RU95121700A - MIXES OF EPOXY RESINS - Google Patents

MIXES OF EPOXY RESINS

Info

Publication number
RU95121700A
RU95121700A RU95121700/04A RU95121700A RU95121700A RU 95121700 A RU95121700 A RU 95121700A RU 95121700/04 A RU95121700/04 A RU 95121700/04A RU 95121700 A RU95121700 A RU 95121700A RU 95121700 A RU95121700 A RU 95121700A
Authority
RU
Russia
Prior art keywords
mixture
epoxy resins
epoxy
paragraphs
phosphorus
Prior art date
Application number
RU95121700/04A
Other languages
Russian (ru)
Other versions
RU2118970C1 (en
Inventor
фон Генцков Вольфганг
Хубер Юрген
Капица Хайнрих
Роглер Вольфган
Клайнер Ханс-Йерг
Вильхельм Дитер
Original Assignee
Сименс АГ
Хехст АГ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE4308187A external-priority patent/DE4308187A1/en
Application filed by Сименс АГ, Хехст АГ filed Critical Сименс АГ
Publication of RU95121700A publication Critical patent/RU95121700A/en
Application granted granted Critical
Publication of RU2118970C1 publication Critical patent/RU2118970C1/en

Links

Claims (10)

1. Смеси эпоксидных смол для изготовления препрегов и комбинированных материалов, отличающиеся тем, что они содержат следующие компоненты: фосфоромодифицированную эпоксидную смолу с эпоксидным показателем от 0,02 до 1 моль/100 г, получаемую реакцией полиэпоксидных соединений с по меньшей мере двумя эпоксидными группами на молекулу и ангидридов фосфиновых кислот и/или ангидридов фосфоновых кислот, и ароматический полиамин в качестве отвердителя следующей структуры:
Figure 00000001

причем в каждой из трех ароматических частичных структурах один из остатков R1 и R2 соответственно означает водород, а другой - алкил.1. Mixtures of epoxy resins for the manufacture of prepregs and composite materials, characterized in that they contain the following components: phosphor-modified epoxy resin with an epoxy index from 0.02 to 1 mol / 100 g obtained by the reaction of polyepoxide compounds with at least two epoxy groups a molecule and anhydrides of phosphinic acids and / or anhydrides of phosphonic acids, and an aromatic polyamine as a hardener of the following structure:
Figure 00000001

moreover, in each of the three aromatic partial structures, one of the residues R 1 and R 2, respectively, is hydrogen and the other is alkyl. 2. Смеси эпоксидных смол по п. 1, отличающиеся тем, что содержание фосфора в фосфоромодифицированной эпоксидной смоле составляет 0,5 - 13,0 мас. %, предпочтительно 1 - 8 мас. %. 2. A mixture of epoxy resins under item 1, characterized in that the phosphorus content in phosphorus-modified epoxy resin is 0.5 - 13.0 wt. %, preferably 1 to 8 wt. % 3. Смеси эпоксидных смол по п. 1 или 2, отличающиеся тем, что они дополнительно содержат свободную от фосфора ароматическую и/или гетероциклическую эпоксидную смолу при необходимости в смеси с циклоалифатической эпоксидной смолой. 3. A mixture of epoxy resins according to claim 1 or 2, characterized in that they additionally contain an aromatic and / or heterocyclic epoxy resin free from phosphorus, if necessary, mixed with cycloaliphatic epoxy resin. 4. Смеси эпоксидных смол по п. 3, отличающиеся тем, что до 80 мас. % фосфоромодифицированной эпоксидной смолы замещены свободной от фосфора эпоксидной смолой. 4. A mixture of epoxy resins under item 3, characterized in that up to 80 wt. % phosphorus modified epoxy resin replaced with phosphorus-free epoxy resin. 5. Смеси эпоксидных смол по одному из пп. 1 - 4, отличающиеся тем, что соотношение эпоксидной и аминоводородной функций составляет 1: 0,5 - 1,1, предпочтительно 1: 0,7 - 0,9. 5. A mixture of epoxy resins in one of paragraphs. 1 to 4, characterized in that the ratio of epoxy and hydrogen-amine functions is 1: 0.5 - 1.1, preferably 1: 0.7 - 0.9. 6. Смеси эпоксидных смол по одному или нескольким пп. 1 - 5, отличающиеся тем, что отвердитель присутствует в смеси с другими ароматическими и/или гетероциклическими полиаминами. 6. A mixture of epoxy resins in one or more paragraphs. 1 to 5, characterized in that the hardener is present in a mixture with other aromatic and / or heterocyclic polyamines. 7. Смеси эпоксидных смол по одному или нескольким пп. 1 - 6, отличающиеся тем, что они содержат ускоритель. 7. A mixture of epoxy resins in one or more paragraphs. 1 - 6, characterized in that they contain an accelerator. 8. Смеси эпоксидных смол по одному или нескольким пп. 1 - 7, отличающиеся тем, что содержание фосфора составляет 0,5 - 6,0 мас. %, предпочтительно 1 - 4 мас. % к смеси смол. 8. A mixture of epoxy resins in one or more paragraphs. 1 to 7, characterized in that the phosphorus content is 0.5 to 6.0 wt. %, preferably 1 to 4 wt. % of the resin mixture. 9. Препреги и комбинированные материалы на основе неорганических или органических армирующих материалов в форме волокон, нетканых материалов или тканей или соответственно плоских материалов, которые изготовлены из смесей эпоксидных смол по одному или нескольким пп. 1 - 8. 9. Prepregs and composite materials based on inorganic or organic reinforcing materials in the form of fibers, nonwoven materials or fabrics or respectively flat materials, which are made of mixtures of epoxy resins according to one or more paragraphs. 18. 10. Печатные платы из препрегов, которые изготовлены из стекловолоконной ткани и смесей эпоксидных смол по одному или нескольким пп. 1 - 8. 10. Printed circuit boards of prepregs, which are made of fiberglass cloth and mixtures of epoxy resins in one or more paragraphs. 18.
RU95121700A 1993-03-15 1994-03-10 Mixture for producing prepregs and combined materials, prepregs and printing array based on thereof RU2118970C1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4308187.8 1993-03-15
DE4308187A DE4308187A1 (en) 1993-03-15 1993-03-15 Epoxy resin mixtures

