RU96109038A - COATINGS FOR METAL SURFACES CHEMICALLY INTERACTING WITH A SUBSTRATE - Google Patents

COATINGS FOR METAL SURFACES CHEMICALLY INTERACTING WITH A SUBSTRATE

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Publication number
RU96109038A
RU96109038A RU96109038/02A RU96109038A RU96109038A RU 96109038 A RU96109038 A RU 96109038A RU 96109038/02 A RU96109038/02 A RU 96109038/02A RU 96109038 A RU96109038 A RU 96109038A RU 96109038 A RU96109038 A RU 96109038A
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RU
Russia
Prior art keywords
ppm
coating composition
ions
composition according
present
Prior art date
Application number
RU96109038/02A
Other languages
Russian (ru)
Other versions
RU2107746C1 (en
Inventor
Е.Томлинсон Чарльз
Original Assignee
Секл-Проско, Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/137,583 external-priority patent/US5380374A/en
Application filed by Секл-Проско, Инк. filed Critical Секл-Проско, Инк.
Application granted granted Critical
Publication of RU2107746C1 publication Critical patent/RU2107746C1/en
Publication of RU96109038A publication Critical patent/RU96109038A/en

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Claims (27)

1. Водная композиция для покрытия сплавов алюминия, железа или магния, включающая: (a) от приблизительно 10 ppm до приблизительно 5000 ppm (из расчета на водную композицию) растворенных ионов металла IV группы, выбранного из группы, включающей титан, цирконий и гафний; (b) от приблизительно 80 ppm до приблизительно 1300 ppm (из расчета на водную композицию) ионов металла II группы, выбранного из группы, включающей магний и кальций; (с) от приблизительно 10 ppm до приблизительно 6000 ppm (из расчета на водную композицию) растворенных ионов фтора; (d) воду; причем значение рН указанной композиции заключается в интервале от приблизительно 2,0 до приблизительно 5,0.1. An aqueous composition for coating aluminum, iron or magnesium alloys, comprising: (a) from about 10 ppm to about 5000 ppm (based on the aqueous composition) of dissolved Group IV metal ions selected from the group consisting of titanium, zirconium and hafnium; (b) from about 80 ppm to about 1300 ppm (based on the aqueous composition) of Group II metal ions selected from the group consisting of magnesium and calcium; (c) from about 10 ppm to about 6000 ppm (based on the aqueous composition) of dissolved fluorine ions; (d) water; moreover, the pH value of the specified composition is in the range from about 2.0 to about 5.0. 2. Водная композиция по п.1, в которой металлом IV группы является цирконий. 2. The aqueous composition according to claim 1, in which the metal of group IV is zirconium. 3. Водная композиция по п.1, в которой металлом II группы является кальций. 3. The aqueous composition according to claim 1, in which the metal of group II is calcium. 4. Композиция покрытия по п.3, в которой указанные ионы кальция присутствуют в количестве от приблизительно 100 ppm до приблизительно 500 ppm (из расчета на водную композицию). 4. The coating composition according to claim 3, in which these calcium ions are present in an amount of from about 100 ppm to about 500 ppm (based on the aqueous composition). 5. Композиция покрытия по п.3, в которой указанные ионы кальция присутствуют в количестве от приблизительно 150 ppm до приблизительно 250 ppm (из расчета на водную композицию). 5. The coating composition according to claim 3, in which these calcium ions are present in an amount of from about 150 ppm to about 250 ppm (based on the aqueous composition). 6. Композиция покрытия по п.3, в которой указанные ионы циркония присутствуют в количестве от приблизительно 200 ppm до приблизительно 1000 ppm (из расчета на водную композицию). 6. The coating composition according to claim 3, in which these zirconium ions are present in an amount of from about 200 ppm to about 1000 ppm (based on the aqueous composition). 7. Композиция покрытия по п.3, в которой указанные ионы циркония присутствуют в количестве от приблизительно 200 ppm до приблизительно 400 ppm (из расчета на водную композицию). 7. The coating composition according to claim 3, in which these zirconium ions are present in an amount of from about 200 ppm to about 400 ppm (based on the aqueous composition). 8. Композиция покрытия по п.3, включающая также источник триполифосфатных ионов. 8. The coating composition according to claim 3, including also a source of tripolyphosphate ions. 9. Композиция покрытия по п.8, в которой указанным источником триполифосфатных ионов является триполифосфат натрия. 9. The coating composition of claim 8, in which the indicated source of tripolyphosphate ions is sodium tripolyphosphate. 10. Композиция покрытия по п.9, в которой указанные триполифосфатные ионы присутствуют в количестве от приблизительно 60 ppm до приблизительно 4400 ppm. 10. The coating composition of claim 9, wherein said tripolyphosphate ions are present in an amount of from about 60 ppm to about 4400 ppm. 11. Композиция покрытия по п.10, в которой указанные триполифосфатные ионы присутствуют в количестве от приблизительно 150 ppm до приблизительно 200 ppm. 11. The coating composition of claim 10, wherein said tripolyphosphate ions are present in an amount of from about 150 ppm to about 200 ppm. 12. Композиция покрытия по п.3, включающая также по меньшей мере приблизительно 10 ppm дубильной кислоты или растительного танина. 12. The coating composition according to claim 3, also comprising at least about 10 ppm of tannic acid or vegetable tannin. 13. Композиция покрытия по п.12, в которой указанная дубильная кислота или растительный танин присутствует в количестве от приблизительно 50 ppm до приблизительно 200 ppm. 13. The coating composition of claim 12, wherein said tannic acid or vegetable tannin is present in an amount of from about 50 ppm to about 200 ppm. 14. Композиция покрытия по п.3, включающая также изолирующий агент в количестве, эффективном для связывания по существу всех растворенных ионов железа, присутствующих в композиции. 