RU96107895A - CONVENIENT IN OPERATION LIQUID OR GEL WASHING COMPOSITIONS FOR WASHING DISHES CONTAINING PROTEASIS - Google Patents

CONVENIENT IN OPERATION LIQUID OR GEL WASHING COMPOSITIONS FOR WASHING DISHES CONTAINING PROTEASIS

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Publication number
RU96107895A
RU96107895A RU96107895/04A RU96107895A RU96107895A RU 96107895 A RU96107895 A RU 96107895A RU 96107895/04 A RU96107895/04 A RU 96107895/04A RU 96107895 A RU96107895 A RU 96107895A RU 96107895 A RU96107895 A RU 96107895A
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RU
Russia
Prior art keywords
mixtures
group
protease
alkyl
washing
Prior art date
Application number
RU96107895/04A
Other languages
Russian (ru)
Other versions
RU2142981C1 (en
Inventor
Хсянг-Куен Мао Марк
Лейн Маршалл Джанет
Оррико Вискер Марта
Original Assignee
Дзе Проктер Энд Гэмбл Компани
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Дзе Проктер Энд Гэмбл Компани filed Critical Дзе Проктер Энд Гэмбл Компани
Priority claimed from PCT/US1994/009923 external-priority patent/WO1995007971A1/en
Publication of RU96107895A publication Critical patent/RU96107895A/en
Application granted granted Critical
Publication of RU2142981C1 publication Critical patent/RU2142981C1/en

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Claims (6)