Publications (2)

Publication Number Publication Date
RU95121700A true RU95121700A (en) 1997-09-27
RU2118970C1 RU2118970C1 (en) 1998-09-20

Family

ID=6482841

Family Applications (1)

Application Number Title Priority Date Filing Date
RU95121700A RU2118970C1 (en) 1993-03-15 1994-03-10 Mixture for producing prepregs and combined materials, prepregs and printing array based on thereof

Country Status (14)

Country Link
US (1) US5587243A (en)
EP (1) EP0689557B1 (en)
JP (1) JPH08507811A (en)
KR (1) KR100304601B1 (en)
CN (1) CN1046950C (en)
AT (1) ATE166660T1 (en)
CA (1) CA2158367A1 (en)
CZ (1) CZ287738B6 (en)
DE (2) DE4308187A1 (en)
FI (1) FI107613B (en)
HU (1) HU214197B (en)
PL (1) PL176640B1 (en)
RU (1) RU2118970C1 (en)
WO (1) WO1994021703A1 (en)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR960701117A (en) * 1993-03-15 1996-02-24 크리스트, 노르드만 Phosphorus-Modified Epoxy Resins, Processes For Making Them And Their Uses (PHOSPHORUS-MODIFIED EPOXY RESINS, PROCESS FOR PRODUCING THEM AND THEIR USE)
DE4427456A1 (en) * 1994-08-03 1996-02-08 Siemens Ag Phosphorus modified epoxy resins, process for their preparation and their use
TW297034B (en) * 1994-09-09 1997-02-01 Siemens Ag
TW294694B (en) * 1994-09-09 1997-01-01 Siemens Ag
TW294693B (en) * 1994-09-09 1997-01-01 Siemens Ag
WO1996023018A1 (en) * 1995-01-26 1996-08-01 Siemens Aktiengesellschaft Reaction resin system with a phosphorus-containing component
DE19608612C2 (en) * 1996-03-06 1998-12-24 Clariant Gmbh Phosphorus-modified coating compositions, a process for their preparation and their use as intumescent coatings
DE19608611A1 (en) * 1996-03-06 1997-09-11 Hoechst Ag Phosphorus-modified coating compositions, a process for their preparation and their use
DE19608613C2 (en) * 1996-03-06 2002-01-17 Celanese Ventures Gmbh Storage stable, phosphor modified epoxy resins
DE19619095A1 (en) 1996-05-06 1997-11-13 Schill & Seilacher Flame retardant epoxy resins and flame retardants for epoxy resins
JP2001503790A (en) 1996-09-26 2001-03-21 シーメンス アクチエンゲゼルシヤフト Epoxy resin mixture
US6353080B1 (en) 1997-06-26 2002-03-05 The Dow Chemical Company Flame retardant epoxy resin composition
DE19917428A1 (en) 1999-04-19 2000-10-26 Clariant Gmbh Flame retardant phosphor modified epoxy resins
JP5485487B2 (en) 1999-12-13 2014-05-07 ダウ グローバル テクノロジーズ エルエルシー Flame retardant phosphorus element-containing epoxy resin composition
US6403220B1 (en) 1999-12-13 2002-06-11 The Dow Chemical Company Phosphorus element-containing crosslinking agents and flame retardant phosphorus element-containing epoxy resin compositions prepared therewith
US6495244B1 (en) * 2000-09-07 2002-12-17 Oak-Mitsui, Inc. Manufacturing fire retardant circuit boards without the use of fire retardant resin additives
US6887950B2 (en) * 2001-02-15 2005-05-03 Pabu Services, Inc. Phosphine oxide hydroxyaryl mixtures with novolac resins for co-curing epoxy resins
US20060099458A1 (en) * 2001-02-15 2006-05-11 Hanson Mark V 1, 4-Hydroquinone functionalized phosphinates and phosphonates