14. The coating composition according to claim 3, including also an insulating agent in an amount effective to bind essentially all of the dissolved iron ions present in the composition. 15. Композиция покрытия по п.3, включающая также источник бора. 15. The coating composition according to claim 3, including also a source of boron. 16. Композиция покрытия по п.15, в которой указанный бор присутствует в количестве от приблизительно 10 ppm до приблизительно 200 ppm. 16. The coating composition of claim 15, wherein said boron is present in an amount of from about 10 ppm to about 200 ppm. 17. Композиция покрытия по п.16, в которой указанный бор присутствует в количестве от приблизительно 500 ppm до приблизительно 100 ppm. 17. The coating composition of claim 16, wherein said boron is present in an amount of from about 500 ppm to about 100 ppm. 18. Композиция покрытия по п.3, включающая также фосфатную соль в количестве, эффективном для обеспечения концентрации фосфата от приблизительно 10 ppm до приблизительно 600 ppm. 18. The coating composition according to claim 3, also comprising a phosphate salt in an amount effective to provide a phosphate concentration of from about 10 ppm to about 600 ppm. 19. Композиция покрытия по п. 18, в которой указанная фосфатная соль присутствует в количестве, эффективном для обеспечения концентрации фосфата от приблизительно 150 ppm до приблизительно 300 ppm. 19. The coating composition of claim 18, wherein said phosphate salt is present in an amount effective to provide a phosphate concentration of from about 150 ppm to about 300 ppm. 20. Композиция покрытия по п.3, содержащая также ионы цинка в концентрации от приблизительно 10 ppm до приблизительно 100 ppm. 20. The coating composition according to claim 3, also containing zinc ions in a concentration of from about 10 ppm to about 100 ppm. 21. Композиция покрытия по п.20, в которой указанные ионы цинка присутствуют в концентрации от приблизительно 20 ppm до приблизительно 30 ppm. 21. The coating composition of claim 20, wherein said zinc ions are present in a concentration of from about 20 ppm to about 30 ppm. 22. Композиция покрытия по п.3, значение рН которой заключается в пределах примерно 2,6 - 3,1. 22. The coating composition according to claim 3, the pH of which is in the range of about 2.6 to 3.1. 23. Композиция покрытия по п.3, включающая также агент кристаллической деформации. 23. The coating composition according to claim 3, including also a crystalline deformation agent. 24. Композиция покрытия по п.23, в которой указанным агентом кристаллической деформации является нитрилотрис (метилен) трифосфоновая кислота (АТМР). 24. The coating composition of claim 23, wherein said crystalline deformation agent is nitrilotris (methylene) triphosphonic acid (ATMMP). 25. Композиция покрытия по п.3, включающая также растворенные ионы алюминия в концентрации от приблизительно 10 до приблизительно 3000 ppm. 25. The coating composition according to claim 3, including also dissolved aluminum ions in a concentration of from about 10 to about 3000 ppm. 26. Композиция покрытия по п. 25, в которой указанный алюминий присутствует в концентрации от приблизительно 100 до приблизительно 600 ppm. 26. The coating composition of claim 25, wherein said aluminum is present in a concentration of from about 100 to about 600 ppm. 27. Способ обработки металла, включающий применение к металлу водной композиции покрытия, включающей (а) от приблизительно 10 ppm до приблизительно 5000 ppm (из расчета на водную композицию) растворенных ионов металла, выбранного из группы, состоящей из титана, циркония и гафния; (b) от приблизительно 80 ppm до приблизительно 1300 ppm (из расчета на водную композицию) растворенных ионов металла, выбранного из группы, состоящей из магния и кальция; (c) от приблизительно 10 ppm до приблизительно 6000 ppm (из расчета на водную композицию) растворенных ионов фтора; (d) воду; причем значение рН указанной композиции заключается в интервале от приблизительно 2,0 до приблизительно 5,0. 27. A metal processing method, comprising applying to a metal an aqueous coating composition comprising (a) from about 10 ppm to about 5000 ppm (based on the aqueous composition) of dissolved metal ions selected from the group consisting of titanium, zirconium and hafnium; (b) from about 80 ppm to about 1300 ppm (based on the aqueous composition) of dissolved metal ions selected from the group consisting of magnesium and calcium; (c) from about 10 ppm to about 6000 ppm (based on the aqueous composition) of dissolved fluorine ions; (d) water; moreover, the pH value of the specified composition is in the range from about 2.0 to about 5.0.
RU96109038A 1993-10-15 1994-10-14 Coatings for metal surfaces chemically interacting with base RU2107746C1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/137.583 1993-10-15
US08/137,583 1993-10-15
US08/137,583 US5380374A (en) 1993-10-15 1993-10-15 Conversion coatings for metal surfaces
PCT/US1994/011684 WO1995010641A1 (en) 1993-10-15 1994-10-14 Conversion coatings for metal surfaces

Publications (2)

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RU2107746C1 RU2107746C1 (en) 1998-03-27
RU96109038A true RU96109038A (en) 1998-06-20

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US (1) US5380374A (en)
EP (1) EP0723603A1 (en)
JP (1) JPH09503823A (en)
AU (1) AU7979594A (en)
BR (1) BR9407787A (en)
CA (1) CA2172367A1 (en)
CZ (1) CZ286674B6 (en)
RU (1) RU2107746C1 (en)
WO (1) WO1995010641A1 (en)

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