масла в которой имеют средний размер менее 150 нм, включающая амфифильную липидную фазу, отличающаяся тем, что вышеуказанная амфифильная липидная фаза содержит по крайней мере один амфифильный неионный липид, жидкий при температуре ниже 45oС, и по крайней мере один амфифильный катионный липид, массовое соотношение в которой масла к амфифильной липидной фазе составляет 2-10 и предпочтительно 3-6.1. Emulsion oil-in-water, globules of oil in which have an average size of less than 150 nm, including the amphiphilic lipid phase, characterized in that the above amphiphilic lipid phase contains at least one amphiphilic non-ionic lipid, liquid at a temperature below 45 o C, and at least one amphiphilic cationic lipid, the mass ratio in which the oil to the amphiphilic lipid phase is 2-10 and preferably 3-6. 2. Эмульсия по п. 1, отличающаяся тем, что амфифильный неионный липид выбирают из силиконовых поверхностно-активных веществ и сложных эфиров по крайней мере одного полиола, выбираемого из группы, состоящей из полиэтиленгликоля, включающего 1-60 этиленоксидных звеньев, сорбитана, глицерина, включающего 2-30 этиленоксидных звеньев, или полиглицеринов, включающих 2-15 глицериновых звеньев, и по крайней мере одной жирной кислоты, содержащей по крайней мере одну насыщенную или ненасыщенную, линейную или разветвленную алкильную цепь с 8-22 атомами углерода, и их смесей. 2. Emulsion under item 1, characterized in that the amphiphilic non-ionic lipid is chosen from silicone surfactants and esters of at least one polyol selected from the group consisting of polyethylene glycol, including 1-60 ethylene oxide units, sorbitan, glycerin, comprising 2-30 ethylene oxide units, or polyglycerols, including 2-15 glycerol units, and at least one fatty acid containing at least one saturated or unsaturated, linear or branched alkyl chain with 8-22 carbon atoms kind, and mixtures thereof. 3. Эмульсия по любому из пп. 1 или 2, отличающаяся тем, что амфифильный катионный липид выбирают из группы, состоящей из четвертичных аммониевых солей и жирных аминов. 3. Emulsion according to any one of paragraphs. 1 or 2, characterized in that the amphiphilic cationic lipid is selected from the group consisting of quaternary ammonium salts and fatty amines. 4. Эмульсия по п. 3, отличающаяся тем, что четвертичные аммониевые соли выбирают из группы, состоящей из: четвертичных аммониевых солей следующей общей формулы (IV):
Figure 00000001

в которой радикалы R1 oCR4, которые могут быть одинаковыми или разными, означают линейный или разветвленный алифатический радикал с 1-30 атомами углерода или ароматический радикал, такой, как арил или алкиларил; Х означает анион, выбираемый из группы, состоящей из галогенидов, фосфатов, ацетатов, лактатов, (C2-C6)-алкилсульфатов, алкил(или алкиларил-) сульфонатов; четвертичных аммониевых солей имидазолиния: четвертичных диаммониевых солей формулы (VI):
Figure 00000002

в которой R9 означает алифатический радикал примерно с 16-30 атомами углерода; R10, R11, R12, R13 и R14 выбирают среди водорода или алкильного радикала с 1-4 атомами углерода; и Х означает анион, выбираемый в группе, состоящей из галогенидов, ацетатов, фосфатов, нитратов и метилсульфатов; четвертичных аммониевых солей, содержащих по крайней мере одну сложноэфирную функцию.4. Emulsion according to claim. 3, characterized in that the quaternary ammonium salts are selected from the group consisting of: the quaternary ammonium salts of the following general formula (IV):
Figure 00000001

in which the radicals R 1 o CR 4, which may be identical or different, represent a linear or branched aliphatic radical having 1-30 carbon atoms or an aromatic radical such as aryl or alkylaryl; X means an anion selected from the group consisting of halides, phosphates, acetates, lactates, (C 2 -C 6 ) alkyl sulfates, alkyl (or alkylaryl) sulfonates; Quaternary ammonium salts of imidazolinium: Quaternary diammonium salts of the formula (VI):
Figure 00000002