1. Удобная в эксплуатации жидкая или гелевая моющая композиция для мытья посуды, включающая, мас.%:
(а) от 5% до 99% моющего поверхностно-активного вещества, выбранного из группы, состоящей из амидов полигидрокси жирной кислоты, неионных жирных алкилполигликозидов, C8-22 алкилсульфатов, C9-15 алкилбензолсульфонатов, C8-22 алкилэфирсульфатов, C8-22 олефинсульфонатов, C8-22 парафинсульфатов, C8-22 алкилглицерилэфирсульфонатов, сульфонатов сложных эфиров жирной кислоты, сульфатов вторичных спиртов, C12-16 алкилэтоксикарбоксилатов, C11-16 вторичных мыл, амфотерных моющих поверхностно-активных веществ, цвиттерионных моющих поверхностно-активных веществ, и их смесей;
(b) от 0,001% до 5% активной протеазы, предпочтительно протеазы, выбранной из группы, состоящей из серинового протеолитического фермента, получаемого из Bacillus, Bacillus subtilis, Bacillus licheniformis и их смесей;
(с) от 1% до 20% усилителя мыльной пены, выбранного из группы, состоящей из бетаинов, конденсатов этиленоксида, амидов жирной кислоты, аминоксид полуполярных неионных соединений, султаннов, сложных бетаинов, катионных поверхностно-активных веществ и их смесей;
причем указанная композиция имеет pH в диапазоне 4 - 11, предпочтительно в диапазоне 6 - 10.
1. Convenient to use liquid or gel washing composition for washing dishes, including, wt.%:
(a) from 5% to 99% detergent surfactant selected from the group consisting of polyhydroxy fatty acid amides, non-ionic fatty alkyl polyglycosides, C 8-22 alkyl sulfates, C 9-15 alkyl benzene sulfonates, C 8-22 alkyl ether sulfates, C 8 -22 olefin sulfonates, C 8-22 parafinsulfatov, C 8-22 alkilglitserilefirsulfonatov sulfonates, fatty acid esters, secondary alcohol sulfates, C 12-16 alkyl ethoxy carboxylates, C 11-16 secondary soaps, amphoteric detergent surfactants, zwitterionic detergent surfactants active substances and mixtures thereof;
(b) 0.001% to 5% active protease, preferably a protease selected from the group consisting of a serine proteolytic enzyme, derived from Bacillus, Bacillus subtilis, Bacillus licheniformis, and mixtures thereof;
(c) from 1% to 20% of a soap suds enhancer selected from the group consisting of betaines, ethylene oxide condensates, fatty acid amides, semi-polar non-ionic aminoxide compounds, sultanns, complex betaines, cationic surfactants, and mixtures thereof;
and this composition has a pH in the range of 4 to 11, preferably in the range of 6 to 10.
2. Композиция по п.1, включающая от 0,003% до 4% активной протеазы, в которой протеазу выбирают из группы, состоящей из MaxacalR, SavinaseR, протеазы A, протеазы B, и их смесей.2. The composition according to claim 1, comprising from 0.003% to 4% of the active protease, in which the protease is selected from the group consisting of Maxacal R , Savinase R , protease A, protease B, and mixtures thereof. 3. Композиция по п. 1 или 4, включающая от 10% до 70% моющего поверхностно-активного вещества, выбранного из группы, состоящей из амидов полигидрокси жирной кислоты, C8-22 алкилсульфатов, C8-22 алкилэфирсульфатов, C12-16 алкилэтоксикарбоксилатов, и C11-16 вторичных мыл.3. The composition according to claim 1 or 4, comprising from 10% to 70% of a washing surfactant selected from the group consisting of polyhydroxy fatty acid amides, C 8-22 alkyl sulfates, C 8-22 alkyl ether sulfates, C 12-16 alkyl ethoxycarboxylates, and C 11-16 secondary soaps. 4. Композиция по любому из предшествующих пунктов, дополнительно включающая от 0,0001% до 10% системы, стабилизирующей фермент. 4. Composition according to any one of the preceding paragraphs, further comprising from 0.0001% to 10% of an enzyme stabilizing system. 5. Композиция по любому из предшествующих пунктов, дополнительно включающая от 0,01% до 4% ионов магния, или кальция, или их смесей, в которой ионы магния или кальция добавляют в виде соли, выбранной из группы, состоящей из гидроксида, оксида, хлорида, формиата, ацетата и их смесей, и систему, стабилизирующую фермент, выбирают из группы, состоящей из иона кальция, борной кислоты, пропиленгликоля, карбоновой кислоты с короткой цепью, бороновой кислоты, полигидроксильных соединений и их смесей. 5. Composition according to any one of the preceding paragraphs, further comprising from 0.01% to 4% of magnesium or calcium ions, or mixtures thereof, in which magnesium or calcium ions are added in the form of a salt selected from the group consisting of hydroxide, oxide, chloride, formate, acetate and their mixtures, and the system stabilizing the enzyme are selected from the group consisting of calcium ion, boric acid, propylene glycol, carboxylic acid with a short chain, boronic acid, polyhydroxy compounds and their mixtures. 6. Удобная в эксплуатации жидкая моющая композиция для мытья посуды, включающая, мас.%:
(а) от 20% до 60% моющего поверхностно-активного вещества, выбранного из группы, состоящей из C8-22 алкилэфирсульфатов, C12 глюкоза амида, C8-12 алкилсульфатов, и их смесей;
(b) от 0,005% до 3% активной протеазы, выбранной из группы, состоящей из протеазы A, протеазы B и их смесей;
(с) от 0,1% до 10% неионного поверхностно-активного вещества, выбранного из группы, состоящей из полиэтилена, полипропилена и полибутиленоксидных конденсатов алкилфенолов, продуктов конденсации алифатических спиртов с от 1 до 25 молями этиленоксида, продуктов конденсации этиленоксида с гидрофобным основанием, образованным конденсацией пропиленоксида с пропиленгликолем, и их смесей;
(d) от 2% до 15% усилителя мыльной пены, выбранного из группы, состоящей из бетаинов, аминоксид полуполярных неионных соединений и их смесей;
(е) от 0,5% до 1% ионов магния или кальция или их смесей, где ионы, добавленные в виде соли, выбраны из группы, состоящей из гидроксида, хлорида, формиата, и их смесей,
причем указанный состав имеет pH в 10%-ном водном растворе при 20oC в диапазоне 6,5 - 9,5.
6. Easy-to-use liquid detergent composition for washing dishes, including, wt.%:
(a) from 20% to 60% detergent surfactant selected from the group consisting of C 8-22 alkyl ether sulfates, C 12 glucose amide, C 8-12 alkyl sulfates, and mixtures thereof;
(b) 0.005% to 3% active protease selected from the group consisting of protease A, protease B, and mixtures thereof;
(c) from 0.1% to 10% of a non-ionic surfactant selected from the group consisting of polyethylene, polypropylene and alkylphenol polybutylene oxide condensates, condensation products of aliphatic alcohols with from 1 to 25 moles of ethylene oxide, condensation products of ethylene oxide with a hydrophobic base formed by condensation of propylene oxide with propylene glycol, and mixtures thereof;
(d) from 2% to 15% of a soap sump enhancer selected from the group consisting of betaines, aminoxide, semi-polar non-ionic compounds, and mixtures thereof;
(e) from 0.5% to 1% of magnesium or calcium ions or mixtures thereof, where the ions added as a salt are selected from the group consisting of hydroxide, chloride, formate, and mixtures thereof,
moreover, the composition has a pH in a 10% aqueous solution at 20 o C in the range of 6.5 to 9.5.
RU96107895A 1993-09-14 1994-08-30 Liquid or gel washing composition suitable in use for washing up and liquid washing composition suitable in use for washing up RU2142981C1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12133193A 1993-09-14 1993-09-14
US08/121,331 1993-09-14
PCT/US1994/009923 WO1995007971A1 (en) 1993-09-14 1994-08-30 Light duty liquid or gel dishwashing detergent compositions containing protease

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RU96107895A true RU96107895A (en) 1998-07-20
RU2142981C1 RU2142981C1 (en) 1999-12-20

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EP (1) EP0719321B2 (en)
JP (1) JP2904930B2 (en)
KR (1) KR100351396B1 (en)
CN (2) CN1162532C (en)
AT (1) ATE178649T1 (en)
AU (1) AU685844B2 (en)
BR (1) BR9407498A (en)
CA (1) CA2170024C (en)
CZ (1) CZ76096A3 (en)
DE (1) DE69417755T3 (en)
DK (1) DK0719321T3 (en)
EG (1) EG21117A (en)
ES (1) ES2131703T5 (en)
FI (1) FI961173A (en)
GR (1) GR3030286T3 (en)
HU (1) HU219172B (en)
NO (1) NO961001L (en)
NZ (1) NZ273214A (en)
PL (1) PL180210B1 (en)
RU (1) RU2142981C1 (en)
SK (1) SK31996A3 (en)
WO (1) WO1995007971A1 (en)

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