WO2002066485A2 (en) * 2001-02-15 2002-08-29 Pabu Services, Inc. Novel hydroxyaryl phosphine oxides, glycidyl ethers and epoxy compositions, composites and laminates derived therefrom
US20050075024A1 (en) * 2003-10-01 2005-04-07 Ranken Paul F. Flame retardant epoxy prepregs, laminates, and printed wiring boards of enhanced thermal stability
WO2005118604A1 (en) 2004-05-28 2005-12-15 Dow Global Technologies Inc. Phosphorus-containing compounds useful for making halogen-free, ignition-resistant polymers
US20110065838A1 (en) 2009-09-11 2011-03-17 Chemtura Corporation Hydroxyphenyl Phosphine Oxide Mixtures and their use as Flame Retardants for Epoxy Resins
US20110065870A1 (en) 2009-09-11 2011-03-17 Chemtura Corporation Tris(Hydroxoxyphenyl) Phosphine Oxides and their Use as Flame Retardants for Epoxy Resins
WO2012064703A1 (en) 2010-11-12 2012-05-18 Albemarle Corporation Dopo-derived flame retardant and synthetic hydrogarnets for epoxy resin compositions
DE102011077927A1 (en) * 2011-06-21 2012-12-27 Tesa Se Process for the reversible covalent crosslinking of adhesives
CN103382242B (en) 2013-06-25 2015-06-24 江苏雅克科技股份有限公司 Phosphorus-containing flame-retardant phenolic resin and flame-retardant cured epoxy resin prepared with phosphorus-containing flame-retardant phenolic resin as raw material
CN104592467A (en) 2014-08-15 2015-05-06 江苏雅克科技股份有限公司 Phosphorus-containing phenol formaldehyde resin compound and phosphorus-containing fire retardation epoxy resin cured product prepared by adopting phosphorus-containing phenol formaldehyde resin compound as raw material
CN107033343B (en) 2014-11-06 2019-01-08 江苏雅克科技股份有限公司 Phosphorous functionalized poly (arylene ether) and the curable compositions comprising phosphorous functionalized poly (arylene ether)
CN106750226B (en) 2014-11-11 2019-01-08 江苏雅克科技股份有限公司 The preparation method of phosphorous-containing polyester compound composition and phosphorus-containing flame-retardant epoxy resin solidfied material
US9534108B2 (en) 2015-03-13 2017-01-03 Chemtura Corporation Flame retardant epoxy resins comprising phosphorus containing flame retardants
WO2016166226A1 (en) 2015-04-17 2016-10-20 Alzchem Ag Curing agent and curing accelerator with flame-retardent effect for curing epoxy resins
WO2018164833A1 (en) 2017-03-07 2018-09-13 Icl-Ip America Inc. Non-migratory, high-melting/softening polymeric phosphorus-containing flame retardant for printed wiring boards
DE102017204982A1 (en) * 2017-03-24 2018-09-27 Siemens Aktiengesellschaft Fiber composite component
US20220056261A1 (en) * 2019-03-28 2022-02-24 Safran Cabin Inc. Fire retardant epoxy resin
RU2769911C2 (en) * 2019-08-05 2022-04-08 Акционерное общество "ЭНПЦ Эпитал" Polymer composition
EP3926024A1 (en) 2020-06-17 2021-12-22 Clariant International Ltd Phosphorus-containing flame retardant compounds, method for their preparation and their use and epoxy resin formulations containing these flame retardant compounds