in which R 9 means an aliphatic radical with about 16-30 carbon atoms; R 10 , R 11 , R 12 , R 13 and R 14 are selected from hydrogen or an alkyl radical with 1-4 carbon atoms; and X is an anion selected from the group consisting of halides, acetates, phosphates, nitrates and methyl sulfates; Quaternary ammonium salts containing at least one ester function. 5. Эмульсия по любому из пп. 1-4, отличающаяся тем, что амфифильный катионный липид находится в концентрациях от 1 до 60% масс., в расчете на общую массу амфифильной липидной фазы, и предпочтительно 10-50 мас.%. 5. Emulsion according to any one of paragraphs. 1-4, characterized in that the amphiphilic cationic lipid is in concentrations from 1 to 60 wt.%, Calculated on the total weight of the amphiphilic lipid phase, and preferably 10-50 wt.%. 6. Эмульсия по любому из пп. 1-5, отличающаяся тем, что она включает количество масла 5-40 мас.%, в расчете на общую массу эмульсии. 6. Emulsion according to any one of paragraphs. 1-5, characterized in that it includes the amount of oil 5-40 wt.%, Calculated on the total weight of the emulsion. 7. Эмульсия по любому из пп. 1-6, отличающаяся тем, что масло выбирают из группы, состоящей из: животных или растительных масел, образованных сложными эфирами жирных кислот и полиолов, или альтернативно растительных или животных масел формулы R9COOR10, в которой R9 означает остаток высшей жирной кислоты с 7-29 атомами углерода, a R10 означает линейную или разветвленную углеводородную цепь с 3-30 атомами углерода; природных или синтетических эфирных масел; углеводородов; галогенуглеродных соединений; эфиров неорганической кислоты и спирта; простых эфиров и простых полиэфиров; силиконов в смеси по крайней мере с одним из вышеуказанных масел.7. Emulsion according to any one of paragraphs. 1-6, characterized in that the oil is chosen from the group consisting of: animal or vegetable oils formed by esters of fatty acids and polyols, or alternatively vegetable or animal oils of the formula R 9 COOR 10 , in which R 9 means the residue of higher fatty acid with 7-29 carbon atoms, a R 10 means a linear or branched hydrocarbon chain with 3-30 carbon atoms; natural or synthetic essential oils; hydrocarbons; halogen-carbon compounds; inorganic acid esters and alcohol; ethers and polyethers; silicones in a mixture with at least one of the above oils. 8. Эмульсия по любому из пп. 1-7, отличающаяся тем, что она содержит водорастворимое или жирорастворимое косметически или дерматологически активное вещество. 8. Emulsion according to any one of paragraphs. 1-7, characterized in that it contains a water-soluble or liposoluble cosmetically or dermatologically active substance. 9. Композиция для наружного применения, отличающаяся тем, что она образована эмульсией или включает эмульсию по любому из пп. 1-8. 9. Composition for external use, characterized in that it is formed by an emulsion or includes an emulsion according to any one of paragraphs. 1-8. 10. Эмульсия по любому из пп. 1-9, отличающаяся тем, что ее используют в качестве или в продуктах по уходу, и/или для мытья, и/или макияжа, и/или удаления макияжа, для тела и/или лица, и/или слизистых оболочек, и/или волосяного покрова, и/или волос, и/или ногтей, и/или ресниц, и/или бровей. 10. Emulsion according to any one of paragraphs. 1-9, characterized in that it is used in quality or in care products, and / or for washing, and / or makeup, and / or removal of makeup, for the body and / or face, and / or mucous membranes, and / or hairline and / or hair and / or nails and / or eyelashes and / or eyebrows. 11. Способ нетерапевтической обработки кожи, волос, слизистых оболочек, ногтей, ресниц, бровей и/или волосяного покрова, отличающийся тем, что на кожу, волосы, слизистые оболочки, ногти, ресницы, брови или волосяной покров наносят эмульсию по любому из пп. 1-9. 11. The method of non-therapeutic treatment of skin, hair, mucous membranes, nails, eyelashes, eyebrows and / or hair, characterized in that the skin, hair, mucous membranes, nails, eyelashes, eyebrows or hair coat emulsion according to any one of paragraphs. 1-9. 12. Способ получения эмульсии по любому из пп. 1-9, отличающийся тем, что водную фазу смешивают с масляной фазой при интенсивном перемешивании и при температуре менее 45oС, затем осуществляют гомогенизацию высокого давления при давлении выше 108 Па.12. The method of obtaining the emulsion according to any one of paragraphs. 1-9, characterized in that the aqueous phase is mixed with the oil phase with vigorous stirring and at a temperature of less than 45 o With, then carry out the homogenization of high pressure at a pressure above 10 8 Pas. 13. Способ по п. 12, отличающийся тем, что давление изменяется в пределах от 12•107 до 18•107 Па.13. The method according to p. 12, characterized in that the pressure varies from 12 • 10 7 to 18 • 10 7 PA.
RU97119736A 1996-11-15 1997-11-14 Oil-in-water emulsion for preparing cosmetic preparations, cosmetic and dermatologic compositions containing thereof, method of preparing emulsion and method of using it RU2141813C1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR9613978A FR2755853A1 (en) 1996-11-15 1996-11-15 Oil:in:water emulsions comprise nonionic and cationic amphiphilic lipids
FR9613978 1996-11-15
FR9703281 1997-03-18
FR9703281A FR2755854B1 (en) 1996-11-15 1997-03-18 NANOEMULSION BASED ON NON-IONIC AND CATIONIC AMPHIPHILIC LIPIDS AND USES

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RU97119736A true RU97119736A (en) 1999-08-10
RU2141813C1 RU2141813C1 (en) 1999-11-27

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US (1) US6039936A (en)
EP (1) EP0842652B1 (en)
JP (1) JP3317886B2 (en)
KR (1) KR100263213B1 (en)
CN (1) CN1091587C (en)
AR (1) AR009417A1 (en)
AT (1) ATE219918T1 (en)
AU (1) AU691148B1 (en)
BR (1) BR9705382A (en)
CA (1) CA2217339C (en)
DE (1) DE69713711T2 (en)
DK (1) DK0842652T3 (en)
ES (1) ES2180008T3 (en)
FR (1) FR2755854B1 (en)
HU (1) HUP9702032A1 (en)
PL (1) PL187493B1 (en)
PT (1) PT842652E (en)
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