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2732367A (en) * 1956-01-24 ruuivj
GB191110794A (en) * 1911-05-04 1912-04-11 John Dugmore Improvements in or relating to Studs, Solitaires, Buttons or the like.
US2766139A (en) * 1955-04-13 1956-10-09 Masonite Corp Method of producing fire resistant lignocellulose hardboard products
US3398019A (en) * 1963-02-21 1968-08-20 Monsanto Co Method for fireproofing cellulosic material
US3373135A (en) * 1964-12-01 1968-03-12 Kalk Chemische Fabrik Gmbh Shaped articles of self-extinguishing epoxy resins
GB1112139A (en) * 1967-01-13 1968-05-01 Shell Int Research Curable polyepoxide compositions for making flame retardant articles
DE2743680C2 (en) * 1977-09-28 1985-04-11 Siemens AG, 1000 Berlin und 8000 München Self-extinguishing composites
GB8610067D0 (en) * 1986-04-24 1986-05-29 Steetley Refractories Ltd Coated magnesium hydroxide
ATE72450T1 (en) * 1986-12-15 1992-02-15 Siemens Nixdorf Inf Syst PROCESS FOR THE MANUFACTURE OF PREPREGS AND THEIR USE.
DE58907953D1 (en) * 1989-03-03 1994-07-28 Siemens Ag Epoxy resin mixtures.
EP0384939B1 (en) * 1989-03-03 1994-06-22 Siemens Aktiengesellschaft Epoxy resin moulding compositions
US4952646A (en) * 1989-07-20 1990-08-28 Akzo America Inc. Epoxy resin compositions containing a polyphosphoric/polyphosphonic anhydride curing agent
DE4340834A1 (en) * 1993-03-15 1994-09-22 Siemens Ag Phosphorus-modified epoxy resins, process for their preparation, and their use

Similar Documents

Publication Publication Date Title
RU95121700A (en) MIXES OF EPOXY RESINS
RU95121641A (en) MIXES OF EPOXY RESINS
KR960701115A (en) EPOXY RESIN MIXTURES
KR960701116A (en) EPOXY RESIN MIXTURES
KR970705594A (en) EPOXY RESIN MIXTURES FOR PREPREGS AND COMPOSITES FOR PREPREG AND COMPOSITE MATERIALS
KR900014508A (en) Epoxy resin mixture
KR101237125B1 (en) Benzoxazine compounds derivated from phenolphtalein having flame-retardant properties and a process for their preparation
KR970705595A (en) EPOXY RESIN MIXTURES FOR PREPREGS AND COMPOSITES FOR PREPREG AND COMPOSITE MATERIALS
KR970070096A (en) Phosphorus modified epoxy resin mixture comprising epoxy resin, phosphorus containing compound and curing agent
CN1157628A (en) Epoxy resin mixtures for prepregs and composites
KR940004013A (en) Reinforced Thermosetting Resin System
US6548627B1 (en) Flame-retardant phosphorus-modified epoxy resins
KR950018260A (en) Composition based on epoxy resin
CA1336935C (en) Epoxy resins comprising an aromatic diamine curing agent
KR970070097A (en) Phosphorus Modified Epoxy Resin Mixture Including Epoxy Resin, Phosphorus-Containing Compound and Curing Agent
JPH0365811B2 (en)
JPH0365812B2 (en)
US5830973A (en) Phosphorus-modified epoxy resins comprising epoxy resins and phosphorus-containing compounds
US5854361A (en) Process for preparing phosphorus-modified epoxy resins
JPH0365813B2 (en)
JPH0625389A (en) Aminophosphazene-type curing agent for epoxy resin
RU99108679A (en) MIXES OF EPOXY RESINS
CA2213275A1 (en) Adduct of bisepoxy compound and p-guanamine
SU642330A1 (en) Prepreg
KR910008067A (en) Epoxy Resin Mixture